Chapter XIV: Part 14
So far as mere existence is concerned, heat-forming food may be looked upon as the real fuel on which the lamp of life is sustained. But man, considered as a working being, cannot exist without _energy-forming_ food. All work, whether of the brain or of the limbs, involves the exhaustion of nervous and muscular matter; and unless the exhausted matter be renewed, the work must come to an end. The supply of heat-giving food may be compared to the supply of fuel for the fire of a steam-engine. By means of this supply the _fire_ is kept alive; but if the fire have nothing to work upon, its energies are wasted or used to the injury of the machine itself. The supply of water, and its continual use (in the form of steam) in the propulsion of the engine, are the processes corresponding to the continual exhaustion and renewal of the muscles and nerves of the human frame. And the comparison may be carried yet further. We see that in the case of the engine the amount of smoke, or rather of carbonic acid, thrown out by the blast-pipe is a measure of the vital energy (so to speak) within the engine; but the amount of work done by the engine is measured rather by the quantity of steam which is thrown out, because the elastic force of every particle of steam has been exerted in the propulsion of the engine before being thrown out through the blast-pipe. In a manner precisely corresponding to this, the amount of carbonic acid gas exhaled by a man is a measure of the rate at which mere existence is proceeding; but the amount of work, mental or muscular, which the man achieves, is measured by the amount of used-up brain-material and muscle-material which is daily thrown off by the body. I shall presently show in what way this amount is estimated.
In the composition of the muscles there is a material called _fibrine_, and in the composition of the nerves there is a material called _albumen_. These are the substances[42] which are exhausted during mental and bodily labour, and which have to be renewed if we are to continue working with our head or with our hands. Nay more, life itself involves work; the heart, the lungs, the liver, each internal organ of the body, performs its share of work, just as a certain proportion of the power of a steam-engine is expended in merely moving the machinery which sets it in action. If the waste of material involved in this form of work is not compensated by a continual and sufficient supply of fibrine and albumen the result will be a gradual lowering of all the powers of the system, until some one or other gives way,—the heart ceases to beat, or the stomach to digest, or the liver to secrete bile,—and so death ensues.
The fibrine and albumen in the animal frame are derived exclusively from vegetables. For although we seem to derive a portion of the supply from animal food, yet the fibrine and albumen thus supplied have been derived in the beginning from the vegetable kingdom. “It is the peculiar property of the plant,” says Dr. Lankester, “to be able, in the minute cells of which it is composed, to convert the carbonic acid and ammonia which it gets from the atmosphere into fibrine and albumen, and by easy chemical processes we can separate these substances from our vegetable food. Wheat, barley, oats, rye, rice, all contain fibrine, and some of them also albumen. Potatoes, cabbage, and asparagus contain albumen. It is a well-ascertained fact that those substances which contain most of these ‘nutritious secretions,’ as they have been called, support life the longest.” They change little during the process of digestion, entering the blood in a pure state, and being directly employed to renew the nervous and muscular matter which has been used up during work, either mental or muscular. Thus the supply of these substances is continually being drawn upon. The carbon, which forms their principal constituent, is converted into carbonic acid; and the nitrogen, which forms about a sixth part of their substance, re-appears in the nitrogen of urea, a substance which forms the principal solid constituent of the matter daily thrown from the system through the action of the kidneys. Thus the amount of urea which daily passes from the body affords a measure of the work done during the day. “This is not,” says Dr. Lankester, “the mere dream of the theorist; it has been practically demonstrated that increased stress upon the nervous system, viz., brain work, emotion, or excitement from disease, increases the quantity of urea and the demand for nitrogenous food. In the same manner the amount of urea is the representative of the amount of muscular work done.”
It has been calculated that the average amount of urea daily formed in the body of a healthy man is about 470 grains. To supply this daily consumption of nitrogenous matter, it is necessary that about four ounces of flesh-forming substance should be consumed daily. It is important, therefore, to inquire how this substance may be obtained. The requisite quantity of albuminous and fibrinous matter “is contained,” says Dr. Lankester, “in a pound of beef; in two pounds of eggs; in two quarts of milk; in a pound of peas; in five pounds of rice; in sixteen pounds of potatoes; in two pounds of Indian meal; in a pound and a half of oatmeal; and in a pound and three-quarters of flour.” A consideration of this list will show the importance of attending to the quality as well as the quantity of our food. A man of ordinary appetite might satisfy his hunger on potatoes or on rice, without by any means supplying his system with a sufficient amount of flesh-forming food. On the other hand, if a man were to live on bread and beef alone, he would load his system with an amount of nitrogenous food, although not taking what could be considered an excessive amount of daily nourishment. We see, also, how it is possible to continually vary the form in which we take the required supply of nitrogenous food, without varying the amount of that supply from day to day.
The supply itself should of course also vary from day to day as the amount of daily work may vary. What would be ample for a person performing a moderate amount of work would be insufficient for one who underwent daily great bodily or mental exertions, and would be too much for one who was taking holiday. It would appear, from the researches of Dr. Haughton, that the amount of urea daily formed in the body of a healthy man of average weight varies from 400 to 630 grains. Of this weight it appears that 300 grains results from the action of the internal organs. It would seem, therefore, that the amount of flesh-forming food indicated in the preceding paragraph may be diminished in the proportion of 47 to 40 in the case of a person taking the minimum of exercise—that is, avoiding all movements save those absolutely necessary for comfort or convenience. On the other hand, that amount must be increased in the proportion of 74 to 63 in the case of a person (of average weight) working up to his full powers. It will be seen at once, therefore, that a hardworking man, whether labourer or thinker, must make good flesh-forming food constitute a considerable portion of his diet; otherwise he would require to take an amount of food which would seriously interfere with his comfort and the due action of his digestive organs. For instance, if he lived on rice alone, he would require to ingest nearly seven pounds of food daily; if on potatoes, he would require upwards of twenty-one pounds; whereas one pound and a third of meat would suffice to supply the same amount of flesh-forming food.
Men who have to work, quickly find out what they require in the way of food. The Irishman who, while doing little work, will live contentedly on potatoes, asks for better flesh-forming food when engaged in heavy labour. In fact, the employer of the working man, so far from feeling aggrieved when his men require an improvement in their diet, either as respects quality or quantity, ought to look on the want as evidence that they are really working hard in his service, and also that they have a capacity for continuous work. The man who lives on less than the average share of flesh-forming food is doing less than an average amount of work; the man who is unable to eat an average quantity of flesh-forming food, is _unable_ to do an average amount of work. “‘On what principle do you discharge your men?’ I once said,” relates Dr. Lankester, “to a railway contractor. ‘Oh,’ he said, ‘it’s according to their appetites.’ ‘But,’ I said, ‘how do you judge of that?’ ‘Why,’ he said, ‘I send a clerk round when they are getting their dinners, and those who can’t eat he marks with a bit of chalk, and we send them about their business.’”
At a lecture delivered at the Royal Museum of Physics and Natural History at Florence, by Professor Mantegazza, a few years since, the Professor dwelt on the insufficient food which Italians are in the habit of taking, as among the most important causes of the weakness of the nation. “Italians,” he said, “you should follow as closely as you can the example of the English in your eating and in your drinking, in the choice of flesh-meat (in tossing off bumpers of your rich wines),[43] in the quality of your coffee, your tea, and your tobacco. I give you this advice, dear countrymen, not only as a medical man, but also as a patriot. It is quite evident, from the way millions of you perform the process which you call eating and drinking, that you have not the most elementary notions of the laws of physiology. You imagine that you are living. You are barely prolonging existence on maccaroni and water-melons. You neither know how to eat nor how to drink. You have no muscular energy; and, therefore, you have no continuous mental energy. The weakness of the individual, multiplied many millions of times, results in the collective weakness of the nation. Hence results insufficient work, and thence insufficient production. Thus the returns of the tax-collector and the custom-house officer are scanty, and the national exchequer suffers accordingly.” Nor is all this, strange as it may sound, the mere gossip of the lecture-room. “The question of good feeding,” says Dr. Lankester, “is one of national importance. It is vain to expect either brain or muscles to do efficient work when they are not provided with the proper material. Neither intellectual nor physical work can be done without good food.”
We have now considered the two principal forms of food, the heat-forming—sometimes called the _amylaceous_—constituents, and the flesh-forming or _nitrogenous_ constituents. But there are other substances which, although forming a smaller proportion of the daily food, are yet scarcely less important. Returning to our comparison of the human system to a steam-engine—we have seen how the heat-forming and flesh-forming constituents of food correspond to the supply of fuel and water; but an engine would quickly fall into a useless state if the wear and tear of the material of which it is constructed were not attended to and repaired. Now, in the human frame there are materials which are continually being used up, and which require to be continually restored, if the system is to continue free from disease. These materials are the mineral constituents of the system. Amongst them we must include _water_, which composes a much larger portion of our bodies than might be supposed. Seven-ninths of our weight consists simply of water. Every day there is a loss of about one-thirtieth part of this constituent of our system. The daily repair of this important waste of material is not effected by imbibing a corresponding supply of water. A large proportion of the weight of water daily lost is renewed in the solid food. Many vegetables consist principally of water. This is notably the case with potatoes. Where the water supplied to a district is bad, so that little water is consumed by the inhabitants—at least, without the addition of some other substance—it becomes important to notice the varying proportion of water present in different articles of food. As an instance of this, I may call attention to a remarkable circumstance observed during the failure of the potato crops in Ireland. Notwithstanding the great losses which the people sustained at that time, it was noticed that the amount of tea imported into Ireland exhibited a remarkable increase. This seemed at first sight a somewhat perplexing phenomenon. The explanation was recognized in the circumstance that the potato—a watery vegetable, as we have said—no longer formed the chief portion of the people’s diet. Thus the deficiency in the supply of water had to be made up by the use of a larger quantity of fluid food; and as simple water was not palatable to the people, they drank tea in much larger quantities than they had been in the habit of taking before the famine.
But we have to consider the other mineral constituents of the system.
If I were to run through the list of all the minerals which exist within the body, I should weary the patience of the reader, and perhaps not add very much to the clearness of his ideas respecting the constitution of the human frame. Let it suffice to state generally that, according to the calculations of physiologists, a human body weighing 154 pounds contains about 17½ pounds of mineral matter; and that the most important mineral compounds existing within the body are those which contain lime, soda, and potash. Without pretending to any strictly scientific accuracy in the classification, we may say that the lime is principally found in the bones, the soda in the blood, the potash in the muscles; and according as one or other of these important constituents is wanting in our food, so will the corresponding portions of the frame be found to suffer.
We have a familiar illustration of the effects of unduly diminishing the supply of the mineral constituents of the body in the ravages which scurvy has worked amongst the crews of ships which have remained for a long period ill-supplied with fresh vegetables. Here it is chiefly the want of potash in the food which causes the mischief. An interesting instance of the rapid—almost startling—effects of food containing potash, in the cure of men stricken by scurvy, is related by Dana. The crew of a ship which had been several months at sea, but was now nearing the land, were prostrated by the ravages of scurvy. Nearly all seemed hopelessly ill. One young lad was apparently dying, the livid spots which were spreading over his limbs seeming to betoken his rapidly approaching end. At this moment a ship appeared in view which had but lately left the land, and was laden with fresh vegetables. Before long large quantities of the life-bearing food had been transferred to the decks of the other ship. The instincts of life taught the poor scurvy-stricken wretches to choose the vegetable which of all others was best suited to supply the want under which their frames were wasting. They also were led by the same truthful instincts to prefer the raw to cooked vegetables. Thus the sick were to be seen eating raw onions with a greater relish than the gourmand shows for the most appetising viands. But the poor lad who was the worse of the sufferers had already lost the power of eating; and it was without a hope of saving his life that some of his companions squeezed the juice of onions between his lips, already quivering with the tremor of approaching death. He swallowed a few drops, and presently asked for more. Shortly he began to revive, and to the amazement of all those who had seen the state of prostration to which he had been reduced, he regained in a few days his usual health and strength.
The elements which we require in order to supply the daily waste of the mineral constituents of the body are contained in greater or less quantities in nearly all the articles which man uses for food. But it may readily happen that, by adopting an ill-regulated diet, a man may not take a sufficient quantity of these important elements. It must also be noticed that articles of food, both animal and vegetable, may be deprived of a large proportion of their mineral elements by boiling; and if, as often happens, the water in which the food has been boiled is thrown away, injurious effects can scarcely fail to result from the free use of food which has lost so important a portion of its constituent elements. Accordingly, when persons partake much of boiled meat, they should either consume the broth with the meat, or use it as soup on the alternate days. Vegetables steamed in small quantities of water (this water being taken with them), also afford a valuable addition to boiled meat. In fact, experience seems to have suggested the advantage of mixing carrots, parsnips, turnips, and greens with boiled meat; but unfortunately the addition is not always made in a proper manner. If the vegetables are boiled separately in large quantities of water, and served up after this water has been thrown away, more harm than good is done by the addition; since the appetite is satisfied with comparatively useless food, instead of being left free to choose, as it might otherwise do, such forms of food as would best supply the requirements of the system. Salads and uncooked fruits, for instance, contain saline ingredients in large proportion, and could be used advantageously after a meal of boiled meat. Potatoes are likewise a valuable article of food on account of the mineral elements contained in them. And there can be no doubt that the value of potatoes as an article of food is largely increased when they are cooked in their skins, after the Irish fashion.
Lastly, we must consider those articles of food which promote the natural vital changes, but do not themselves come to form part of the frame, or, at least, not in any large proportion of their bulk. Such are tea, coffee, and cocoa: alchoholic drinks; narcotics; and lastly, spices and condiments. We may compare the use of these articles of food to that of oil in lubricating various parts of a steam-engine. For, as the oil neither forms part of the heat-supply nor of the force-supply of the steam-engine, nor is used to replace the worn material of its structure, yet serves to render the movements of the machine more equable and effective, so the forms of food we are considering are neither heat-producing nor flesh-forming, nor do they serve to replace, to any great extent, the mineral constituents of the body, yet they produce a sense of refreshment accompanied with renewed vigour. It is difficult to determine in what precise way these effects are produced, but no doubt can exist as to the fact that they are really attributable to the forms of food to which we have assigned them.
Tea, coffee, and cocoa owe their influence on the nervous system to the presence of a substance which has received the various names of _theine_, _caffeine_, and _theobromine_. It is identical in composition with _piperine_, the most important ingredient in pepper. It may be separated in the form of delicate white, silky crystals, which have a bitter taste. In its concentrated form this substance is poisonous, and to this circumstance must be ascribed the ill effects which follow from the too free use of strong tea or coffee. However, the instances of bad effects resulting from the use of “the cup which cheers but not inebriates” are few and far between, while the benefits derived from it are recognized by all. It has, indeed, been stated that no nation which has begun to make use of tea, coffee, or cocoa, has ever given up the practice; and no stronger evidence can be required of the value of those articles of food.
Of alcoholic liquors it is impossible to speak so favourably. They are made use of, indeed, almost as extensively as tea or coffee; they have been made the theme of the poet, and hailed as the emblems of all that is genial and convivial. Yet there can be little doubt that, when a balance is struck between the good and evil which have resulted to man from their use, the latter is found largely to preponderate. The consideration of these evils belongs, however, rather to the moralist than to the physiologist. I have here simply to consider alcoholic liquors as articles of food. There can be little doubt that, when used with caution and judgment, they afford in certain cases an important adjunct to those articles which are directly applied to the reparation of bodily waste. Without absolutely nourishing the frame, they ultimately lead to this end by encouraging the digestive processes which result in the assimilation of nutritive articles of food. But the quantity of alcohol necessary to effect this is far less than is usually taken even by persons who are termed temperate. It is also certain that hundreds make use of alcoholic liquors who have no necessity for them, and who would be better without them. Those who require them most are men who lead a studious sedentary life; and it is such men, also, who suffer most from excess in the use of alcoholic liquors.
It remains that I should make a few remarks on mistakes respecting the quantity of food.
Some persons fall into the habit of taking an excessive quantity of food, not from greediness, but from the idea that a large amount of food is necessary for the maintenance of their strength. They thus overtax the digestive organs, and not only fail of their purpose, but weaken instead of strengthening the system. Especially serious is the mistake often made by persons in delicate health of swallowing—no other word can be used, for the digestive organs altogether refuse to respond to the action of the mouth—large quantities of some concentrated form of food, such as even the strongest stomach could not deal with in that form. I knew a person who, though suffering from weakness such as should have suggested the blandest and simplest forms of food, adopted as a suitable breakfast mutton-chops and bottled stout, arguing, when remonstrated with, that he required more support than persons in stronger health. He was simply requiring his weak digestive organs to accomplish work which would have taxed the digestive energies of the most stalwart labourer working daily in the open air for many hours.
On the other hand, a too abstemious diet is as erroneous in principle as a diet in excess of the natural requirements of the system. A diet which is simply too abstemious is perhaps less dangerous than persistent abstinence from the use of certain necessary forms of food. Nature generally prevents us from injuring ourselves by unwisely diminishing the quantity of food we take; but unfortunately she is not always equally decided in her admonitions respecting the quality of our food. A man may be injuring his health through a deficiency in the amount either of the heat-forming or of the flesh-forming food which he consumes, and yet know nothing of the origin of the mischief. It may also be noted that systematic abstinence, either as respects quantity or quality of food, is much more dangerous than an occasional fast. Indeed, it is not generally injurious either to abstain for several days from particular articles or forms of food, or to remain, for several hours beyond the usual interval between meals, without food of any sort. On the contrary, benefit often arises from each practice. The Emperor Aurelian used to attribute the good health he enjoyed to his habit of abstaining for a whole day, once a month, from food of all sorts; and many have found the Lenten rules of abstinence beneficial. As a rule, however, change of diet is a safer measure than periodical fasting or abstinence from either heat-producing or flesh-forming food. It must be noticed, in conclusion, that young persons ought not, without medical advice, to fast or abstain for any length of time from the more important forms of food, as serious mischief to the digestive organs frequently follows from either course.
_OZONE._
The singular gas termed ozone has attracted a large amount of attention from chemists and meteorologists. The vague ideas which were formed as to its nature when as yet it had been but newly discovered, have given place gradually to more definite views; and though we cannot be said to have thoroughly mastered all the difficulties which this strange element presents, yet we know already much that is interesting and instructive.
Let us briefly consider the history of ozone.
Nine years after Priestley had discovered oxygen, Van Marum, the electrician, noticed that when electric sparks are taken through that gas, a peculiar odour is evolved. Most people know this odour, since it is always to be recognized in the neighbourhood of an electrical machine in action. In reality, it indicates the presence of ozone in the air. But for more than half a century after Van Marum had noticed it, it was supposed to be the “smell of electricity.”
In 1840, Schönbein began to inquire into the cause of this peculiar odour. He presently found that it is due to some change in the oxygen; and that it can be produced in many ways. Of these, the simplest, and, in some respects, the most interesting, is the following:—“Take sticks of common phosphorus, scrape them until they have a metallic lustre, place them in this condition under a large bell-jar, and half-cover them with water. The air in the bell-jar is soon charged with ozone, and a large room can readily be supplied with ozonized air by this process.”
Schönbein set himself to inquire into the properties of this new gas, and very interesting results rewarded his researches. It became quite clear, to begin with, that whatever ozone may be, its properties are perfectly distinct from those of oxygen. Its power of oxidizing or rusting metals, for example, is much greater than that which oxygen possesses. Many metals which oxygen will not oxidize at all, even when they are at a high temperature, submit at once to the influence of ozone. But the power of ozone on other substances than metals is equally remarkable. Dr. Richardson states that, when air is so ozonized as to be only respirable for a short time, its destructive power is such that gutta-percha and india-rubber tubings are destroyed by merely conveying it.
The bleaching and disinfecting powers of ozone are very striking. Schönbein was at first led to associate them with the qualities of chlorine gas; but he soon found that they are perfectly distinct.
It had not yet been shown whether ozone was a simple or a compound gas. If simple, of course it could be but another form of oxygen. At first, however, the chances seemed against this view; and there were not wanting skilful chemists who asserted that ozone was a compound of the oxygen of the air with the hydrogen which forms an element of the aqueous vapour nearly always present in the atmosphere.
It was important to set this question at rest. This was accomplished by the labours of De la Rive and Marignac, who proved that ozone is simply another form of oxygen.
Here we touch on a difficult branch of modern chemical research. The chemical elements being recognized as the simplest forms of matter, it might be supposed that each element would be unchangeable in its nature. That a compound should admit of change, is of course a thing to be expected. If we decompose water, for instance, into its component elements, oxygen and hydrogen, we may look on these gases as exhibiting water to us in another form. And a hundred instances of the sort might be adduced, in which, either by separating the elements of a compound, or by re-arranging them, we obtain new forms of matter without any real change of substance. But with an element, the case, one would suppose, should be different.
However, the physicist must take facts as he finds them; and amongst the most thoroughly recognized chemical facts we have this one, that elementary substances may assume different forms. Chemists call the phenomenon allotropy. A well-known instance of allotropy is seen in red phosphorus. Phosphorus is one of the chemical elements; and, as every one knows, the form in which it is usually obtained is that of a soft, yellow, semi-transparent solid, somewhat resembling bees’ wax in consistence, poisonous, and readily taking fire. Red phosphorus is the same element, yet differs wholly in its properties. It is a powder, it does not readily take fire, and it is not poisonous.
Ozone, then, is another form of oxygen. It is the only instance yet discovered of gaseous allotropy.
And now we have to deal with the difficult and still-vexed questions of the way in which the change from oxygen is brought about, and the actual distinction between the two forms of the same gas. Schönbein held that common oxygen is produced by the combination of two special forms of oxygen—the positive and the negative, or, as he called them, ozone and antozone. He showed that, in certain conditions of the air, the atmospheric oxygen exhibits qualities which are the direct reverse of those which ozone exhibits, and are distinct from those of ordinary oxygen. In oxygen thus negatived or antozonized, animals cannot live any more than they can in nitrogen. The products of decomposition are not only not destroyed as by ozone, but seem subject to preservative influences, and speedily become singularly offensive; dead animal matter rapidly putrefies, and wounds show a tendency to mortification.
But the theory of positive and negative forms of oxygen, though still held by a few physicists, has gradually given way before the advance of new and sounder modes of inquiry. It has been proved, in the first place, that ozone is denser than ordinary oxygen. The production of ozone is always followed by a contraction of the gas’s volume, the contraction being greater or less according to the amount of oxygen which has been ozonized. Regularly as the observers—Messrs. Andrews and Tait—converted a definite proportion of oxygen into ozone, the corresponding contraction followed, and as regularly was the original volume of the gas restored when, by the action of heat, the ozone was reconverted into oxygen.
And now a very singular experiment was made by the observers, with results which proved utterly perplexing to them. Mercury has the power of absorbing ozone; and the experimenters thought that if, after producing a definite contraction by the formation of ozone, they could absorb the ozone by means of mercury, the quantity of oxygen which remained would serve to show them how much ozone had been formed, and thence, of course, they could determine the density of ozone.
Suppose, for instance, that we have one hundred cubic inches of oxygen, and that by any process we reduce it to a combination of oxygen and ozone occupying ninety-five cubic inches. Now, if the mercury absorbed the ozone, and we found, say, that there only remained eighty-five cubic inches of oxygen, we could reason in this way:—Ten cubic inches were occupied by the ozone before the mercury absorbed it; but these correspond to fifteen cubic inches of oxygen; hence, ozone must be denser than oxygen in the proportion of fifteen to ten, or three to two. And whatever result might have followed, a real absorption of the ozone by the mercury would have satisfactorily solved the problem.
But the result actually obtained did not admit of interpretation in this way. The apparent absorption of the ozone by the mercury, that is, the disappearance of the ozone from the mixture, was accompanied by _no diminution of volume at all_. In other words, returning to our illustrative case, after the absorption of the ozone from the ninety-five cubic inches occupied by the mixture, there still remained ninety-five cubic inches of oxygen; so that it seemed as though an evanescent volume of ozone corresponded in weight to five cubic inches of oxygen. This solution, of course, could not be admitted, since it made the density of ozone _infinite_.
The explanation of this perplexing experiment is full of interest and instruction. The following is the account given by Mr. C. W. Heaton (Professor of Chemistry at Charing Cross Hospital), slightly modified, however, so that it may be more readily understood.
Modern chemists adopt, as a convenient mode of representing the phenomena which gases exhibit, the theory that every gas, whether elementary or compound, consists of minute molecules. They suppose that these molecules are of equal size, and are separated by equal intervals so long as the gas remains unchanged in heat and density. This view serves to account for the features of resemblance presented by all gases. The features in which gases vary are accounted for by the theory that the molecules are differently constituted. The molecules are supposed to be clusters of atoms, and the qualities of a gas are assumed to depend on the nature and arrangement of these ultimate atoms. The molecules of some elements consist but of a single atom; the molecules of others are formed by pairs of atoms; those of others by triplets; and so on. Again, the molecules of compound gases are supposed to consist of combinations of different _kinds_ of atoms.
Now, Dr. Odling, to whom we owe the solution of the perplexing problem described above, thus interpreted the observed phenomena. A molecule of oxygen contains two atoms, one of ozone contains three, _and the oxidizing power of ozone depends on the ease with which it parts with its third atom of oxygen_. Thus, in the experiment which perplexed Messrs. Andrews and Tait, the mercury only _seemed_ to absorb the ozone; in reality it converted the ozone into oxygen by removing its third atom. And now we see how to interpret such a result as we considered in our illustrative case. Five cubic inches of oxygen gave up their atoms, each atom combining with one of the remaining oxygen doublets, so as to form a set of ozone triplets. Clearly, then, fifteen cubic inches of oxygen were transformed into ozone. They now occupied but ten cubic inches; so that the mixture, or ozonized oxygen, contained eighty-five cubic inches of oxygen and ten of ozone. When the mercury was introduced, it simply transformed all the ozone triplets into oxygen doublets, by taking away the odd atom from each. It thus left ten cubic inches of oxygen, which, with the remaining eighty-five, constituted the ninety-five cubic inches observed to remain after the supposed absorption of the ozone.
It follows, of course, that ozone is half as heavy again as oxygen.
But, as Mr. Heaton remarked, “this beautiful hypothesis, although accounting perfectly for all known facts, was yet but a probability. One link was lacking in the chain of evidence, and that link M. Soret has supplied by a happily devised experiment.” Although mercury and most substances are only capable of converting ozone into oxygen, oil of turpentine has the power of absorbing ozone in its entirety. Thus, when the experiment was repeated, with oil of turpentine in place of the mercury, the ozone was absorbed, and the remaining oxygen, instead of occupying ninety-five inches, occupied but eighty-five. After this, no doubt could remain that Dr. Odling’s ingeniously conceived hypothesis was the correct explanation of Messrs. Andrews and Tait’s experiment.
We recognize, then, in ozone a sort of concentrated oxygen, with this peculiar property, that it possesses an extraordinary readiness to part with its characteristic third atom, and so disappear _as ozone_, two-thirds of its weight remaining as oxygen.
It is to this peculiarity that ozone owes the properties which render it so important to our welfare. We are indeed, as yet, in no position to theorize respecting this element, our knowledge of its very existence being so recent, and our information respecting its presence in our atmosphere being of still more recent acquisition.
Indeed, it is well remarked by Mr. Heaton, that we had, until quite lately, no reason for confidently adopting Schönbein’s view that ozone exists in our atmosphere. The test-papers which Schönbein made use of turned blue under the influence of ozone, it is true, but they were similarly influenced by other elements which are known to exist in our atmosphere, and even the sun’s rays turned them blue. However, Dr. Andrews has shown how the character of the air producing the change can be further tested, so as to render it certain that ozone only has been at work. If air which colours the test-papers be found to lose the property after being heated, the change can only be due to ozone, because nitrous and nitric acids (which have the power of colouring the test-papers) would not be removed by the heat, whereas ozone is changed by heat into oxygen.
Once we are certain that ozone exists in the air, we must recognize the fact that its presence cannot fail to have an important bearing on our health and comfort; for ozone is an exceedingly active agent, and cannot exist anywhere without setting busily to its own proper work. What that work is, and whether it is beneficial or deleterious to ourselves, remains to be considered.
In the first place, ozone has immense power as a disinfectant. It decomposes the products emanating from putrefying matter more effectually than any other known element. Perhaps the most striking proof ever given of its qualities in this respect is that afforded by an experiment conducted by Dr. Richardson a few years ago.
He placed a pint of blood taken from an ox in a large wide-mouthed bottle. The blood had then coagulated, and it was left exposed to the air until it had become entirely redissolved by the effects of decomposition. At the end of a year the blood was put into a stoppered bottle, and set aside for seven years. “The bottle was then taken from its hiding-place,” says Dr. Richardson, “and an ounce of the blood was withdrawn. The fluid was so offensive as to produce nausea when the gases evolved from it were inhaled. It was subjected by Dr. Wood and myself to a current of ozone. For a few minutes the odour of ozone was destroyed by the odour of the gases from the blood; gradually the offensive smell passed away; then the fluid mass became quite sweet, and at last a faint odour of ozone was detected, whereupon the current was stopped. The blood was thus entirely deodorized; but another and most singular phenomenon was observed. The dead blood coagulated as the products of decomposition were removed, and this so perfectly, that from the new clot that was formed serum exuded. Before the experiment commenced, I had predicted on theoretical grounds that secondary coagulation would follow on purification; and this experiment, as well as several others afterwards performed, verified the truth of the prediction.”
It will of course be understood that ozone, in thus acting as a disinfectant, is transformed into oxygen. It parts with its third atom as in the mercury experiment, and so loses its distinctive peculiarity. Thus we might be led to anticipate the results which come next to be considered.
Ozone has certain work to do, and in doing that work is transmuted into oxygen. It follows, then, that where there has been much work for ozone to do, there we shall find little ozone left in the air. Hence, in open spaces where there is little decomposing matter, we should expect to find more ozone than in towns or cities. This accords with what is actually observed. And not only is it found that country air contains more ozone than town air, but it is found that air which has come from the sea has more ozone than even the country air, while air in the crowded parts of large cities has no ozone at all, nor has the air of inhabited rooms.
So far as we have gone, we might be disposed to speak unhesitatingly in favour of the effects produced by ozone. We see it purifying the air which would otherwise be loaded by the products of decomposing matter, we find it present in the sea air and the country air which we know to be so bracing and health-restoring after a long residence in town, and we find it absent just in those places which we look upon as most unhealthy.
Again, we find further evidence of the good effects of ozone in the fact that cholera and other epidemics never make their dreaded appearance in the land when the air is well supplied with ozone—or in what the meteorologists call “the ozone-periods.” And though we cannot yet explain the circumstance quite satisfactorily, we yet seem justified in ascribing to the purifying and disinfecting qualities of ozone our freedom at those times from epidemics to which cleanliness and good sanitary regulations are notedly inimical.
But there is a reverse side to the picture. And as we described an experiment illustrating the disinfecting qualities of ozone before describing the good effects of the element, we shall describe an experiment illustrating certain less pleasing qualities of ozone, before discussing the deleterious influences which it seems capable of exerting.
Dr. Richardson found that when the air of a room was so loaded with ozone as to be only respirable with difficulty, animals placed in the room were affected in a very singular manner. “In the first place,” he says, “all the symptoms of nasal catarrh and of irritation of the mucous membranes of the nose, the mouth, and the throat were rapidly induced. Then followed free secretion of saliva and profuse action of the skin—perspiration. The breathing was greatly quickened, and the action of the heart increased in proportion.” When the animals were suffered to remain yet longer within the room, congestion of the lungs followed, and the disease called by physicians “congestive bronchitis” was set up.
A very singular circumstance was noticed also as to the effects of ozone on the different orders of animals. The above-mentioned effects, and others which accompanied them, the description of which would be out of place in these pages, were developed more freely in carnivorous than in herbivorous animals. Rats, for example, were much more easily influenced by ozone than rabbits were.
The results of Dr. Richardson’s experiments prepare us to hear that ozone-periods, though characterized by the absence of certain diseases, bring with them their own forms of disease. Apoplexy, epilepsy, and other similar diseases seem peculiarly associated with the ozone-periods, insomuch that eighty per cent. of the deaths occurring from them take place on days when ozone is present in the air in larger quantities than usual. Catarrh, influenza, and affections of the bronchial tubes, also affect the ozone-periods.
We see, then, that we have much yet to learn respecting ozone before we can pronounce definitively whether it is more to be welcomed or dreaded. We must wait until the researches which are in progress have been carried out to their conclusion, and perhaps even then further modes of inquiry will have to be pursued before we can form a definite opinion.
_DEW._
There are few phenomena of common occurrence which have proved more perplexing to philosophers than those which attend the deposition of dew. Every one is familiar with these phenomena, and in very early times observant men had noticed them; yet it is but quite recently that the true theory of dew has been put forward and established. This theory affords a striking evidence of the value of careful and systematic observation applied even to the simplest phenomena of nature.
It was observed, in very early times, that dew is only formed on clear nights, when, therefore, the stars are shining. It was natural, perhaps, though hardly philosophical, to conclude that dew is directly shed down upon the earth from the stars; accordingly, we find the reference of dew to stellar influences among the earliest theories propounded in explanation of the phenomenon.
A theory somewhat less fanciful, but still depending on supposed stellar influences, was shortly put forward. It was observed that dew is only formed when the atmosphere is at a low temperature; or, more correctly, when the air is at a much lower temperature than has prevailed during the daytime. Combining this peculiarity with the former ancient philosophers reasoned in the following manner: Cold generates dew, and dew appears only when the skies are clear—that is, when the stars are shining; hence it follows that the stars generate cold, and thus lead indirectly to the formation of dew. Hence arose the singular theory, that as the sun pours down heat upon the earth, so the stars (and also the moon and planets) pour down cold.
Nothing is more common—we may note in passing—than this method of philosophizing, especially in all that concerns weather-changes; and perhaps it would be impossible to find a more signal instance of the mistakes into which men are likely to fall when they adopt this false method of reasoning; for, so far is it from being true that the stars shed cold upon the earth, that the exact reverse is the case. It has been established by astronomers and physicists that an important portion of the earth’s heat-supply is derived from the stars.
Following on these fanciful speculations came Aristotle’s theory of dew—celebrated as one of the most remarkable instances of the approximation which may sometimes be made to the truth by clever reasoning on insufficient observations. For we must not fall into the mistake of supposing, as many have done, that Aristotle framed hypotheses without making observations; indeed, there has seldom lived a philosopher who has made more observations than he did. His mistake was that he extended his observations too widely, not making enough on each subject. He imagined that, by a string of syllogisms, he could make a few supply the place of many observations.
Aristotle added two important facts to our knowledge respecting dew—namely, first, that dew is only formed in serene weather; and secondly, that it is not formed on the summits of mountains. Modern observations show the more correct statement of the case to be that dew is _seldom_ formed either in windy weather or on the tops of mountains. Now, Aristotle reasoned in a subtle and able manner on these two observations. He saw that dew must be the result of processes which are interfered with when the air is agitated, and which do not extend high above the earth’s surface; he conjectured, therefore, that dew is simply caused by the discharge of vapour from the air. “Vapour is a mixture,” he said, “of water and heat, and as long as water can get a supply of heat, vapour rises. But vapour cannot rise high, or the heat would get detached from it; and vapour cannot exist in windy weather, but becomes dissipated. Hence, in high places, and in windy weather, dew cannot be formed for want of vapour.” He derided the notion that the stars and moon cause the precipitation of dew. “On the contrary, the sun,” he said, “is the cause; since its heat raises the vapour, from which the dew is formed when that heat is no longer present to keep up the vapour.”
Amidst much that is false, there is here a good deal that is sound. The notion that heat is some substance which floats up the vapour, and may become detached from it in high or windy places, is of course incorrect. So also is the supposition that the dew is produced by the _fall_ of condensed vapour as the heat passes away. Nor is it correct to say that the absence of the sun causes the condensation of vapour, since, as we shall presently see, the cold which causes the deposition of dew results from more than the mere absence of the sun. But, in pointing out that the discharge of vapour from the air, owing to loss of heat, is the true cause of the deposition of dew, Aristotle expressed an important truth. It was when he attempted to account for the discharge that he failed. It will be observed, also, that his explanation does not account for the observed fact that dew is only formed in clear weather.
Aristotle’s views did not find acceptance among the Greeks or Romans; they preferred to look on the moon, stars, and planets as the agents which cause the deposition of dew. “This notion,” says a modern author, “was too beautiful for a Greek to give up, and the Romans could not do better than follow the example of their masters.”
In the middle ages, despite the credit attached to Aristotle’s name, those who cultivated the physical sciences were unwilling to accept his views; for the alchemists (who alone may be said to have been students of nature) founded their hopes of success in the search for the philosopher’s stone, the _elixir vitæ_, and the other objects of their pursuit, on occult influences supposed to be exercised by the celestial bodies. It was unlikely, therefore, that they would willingly reject the ancient theory which ascribed dew to lunar and stellar radiations.
But at length Baptista Porta adduced evidence which justified him in denying positively that the moon or stars exercise any influence on the formation of dew. He discovered that dew is sometimes deposited on the inside of glass panes; and again, that a bell-glass placed over a plant in cold weather is more copiously covered with dew within than without; nay, he observed that even some opaque substances show dew on their _under_ surface when none appears on the upper. Yet, singularly enough, Baptista Porta rejected that part of Aristotle’s theory which was alone correct. He thought his observations justified him in looking on dew as condensed—not from vapour, as Aristotle thought—but from the air itself.
But now a new theory of dew began to be supported. We have seen that not only the believers in stellar influence, but Aristotle also, looked on dew as falling from above. Porta’s experiments were opposed to this view. It seemed rather as if dew rose from the earth. Observation also showed that the amount of dew obtained at different heights from the ground diminishes with the height. Hence, the new theorists looked upon dew as an exhalation from the ground and from plants—a fine steam, as it were, rising upwards, and settling principally on the under surfaces of objects.
But this view, like the others, was destined to be overthrown. Muschenbroek, when engaged in a series of observations intended to establish the new view, made a discovery which has a very important bearing on the theory of dew: he found that, instead of being deposited with tolerable uniformity upon different substances,—as falling rain is, for instance, and as the rising rain imagined by the new theorists ought to be,—dew forms very much more freely on some substances than on others.
Here was a difficulty which long perplexed physicists. It appeared that dew neither fell from the sky nor arose from the earth. The object itself on which the dew was formed seemed to play an important part in determining the amount of deposition.
At length it was suggested that Aristotle’s long-neglected explanation might, with a slight change, account for the observed phenomena. The formation of dew was now looked upon as a discharge of vapour from the air, this discharge not taking place necessarily upwards or downwards, but always from the air next to the object. But it was easy to test this view. It was understood that the coldness of the object, as compared with the air, was a necessary element in the phenomenon. It followed, that if a cold object is suddenly brought into warm air, there ought to be a deposition of moisture upon the object. This was found to be the case. Any one can readily repeat the experiment. If a decanter of ice-cold water is brought into a warm room, in which the air is not dry—a crowded room, for example—the deposition of moisture is immediately detected by the clouding of the glass. But there is, in fact, a much simpler experiment. When we breathe, the moisture in the breath generally continues in the form of vapour. But if we breathe upon a window-pane, the vapour is immediately condensed, because the glass is considerably colder than the exhaled air.
Comments
Log in to leave a comment.
Pleasant Ways in ScienceChapter XIV: Part 14
0%37 min left in chapter