Chapter IV: , pp. 21-36. The Herbert-Smith refractometer is there (2)
While it is true that color, unless skillfully estimated and wisely used in conjunction with other properties, is a most unreliable guide, yet when thus used, it becomes a great help and serves sometimes to narrow down the chase, at the start, to a very few species. To thus make use of it requires an actual acquaintance with the various gem materials, in their usual colors and shades and an eye trained to note and to remember minute differences of tint and shade. The suggestions which follow as to usual colors of mineral species must then be used only with discretion and after much faithful study of many specimens of each of the species.
Let us begin with the beginning color of the visible spectrum, red, and consider how a close study of shades of red can help in distinguishing the various red stones from each other. In the first place we will inquire what mineral species are likely to furnish us with red stones. Omitting a number of rare minerals, we have (1) corundum ruby, (2) garnet of various types, (3) zircon, (4) spinel, (5) tourmaline. These five minerals are about the only common species which give us an out-and-out red stone. Let us now consider the distinctions between the reds of these different species. The red of the ruby, whether dark (Siam type), blood red (Burmah type), or pale (Ceylon), is more pleasing usually than the red of any of the other species. Viewed from the back of the stone (by transmitted light) it is still pleasing. It may be purplish, but is seldom orange red. Also, owing to the dichroism of the ruby the red is variable according to the changing position of the stone. It therefore has a certain life and variety not seen in any of the others except perhaps in red tourmaline, which, however, does not approach ruby in fineness of red color.
RED STONES OF SIMILAR SHADES. The garnet, on the other hand, when of fire-red hue, is darker than any but the Siam ruby. It is also more inclined to orange red or brownish red--and the latter is especially true when the stone is seen against the light (by transmitted light). Its color then resembles that of a solution of "iron" such as is given as medicine. The so-called "almandine" garnets (those of purplish-red tint) do not equal the true ruby in brightness of color and when held up to the light show more prismatic colors than the true ruby, owing to the greater dispersion of garnet. The color also lacks variety (owing to lack of dichroism). While a fine garnet may make a fair-looking "ruby" when by itself, it looks inferior and dark when beside a fine ruby. By artificial light, too, the garnet is dark as compared with the true ruby, and the latter shows its color at a distance much more strongly than the garnet.
The red zircon, or true hyacinth, is rare. (Many hessonite garnets are sold as hyacinths in the trade. These are usually of a brownish red.) The red of the hyacinth is never equal to that of the ruby. It is usually more somber, and a bit inclined to a brownish cast. The dispersion of zircon, too, is so large (about 87 per cent. of that of diamond) that some little "color-play" is likely to appear along with the intrinsic color. The luster too is almost adamantine while that of ruby is softer and vitreous. Although strongly doubly refracting, the hyacinth shows scarcely any dichroism and thus lacks variety of color. Hence a trained eye will at once note these differences and not confound the stone with ruby.
Spinels, when red, are almost always more yellowish or more purplish than fine corundum rubies. They are also singly refracting and hence exhibit no dichroism and therefore lack variety of color as compared with true ruby. Some especially fine ones, however, are of a good enough red to deceive even jewelers of experience, and one in particular that I have in mind has been the rounds of the stores and has never been pronounced a spinel, although several "experts" have insisted that it was a scientific ruby. The use of a dichroscope would have saved them that error, for the stone is singly refracting. Spinels are usually clearer and more transparent than garnets and show their color better at a distance or when in a poor light.
Tourmaline of the reddish variety (rubellite) is seldom of a deep red. It is more inclined to be pinkish. The dichroism of tourmaline is stronger than that of ruby and more obvious to the unaided eye. The red of the rubellite should not deceive anyone who has ever seen a fine corundum ruby.
YELLOW STONES
Considering next the stones of yellow color, we have the following species to deal with: (1) diamond, (2) corundum, (3) precious topaz, (4) quartz, (5) beryl, (6) zircon, (7) tourmaline.
YELLOW ZIRCON RESEMBLES YELLOW DIAMOND. Here we have less opportunity to judge of the species by the color than was the case with the red stones. The diamond, of course, is easy to tell, not by the kind of yellow that it displays, for it varies greatly in that respect, but rather by its prismatic play blended with the intrinsic color. Its luster also gives an immediate clue to its identity. It is necessary, however, to be sure that we are not being deceived by a yellow zircon, for the latter has considerable "fire" and a keen luster. Its strong double refraction and its relative softness, as well as its great density will serve to distinguish it. Of the other yellow stones, the true or precious topaz is frequently inclined to a pinkish or wine yellow and many such stones lose all their yellow (retaining their pink) when gently heated. The so-called "pinked" topazes are thus produced.
The yellow corundum rarely has a color that is at all distinctive. As far as color goes the material might be yellow quartz, or yellow beryl, or yellow zircon, or yellow tourmaline (Ceylon type). Many of the yellowish tourmalines have a decidedly greenish cast (greenish-yellow chrysoberyl might resemble these also). However, in general if one has a yellow stone to determine it will be safer to make specific gravity or hardness tests, or both, before deciding, rather than to rely upon color.
LESSON XII
COLOR--_Continued_
GREEN STONES
Let us first consider what mineral species are most likely to give us green stones. Omitting the semi-precious opaque or translucent stones we have:
1. Grass-green beryl (the emerald) which is, of course, first in
value among the green stones and first in the fine quality of its
color.
2. Tourmaline (some specimens of which perhaps more nearly approach
the emerald than any other green stones).
3. The demantoid garnet (sometimes called "olivine" in the trade).
4. True olivine (the peridot and the chrysolite of the trade).
5. Bluish-green beryl (aquamarine).
6. Green sapphire (Oriental emerald or Oriental aquamarine).
7. Chrysoberyl (alexandrite and also the greenish-yellow
chrysoberyl).
1. Considering first the emerald, we have as legitimate a use of color in distinguishing a stone as could be selected, for emerald of fine grass-green color is not equaled by any other precious stone in the rich velvety character of its color. We have to beware here, however, of the fine glass imitations, which, while lacking the variety of true emerald, because of lack of dichroism, are nevertheless of a color so nearly like that of the emerald that no one should attempt to decide by color alone as to whether a stone is genuine or imitation emerald. If a hardness test shows that the material is a genuine hard stone and not a paste, then one who is well accustomed to the color of fine emerald can say at once whether a stone is a fine emerald or some other hard green stone. Where the color is less fine, however, one might well refuse to decide by the color, even when sure that the material is not glass, for some fine tourmalines approach some of the poorer emeralds in richness of color.
THE "SCIENTIFIC EMERALD" FRAUD. No "scientific" emeralds of marketable size have ever been produced as far as can be learned. Many attempts to reproduce emerald by melting beryl or emerald of inferior color have resulted only in the production of a beryl glass, which, while its color might be of desirable shade, was softer and lighter in weight than true emerald. It was also a true glass and hence singly refracting and without dichroism, whereas emerald is crystalline (not glassy or amorphous), is doubly refracting, and shows dichroism.
Do not be misled, then, into buying or selling an imitation of emerald under the terms "synthetic," "scientific," or "reconstructed," as such terms, when so used, are used to deceive one into thinking that the product offered bears the same relation to the true emerald that scientific rubies and sapphires bear to the natural stones. Such is not the case.
About the most dangerous imitation of the emerald that is ever seen in the trade is the triplet that has a top and a back made of true but pale beryl (the same mineral as emerald, but not of the right color) and a thin slice of deep emerald green glass laid between. This slice of glass is usually placed behind the girdle so that a file will not find any point of attack. The specific gravity of the triplet is practically that of emerald, its color is often very good, and it is doubly refracting. It is thus a dangerous imitation. (See Fig. 8.)
EMERALD TRIPLETS. A careful examination of one of these triplets, in the unset condition, with a good lens, will reveal the thin line of junction of the beryl with the glass. (The surface lusters of the two materials are enough different for the trained eye to detect the margin at once.) Such a triplet, if held in the sun, will reflect onto a card two images in pale or white light, one coming from the top surface of the table and the other from the top surface of the glass slice within. In other words, it acts in this respect like a doublet. A true emerald would give only one such reflection, which would come from the top surface of the table.
2. Tourmalines, when green, are usually darker than emeralds and of a more pronounced yellow green, or they may be of too bluish a green, as is the case with some of the finest of the green tourmalines from Maine. Connecticut green tourmaline tends more to the dark yellowish green, and Ceylon tourmaline to the olive green. The stronger dichroism of the tourmaline frequently reveals itself to the naked eye, and there is usually one direction or position in which the color of the stone is very inferior to its color in the opposite direction or position. Most tourmalines (except the very lightest shades) must be cut so that the table of the finished stone lies on the side of the crystal, as, when cut with the table lying across the crystal (perpendicular to the principal optical axis) the stones are much too dark to be pretty. Hence when one turns the cut stone so that he is looking in the direction which was originally up and down the crystal (the direction of single refraction and of no dichroism) he gets a glimpse of a less lovely color than is furnished by the stone in other positions. With a true emerald no such disparity in the color would appear. There might be a slight change of shade (as seen by the naked eye), but no trace of an ugly shade would appear.
By studying many tourmalines and a few emeralds one may acquire an eye for the differences of color that characterize the two stones, but it is still necessary to beware of the fine glass imitation and to use the file and also to look with a high-power glass for any rounding bubbles. The emerald will never have the latter. The glass imitation frequently does have them. The sharp jagged flaws and cracks that so often appear in emerald are likely to appear also in tourmaline as both are brittle materials. The glass imitations frequently have such flaws put into them either by pinching or by striking the material. Frequently, too, wisps of tiny air bubbles are left in the glass imitations in such fashion that unless one scrutinizes them carefully with a good lens they strongly resemble the flaws in natural emerald.
I have thus gone into detail as to how one may distinguish true emerald from tourmaline and from glass imitations because, on account of the high value of fine emerald and its infrequent occurrence, there is perhaps more need for the ability to discriminate between it and its imitations and substitutes than there is in almost any other case. Where values are high the temptation to devise and to sell imitations or substitutes is great and the need for skill in distinguishing between the real and the false is proportionally great.
3. The demantoid garnet (often unfortunately and incorrectly called "olivine" in the trade) is usually of an olive or pistachio shade. It may, however, approach a pale emerald. The refraction being single in this, as in all garnets, there is little variety to the color. The dispersion being very high, however, there is a strong tendency, in spite of the depth of the body color, for this stone to display "fire," that is, rainbow color effects. The luster, too, is diamond-like as the name "demantoid" signifies. With this account of the stone and a few chances to see the real demantoid garnet beside an emerald no one would be likely to mistake one for the other. The demantoid garnet is also very soft as compared with emerald (6-1/2 as against nearly 8).
4. True olivine (the peridot or the chrysolite of the trade) is of a fine leaf-green or bottle-green shade in the peridot. The chrysolite of the jeweler is usually of a yellower green. Frequently an olive-green shade is seen. The luster of olivine (whether of the peridot shade or not) is oily, and this may serve to distinguish it from tourmaline (which it may resemble in color). Its double refraction is very large also, so that the doubling of the edges of the rear facets may easily be seen through the table with a lens. The dichroism is feeble too, whereas that of tourmaline is strong. No one would be likely to confuse the stone with true emerald after studying what has preceded.
5. Bluish-green beryl (aquamarine) is usually of a pale transparent green or blue green (almost a pure pale blue is also found).
Having all the properties of its more valuable variety, emerald, the pale beryl may, by the use of these properties, be distinguished from the pale blue-green topaz which so strongly resembles it in color.
6. Green sapphire seldom even approaches emerald in fineness of color. When it remotely suggests emerald it is called "Oriental" emerald to denote that it is a corundum gem. Most green sapphires are of too blue a green to resemble emerald. Some are really "Oriental" aquamarines. In some cases the green of the green sapphire is due to the presence, within the cut stone, of both blue and yellow portions, the light from which, being blended by its reflection within the stone, emerges as green as seen by the unaided eye, which cannot analyze colors. The dark sapphires of Australia are frequently green when cut in one direction and deep blue when cut in the opposite direction. The green, however, is seldom pleasing.
7. Chrysoberyl as usually seen is of a yellowish green. The fine gem chrysoberyls known as alexandrites, however, have a pleasing bluish green or deep olive green color by daylight and change in a most surprising fashion by artificial light under which they show raspberry red tints. This change, according to G. F. Herbert-Smith, is due principally to the fact that the balance in the spectrum of light transmitted by the stone is so delicate that when a light, rich in short wave lengths, falls upon it the blue green effect is evident, whereas when the light is rich in long wave lengths (red end of the spectrum), the whole stone appears red. The strong dichroism of the species also aids this contrast. The chrysoberyls of the cat's-eye type (of fibrous or tubular internal structure) are usually of olive green or brownish-green shades.
Those who wish to further study color distinctions in green stones are recommended to see the chapters on beryl (pp. 184-196), peridot (pp. 225-227), corundum (pp. 172-183), tourmaline (pp. 219-224), chrysoberyl (pp. 233-237), and garnet (demantoid, pp. 216-218) in G. F. Herbert-Smith's _Gem-Stones_.
LESSON XIII
COLOR--_Continued_
BLUE STONES
The species that furnish blue stones in sufficient number to deserve consideration are, aside from opaque stones:
1. Corundum (sapphire).
2. Spinel.
3. Tourmaline.
4. Topaz.
5. Diamond.
6. Zircon.
1. Of these minerals the only species that furnishes a fine, deep velvety blue stone is the corundum, and fine specimens of the cornflower blue variety are very much in demand and command high prices. The color in sapphires ranges from a pale watery blue through deeper shades (often tinged with green) to the rich velvety cornflower blue that is so much in demand, and on to dark inky blues that seem almost black by artificial light. Most sapphires are better daylight stones than evening stones. Some of the sapphires from Montana, however, are of a bright electric blue that is very striking and brilliant by artificial light.
HOW SAPPHIRES SHOULD BE CUT. The direction in which the stone is cut helps determine the quality of the blue color, as the "ordinary" ray (sapphire exhibits dichroism) is yellowish and ugly in color, and if allowed to be conspicuous in the cut stone, its presence, blending with the blue, may give it an undesirable greenish cast. Sapphires should usually be cut so that the table of the finished stone is perpendicular to the principal optical axis of the crystal. Another way of expressing this fact is that the table should cross the long axis of the usual hexagonal crystal of sapphire, at right angles. This scheme of cutting puts the direction of single refraction up and down the finished stone, and leaves the ugly ordinary rays in poor position to emerge as the light that falls upon the girdle edges cannot enter and cross the stone to any extent.
To find out with a finished stone whether or not the lapidary has cut it properly as regards its optical properties one may use the dichroscope, and if there is little or no dichroism in evidence when looking through the table of the stone it is properly cut.
Where a sapphire shows a poor color and the dichroscope shows that the table was laid improperly, there is some possibility of improving the color by recutting to the above indicated position. However, one must use much judgment in such a case, as sapphires, like other corundum gems, frequently have their color irregularly distributed, and the skillful lapidary will place the culet of the stone in a bit of good color, and thus make the whole stone appear to better advantage. It would not do to alter such an arrangement, as one would get poorer rather than better color by recutting in such a case.
While some of the blue stones about to be described may resemble inferior sapphires, none of them approaches the better grades of sapphire in fineness of blue coloration. The scientific sapphire, of course, does approach and even equals the natural sapphire so that one must know how to distinguish between them. This distinction is not one of color, however, and it will be separately considered a little later.
2. Blue spinels are infrequently seen in commerce. They never equal the fine sapphire in their color, being more steely. They, of course, lack dichroism and are softer than sapphire as well as lighter.
3. Blue tourmalines are never of fine sapphire blue. The name indicolite which mineralogists give to these blue stones suggests the indigo-blue color which they afford. The marked dichroism of tourmaline will also help detect it. Some tourmalines from Brazil are of a lighter shade of blue and are sometimes called "Brazilian sapphires."
4. Blue topaz is usually of a pale sky blue or greenish blue and is likely to be confused with beryl of similar color. The high density of topaz (3.53) as compared with beryl (2.74) serves best to distinguish it.
"FANCY" BLUE DIAMONDS. 5. Blue diamonds are usually of very pale bluish or violet tint. A few deeper blue stones are seen occasionally as "fancy" diamonds. These are seldom as deep blue as pale sapphires. Even the famous Hope Blue Diamond, a stone of about forty-four carats and of great value, is said to be too light in color to be considered a fine sapphire blue. Some of the deeper blue diamonds have a steely cast. The so-called blue-white stones are rarely blue in their body color, but rather are so nearly white that the blue parts of the spectra which they produce are very much in evidence, thus causing them to face up blue. There is little likelihood of mistaking a bluish diamond for any other stone on account of the "fire" and the adamantine luster of the diamond.
6. Blue zircon, however, has nearly adamantine luster and considerable fire. The color is usually sky blue. Such stones are seldom met with in the trade.
For a more detailed account of the various blue stones see G. F. Herbert-Smith's _Gem-Stones_, as follows:
For sapphires, pp. 172-173, 176, 182; for spinel, pp. 203, 204, 205; for tourmaline, pp. 220, 221, 223; for topaz, pp. 198, 200, 201; for diamond, pp. 130, 136, 170, and for zircon, pp. 229, 231.
LESSON XIV
COLOR--_Concluded_
PINK, PURPLE, BROWN, AND COLORLESS STONES
PINK STONES. Pink stones are yielded by (1) corundum (pink sapphire), (2) spinel (balas ruby), (3) tourmaline (rubellite), (4) true topaz (almost always artificially altered), (5) beryl (morganite), (6) spodumene (kunzite), and (7) quartz (rose-quartz).
These pink minerals are not easily differentiated by color alone, as the depth and quality of the pink vary greatly in different specimens of the same mineral and in the different minerals. There is dichroism in the cases of pink sapphire, pink tourmaline (strong), pink topaz (strong), pink beryl (less pronounced), and kunzite (very marked and with a yellowish tint in some directions that contrasts with the beautiful violet tint in another direction in the crystal). Pink quartz is almost always milky, and shows little dichroism. Pink spinel is without dichroism, being singly refracting. Hardness and specific gravity tests will best serve to distinguish pink stones from each other. The color alone is not a safe guide.
PURPLE STONES. Among the mineral species that furnish purple stones, (1) quartz is pre-eminent in the fineness of the purple color. Such purple stones are, of course, known as amethysts. After quartz come (2) corundum (Oriental amethyst), (3) spinel (almandine spinel), (4) garnet (almandine), and (5) spodumene (variety kunzite).
The purple of the amethyst varies from the palest tints to the full rich velvety grape-purple of the so-called Siberian amethysts. The latter are of a reddish purple (sometimes almost red) by artificial light, but of a fine violet by daylight. No other purple stone approaches them in fineness of coloring, so that here we have a real distinction based on color alone. If the purple is paler, however, one cannot be sure of the mineral by its color. Purple corundum (Oriental amethyst) is seldom as fine in color as ordinary amethyst, and never as fine as the best amethyst. It is usually of a redder purple, and by artificial light is almost ruby-like in its color.
Purple spinels are singly refracting, and lack dichroism, and hence lack variety of color. Almandine garnets also show no dichroism and lack variety of color. The garnets are, as a rule, apt to be more dense in color than the spinels.
Purple spodumene (kunzite) is pinkish to lilac in shade--usually pale, unless in large masses, and it shows very marked dichroism. A yellowish cast of color may be seen in certain directions in it also, which will aid in distinguishing it from other purple stones.
BROWN STONES. (1) Diamond, (2) garnet, (3) tourmaline, and (4) zircon furnish the principal brown stones.
Diamond, when brown, unless of a deep and pleasing color, is very undesirable, as it absorbs much light, and appears dirty by daylight and dark and sleepy by artificial light. When of a fine golden brown a diamond may have considerable value as a "fancy" stone. Such "golden fancies" can be distinguished from other brown stones (except perhaps brown zircons) by their adamantine luster, and their prismatic play or "fire."
Brown garnet (hessonite or cinnamon stone), sometimes wrongly called hyacinth in the trade, is of a deep reddish-brown color. Usually the interior structure, as seen under a lens, is streaky, having a sort of mixed oil and water appearance.
Brown tourmaline is sometimes very pleasing in color. It is deep in shade, less red than cinnamon stone, and with marked dichroism, which both brown diamond and brown garnet lack.
Brown zircon, while lacking dichroism, is frequently rich and pleasing in shade, and when well cut is very snappy, the luster being almost adamantine, the dispersion being large, and the refractive index high. It is useless to deny that by the unaided eye one might be deceived into thinking that a fine brown zircon was a brown diamond. However, the large double refraction of the zircon easily distinguishes it from diamond (use the sunlight-card method or look for the doubling of the edges of the rear facets as seen through the table). The relative softness (7-1/2) also easily differentiates it from diamond.
COLORLESS STONES. Few colorless stones other than diamond, white sapphire (chiefly scientific), and quartz are seen in the trade. Colorless true topaz is sometimes sold and artificially whitened zircon (jargoon) is also occasionally met with. Beryl of very light green tint or even entirely colorless may also be seen at times.
Such colorless stones must of course be distinguished by properties other than color. They are mentioned here merely that the learner may be aware of what varieties of gem minerals occur in the colorless condition, and that all these minerals also occur with color in their more usual forms. This does not even except the diamond, which is rarely truly colorless.
LESSON XV
HOW TO TELL SCIENTIFIC STONES FROM NATURAL GEMS
It should be said first that the only true scientific or synthetic stones on the market are those having the composition and properties of corundum, that is to say, the ruby and the several color varieties of sapphire, as blue, pink, yellow, and white. There is also a greenish stone that appears reddish by artificial light, which is called scientific alexandrite but which has, however, the composition and properties of the corundum gems rather than those of true alexandrite. All so-called "scientific emeralds" have proved to be either of paste of one sort or another, or else triplets having a top and a back of some inexpensive but hard stone of pale color, and a central slice of deep green glass, the three pieces being cemented together so skillfully that the junctions frequently escape any but a very careful examination with a lens.
ALL SCIENTIFIC STONES ARE CORUNDUM GEMS. Now the fact that all true scientific stones are corundum gems makes their determination fairly simple on the following basis: Among the considerable number of corundum gems of nature, whether ruby or sapphire of various colors, there is seldom found one that is entirely free from defects. Almost always, even in what are regarded as fine specimens, one will easily find with a glass, defects in the crystallization. Moreover these defects are characteristic of the corundum gems.
The scientific corundum gems, however, never have these specific defects. Hence the surest and simplest way of distinguishing between the two kinds of stones is to acquaint oneself with the typical defects of natural corundum gems, and then to look for such defects in any specimen of ruby or sapphire that is in question.
While a description of some of the most common of the typical defects of rubies and sapphires is to follow, the jeweler, who may not yet be familiar with them by actual experience, owes it to himself and to his customers to acquaint himself at first hand with the natural defects of such material, which he is always in a position to do through the courtesy of representatives of houses dealing in precious stones, if he himself does not carry such material in stock.
TYPICAL DEFECTS OF NATURAL CORUNDUM GEMS. Perhaps the most common of the defects of natural corundum gems is the peculiar appearance known as "silk." This is best seen when a strong light is allowed to stream through the stone at right angles to the observer's line of sight. Sets of fine, _straight_, parallel lines will be seen, and these will frequently meet other sets of similar lines at an angle of 120 degrees (like the angle at which the sides of a regular hexagon meet) or the lines may cross each other at that angle or at an angle of 60 degrees (the supplement of 120 degrees). Such _straight_ parallel lines are never seen in scientific stones, and their presence may be taken to indicate positively that the stone having them is a natural stone. In fine specimens of natural ruby or sapphire such lines will be few and difficult to find, but in some position or other they will usually be found if the search is even as careful as that which one would habitually employ in looking for defects in a diamond. In the vast majority of cases no such careful search will be required to locate "silk" in natural rubies, and if a stone that is apparently a ruby is free from such defects it is almost a foregone conclusion it is a scientific stone.
Another common type of defect in corundum gems is the occurrence of patches of milky cloudiness within the material. A little actual acquaintance with the appearance of this sort of defect in natural stones will make it easy to distinguish from the occasional cloudiness found in scientific stones, which latter cloudiness is due to the presence of swarms of minute gas bubbles. These tiny bubbles can be seen under a high power lens, and this suggests a third feature that may be used to tell whether one has a natural stone or not.
Natural rubies and sapphires, like scientific ones, frequently contain bubbles, but these are always _angular_ in the natural stones, while those of the scientific stones are generally _round_ or rounding, never angular.
To sum up the suggestions already presented it may be said that, since natural and scientific corundum gems are composed of essentially the same material, and have identically the same physical and chemical properties, and frequently very closely resemble each other in color, it is necessary to have recourse to some other means of distinguishing between them. The best and simplest means for those who are acquainted with the structural defects common to natural corundum gems is to seek for such defects in any specimen that is in question, and if no such defects can be found, to be very sceptical as to the naturalness of the specimen, inasmuch as perfect corundum gems are very rare in nature, and when of fine color command exceedingly high prices. No jeweler can afford to risk his reputation for knowledge and for integrity by selling as a natural stone any gem which does not possess the minor defects common to practically all corundum gems.
STRUCTURAL DEFECTS OF SCIENTIFIC STONES. So far our tests have been mostly negative. It was said, however, that spherical bubbles sometimes appear in scientific gems. Another characteristic _structural_ defect of practically every scientific gem may be utilized to distinguish them. As is well known, the rough material is formed in boules or pear-shaped drops under an inverted blowpipe. The powdered material is fed in with one of the gases and passes through the flame, melting as it goes, and then accumulating and crystallizing below as a boule. The top or head of this boule is rounding from the start, and hence the successive layers of material gather in thin curved zones. The color and structure of these successive zones are not perfectly uniform, hence when cut stones are made from the boules these _curving_ parallel layers may be seen within by the use of a good lens, especially if the cut stone is held in a strong crossing light, as was suggested when directions were given above as to the best way to look for "silk" in a natural stone.
Owing to the shape of a well cut stone it is sometimes difficult to get light through the material, yet by turning the stone repeatedly, some position will be found in which the curving parallel striæ can be seen. They are easily seen in scientific ruby, less easily in dark blue sapphire, but still they can be found on close search. In the light colored stones and in white sapphire, the difficulty is greater, as there are no color variations in the latter case. However, the value of white sapphire is so slight, whether natural or artificial, that it is a matter of but little moment, and what has already been said as to natural defects, applies to white sapphire as well as to the colored varieties, and absolutely clear and perfect natural white sapphire is rare.
One more distinguishing mark of the scientific stones may be added to give full measure to the scheme of separation, that no one need be deceived.
The surface finish of the scientific stones is rarely as good as that of the natural material and it appears to be more difficult to produce a good polish on scientific stones than on natural ones. The degree of hardness of the scientific stones seems to be slightly variable in different parts of the same piece so that the polishing material removes the surface material unequally, leaving minute streaky marks on the surfaces of the facets. Possibly this condition might be remedied by skillful treatment, but hardly at the price obtainable for the product, so that a close study of the surface finish will sometimes help in distinguishing between natural and artificial material. Any fine specimen of natural ruby or sapphire will have usually received very expert treatment and a splendid surface finish.
In conclusion, then, the points to be remembered in determining the origin of corundum gems are four in number.
1. Expect to find natural defects, such as "silk" or cloudy patches, or _angular_ bubbles in all natural stones.
2. If bubbles are present in artificial material they will be _round_ or rounding.
3. Artificial material will always have _curving_ parallel striæ within it.
4. The _surface finish_ of artificial material is seldom or never equal to that of natural material.
It ought not to be necessary to add that material from either source may be cut to any shape, and that artificial rubies may be seen in most Oriental garb, hence all specimens should have applied to them the above tests regardless of the seeming antiquity of their cut or of their alleged pedigree.
LESSON XVI
HOW TO TEST AN "UNKNOWN" GEM
Having now considered separately the principal physical properties by means of which one can identify a precious stone, let us attempt to give as good an idea as the printed page can convey of how one should go about determining to what species a gem belongs.
SIGNS OF WEAR IN AN EMERALD. To make the matter more concrete, and therefore more interesting, let us consider a real case, the most recent problem, in fact, that the author has had to solve. A lady of some wealth had purchased, for a large sum, a green stone which purported to be an emerald. After a few years of wear as a ring stone she noticed one day that the stone had dulled around the edges of its table, and thinking that that ought not to be the case with a real emerald, she appealed to a dealer in diamonds to know if her stone was a real emerald. The diamond merchant told her frankly that, while he was competent in all matters pertaining to diamonds, he could not be sure of himself regarding colored stones, and advised the lady to see the author.
The matter being thus introduced, the lady was at once informed that even a real emerald might show signs of wear after a few years of the hard use that comes to a ring stone.
While emerald has, as we saw in the lesson on hardness, a degree of hardness rated as nearly 8 (7-1/2 in the table), it is nevertheless a rather brittle material and the long series of tiny blows that a ring stone is bound to meet with will cause minute yielding along the exposed edges and corners of the top facets. This being announced, the first step in the examination of the stone was to clean it and to give it a careful examination with a ten-power lens. (An aplanatic triplet will be found best for this purpose.)
COLOR. The color was, of course, the most obvious property, but, as has already been said, color is not to be relied upon in all cases. In this case the color was a good emerald green but a bit bluer than the finest grass green. A very fine Maine tourmaline might approach this stone in color, so it became necessary to consider this possibility. A glass imitation, too, might have a color equal or superior to this.
IMPERFECTIONS. While noting the color, the imperfections of the stone claimed attention. They consisted mainly of minute jagged cracks of the character peculiar to brittle materials such as both emerald and tourmaline. So far it will be noted either of the above minerals might have furnished the lady's gem. As glass can be artificially crackled to produce similar flaws the stone might have been only an imitation as far as anything yet learned about it goes.
FILE TEST. The next step was to test its hardness by gently applying a very fine file to an exposed point at one corner of the girdle. The file slipped on the material as a skate slips on ice. Evidently we did not have to do with a glass imitation.
REFRACTION. Knowing now that we had a true hard mineral, it remained to be determined what mineral it was. On holding the stone in direct sunlight and reflecting the light onto a white card it was seen at once that the material was doubly refracting, for a series of _double_ images of the back facets appeared. These double images might have been produced by tourmaline as well as by emerald. (Not however by glass which is singly refracting.) If a direct reading refractometer had been available the matter could have been settled at once by reading the refractive indices of the material, for tourmaline and emerald have not only different refractive indices but have double refraction to different degrees. Such an instrument was not available at the time and will hardly be available to most of those who are studying this lesson, so we can go on with our account of the further testing of the green stone.
HARDNESS. A test upon the surface of a quartz crystal showed that the stone was harder than quartz (but so is tourmaline). A true topaz crystal was too hard for the ring stone, whose edge slipped over the smooth topaz surface. The green stone was therefore not a green corundum (Oriental emerald) as the latter has hardness 9 and scratches topaz.
With hardness evidently between 7 and 8 and with double refraction and with the kind of flaws peculiar to rather brittle minerals we had in all probability either a tourmaline or an emerald.
DICHROISM. The dichroscope (which might have been used much earlier in the test but was not at hand at the time) was next tried and the stone was seen to have marked dichroism--a bluish green and a yellowish green appearing in the two squares of the instrument when the stone was held in front of the opening and viewed against a strong light.
As either tourmaline or emerald might thus exhibit dichroism (the tourmaline more strongly, however, than the emerald) one more test was tried to finally decide the matter.
SPECIFIC GRAVITY. The stone was removed from its setting and two specific gravity determinations made by means of a specific gravity bottle and a fine chemical balance. The two results, which came closely alike, averaged 2.70 which agrees very nearly with emerald (2.74) and which is far removed from the specific gravity of tourmaline (3.10). The stone was now _definitely known_ to be an emerald, as each of several tests agreed with the properties of emerald, namely:
Color--nearly grass green.
Imperfections--like those of emerald.
Hardness--7-1/2.
Refraction--double.
Dichroism--easily noted.
Specific gravity--2.70.
While one who was accustomed to deal in fine emeralds might not need to make as detailed an examination of the stone as has just been indicated above, yet for most of us who do not have many opportunities of studying valuable emeralds it is safer to make sure by complete tests.
One other concrete example of how to go about testing unknown stones must suffice to conclude this lesson, after which the student, who has mastered the separate lessons preceding this, should proceed to test as many "unknowns" as his time and industry permit in order to really make _his own_ the matter of these lessons. It may be added here that the task of testing a stone is much more rapid than this laborious effort to teach others how to do it might indicate. To one skilled in these matters only a few seconds are required for the inspection of a stone with the lens, the dichroscope, or the refractometer, and hardness tests are swiftly made. A specific gravity test requires more time and should be resorted to only when there remains a reasonable doubt after other tests have been applied.
Now for our final example. A red stone, cut in the form of a pear-shaped brilliant, was submitted to the writer for determination. It had been acquired by an American gentleman in Japan from an East Indian who was in financial straits. Along with it, as security for a loan, the American obtained a number of smaller red stones, a bluish stone, and a larger red stone. The red stones were all supposed to be rubies. On examination of the larger red stone with a lens it was at once noted that the internal structure was that of _scientific ruby_.
TESTING OTHER STONES. Somewhat dashed by the announcement of this discovery the owner began to fear that all his gems were false. Examination of the small red stones showed abundance of "silk," a peculiar fibrous appearance within the stone caused by its internal structure. The fibers were _straight_ and _parallel_, not _curved_ and _parallel_ as in synthetic ruby. Tiny bubbles of angular shape also indicated that the small stones were natural rubies. They exhibited dichroism and scratched topaz and it was therefore decided that they at least were genuine.
The pear-shaped brilliant which was first mentioned was of a peculiar, slightly yellowish, red color. It was very pellucid and free from any striæ either of the straight or curved types. It had in fact no flaws except a rather large nick on one of the back surfaces near the girdle. This was not in evidence from the front of the stone and had evidently been left by the Oriental gem cutter to avoid loss in weight while cutting the stone.
The peculiar yellowish character of the red color led us to suspect ruby spinel. The stone was therefore inspected with the dichroscope and found to possess no dichroism. The sunlight-card test, too, showed that the stone was singly refracting.
A test of the hardness showed that the material barely scratched topaz, but was attacked by sapphire. It was therefore judged to be a red spinel.
The large bluish stone which the gentleman acquired with the red stones proved to be iolite, sometimes called cordierite or water-sapphire (_Saphir d'eau_), a stone seldom seen in this country. It had marked dichroism--showing a smoky blue color in one direction and a yellowish white in another. The difference was so marked as to be easily seen without the dichroscope.
LESSON XVII
SUITABILITY OF STONES FOR VARIOUS TYPES OF JEWELS, AS DETERMINED BY HARDNESS, BRITTLENESS, AND CLEAVABILITY
HARD STONES NOT NECESSARILY TOUGH. As was suggested in the lesson on hardness there is prevalent in the public mind an erroneous belief that hardness carries with it ability to resist blows as well as abrasion. Now that _it does not follow that because a precious stone is very hard, it will wear well_, should be made plain. Some rather hard minerals are seldom or never used as gems, in spite of considerable beauty and hardness, because of their great brittleness. Other stones, while fairly hard and reasonably tough in certain directions, have nevertheless so pronounced a cleavage that they do not wear well if cut, and are sometimes very difficult to cut at all.
In view of these facts it will be well to consider briefly what stones, among those most in use, are sufficiently tough as well as hard, to give good service in jewels, such as rings, which are subject to rough wear. We may also consider those stones, whose softness, or brittleness, or ready cleavability, requires that they should be reserved for use only in those jewels which, because of their nature, receive less rough usage.
In order to deal with the principal gems systematically, let us consider them in the order of their hardness, beginning with the hardest gem material known, which is, of course, diamond.
DURABILITY OF THE DIAMOND. Fortunately this king of gems possesses in addition to its great hardness, considerable toughness, and although it is readily cleavable in certain directions it nevertheless requires a notable amount of force applied in a particular direction to cause it to cleave. Although sharp knocks will occasionally flake off thin layers from diamonds when roughly worn in rings, or even in extreme cases fracture them, yet this happens but seldom and, as the enormous use of the diamond in ring mountings proves, it is entirely suitable for that purpose. It follows that, if a stone can stand ring usage, it can safely be used for any purpose for which precious stones are mounted.
THE CORUNDUM GEMS. Next after the diamond in hardness come the corundum gems, _i. e._, ruby, sapphire, and the series of corundum gems of colors other than red and blue. These stones have no noticeable cleavage and are exceedingly tough, for minerals, as well as very hard. We have only to consider the use of impure corundum (emery) as a commercial abrasive in emery wheels, emery cloth, emery paper, etc., to see that the material is tough. Any of the corundum gems therefore may be used in any type of jewel without undue risk of wear or breakage. Customers of jewelers should, however, be cautioned against wearing ruby or sapphire rings on the same finger with a diamond ring in cases where it would be possible for the two stones to rub against each other. So much harder than the ruby is the diamond (in spite of the seeming closeness of position in Mohs's scale) that the slightest touch upon a ruby surface with a diamond will produce a pronounced scratch. The possessor of diamonds and other stones should also be cautioned against keeping them loose in the same jewel case or other container, as the shaking together may result in the scratching of the softer materials. The Arabs are said to have a legend to the effect that the diamond is an _angry_ stone and that it should not be allowed to associate with other stones lest it scratch them.
CHRYSOBERYL. Passing on to the next mineral in the scale of hardness we come to chrysoberyl, which is rated as 8-1/2 on Mohs's scale. This mineral furnishes us the gem, alexandrite, which is notable for its power to change in color from green in daylight to red in artificial light. Chrysoberyl also supplies the finest cat's-eyes (when the material is of a sufficiently fibrous or tubular structure), and it further supplies the greenish-yellow stones frequently (though incorrectly) called "chrysolite" by jewelers. The material is very hard and reasonably tough and may be used in almost any suitable mounting.
SPINEL. After chrysoberyl come the materials rated as about 8 in hardness. First and hardest of these is spinel, then comes true or precious topaz. The various spinels are very hard and tough stones. The rough material persists in turbulent mountain streams where weaker minerals are ground to powder, and when cut and polished, spinel will wear well in any jewel. The author has long worn a ruby spinel in a ring on the right hand and has done many things that have subjected it to hard knocks, yet it is still intact, except for a spot that accidentally came in contact with a fast-flying carborundum wheel, which of course abraded the spinel.
TOPAZ. The true topaz is a bit softer than spinel, and the rough crystals show a very perfect basal cleavage. That is, they will cleave in a plane parallel to the bases of the usual orthorhombic crystals. This being the case a cut topaz is very likely to be damaged by a blow or even by being dropped on a hard surface, and it would be wiser not to set such a stone in a ring unless it was to be but little used, or used by one who would not engage in rough work while wearing it. Thus a lady might wear a topaz ring on dress occasions for a long time without damaging it, but it would not do for a machinist to wear one in a ring.
GEMS BETWEEN 7 AND 8 IN HARDNESS. We now come to a rather long list of gem minerals ranging between 7 and 8 in hardness. Of these the principal ones are zircon, almandine garnet, and beryl (emerald and aquamarine) rated as 7-1/2 in hardness, and pyrope and hessonite garnet rated as 7-1/4 in hardness. Tourmaline and kunzite may also be included in this group as being on the average slightly above 7 in hardness.
The above minerals are all harder than quartz, and hence not subject to abrasion by the quartz dust which is everywhere present. In this respect they are suitable for fairly hard wear. The garnets are of sufficient toughness so that they may be freely used in rings--and the extensive use of thin slices of garnet to top doublets proves the suitability of the material for resisting wear. The zircon is rather more brittle and the artificially whitened zircons (known as jargoons) are especially subject to breakage when worn in rings. Fortunately jargoons are not commonly sold.
The beryl, whether emerald or aquamarine, is rather brittle. Emeralds are seldom found in river gravels. The material cannot persist in the mountain streams that bring down other and tougher minerals. The extreme beauty and value of the emerald has led to its use in the finest jewels, and the temptation is strong to set it in rings, especially in rings for ladies. If such rings are worn with the care that valuable jewels should receive they will probably last a long time without any more serious damage than the dulling of the sharp edges of the facets around the table. This slight damage can at any time be repaired by a light repolishing of the affected facets. If an emerald is already badly shattered, or as it is called "mossy" in character, it will not be wise to set it in a ring, as a slight shock might complete its fracture. What has been said about emerald applies equally to aquamarine except that the value at stake is much less and the material is usually much freer from cracks.
Tourmalines, like emeralds, are brittle, and should be treated accordingly. Here, however, we are dealing with a much less expensive material than emerald, and if a customer desires a tourmaline in a ring mounting, while it will be best to suggest care in wearing it, the loss, in case of breakage, will usually be slight.
Kunzite, like all spodumene, has a pronounced cleavage. It should therefore be used in brooches, pendants, and such jewels, rather than in rings. Lapidaries dislike to cut it under some conditions because of its fragility.
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A Text-Book of Precious Stones for Jewelers and the Gem-Loving PublicChapter IV: , pp. 21-36. The Herbert-Smith refractometer is there (2)
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