Chapter XIII: Part 13
His method of applying the test is as follows: Cut the specimens into two-inch cubes, with flat sides and sharp edges and corners, mark each specimen with a number, either by ink or scratching, and enter in a book all particulars concerning it. Make a saturated solution of the sulphate of soda in rain or distilled water, by adding the salt until no more will dissolve; perfect saturation being shown by finding, after repeated stirring, that a little of the salt remains at the bottom an hour or two after the solution was made. Heat this solution in a suitable vessel, and when it boils put in the marked specimens one by one, and keep them immersed in the boiling solution for half an hour. Take out the specimens separately and suspend them by threads, each over a separate vessel containing some of the liquid in which they were boiled, but which has been carefully strained to free it from any solid particles. In the course of a day or two, as the cubes dry, they will become covered with an efflorescence of snow-like crystals; wash these away by simply plunging the specimen into the vessel below, and repeat this two or three times daily for four or five days or longer. The most suitable vessel for the purpose is a glass “beaker,” sold by vendors of chemical apparatus.
In comparing competing samples, be careful to treat all alike, _i.e._, boil them together in the same solution, and dip them an equal number of times at equal intervals.
Having done this, the result is now to be examined. If the stone is completely resistant the cube will remain smooth on its surfaces and sharp at its edges and corners, and there will be no particles at the bottom of the vessel. Otherwise, the inability of the stone to resist the test will be shown by the disfigurement of the cube or the small particles wedged off and lying at the bottom of the liquid. Care must be taken not to confound these with crystals of the salt which may also be deposited. These crystals are easily removed by adding a little more water or warming the solution.
For strict comparison the fragments thus separated should be weighed in a delicate balance, such as is used in chemical analysis.
THE CORROSION OF BUILDING STONES.
About fifty years ago two eminent French chemists visited London, and rather “astonished the natives” by a curious feature of their dress. They wore on their hats large patches of colored paper. Coming, as they did, from Paris, many supposed that this was one of the latest Paris fashions, and the dandies of the period narrowly escaped the compulsion to follow it. They probably would have done so had the Frenchmen shown any attempt at decorative shaping of the paper. They neglected this because it was litmus paper, and their object in attaching it to their hats was to test the impurities of the London atmosphere.
Blue litmus paper, as everybody knows now-a-days, turns red when exposed to an acid. The French chemists found that their hat-decorations changed color, and indicated the presence of acid in the air of London; but when they left the metropolis and wandered in the open fields their blue litmus paper retained its original color. By using alkaline paper they contrived to collect enough of the acid to test its composition. They found it to be the acid which is formed by the burning of sulphur, and attributed its existence to the sulphur of our coal. At this time the domestic use of coal was scarcely known in Paris.
Subsequent experiments have proved that they were right; that the air of London contains a very practical quantity of sulphurous and sulphuric acids, which are due to the combustion of that yellow shining material more or less visible in most kinds of coal, and has been occasionally supposed to be gold. It is iron pyrites, a compound of iron and sulphur. When heated the sulphur is separated and burns, producing sulphurous acid, which, exposed to moist air, gradually takes up more oxygen and becomes sulphuric acid, which in concentrated solution is oil of vitriol. In the air it is very much diluted by diffusion, but is still strong enough to do mischief to some kinds of building materials.
In manufacturing towns, such as Birmingham and Sheffield, the quantity of this acid in the air is much greater than in London, and there its mischief is consequently more distinctly visible. The church of St. Philip, which stands nearly in the middle of Birmingham, and is surrounded by an old churchyard, was so corroded by this acid that the stone peeled away on all sides, and its condition was most deplorable. The tombstones were similarly disintegrated on their surfaces, and inscriptions quite obliterated. It became so bad that a few years ago restoration was necessary, and it was newly faced accordingly.
Some of the old tombstones that are preserved may still be seen against the church wall, and their peculiar structure is well worthy of study. They display a lamination or peeling away due to unequal corrosion, certain layers of the material of the stone having been evidently eaten away more rapidly than others. Anybody visiting Birmingham may easily examine these, as St. Philip’s churchyard is situated between the two railway stations of New Street and Snow Hill, and is but two minutes’ walk from either.
Other stone buildings in the town have suffered, but in very different degrees, and some have quite escaped, proving the necessity of careful selection of material wherever coal fires abound. In Birmingham the action of coal fires is assisted by other sources of acid vapor. The process of “pickling” brass castings, _i.e._, brightening their surface, by dipping first in common nitric acid (“pickle acky”) and then in water, is attended with considerable evolution of acid fumes. Besides this very widespread use of acid, there are several chemical manufactories that throw still more acid into the air immediately surrounding them.
As an example of the action of the atmospheric acids of London upon building stones, I have but to name the Houses of Parliament, which have only been rescued from superficial ruin by the patchwork replacing of certain blocks of stone, and various devices of siliceous and other washings that have been carried out at great cost to the nation. That such an unsuitable material should have been used is disgraceful to all concerned. The ruin commenced before the building was finished. At the time when its erection commenced there were abundant evidences of the ruinous action of London atmosphere on some kinds of stone and the capability of others to resist it, for while many modern buildings are peeling and crumbling, some of the oldest in the midst of the city show scarcely any signs of corrosion.
The Birmingham and Midland Institute was established and in practical operation a few years before the present noble building was erected. I was the first teacher there and conducted the Science classes in the temporary premises in Cannon street. Having observed with some interest the disintegration of St. Philip’s Church and other buildings, I was anxious for the safety of the new Institute buildings, and accordingly made some experiments upon the material proposed to be used by the architect. My method of testing was very simple, and as the practical result has verified my anticipations I think it might be adopted by others.
First, I immersed some lumps of the stone in moderately strong solutions of sulphuric and hydrochloric acids successively, and observed whether any visible action occurred after some days. There was none. I then roughly tested the crushing pressure of small samples in their natural state, and subjected similar sized pieces to the same test after they had been immersed in the acids. I found thus that there were no evidences of internal disintegration even after several days’ immersion, and therefore inferred that the stone would stand the acid vapors of the Birmingham atmosphere. This has been the case with that portion of the building that was built of the material I tested. As I know nothing of the stone which is used for the extension of the building under the present architect, Mr. Chamberlain, I am unable to make any forecast of its probable durability.
The experiments I made at the time named with this and other building materials justified the conclusion that the worst of all material for exposure to acid atmospheres is a sandstone, the particles of which are held together by limestone, or are otherwise surrounded by or intermingled with limestone; and that the best of _ordinary_ material is a pure sandstone quite free from lime. I do not here consider such luxurious material as granite or porphyries.
Compact limestone, such as good homogeneous marble, stands fairly well, although it is slowly corroded. The corrosion, however, in this case, is purely superficial and tolerably uniform. It is a very slow washing away of the surface, without any disintegration such as occurs where a small quantity of limestone acts as binding material to hold together a large quantity of siliceous or sandy material, and where the agglomeration is porous, and the stone is so laid that a downward infiltration of water can take place; for it must be remembered that although the acid originally exists as vapor in the air, it is taken up by the falling rain, and the mischief is directly done to the stone by the acidified water. This, of course, is very weak acid indeed. That which I used for testing the stone was many thousand times stronger, but then I exposed the stone for only a few days instead of many thousand days.
As above stated, my experiments were but rude, but I think it would be quite worth while to construct crushing apparatus capable of registering accurately the pressure used, and to operate with standard solutions of acid upon carefully squared blocks of standard size, and thus to make comparative tests of various samples of stone when competitions for building materials are offered. In the case of the Birmingham and Midland Institute building there was no such competition, the choice was left entirely to the architect, and my examination was unofficially conducted upon the material already chosen with the intent of protesting if it failed. As it stood the test I merely reported the results informally to the architect, the late Sir Edward Barry, no further action being demanded.
FIRE-CLAY AND ANTHRACITE.
For household fire-places, whether open or closed, these may be regarded as the material and the fuel of the future, and should be more generally and better understood than they are.
The merits of fire-clay were fully appreciated and described nearly a hundred years ago by that very remarkable man, Benjamin Thompson, Count of Rumford. Any sound scientific exposition of the relative value of fire-clay and iron as fire-place materials can be little more or less than a repetition of what he struggled to teach at the beginning of the present century.
It is impossible to fairly understand this subject unless we start with a firm grasp of first principles. The business before us is to get as much heat as possible from fuel burning in a certain fashion, and to do this with the smallest possible emission of smoke.
Substances that are hotter than their surroundings communicate their excess of temperature in three different ways; 1st, by _Conduction_; 2d, by _Convection_; 3d, by _Radiation_. All of these are operating in every form of fire-place, but in very different proportions according to certain variations of construction.
To demonstrate the conduction of heat, hold one end of a pin between the finger and thumb, and the other end in the flame of a candle. The experiment will terminate very speedily. Then take a piece of a lucifer match of the same length as the pin, and hold that in the candle. This may become red-hot and flaming without burning the fingers, as the pin did at a much lower temperature. It matters not whether the pin be held upwards, downwards, or sideways, the heat will travel throughout its substance, and this sort of traveling is called “conduction,” and the pin a “conductor” of heat. The conducting power of different substances varies greatly, as the above experiment shows. Metals generally are the best conductors, but they differ among themselves; silver is the best of all, copper the next. Calling (for comparison sake) the conductivity of silver 1000, that of copper is 736, gold 532, brass 236, iron 119, marble and other building stones 6 to 12, porcelain 5, ordinary brick earth only 4, and fire-brick earth less than this. Thus we may at once start upon our subject, with the practical fact that iron conducts heat thirty times more readily than does fire-brick.
_Convection_ is different from conduction, inasmuch as it is effected by the movements of the something which has been heated by contact with something else. Water is a very bad conductor of heat, much worse than fire-brick, and yet, as we all know, heat is freely transmitted by it, as when we boil water in a kettle. If, however, we placed the water in a fire-clay kettle, and applied the heat at the top we should have to wait for our tea until to-morrow or the next day. When the heat is applied below, the hot metal of the kettle heats the bottom film of water by _direct contact_; this film expands, and thus, being lighter, rises through the rest of the water, heating other portions by contact as it meets them, and so on throughout. The heat is thus conveyed, and the term “convection” is based on the view that each particle is a carrier of heat as it proceeds. Air conveys heat in the same manner; so may all gases and liquids, but no such convection is possible in solids. The common notion that “heat ascends” is based on the well-known facts of convection. It is the heated gas or liquid that really ascends. No such preference is given to an upward direction, when heat is conducted or radiated.
_Radiation_ is a flinging off of heat in all directions by the heated body. Radiation from solids is mainly superficial, and it depends on the nature of the heated surface. The rougher and the more porous the surface of a given substance the better it radiates. Bright metals are the worst radiators; lampblack the best, and fire-brick nearly equal to it. To show the effect of surface, take three tin canisters of equal size, one bright outside, the second scratched and roughened, the third painted over with a thin coat of lampblack. Fill each with hot water of the same temperature, and leave them equally exposed. Their rates of radiation will then be measurable by their rates of cooling. The black will cool the most rapidly, the rough canister next, and the bright one the slowest.
Radiant heat may be reflected like light from bright surfaces, the reflecting substance itself becoming heated in a proportion which diminishes just as its reflecting powers increase. Good reflectors are bad radiators and bad absorbers of heat, and the power of _absorbing_ heat, or becoming superficially hot when exposed to radiant heat, is exactly proportionate to radiating efficiency.
Fire-clay is a good absorber of radiant heat, _i.e._, it becomes readily heated when near to hot coals or flames, without requiring actual contact with them. It is an equally good radiator.
Let us now apply these facts to fire-clay in fireplaces, beginning with ordinary open grates used for the warming of apartments; first supposing that we have an ordinary old-fashioned grate all made of iron—front, sides, and back, as well as bars, and next that we have another of similar form and position, but all the fire-box and the back and cheeks of the grate made of fire-clay.
It is evident that the fire-clay not in actual contact with the coals, but near to them, will absorb more heat than the iron, and thus become hotter. Even at the same temperature it will radiate much more heat than iron, but being so much hotter this advantage will be proportionately increased. An open fireplace lined throughout with fire-clay thus throws into the room a considerable amount of its own radiation in addition to that thrown out from the coal.
But what becomes of this portion of the heat when the fireplace is all of metal? It is carried up the chimney by convection, for the metal, while it parts with less heat by radiation, gives up more to the air by direct contact. Therefore, if we must burn our coals inside the chimney, we lose less by burning them in a fire-clay box than in a metal box.
Count Rumford demonstrates this, and described the best form of open firegrate that can be placed in an ordinary English hole-in-the-wall fireplace. The first thing to be done, according to his instructions, is to brick up your large square fireplace recess, so that the back of it shall come forward to about 4 inches from the front inside face of the chimney, thus contracting the _throat_ of the chimney, just behind the mantel, to this small depth (Rumford’s device for sweeping need not be here described). The sides or “covings” of this shallowed recess are now to be sloped inwards so that each one shall horizontally be at an angle of 135 deg. to the plane of this new back, and meet it at a distance of six or more inches apart, according to the size of grate required. The covings will thus spread out at right angles with each other, and leave an annular opening to be lined with fire-brick, and run straight up to the chimney. The fire-bars and grate-bottom to be simply let into this as far forward as possible.
By this simple arrangement we get a fire-grate with a narrow flat back and out-sloping sides; all these three walls are of fire-brick; the back radiates perpendicularly across the room; and the sloping sides radiate outwards, instead of merely across the fire from one to the other, as when they are square to the walls.
At Rumford’s time our ordinary fireplaces were square recesses; now we have adopted something like his suggestion in the sloping sides of our register grates, and we bring our fireplaces forward. We have gone backwards in material, by using iron, but this, after all, may be merely due to the ironmongery interest overpowering that of the bricklayers. The preponderance of this interest in the South Kensington Exhibition may account for the fact that Rumford’s simple device was not to be seen in action there. It could not pay anybody to exhibit such a thing, as nobody can patent it, and nobody can sell it. I have seen the Rumford arrangement carried out in office fireplaces with remarkable success. To apply it anywhere requires only an intelligent bricklayer, a few bricks, and some iron bars.
Although nobody exhibited this, a very near approach to it was described in an admirable lecture delivered at South Kensington, by Mr. Fletcher, of Warrington. In one respect Mr. Fletcher goes further than Count Rumford in the application of fire-clay. He makes the bottom of the fire-box of a slab of fire-clay instead of ordinary iron fire-bars. This demands a little more trouble and care in lighting the fire, owing to the absence of bottom-draught, but when the fire is well started the advantages of this further encasing in fire-clay are considerable. They depend upon another effect of the superior radiant and absorbent properties of fire-clay that I will now explain.
So far, I have only described the beneficial effect of its radiation on the room to be heated, but it performs a further duty inside the fireplace itself. Being a bad conductor, it does not readily carry away the heat of the burning coal that rests upon it, and being also an excellent absorber, it soon becomes very hot—_i.e._, superficially hot, or hot where its heat is effective. This action may be seen in a common register stove with fire-clay back and iron sides. When the fire is brisk the back is visibly red-hot, while the sides are still dull. If, after such a fire has burnt itself out, we carefully examine the ashes, there will be found more fine dust in contact with the fire-brick than with the iron—_i.e._, evidence of more complete combustion there; and one of the advantages justly claimed by Mr. Fletcher is, that with his solid fire-clay bottom there will be no unburnt cinders—nothing left but the incombustible mineral ash of the coal. Economy and abatement of smoke are the necessary concomitants of such complete combustion.
A valuable “wrinkle” was communicated by Mr. Fletcher. The powdered fire-clay that is ordinarily sold is not easily applied on account of its tendency to crumble and peel off the back and sides of the stove after the first heating. In order to overcome this, and obtain a fine compact lining, Mr. Fletcher recommends the mixing of the fireclay powder with a solution of water-glass (silicate of soda) instead of simple water. It acts by forming a small quantity of glassy silicate of alumina, which binds the whole of the clay together by its fusion when heated.
Londoners, and, in fact, Englishmen generally, have hitherto regarded anthracite as a museum mineral and a curiosity, rather than an everyday coal-scuttle commodity. If it is to be the fuel of the future, it is very desirable that we should all know something about its merits and demerits, as well as the possibilities of supply.
Anthracite is a natural coke. From its position in the earth, and its relations to bituminous coal, as well as from its composition, we are justified in regarding it as a coal that was originally bituminous, but which has been altered by heat, acting under great pressure. In the great coal-field of South Wales, to which we must look for our main supply of anthracite, we are able to trace the action of heat in producing a whole series of different classes of coal in a single seam, which at one part is highly bituminous—soft, flaming coal, like the Wallsend, then it becomes harder and less bituminous, then semi-bituminous “steam coal,” then less and less flaming, until at last we have the hard, shiny form of purely carbonaceous coal, that may be handled without soiling the fingers, and which burns without flame, like coke or charcoal. This change proceeds as the seam extends from the east towards the west. In some places the coal at the base of a hill may be anthracite, while that on the outcrop above it may be bituminous.
An artificial anthracite may be made by heating coal in a closed vessel of sufficient strength to resist the expansion of the gases that are formed. It differs from coke in being compact, is not porous, and therefore, of course, much denser, a given weight occupying less space.
That we Englishmen should be about the last of all the coal-using peoples to apply anthracite to domestic purposes is a very curious fact, but so it is. In America it is the ordinary fuel, and this is the case in all other countries where it is obtainable at the price of bituminous coal. Our perversity in this respect shows out the more strikingly when we go a little further into the subject by comparing the two classes of coal in reference to our methods of using them, and when we consider the fact that our South Wales anthracite is far superior to the American.
Our open fires only do their small fraction of useful work by radiation. Their convection is all up the chimney. Such being the case, and we being theoretically regarded as rational beings, it might be supposed that for our national and especially radiating fireplaces we should have selected a coal of especial radiating efficiency, but, instead of this, we do the opposite. The flaming coal is just that which flings the most heat up the chimney, and the least into the room, and, as though we were all struggling to destroy as speedily as possible the supposed physical basis of our prosperity, we select that coal which in our particular fire-places burns the most wastefully. If we had closed iron stoves with long stove-pipes in the room, giving to the air the heat they had obtained by the convective action of the flame and smoke, there might be some reason for using the flaming coal, as the flame would thereby do useful work, but, as it is, we stubbornly persist in using only the radiated heat, and at the same time select just the coal which supplies the smallest quantity of what we require.
No scientific dissertation is necessary to prove the superior radiating power of an anthracite fire to anybody who has ever stood in the front of one. This is most strikingly demonstrated by those grates that stand well forward, and are kept automatically filled with the radiant-carbon.
Let us now see _why_ anthracite is a better radiator than bituminous coal. This is due to its chemical composition. Of all the substances that we have upon the earth carbon in its ordinary black form is the best radiator. Anthracite contains from 90 to 94 per cent of pure carbon, bituminous coal from 70 to 85, and much of this being combined with hydrogen burns away as flame. On a rough average we may say that the fixed or solid carbon capable of burning with a smokeless flameless glow, amounts to 65 per cent in ordinary British bituminous coal, against an average of 92 per cent in British anthracite. The advantages of anthracite as a fuel for open radiating grates are nearly in the proportion of these figures. Besides this it contains about half the quantity of ash. Thus we see that from a purely selfish point of view, and quite irrespective of our duty to our fellow-citizens as regards polluting the atmosphere, anthracite is preferable to ordinary coal on economical grounds, supposing we can obtain it at the same price as bituminous coal, which is now the case.
Another great advantage of anthracite is its cleanliness, It may be picked up in the fingers without soiling them, and it is similarly cleanly throughout the house. It produces no “blacks,” no grimy dust, and if it were generally in use throughout London one half of the house-cleaning would be saved. White curtains, blinds, etc., might hang quite four times as long, and then come down not half so dirty as now. The saving in soap alone, without counting labor, would at once return a handsome percentage on the capital outlay required for reconstructing all our fireplaces.
Let us now look on the other side, and ask what are the disadvantages of anthracite, and why is it not at once adopted by everybody? There is really only one disadvantage, viz., the greater difficulty of starting an anthracite fire. Practically this is considerable, seeing that laziness is universal and ever ready to find excuses when an innovation is proposed that stands in its way. To light an anthracite fire in an ordinary fireplace the bellows are required unless a specially suitable draught or fire-lighter is used. Some recommend that an admixture of bituminous coal should be used to start it, but this is a feeble device calculated to lead to total failure, seeing that the sole originator and sustainer of our ordinary use of bituminous coal is domestic ignorance and indolence, and if both kinds of coal are kept in a house a common English servant will stubbornly use the easy-lighting kind, and solemnly assert that the other cannot be used at all. The only way to deal with this obstacle, the human impediment, is to say, “This you must use, or go.” This is strictly just, as a simple enforcement of duty.
At the same time some help should be supplied in the way of artificial modes of creating a draught in starting an anthracite fire. This may be done by temporarily closing the front of the fire by a “blower,” or better still by selecting one of the grates specially devised for burning anthracite, of which so many now are made. Another and rather important matter is to obtain the anthracite in suitable condition. It is a very hard coal, too hard to be broken by the means usually at hand in ordinary houses. For domestic purposes it should always be delivered broken up of suitable size, from that of an egg to a cocoa-nut. For furnaces, of course, large lumps are preferable.
Then, again, anthracite must not be stirred and poked about; once fairly started it burns steadily and brightly, demanding only a steady feeding. The best of the special grates are more or less automatic in the matter of feeding, and thus the trouble of lighting is fully compensated by the absence of any further trouble.
As regards the supply. This for London and the greater part of England will doubtless be derived from the great coal-field of South Wales. The total quantity of available coal in this region after deducting the waste in getting, was estimated by the Government Commissioners at 32,456 millions of tons. It is very difficult or impossible to correctly estimate the proportion of anthracite in this, but supposing it to be one tenth of true anthracite it gives us 3245 millions of tons, or about enough for the domestic supply of the whole country during 100 years, assuming that it shall be used less wastefully than we are now using bituminous coal, which would certainly be the case. But, including the imperfect anthracite, the quantity must be far larger than this, and we have to add the other sources of anthracite.
We need not, therefore, have any present fear of insufficient supply; probably before the 100 years are ended we shall find other sources of anthracite, or even have become sufficiently civilized to abolish altogether our present dirty devices, and to adopt rational methods of warming and ventilating our houses. When we do this any sort of coal may be used.
COUNT RUMFORD’S COOKING-STOVES.
In the preceding chapter I described Count Rumford’s modification of the English open firegrate which eighty years ago was offered to the British nation without any patent or other restrictions. Its non-adoption I believe to be mainly due to this—it was nobody’s monopoly, nobody’s business to advertise it, and, therefore, nobody took any further notice of it; especially as it cannot be made and sold as a separate portable article.
An ironmonger or stove-maker who should go to the expense of exhibiting Rumford’s simple structure of fire-bricks and a few bars, described in the last chapter, would be superseding himself by teaching his customers how they may advantageously do without him.
The same remarks apply to his stoves for cooking purposes. They are not iron boxes like our modern kitcheners, but are brick structures, matters of masonry in all but certain adjuncts, such as bars, fire-doors, covers, oven-boxes, etc., which are very simple and inexpensive. Even some of Rumford’s kitchen utensils, such as the steamers, were cheaply covered with wood, because it is a bad conductor, and therefore wastes less heat than an iron saucepan lid.
Rumford was no mere theorist, although he contributed largely to pure science. His greatest scientific discoveries were made in the course of his persevering efforts to solve practical problems. I must not be tempted from my immediate subject by citing any examples of these, but may tell a fragment of the story of his work so far as it bears upon the subject of cooking-ranges.
He began life as a poor schoolmaster in New Hampshire, when it was a British colony. He next became a soldier; then a diplomatist; then in strange adventurous fashion he traveled on the Continent of Europe, entered the Bavarian service and began his searching reform of the Bavarian army by improving the feeding and the clothing of the men. He became a practical working cook in order that they should be supplied with good, nutritious, and cheap food.
But this was not all. He found Munich in a most deplorable condition as regards mendicity; and took in hand the gigantic task of feeding, clothing, and employing the overwhelming horde of paupers, doing this so effectually that he made his “House of Industry” a true workhouse; it paid all its own expenses, and at the end of six years left a net profit of 100,000 florins.
I mention these facts in conformation of what I said above concerning his practical character. Economical cookery was at the root of his success in this maintenance of a workhouse without any poor-rates.
After doing all this he came to England, visited many of our public institutions, reconstructed their fireplaces, and then cooked dinners in presence of distinguished witnesses, in order to show how little need be expended on fuel, when it is properly used.
At the Foundling Institution in London he roasted 112 lbs. of beef with 22 lbs. of coal, or at a cost of less than threepence. The following copy of certificate, signed by the Councillor of War, etc., shows what he did at Munich: “We whose names are underwritten certify that we have been present frequently when experiments have been made to determine the expense of fuel in cooking for the poor in the public kitchen of the military workhouse at Munich, and that when the ordinary dinner has been prepared for 1000 persons, the expense for fuel has not amounted to quite 12 kreutzers.” Twelve kreutzers is about 4½_d._ of our money. Thus only 1-50th of a farthing was expended on cooking each person’s dinner, although the peas which formed the substantial part of the soup required five hours, boiling. The whole average daily fuel expenses of the kitchen of the establishment amounted to 1-20th of a farthing for each person, using wood, which is much dearer than coal. At this rate, _one ton of wood should do the cooking for ten persons during two years and six days, or one ton of coal would supply the kitchen of such a family three and a half years_.
The following is an abstract of the general principles which he expounds for the guidance of all concerned in the construction of cooking stoves.
1. All cooking fires should be enclosed.
2. Air only to be admitted from below and under complete control. All air beyond what is required for the supply of oxygen “is a thief.”
3. All fireplaces to be surrounded by non-conductors, _brickwork, not iron_.
4. The residual heat from the fireplace to be utilized by long journeys in returning flues, and by _doing the hottest work first_.
5. Different fires should be used for different work.
The first of these requirements encounters one of our dogged insular prejudices. The slaves to these firmly believe that meat can only be roasted by hanging it up to dry in front of an open fire; their savage ancestors having held their meat on a skewer or spit over or before an open fire, modern science must not dare to demonstrate the wasteful folly of the holy sacrifice. Their grandmothers having sent joints to a bakehouse, where other people did the same, and having found that by thus cooking beef, mutton, pork, geese, etc., some fresh, and some stale, in the same oven, the flavors became somewhat mixed, and all influenced by sage and onions, these people persist in believing that meat cannot be roasted in any kind of closed chamber.
Rumford proved the contrary, and everybody who has fairly tried the experiment knows that a properly ventilated and properly heated roasting oven produces an incomparably better result than the old desiccating process.
Rumford’s roaster was a very remarkable contrivance, that seems to have been forgotten. It probably demands more intelligence in using it than is obtainable in a present-day kitchen. When the School Boards have supplied a better generation of domestic servants we may be able to restore its use.
It is a cylindrical oven with a double door to prevent loss of heat. In this the meat rests on a grating over a specially constructed gravy and water dish. Under the oven are two “blow-pipes,” _i.e._, stout tubes standing just above the fire so as to be made red hot, and opening into the oven at the back, and above the fireplace in front, where there is a plug to be closed or open as required. Over the front part of the top of the oven is another pipe for carrying away the vapor. It is thus used: The meat is first cooked in an atmosphere of steam formed by the boiling of water placed in the bottom of the double dish, over which the meat rests. When by this means the meat has been raised throughout its whole thickness to the temperature at which its albumen coagulates, the plugs are removed from the blow-pipes, and _then_ the special action of roasting commences by the action of a current of superheated air which enters below and at the back of the oven, travels along and finds exit above and in front of the steam-pipe before named.
The result is a practical attainment of theoretical perfection. Instead of the joint being dried and corticated outside, made tough, leathery, and flavorless to about an inch of depth, then fairly cooked an inch further, and finally left raw, disgusting, and bloody in the middle, as it is in the orthodox roasting by British cooks, the whole is uniformly cooked throughout without the soddening action of mere boiling or steaming, as the excess of moisture is removed by the final current of hot dry air thrown in by the blow-pipes, which at the same time give the whole surface an uniform browning that can be regulated at will without burning any portion or wasting the external fat.
Rumford’s second rule, that air be admitted only from below, and be limited to the requirements, is so simple that no comment upon it is needed. Although we have done so little in the improvement of domestic fireplaces, great progress has been made in engine furnaces, blast furnaces, and all other fireplaces for engineering and manufacturing purposes. Every furnace engineer now fully appreciates Rumford’s assertion that excess of cold air is a thief.
The third rule is one which, as I have already stated, stands seriously in the way of any commercial “pushing” of Rumford’s kitchen ranges. Those which he figures and describes are all of them masonic structures, not ironmongery; the builder must erect them, they cannot be bought ready-made; but, now that public attention is roused, I believe that any builder who will study Rumford’s plans and drawings, which are very practically made, may do good service to himself and his customers by fitting up a few houses with true Rumford kitcheners, and offering to reconstruct existing kitchen ranges, especially in large houses.
The fourth rule is one that is sorely violated in the majority of kitcheners, and without any good reason. The heat from the fire of any kitchener, whether it be of brick or iron, should first do the work demanding the highest temperature, viz., roasting and baking, then proceed to the boiler or boilers, and after this be used for supplying the bed-rooms and bath-room, and the housemaid, etc., with hot water for general use, as Rumford did in his house at Brompton Row, where his chimney terminated in metal pipes that passed through a water-tank at the top of the house.
Linen-closets may also be warmed by this residual heat.
The fifth rule is also violated to an extent that renders the words uttered by Rumford nearly a century ago as applicable now as then. He said, “Nothing is so ill-judged as most of those attempts that are frequently made by ignorant projectors _to force the same fire to perform different services at the same time_.”
Note the last words, “same time.” In the uses above mentioned the heat does different work successively, which is quite different from the common practice of having flues to turn the flame of one fire in opposite directions, to split its heat and make one fireplace appear to do the work of two.
Every householder knows that the kitchen fire, whether it be an old-fashioned open fireplace, or a modern kitchener of any improved construction, is a very costly affair. He knows that its wasteful work produces the chief item of his coal bill, but somehow or other he is helpless under its infliction. If he has given any special attention to the subject he has probably tried three or four different kinds without finding any notable relief. Why is this? I venture to make a reply that will cover 90 per cent, or probably 99 per cent of these cases, viz., that he has never considered the main source of waste, which Rumford so clearly defines as above, and which was eliminated in all the kitchens that he erected.
Let us suppose the case of a household of ten persons, but which in the ordinary course of English hospitality _sometimes_ entertains twice that number. What do we find in the kitchen arrangements? Simply that there is one fireplace suited for the maximum requirements, _i.e._, sufficient for twenty, even though that number may not be entertained more than half a dozen times in the course of a year. To cook a few rashers of bacon, boil a few eggs, and boil a kettle of water for breakfast, a fire sufficient to cook for a dinner party of twenty is at work. This is kept on all day long, because it is just possible that the master of the house may require a glass of grog at bedtime. There may be dampers and other devices for regulating this fire, but such regulation, even if applied, does very little so long as the capacity of the grate remains, and as a matter of ordinary fact the dampers and other regulating devices are neglected altogether; the kitchen fire is blazing and roaring to waste from 6 or 7 A.M. to about midnight, in order to do about three hours and a half work, _i.e._, the dinner for ten, and a nominal trifle for the other meals.
In Rumford’s kitchens, such as those he built for the Baron de Lerchenfeld and for the House of Industry at Munich, the kitchener is a solid block of masonry of work-bench height at top, and with a deep bay in the middle, wherein the cook stands surrounded by his boilers, steamers, roasters, ovens, etc., all within easy reach, each one supplied by its own separate fire of very small dimensions, and carefully closed with non-conducting doors. Each fire is lighted when required, charged with only the quantity of fuel necessary for the work to be done, and then extinguished or allowed to die out.
It is true that Rumford used wood, which is more easily managed in this way than coal. If we worked as he did, we might use wood likewise, and in spite of its very much higher price do our cooking at half its present cost. This would effect not merely “smoke abatement” but “smoke extinction” so far as cooking is concerned. But the lighting of fires is no longer a troublesome and costly process as in the days of halfpenny bundles of firewood. To say nothing of the improved fire-lighters, we have gas everywhere, and nothing is easier than to fix or place a suitable Bunsen or solid flame burner under each of the fireplaces (an iron gaspipe, perforated _below_ to avoid clogging, will do), and in two or three minutes the coals are in full blaze; then the gas may be turned off. The writer has used such an arrangement in his study for some years past, and starts his fire in full blaze in three minutes quite independent of all female interference.
I have no doubt that ultimately gas will altogether supersede coal for cooking; but this and all other scientific improvements in domestic comfort and economy must be impossible with the present generation of uneducated domestics, whose brains (with few exceptions) have become torpid and wooden from lack of systematic exercise during their period of growth.
THE “CONSUMPTION OF SMOKE.”
A great deal has been spoken and written on this subject, but practically nothing has been _done_. At one time I shared the general belief in its possibility, and accordingly examined a multitude of devices for smoke-consuming, and tried several of the most promising, chiefly in furnaces for metallurgical work, for steam boilers and stills. None of them proved satisfactory, and I was driven to the conclusion that smoke-consumption is a delusion, and further, that _economical_ consumption of smoke is practically impossible. When smoke is once formed, the cost of burning it far exceeds the value of the heat that is produced by the combustion of its very flimsy flocculi of carbon. It is a fiend that once raised cannot be exorcised, a Frankenstein that haunts its maker, and will not be appeased.
To describe in detail the many ingenious devices that have been proposed and expensively patented and advertised for this object, would carry me far beyond the intended limits of this paper. I must not even attempt this for a selected few, as even among them there is none that can be pronounced satisfactory.
The common idea is that if the smoke be carried back to the fire that produced it, and made to pass through it again, a recombustion or consumption of the smoke will take place. This is a mistake, as a little reflection will show. First, let us ask why did this particular fire produce such smoke? Everybody now-a-days can answer this question, as we all know that smoke is a result of imperfect combustion, and, knowing this, it can easily be understood that to return the carbonic acid and excess of carbon to the already suffocated fire can only add smother to smotheration, and make the smoky fire more smoky still.
There is, however, one case in which a fire _appears_ to thus consume its own smoke, but the appearance is delusive. I refer to fires lighted from above. These, if properly managed, are practically smokeless, and it is commonly supposed that smoke passes from the raw coal below through the burning coal above, and is thereby consumed. The fact is, however, that no such smoke is formed. That which under these conditions comes from the coal beneath, when gradually heated by the fire above, is combustible _gas_, and this gas is burned as it passes through the fire. In this case the formation or non-formation of smoke depends mainly on how this gas is burned, whether completely or incompletely. If the air supplied for its combustion is insufficient, smoke will be formed as it is when we turn up an Argand gas-flame so high that the gas is too great in proportion to the quantity of air that can enter the glass chimney.
Herein lies the fundamental principle. We may _prevent_ smoke, though we cannot _cure_ it, and this prevention depends upon how we supply air to the gas which the coal gives off when heated, and upon the condition of this gas when we bring it in contact with the air by which its combustion is to be effected. We must always remember that coal when its temperature is sufficiently heated, whether in a gas retort or fireplace, gives off a series of combustible hydrocarbon gases and vapors, and all we have to do in order to obtain smokeless fires is to secure the complete combustion of these.
Now we know that to burn a given quantity of gas we must supply it with a sufficient quantity of oxygen, _i.e._, of the active principle of the air; but this is not all: we all know well enough that if cold coal-gas and cold air be brought together in any proportion whatever no combustion occurs. A certain amount of heat is necessary to start the chemical combination of oxygen with hydrogen and carbon, which combination is the combustion, or burning.
Therefore, when the coal gas and the air are brought together one or the other, or both, must be heated up to a certain point in order that the combustion be complete. If cold there is no combustion; if insufficiently heated, there is imperfect combustion, however well the supplies may be regulated.
A very simple experiment that anybody may make illustrates this. When an ordinary open fire is burning brightly and clearly without flame, throw a few small pieces of raw coal into the midst of the glowing coals. They will flame fiercely, but without smoking. Then throw a heap of coal or one large lump on a similar fire. Now you will have dense volumes of smoke, and little or no flame, simply because the cooling action of the large bulk of coal in the course of distillation brings the temperature of its gases below that required for their complete combustion.
This simple experiment supplies a most important practical lesson, as well as a philosophical example. The best of all smoke-abatement machines is an intelligent and conscientious stoker, and every contrivance for smoke abatement must, in order to be efficient, either be fed by such a stoker or provided with some automatic arrangement by which the apparatus itself does the work of such a stoker by supplying the fresh fuel just when and where it is wanted.
Cornish experience is very instructive in this respect. The engines that pump the water from the mines do a definitely measurable amount of work, and are made to register this. The stoker is a skilled workman, and prizes are given to those who obtain the largest amount of “duty” from given engines per ton of coal consumed. Instead of pitching his coal in anyhow, cramming his fire-hole, and then sitting down to sleep or smoke in company with his chimney, the Cornish, or other good fireman, feeds little and often, and deftly sprinkles the contents of his shovel just where the fire is the brightest and the hottest, and the bars are the least thickly covered. The result is remarkable. A colliery proprietor of South Staffordshire was visiting Cornwall, and went with a friend to see his works. On approaching the engine-house and seeing a whitewashed shaft with no smoke issuing from its mouth, he expressed his disappointment at finding that the engine was not at work. To all who have been accustomed to the “Black Country,” where coal is so shamefully wasted because it is cheap, the tall clean whitewashed shafts of Cornwall, all so smokeless, present quite an astonishing appearance.
This is not a result of “smoke-consuming” apparatus, but mainly of careful firing. It was in the first place promoted by the high price of coal due to the cost of carriage before the Cornish railways were constructed, and it brought about a curious result. Horse-power for horse-power the cost of fuel for working Cornish pumping engines has been brought below that of pumping engines in the places where the price of coal per ton was less than one-half. Another coal famine that should raise the price of coal in London to 60_s._ per ton, and keep it there for two or three years, would effect more smoke abatement than we can hope to result from the present and many future South Kensington efforts. I need scarcely dwell upon the necessity for a due supply of air. This is well understood by everybody. An over supply of air does mischief, by carrying away wastefully a proportionate quantity of heat. The waste due to this is sometimes very serious.
After reviewing all that has been done, the conclusion that London cannot become a clean, smokeless, and beautiful city, so long as we are dependent upon open fire-grates of anything like ordinary construction, and fed with bituminous coal, is inevitable. The general use of anthracite would effect the desired change, but there is no hope of its becoming general without legislative compulsion, and Englishmen will not submit to this.
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Science in Short ChaptersChapter XIII: Part 13
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