Chapter M: Meizel's Reciprocating Exhauster
At the recent Congress of the Societe Technique de l'Industrie du Gaz en France, M. Meizel, Chief Engineer of the St. Etienne Gas Works, described a new exhauster devised by him on the reciprocating principle, and for which he claims certain advantages over the appliances now in general use. Exhausters constructed on the above-named principle have hitherto, M. Meizel says, been costly to fit up, owing to the necessity for providing machinery and special mechanism for the transmission of motion. This has prevented the employment of cylinders of large dimensions; and, consequently, when the quantity of gas to be dealt with has been considerable, the number of exhausters has had to be increased. The result of this has been inconvenience, which has led to a preference being shown for other kinds of exhausters, notwithstanding the manifest advantages which, in M. Meizel's opinion, those of the reciprocating type possess. The improvement which he has effected in these appliances consists in the application to them of cylinders working automatically; and the general features of the arrangement are shown in the accompanying illustrations.
The principal advantages to be gained by the use of this exhauster are stated by M. Meizel to be the following: Considerably less motive force is necessary than is the case with other exhausters, which require steam engines and all the auxiliary mechanism for the transmission of power. By its quiet and regular action, it prevents oscillation and unsteadiness in the flow of gas in the hydraulic main, as well as in the pipes leading therefrom--a defect which has been found to exist with other exhausters. The bells, being of large area, serve the purpose of a condenser; and as, owing to its density, the tar falls to the bottom of the lower vessels, which are filled with water, contact between the gas and tar is avoided. Although the appliance is of substantial construction, its action is so sensitive that it readily adapts itself to the requirements of production. It may be placed in the open air; and therefore its establishment is attended with less outlay than is the case with other exhausters, which have to be placed under cover, and provided with driving machinery and, of course, a supply of steam.
The total superficial area of the exhauster above described, including the governor, is 150 square feet; and its capacity per 24 hours is 230,000 cubic feet. It works silently, with an almost entire absence of friction; and consequently there are few parts which require lubrication. Exhausters of this type (which, M. Meizel says, could be made available for ventilation purposes, in case of necessity) may be constructed of all sizes, from 500 cubic feet per hour upward.
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AUTOMATIC SIPHON FOR IRRIGATION.
When, at an elevated point in a meadow, there exists a spring or vein of water that cannot be utilized at a distance, either because the supply is not sufficient, or because of the permeability of the soil, it becomes very advantageous to accumulate the water in a reservoir, which may be emptied from time to time through an aperture large enough to allow the water to flow in abundance over all parts of the field.
The storing up of the water permits of irrigating a much greater area of land, and has the advantage of allowing the watering to be effected intermittingly, this being better than if it were done continuously. But this mode of irrigating requires assiduous attention. It is necessary, in fact, when the reservoir is full, to go and raise the plug, wait till the water has flowed out, and then put in the plug again as accurately as possible--a thing that it is not always easy to do. The work is a continuous piece of drudgery, and takes just as much the longer to do in proportion as the reservoir is more distant from one's dwelling. In order to do away with this inconvenience, Mr. Giral, of Langogne (Lozere), has invented a sort of movable siphon that primes itself automatically, however small be the spring that feeds the reservoir in which it is placed. The apparatus (see figure) consists of an elbowed pipe, C A B D E, of galvanized iron, whose extremity, C, communicates with the outlet, R, where it is fixed by means of a piece of rubber of peculiar form that allows the other extremity, B D E, to revolve around the axis, K, while at the same time keeping the outlet pipe hermetically closed. This rubber, whose lower extremity is bent back like the bell of a trumpet, forms a washer against which there is applied a galvanized iron ring that is fixed to the mouth of the outlet pipe by means of six small screws. This ring is provided with two studs which engage with two flexible thimbles, K and L, that are affixed to the siphon by four rivets. These studs and thimbles, as well as the screws, are likewise galvanized. Between the branches, A B D E, of the pipe there is soldered a sheet of galvanized iron, which forms isolatedly a receptacle or air-chamber, F, that contains at its upper part a small aperture, _b_, that remains always open, and, at its lower part, a copper screw-plug, _d_, and a galvanized hook, H.
In the interior of this chamber there is arranged a small leaden siphon, _a b c_, whose longer leg, _a_, passes through the bottom, where it is soldered, and whose shorter one, _c_, ends in close proximity to the bottom. Finally, a galvanized iron chain, G H, fixed at G to the bottom of the reservoir, and provided with a weight, P, of galvanized iron, is hooked at H to the siphon and allows it to rise more or less, according as it is given a greater or less length.
From what precedes, it will be seen that the outlet is entirely closed, so that, in order that the water may escape, it must pass into the pipe in the direction, E D B A C.
This granted, let us see how the apparatus works: In measure as the water rises in the reservoir, the siphon gradually loses weight, and its extremity, B D H, is finally lifted by the thrust, so that the entire affair revolves upon the studs, K, until the chain becomes taut. The apparatus then ceases to rise; but the water, ever continuing to rise, finally reaches the apex, _b_, of the smaller siphon, and, through it, enters the air chamber and fills it. The equilibrium being thus broken, the siphon descends to the bottom, becomes primed, and empties the reservoir. When the level of the water, in descending, is at the height of the small siphon, _a b c_, this latter, which is also primed, empties the chamber, F, in turn, so that, at the moment the large siphon loses its priming, the entire apparatus is in the same state that it was at first.
In short, when the water enters the reservoir, the siphon, movable upon its base, rises to the height at which it is desired that the flow shall take place. Being arrested at this point by the chain, it becomes primed, and sinks, and the water escapes. When the water is exhausted, the siphon rises anew in order to again sink; and this goes on as long as the period of irrigation lasts.
This apparatus, which is simple in its operation, and not very costly, is being employed with success for irrigating several meadows in the upper basin of the Allier.--_Le Genie Civil._
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ASSAY OF EARTHENWARE GLAZE.
Lead oxide melted or incompletely vitrified is still in common use in the manufacture of inferior earthenware, and sometimes leads to serious results. To detect lead in a glaze, M. Herbelin moistens a slip of white linen or cotton, free from starch, with nitric acid at 10 per cent. and rubs it for ten to fifteen seconds on the side of the utensil under examination, and then deposits a drop of a solution of potassium iodide, at 5 per cent. on the part which has been in contact. A lead glaze simply fused gives a very highly colored yellow spot of potassium iodide; a lead glaze incompletely vitrified gives spots the more decided, the less perfect the vitrification; and a glaze of good quality gives no sensible color at all.--_M. Herbelin._
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ON THE ELECTRICAL FURNACE AND THE REDUCTION OF THE OXIDES OF BORON, SILICON, ALUMINUM, AND OTHER METALS BY CARBON.[1]
[Footnote 1: Read at the recent meeting of the American
Association, Ann Arbor, Mich.]
By EUGENE H. COWLES, ALFRED H. COWLES, AND CHARLES F. MABERY.
The application of electricity to metallurgical processes has hitherto been confined to the reduction of metals from solutions, and few attempts have been made to effect dry reductions by means of an electric current. Sir W. Siemens attempted to utilize the intense heat of an electric arc for this purpose, but accomplished little beyond fusing several pounds of steel. A short time since, Eugene H. Cowles and Alfred H. Cowles of Cleveland conceived the idea of obtaining a continuous high temperature on an extended scale by introducing into the path of an electric current some material that would afford the requisite resistance, thereby producing a corresponding increase in the temperature. After numerous experiments that need not be described in detail, coarsely pulverized carbon was selected as the best means for maintaining a variable resistance and at the same time as the most available substance for the reduction of oxides. When this material, mixed with the oxide to be reduced, was made a part of the electric circuit in a fire clay retort, and submitted to the action of a current from a powerful dynamo machine, not only was the oxide reduced, but the temperature increased to such an extent that the whole interior of the retort fused completely. In other experiments lumps of lime, sand, and corundum were fused, with indications of a reduction of the corresponding metal; on cooling, the lime formed large, well-defined crystals, the corundum beautiful red, green, and blue hexagonal crystals.
Following up these results with the assistance of Charles F. Mabery, professor of chemistry in the Case School of Applied Science, who became interested at this stage of the experiments, it was soon found that the intense heat thus produced could be utilized for the reduction of oxides in large quantities, and experiments were next tried on a large scale with a current from two dynamos driven by an equivalent of fifty horse power. For the protection of the walls of the furnace, which were made of fire brick, a mixture of the ore and coarsely pulverized gas carbon was made a central core, and it was surrounded on the sides and bottom by fine charcoal, the current following the lesser resistance of the central core from carbon electrodes which were inserted at the ends of the furnace in contact with the core. In order to protect the machines from the variable resistance within the furnace, a resistance box consisting of a coil of German silver wire placed in a large tank of water was introduced into the main circuit, and a Brush ammeter was also attached by means of a shunt circuit, to indicate the quantity of current that was being absorbed in the furnace. The latter was charged by first filling it with charcoal, making a trough in the center, and filling this central space with the ore mixture, which was covered with a layer of coarse charcoal. The furnace was closed at the top with fire brick slabs containing two or three holes for the escape of the gaseous products of the reduction, and the entire furnace made air-tight by luting with fire clay. Within a few minutes after starting the dynamo, a stream of carbonic oxide issued through the openings, burning usually with a flame eighteen inches in height. The time required for complete reduction was ordinarily about an hour.
The furnace at present in use is charged in substantially the same manner, and the current is supplied by a Brush machine of variable electromotive force driven by an equivalent of forty horse power. A Brush machine capable of utilizing 125 horse power, or two and one-half times as large as any hitherto constructed by the Brush Electric Company, is being made for the Cowles Electric Smelting and Aluminum Company, and this machine will soon be in operation. Experiments already made so that aluminum, silicon, boron, manganese, magnesium, sodium and potassium can be reduced from their oxides with ease. In fact, there is no oxide that can withstand temperatures attainable in this electrical furnace. Charcoal is changed to graphite. Does this indicate fusion or solution of carbon? As to what can be accomplished by converting enormous electrical energy into heat within a limited space, it can only be said that it opens the way into an extensive field for both pure and applied chemistry. It is not difficult to conceive of temperatures limited only by the capability of carbon to resist fusion. The results to be obtained with the large Brush machine above mentioned will be of some importance in this direction.
Since the cost of the motive power is the chief expense in accomplishing reductions by this method, its commercial success is closely connected with the cheapest form of power to be obtained. Realizing the importance of this point, the Cowles Electric Smelting and Aluminum Company has purchased an extensive and reliable water power, and works are soon to be erected for the utilization of 1,200 horse power. An important feature in the use of these furnaces, from a commercial standpoint, is the slight technical skill required in their manipulation. The four furnaces in operation in the experimental laboratory at Cleveland are in charge of two young men twenty years of age, who, six months ago, knew absolutely nothing of electricity. The products at present manufactured are the various grades of aluminum bronze made from a rich furnace product that is obtained by adding copper to the charge of ore, silicon bronze prepared in the same manner, and aluminum silver, an alloy of aluminum with several other metals. A boron bronze may be prepared by the reduction of boracic acid in contact with copper.
As commercial results may be mentioned the production in the experimental laboratory, which averages fifty pounds of 10 per cent. aluminum bronze daily, and it can be supplied to the trade in large quantities at prices based on $5 per pound for the aluminum contained, the lowest market quotation of this metal being at present $15 per pound. Silicon bronze can be furnished at prices far below those of the French manufacturers.
The alloys which the metals obtained by the methods above described form with copper have been made the subject of careful study. An alloy containing 10 per cent. of aluminum and 90 per cent. of copper forms the so-called aluminum bronze with a fine golden color, which it retains for a long time. The tensile strength of this alloy is usually given as 100,000 pounds to the square inch; but castings of our ten per cent. bronze have stood a strain of 109,000 pounds. It is a very hard, tough alloy, with a capacity to withstand wear far in excess of any other alloy in use. All grades of aluminum bronze make fine castings, taking very exact impressions, and there is no loss in remelting, as in the case of alloys containing zinc. The 5 per cent. aluminum alloy is a close approximation in color to 18 carat gold, and does not tarnish readily. Its tensile strength in the form of castings is equivalent to a strain of 68,000 pounds to the square inch. An alloy containing 2 or 3 per cent. aluminum is stronger than brass, possesses greater permanency of color, and would make an excellent substitute for that metal. When the percentage of aluminum reaches 13, an exceedingly hard, brittle alloy of a reddish color is obtained, and higher percentages increase the brittleness, and the color becomes grayish-black. Above 25 per cent. the strength again increases.
The effect of silicon in small proportions upon copper is to greatly increase its tensile strength. When more than 5 per cent. is present, the product is exceedingly brittle and grayish-black in color. It is probable that silicon acts to a certain extent as a fluxing material upon the oxides present in the copper, thereby making the metal more homogeneous. On account of its superior strength and high conductivity for electrical currents, silicon bronze is the best material known for telegraph and telephone wire.
The element boron seems to have almost as marked an effect upon copper as carbon does upon iron. A small percentage in copper increases its strength to 50,000 or 60,000 pounds per square inch without diminishing to any large extent its conductivity.
Aluminum increases very considerably the strength of all metals with which it is alloyed. An alloy of copper and nickel containing a small percentage of aluminum, called Hercules metal, withstood a strain of 105,000 pounds, and broke without elongation. Another grade of this metal broke under a strain of 111,000 pounds, with an elongation equivalent to 33 per cent. It must be remembered that these tests were all made upon castings of the alloys. The strength of common brass is doubled by the addition of 2 or 3 per cent. of aluminum. Alloys of aluminum and iron are obtained without difficulty; one product was analyzed, containing 40 per cent. of aluminum. In the furnace iron does not seem to be absorbed readily by the reduced aluminum when copper is present; but in one experiment a mixture composed of old files, 60 per cent.; nickel, 5 per cent.; and of 10 per cent. aluminum bronze 35 per cent., was melted together, and it gave a malleable product that stood a strain of 69,000 pounds.
When the reduction of aluminic oxide by carbon is conducted without the addition of copper, a brittle product is obtained that behaves in many respects like pig iron as it comes from the blast furnace. The same product is formed in considerable quantities, even when copper is present, and frequently the copper alloy is found embedded in it. Graphite is always found associated with it, even when charcoal is the reducing material, and analysis invariably shows a very high percentage of metallic aluminum. This extremely interesting substance is at present under examination.
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THE COWLES ELECTRIC SMELTING PROCESS.
The use of electricity in the reduction of metals from their ores is extending so rapidly, and the methods of its generation and application have been so greatly improved within a few years, that the possibility of its becoming the chief agent in the metallurgy of the future may now be admitted, even in cases where the present cost of treatment is too high to be commercially advantageous.
The refining of copper and the separation of copper, gold, and silver by electrolysis have thus far attracted the greatest amount of attention, but a commercial success has also been achieved in the dry reduction by electricity of some of the more valuable metals by the Cowles Electric Smelting and Aluminum Company, of Cleveland, Ohio. Both this method of manufacture and the qualities of the products are so interesting and important that it is with pleasure we call attention to them as steps toward that large and cheap production of aluminum that the abundance of its ores and the importance of its physical properties have for several years made the unattained goal of many skillful metallurgists.
The Messrs. Cowles have succeeded in greatly reducing the market value of aluminum and its alloys, and thereby vastly extending its uses, and they are now by far the largest producers in the world of these important products. As described in their patents, the Cowles process consists essentially in the use for metallurgical purposes of a body of granular material of high resistance or low conductivity interposed within the circuit in such a manner as to form a continuous and unbroken part of the same, which granular body, by reason of its resistance, is made incandescent, and generates all the heat required. The ore or light material to be reduced--as, for example, the hydrated oxide of aluminum, alum, chloride of sodium, oxide of calcium, or sulphate of strontium--is usually mixed with the body of granular resistance material, and is thus brought directly in contact with the heat at the points of generation, at the same time the heat is distributed through the mass of granular material, being generated by the resistance of all the granules, and is not localized at one point or along a single line. The material best adapted for this purpose is electric light carbon, as it possesses the necessary amount of electrical resistance, and is capable of enduring any known degree of heat when protected from oxygen without disintegrating or fusing; but crystalline silicon or other equivalent of carbon can be employed for the same purpose. This is pulverized or granulated, the degree of granulation depending upon the size of the furnace. Coarse granulated carbon works better than finely pulverized carbon, and gives more even results. The electrical energy is more evenly distributed, and the current can not so readily form a path of highest temperature, and consequently of least resistance through the mass along which the entire current or the bulk of the current can pass. The operation must necessarily be conducted within an air-tight chamber or in a non-oxidizing atmosphere, as otherwise the carbon will be consumed and act as fuel. The carbon acts as a deoxidizing agent for the ore or metalliferous material treated, and to this extent it is consumed, but otherwise than from this cause, it remains unimpaired.
Fig. I. of the accompanying drawings is a vertical longitudinal section through a retort designed for the reduction of zinc ore, according to this process, and Fig. II. is a front elevation of the same. Fig. III. is a perspective view of a furnace adapted to withstand a very high temperature, and Figs. IV. and V. are respectively longitudinal and transverse sections of the same.
This retort consists of a cylinder, A, made of silica or other non-conducting material, suitably embedded in a body, B, of powdered charcoal, mineral wool, or of some other material which is not a good conductor of heat. The rear end of the retort-cylinder is closed by means of a carbon plate, C, which plate forms the positive electrode, and with this plate the positive wire of the electric circuit is connected. The outer end of the retort is closed by means of an inverted graphite crucible, D, to which the negative wire of the electric circuit is attached. The graphite crucible serves as a plug for closing the end of the retort. It also forms a condensing chamber for the zinc fumes, and it also constitutes the negative electrode. The term "electrode" is used in this case as designating the terminals of the circuit proper, or that portion of it which acts simply as an electrical conductor, and not with the intention of indicating the ends of a line between which there is no circuit connection. The circuit between the "electrodes," so called, is continuous, being established by means of and through the body of broken carbon contained in the retort, A. There is no deposit made on either plate of the decomposed constituents of the material reduced. The mouth of the crucible is closed with a luting of clay, or otherwise, and the opening, _d_, made in the upper side of the crucible, near its extremity, comes entirely within the retort, and forms a passage for the zinc fumes from the retort chamber into the condensing chamber. The pipe, E, serves as a vent for the condensing chamber. The zinc ore is mixed with pulverized or granular carbon, and the retort charged nearly full through the front end with the mixture, the plug, D, being removed for this purpose.
A small space is left at the top, as shown. After the plug has been inserted and the joint properly luted, the electric circuit is closed and the current allowed to pass through the retort, traversing its entire length through the body of mixed ore and carbon. The carbon constituents of the mass become incandescent, generating a very high degree of heat, and being in direct contact with the ore, the latter is rapidly and effectually reduced and distilled. The heat evolved reduces the ore and distills the zinc, and the zinc fumes are condensed in the condensing chamber, precisely as in the present method of zinc making, with this important exception that, aside from the reaction produced by heating carbon in the presence of zinc oxide, the electric current, in passing through the zinc oxide, has a decomposing and disintegrating action upon it, not unlike the effect produced by an electric current in a solution. This action accelerates the reduction, and promotes economy in the process.
Another form of furnace is illustrated by Fig. III., which is a perspective view of a furnace adapted for the reduction of ores and salts of non-volatile metals and similar chemical compounds. Figs. IV. and V. are longitudinal and transverse sections, respectively, through the same, illustrating the manner of packing and charging the furnace.
The walls and floors L L', of the furnace are made of fire bricks, and do not necessarily have to be very thick or strong, the heat to which they are subjected not being excessive. The carbon plates are smaller than the cross section of the box, as shown, and the spaces between them and the end walls are packed with fine charcoal.
The furnace is covered with a removable slab of fireclay, N, which is provided with one or more vents, _n_, for the escaping gases.
The space between the carbon plates constitutes the working part of the furnace. This is lined on the bottom and sides with a packing of fine charcoal, O, or such other material as is both a poor conductor of heat and electricity--as, for example, in some cases, silica or pulverized corundum or well-burned lime--and the charge, P, of ore and broken, granular, or pulverized carbon occupies the center of the box, extending between the carbon plates. A layer of granular charcoal, O', also covers the charge on top. The protection afforded by the charcoal jacket, as regards the heat, is so complete, that with the covering-slab removed, the hand can be held within a few inches of the exposed charcoal jacket; but with the top covering of charcoal also removed and the core exposed, the hand cannot be held within several feet. The charcoal packing behind the carbon plates is required to confine the heat and to protect them from combustion.
With this furnace, aluminum can be reduced directly from its ores; and chemical compounds from corundum, cryolite, clay, etc., and silicon, boron, calcium, manganese, magnesium, and other metals are in like manner obtained from their ores and compounds. The reduction of ores according to this process can be practiced, if circumstances require it, without any built furnace.
At present, the Cowles company is engaged mostly in the producing of aluminum bronze and aluminum silver and silicon bronze. The plant, were it run to its full capacity, is capable of turning out eighty pounds of aluminum bronze, containing 10 per cent. of aluminum daily; or, were it to run upon silicon bronze, could turn out one hundred and twenty pounds of that per day, or, we believe, more aluminum bronze daily than can be produced by all other plants in the world combined. This production, however, is but that of the experimental laboratory, and arrangements are making to turn out a ton of bronze daily, and the works have an ultimate capacity of from eight to ten thousand horse power. The energy consumed by the reduction of the ore is almost entirely electrical, only enough carbon being used to unite with the oxygen of the ore to carry it out of the furnace in the form of the carbon monoxide, the aluminum remaining behind. Consequently, the plant necessary to produce aluminum on a large scale involves a large number of the most powerful dynamos. These are to be driven by water-power or natural gas and marine engines of great capacity.
The retail price of standard 10 per cent. aluminum bronze is $1 per pound avoirdupois, which means less than $9 per pound for aluminum, the lowest price at which it has ever been sold, yet the Cowles company has laid a proposition before the Government to furnish this same bronze in large quantities at very much lower prices than this. The Hercules alloy, castings of which will stand over 100,000 pounds to the square inch tensile strain, sells at 75 c. a pound, and is also offered the Government or other large consumers at a heavy discount. The alloys are guaranteed to contain exactly what is advertised; they are standardized into 10 per cent., 7.5 per cent., 5 per cent. and 2.5 per cent. aluminum bronze before shipment.
The current available at the Cowles company's works was, until recently, 330 amperes, driven by an electromotive force of 110 volts and supplied by two Edison dynamos; but the company has now added a large Brush machine that has a current of 560 amperes and 52 volts electromotive force. We shall, on another occasion, give some particulars of experiments in the reduction of refractory ores by the process.--_Eng. and Mining Jour._
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OPTICAL TELEGRAPHY.[1]
[Footnote 1: Continued from page 8094.]
CRYPTOGRAPHY.--PRESERVATION OF TELEGRAMS.
Optical telegraphy, by reason of its very principle, presents both the advantage and inconvenience of leaving no automatic trace of the correspondence that it transmits. The advantage is very evident in cases in which an optical station falls into the hands of the enemy; on the other hand, the inconvenience is shown in cases where a badly transmitted or badly collated telegram allows an ambiguity to stand subject to dispute. Moreover, in case of warfare between civilized nations that have all the resources of science at their disposal, there may be reason to fear lest one of the enemy's optical stations substitute itself for the corresponding station, and take advantage of the situation to throw confusion into the orders transmitted. The remedy for this appears to reside in the use of cryptography and in the exchange, at various intervals, of certain words that have been agreed upon beforehand, and that the enemy is ignorant of.
As for the automatic preservation of telegrams, the problem has not been satisfactorily solved. It has been proposed to connect the key of the manipulator of the optical apparatus with the manipulator of an ordinary Morse apparatus, thus permitting the telegram to be preserved upon a band of paper. It is unnecessary to say that the space occupied by a dispatch thus transmitted would be considerable; but this is not what has stopped innovators. The principal objection resides in the increase in muscular work imposed by this arrangement upon the telegrapher. Obliged to keep his eye fixed intently at the receiving telescope, while at the same time maneuvering the manipulator and spelling aloud the words that he is receiving, the operator should have a very sensitive manipulator at his disposal, and not be submitted to mental or physical overtaxation. So the apparatus that have been devised have not met with much success.
Two French officers, working independently, have hit upon the same idea of receiving the indications transmitted by the vibration of the luminous fascicle directly upon their travel. The method consists in the use of that peculiar property of selenium of becoming a good conductor under the action of a luminous ray, while in darkness it totally prevents the passage of the electric current. Such modification of the physical properties of selenium, moreover, occurs without the perceptible development of any mechanical work. If, then, in the line of travel of the luminous fascicle emitted by the optical apparatus, or in a portion of such fascicle, we interpose a fragment of selenium connected with the two poles of a local pile, it is easy to see that the current from the latter will be opened or closed according as the luminous ray from the apparatus will or will not strike the selenium, and that the length of time during which the current passes will depend upon the length of the luminous attacks. A Morse apparatus interposed in this annexed circuit will therefore give an automatic inscription of the correspondence exchanged. Such is the principle. But, practically, very great difficulties present themselves, these being connected with the rapid weakening of the electric properties of the selenium, and with the necessity of having recourse to infinitely small mechanical actions only. The problem is nevertheless before us, and it is to be hoped that the perseverance of the scientists who are at work upon it will some day succeed in solving it.
Finally, we may call attention to the attempts made to receive the luminous impression upon a band prepared with gelatino-bromide of silver. In practice this band would unwind uniformly at the focus of the receiving telescope, which would be placed in a box, forming a camera obscura. The velocity of this band prepared for photographing the signals would be regulated by clockwork. The experiments that have been made have not given results that are absolutely satisfactory, by reason of the length of the signals received and the mechanical complication of the device.
OPTICAL TELEGRAPHY BY MEANS OF PROJECTORS.
The projectors employed for lighting to a distance the surroundings of a stronghold or of a ship have likewise been applied in optical telegraphy. For this purpose Messrs. Sautter, Lemonnier & Co. have added to their usual projecting apparatus some peculiar arrangements that permit of occultations of the luminous focus at proper intervals. Figs. 21 and 22 show the arrangement of the apparatus, the principle of which is as follows: When the axis of the projector points toward the clouds, and in the direction occupied by a corresponding station, the occultations of the luminous source placed in the focus of the apparatus produce upon the clouds, which act as a screen, an alternate series of flashes and extinctions. It is therefore possible with this arrangement, and by the use of the Morse alphabet, to establish an optical communication at a distance. The use of this projector (the principal inconvenience of which is that it requires a clouded sky) even permits two observers who are hidden from each other by the nature of the ground to easily communicate at a distance of 36 or 48 miles.
USE OF THE PROJECTOR IN OPTICAL TELEGRAPHY.
(Scale 1/15). A. Elliptical mirror. B. Arm of the same. C. Nut for fixing the mirror. D. Support of the mirror. E. Occultator. F. Support for same. G. Lever for maneuvering the occultator. I. Support of the occultator rod. J. Screw for fixing the mirror support. K. Screw for fixing the support of the occultator rod. L. Screw for fixing the occultator support.]
The apparatus shown in Figs. 21 and 22 permits of signaling in three ways:
1. _Upon the Clouds._--In this case the mirror, A, is removed, and the projector inclined above the horizon in such a way as to illuminate the clouds to as great a distance as possible. A maneuver of the occultator, E, between the lamp and the mirror arrests the luminous rays of the source, or allows them to pass, and thus produces upon the clouds the dots and dashes of the conventional alphabet.
2. _Isolated Communication by Luminous Fascicles._--When it is desired to correspond to a short distance of 2 or 3 miles, and establish a communication between two isolated posts, the mirror, A, is put in place upon its support, B. The luminous fascicle emanating from the source reflected by the mirror is thrown vertically. By revolving the mirror 90° around its horizontal axis the fascicle becomes horizontal, and may thus be thrown in a given direction at unequal intervals and during irregular times, and furnish conventional signs.
3. _Night Communication upon the Entire Horizon._--When we wish to correspond at a short distance, say two miles, and make signals visible from the entire horizon, the mirror, A, is put in place, so that it shall reflect the luminous fascicle vertically. The fascicle, at a distance of about fifty feet, meets a white balloon which it renders visible from every point in the horizon. The maneuver of the occultator brings the balloon out of darkness or plunges it thereinto again, and thus produces the signs necessary for aerial communication.
These ingenious arrangements, which depend upon the state of the atmosphere, do not appear to have been imitated outside of the navy.
CAPT. GAUMET'S OPTICAL TELEGRAPH.
The system of optical communication proposed by Capt. Gaumet, and which he names the _Telelogue_, is based upon the visibility of colored or luminous objects, and upon the possibility of piercing the opaque curtain formed by the atmosphere between the observer's eye and a signal, by utilizing the difference in brightness that exists between such objects and the atmosphere. It is a question, then, of giving such difference in intensity its maximum of brightness. To do this, Capt. Gaumet proposes to employ silvered signals upon a black background. He uses the simple letters of the alphabet, but changes their value. His apparatus has the form of a large album glued at the back to a sloping desk. Each silvered letter, glued to a piece of black cloth, is seen in relief upon the open register. A sort of index along the side, as in commercial blank-books, permits of quickly finding any letter at will. Such is the manipulator of the apparatus.
The receiver consists of a spy-glass affixed to the board that carries the register. For a range of two and a half miles, the complete apparatus, with a 12×16 inch manipulator and telescope, weighs but four and a half pounds. For double this range, with a 20×28 inch manipulator and telescope, the total weight is thirteen pounds. The larger apparatus, according to the inventor, have a range of seven miles.
For night work the manipulator is lighted either by one lamp, or by two lamps with reflector, placed laterally against it.
This apparatus, although well known, and having been publicly experimented with, has not, to our knowledge, been applied practically. From a military standpoint, its short range will evidently not permit it to compete with optical telegraphic apparatus, properly so called. Perhaps it might rather be of service for private communications between localities not very far apart, since it costs but little and is easily operated.
OPTICAL SIGNALING BETWEEN BODIES OF TROOPS.
Optical communications by signals, during day and night, with experienced men, may, in the absence of telephones, telegraphs, and messengers, render important service when the distance involved is greater than two thousand feet.
This mode of correspondence is based upon the use of the Morse alphabet. The signals are divided into night and day ones. The day signals are made with small flags. When these are wanting, sheets of white cardboard may be used. The night signals are made with a lantern provided with a support, which may be fixed to a wall or upon a bayonet.
In day signaling, the dashes of the Morse alphabet are formed by means of two flags (Fig. 23) held simultaneously at arm's length by the signaler. The dots are formed with a single flag held in the right hand (Fig. 24). In this way it is possible, by extremely simple combinations, to establish a correspondence, and produce any conventional signal. By means of relay stations, the signals may be transmitted from one to another to a great distance.
In signaling with the lantern, long and short interruptions of the luminous source are produced by means of a screen.
OPTICAL TELEGRAPHY BY LUMINOUS BALLOONS.
Various interesting experiments have been made with a view to utilizing luminous captive balloons for optical communications. As we have already seen, this maybe effected by using opaque balloons, and throwing upon them at unequal intervals a luminous fascicle by means of a projector. As for using a luminous source placed in the car of a balloon, that cannot be thought of in the present state of aeronautic science; the continual rotation of the balloon around its axis would render the projection and reception of the signals in a given direction impossible.
OPTICAL TELEGRAPHY IN THE MARINE.
For communicating optically from ship to ship during the day, the marine uses flags of different forms and colors, and flames. Between ships and the land there are used what are called semaphore signals, which are made by means of a mast provided with three arms and a disk placed at the upper part. The combinations of signs thus obtained, which are analogous in principle to those of the Chappe telegraph, permit of satisfactorily communicating to a distance.
On board ship, hand signals are used like those employed by the army for communicating between bodies of troops. For night communications the marine employs lights corresponding to the day flags, as well as rockets, and luminous rays projected by means of reflectors and intercepted by screens.
In conclusion, it may be said that optical telegraphy, which has only within a few years emerged from the domain of theory to enter that of practice, has taken a remarkable stride in the military art and in science. It is due to its processes that Col. Perrier has in recent years been enabled to carry out certain geodesic work that would have formerly been regarded as impracticable, notably the prolongation of the arc of the meridian between France and Spain. Very recently, an optical communication established between Mauritius and Reunion islands, to a distance of 129 miles, with 24 inch apparatus, proved that, in certain cases, the costly laying of a submarine cable may be replaced by the direct emission of a luminous ray.
* * * * *
A NEW STYLE OF SUBMARINE TELEGRAPH.
Mr. F. Von Faund-Szyll has devised an original system of submarine telegraph, which is based upon the well known property that selenium exhibits of modifying its resistance under the influence of luminous rays, and which he styles the _Selen-Differenzialrecorder_.
Contrary to what is found in the other systems hitherto employed, the Faund-Szyll system utilizes the cable current merely for starting the receiving apparatus, which are operated by means of strong local batteries. The result is that the mechanical work that devolves upon the line current, which is, as well known, very weak, is exceedingly reduced.
The system consists of two essential parts: (1) The receiver, properly so called. (2) The relay as well as the registering apparatus or _differenzialrecorder_. The receiver consists of a closed box, K, in the interior of which there is a very intense source of light whose rays escape by passing through apertures, _a a'_, in the front part (Fig. 1).
As a source of light, there may be conveniently employed an incandescent lamp, _g_, capable of giving an intense light, and arranged (as shown in Fig. 2) behind the side that contains the slits, _a a'_.
The starting apparatus consists of a small galvanometric helix, _r_, analogous to Thomson's siphon recorder, which is suspended from a cocoon fiber and capable of moving in an extremely powerful magnetic field, N S. This helix carries, as may be seen in Figs. 1, 3 and 4, a prolongation, _v_, at its lower end whose form is that of a prism, and which is arranged in front of the partition of the box, K, in such a way that it exactly covers the two slits, a and _a_ when the bobbin is at rest, and in this case prevents the luminous rays of the lamp, _g_, from escaping from the box. But, as soon as the current sent through the cable reaches the spirals of the bobbin, through the conductors, _y y'_, the sum of the elementary electrodynamic actions that arise causes the helix to revolve to the right or left, according to the polarity of the current, while at the same time the helix slightly approaches one or the other of the poles of the magnet. The prolongation, _v_, of the helix, being firmly united with the latter, follows it in its motion, and has the effect of permitting the luminous rays to escape through one or the other of the slits, _a a'_, so that the freeing of the luminous fascicle, if such an expression is allowable, is effected.
In order to prevent oscillations, which could not fail to occur after each emission of a current (so that the helix, instead of returning to a position of equilibrium and stopping there, would go beyond it and alternately uncover the slits, _a a'_), the apparatus is provided with a liquid deadener. To this end, the prolongation, _v_, carries a piece, _o_, which dips into a cup containing a mixture of glycerine and water.
We shall now describe the _differenzialrecorder_. Opposite the two slits, _a_ and _a'_, there are two powerful converging lenses, _l_ and _l'_, whose foci coincide with two sorts of selenium plate rheostat, _z_ and _z'_. The result of this arrangement is that as soon as one of the slits, as a consequence of the displacement of the helix, _r_, allows a luminous fascicle to escape, this latter falls upon the corresponding lens, which concentrates it and sends it to the selenium plates just mentioned. Under the influence of the luminous rays, the resistance that the selenium offers to the passage of an electric current instantly changes. At M and M' are placed two horseshoe magnets whose poles are provided with pieces of soft iron that serve as cores to exceedingly fine wire bobbins, _d_. These polarized pieces are arranged in the shape of a St. Andrew's cross, and in such a way that the poles of the same name occupy the two extremities of the same arm of the cross, an arrangement very clearly shown in Fig. 2.
Between the poles of the magnets, M and M', there is a permanent magnet, A, movable around a vertical axis, _i_. Four spiral springs, _f_, whose tension may be regulated, permit of centering this latter piece in such a way that when the current is traversing the spirals of the polar bobbins it is equally distant from the four poles, _n_, _s_, _s'_, and _n'_. Under such circumstances it is evident that a difference in the power of attraction of these four poles, however feeble it be, will result in moving the magnet, A, in one direction or the other around its axis. The energy and extent of such motion may, moreover, be magnified by properly acting upon the four regulating springs.
The bobbins of the magnet, M, are mounted in series with the selenium plates, _z_, the local battery, B, and a resistance box, W. Those of the magnet, M', are in series with _z'_, B', and W'. The local batteries, B and B', are composed of quite a large number of elements. The current from the battery, B, traverses the selenium plates and the bobbins of the magnet, M, and returns to B through the rheostat, W; and the same occurs with the current from B'. The two currents, then, are absolutely independent of one another.
From this description it is very easy to see how the system works. Let us suppose, in fact, that the current which is traversing the spirals of the helix, _r_, has a direction such that the helix in its movement approaches the pole, S; then the prolongation, _v_, will uncover the slit, _a_, which, along with _a'_, had up to this moment been closed, and a luminous fascicle escaping through _a_ will strike the lens, _l'_, and from thence converge upon the selenium plates, _z'_. This is all the duty that the line current has to perform.
The luminous rays, in falling upon the selenium plates, _z'_, modify the resistance that these offered to the passage of the current produced by the battery, B'. As this resistance diminishes, the intensity of the current in the circuit supplied by the battery, B', increases, the attractive action of the polar pieces of the magnet, M', diminishes, the equilibrium is destroyed, and the piece, A, revolves around the axis, _i_. If the polarity of the line current were different, the same succession of phenomena would occur, save that the direction of A's rotation would be contrary. As for the rheostats, W W', their object is to correct variations in the selenium's resistance and to balance the resistances of the two corresponding circuits. The magnet, A, will be combined with a registering apparatus so as to directly or indirectly actuate the printing lever. The entire first part of this apparatus, which is very sensitive, may be easily protected from all external influence by placing it in a box, and, if need be, in a room distant from the one in which the employes work.
The _differenzialrecorder_ alone has to be in the work room.
As may be seen, the system is not wanting in originality. Experience alone will permit of pronouncing upon the question as to whether it is as practical as ingenious.--_La Lumiere Electrique._
* * * * *
A NEW CIRCUIT CUTTER.
Messrs. Thomson & Bottomley have recently invented a peculiar circuit cutter based upon the use of a metal whose melting point is exceedingly low. Recourse is had to this process for breaking the current within as short a time as possible. In this new device the ends of the conductors are soldered together with the metal in question at one or several points of the circuit. The metal employed is silver or copper of very great conductivity, seeing that the increase of temperature in a conductor, due to a sudden increase of the current, is inversely proportional to the product of the electric resistance by the specific heat of the conductor; that these metals are best adapted for giving constant and definite results; and that the contacts are better than with lead or the other metals of low melting point which are frequently employed in circuit cutters.
Fig. 1 represents one form of the new device. Here, a is the copper or silver wire, and _b_ is a soldering made with a very fusible metal and securing a continuity of the circuit. Each extremity of the wire, _a_, is connected with a heavy ring, _c_, of copper or other good conducting metal. The hook, _d_, with which the upper ring, _c_, is in contact, communicates metallically with one of the extremities of the conductor at the place where the latter is interrupted for the insertion of the circuit cutter. The hook, _e_, with which the lower ring, _c_, is in contact, tends constantly to descend under the action of a spiral spring, _f_, which is connected metallically with the other extremity of the principal conductor. The hooks, _d_ and _e_, are arranged approximately in the same vertical plane, and have a slightly rounded upper and lower surface, designed to prevent the rings, _c_, of the fusible wire, _a_, from escaping from the hooks. In Fig. 1 the position of the arm, _e_, when there is no fusible wire in circuit, is shown by dotted lines. When this arm occupies the position shown by entire lines, it exerts a certain traction upon the soldering, _b_, and separates the two halves of the wire, _a_, as soon as the intensity of circulation exceeds its normal value. The mode of putting the wire with fusible soldering into circuit is clearly shown in the engraving.
Fig. 2 shows a different mode of mounting the wire. The wire, _q_, is soldered in the center, and is bent into the shape of a U, and kept in place by the pieces, _r_ and _s_. In this way the two ends of it tend constantly to separate from each other. Messrs. Thomson & Bottomley likewise employ weights, simply, for submitting the wire to a constant stress. The apparatus is inclosed in a box provided with a glass cover.--_La Lumiere Electrique._
* * * * *
NEW MICRO-TELEPHONIC APPARATUS.
Despite the simplicity of their parts, and the slight value of the materials employed, the existing micro-telephonic apparatus keep at relatively high prices, and the use of them is often rejected, to the benefit of speaking tubes, when the distance between stations is not too great. We propose to describe a new style of apparatus that are in no wise inferior to those in general use, and the price of which is relatively low.
The microphone transmitter may have several forms. The most elementary of these consists of two pieces of carbon, from one to one and a quarter inches in length by one-half inch in width, between which are fixed two _nails_, about two inches in length, whose extremities, filed to a point, enter small conical apertures in the carbons. Fig. 1 gives an idea of the arrangement.
Fig. 2 represents a model which is a little more complicated, but which gives remarkable results. The largest nail is here two inches in length, and the shortest three-quarter inch.
The receivers may be Bell telephones of the simplest form found in the market (Fig. 3); but for these there may be substituted a bar of soft iron, cast iron, or steel, one of the extremities of which is provided with a bobbin upon, which is wound insulated copper wire 0.02 inch in diameter. The apparatus is mounted like an ordinary Bell telephone. A horseshoe electro may also be used, and the poles be made to act (Fig. 4). The current sent by the transmitter suffices to produce a magnetic field in which the variations in intensity produced by the microphone succeed perfectly in reproducing speech and music. With four Leclanche elements, the sounds are perceived very clearly. The elements used may be bichromate of potash ones, those of Lelande and Chaperon, etc.
To this apparatus there may be added a second bobbin of coarser wire into which is passed a current from a local pile. This produces a much intenser magnetic field, and, consequently, louder sounds. This modification, however, is really useful only for long distances.
Any arrangement imaginable may be given the transmitter and receiver; but, aside from the fact that the ones just indicated are the simplest, they give results that are at least equal, if not superior, to all others.
We shall insist here only upon the arrangement of the microphone, which is new (at least in practice), and upon the uselessness of having well magnetized steel bars and wires of extreme fineness in the receiver.
We have stated that the nail microphones are the simplest. The nails may be replaced by copper or any other metal, or they may be well nickelized; but common nails answer very well, and do not oxidize much. An apparatus of this kind (Fig. 5) that has been for more than a year in a laboratory filled with acid vapors is yet working very well. These apparatus possess the further advantage of being very strong, and of undergoing violent shocks without breaking or even getting out of order. They may be used either with or without induction coils. We have not yet measured their range, but can cite the following fact:
One of these apparatus, quite crudely mounted, was put into a circuit with a resistance of 300 ohms. With a single already exhausted bichromate element, giving scarcely 2 volts, musical sounds and speech reached the receiver without being notably weakened. Such resistance represents a length of eighteen miles of ordinary telegraph wire. After this, 700 ohms were overcome with 3.4 volts. This result was obtained by direct transmission, and without an induction coil, and it is probable that it might be much exceeded without sensibly increasing the electromotive force of the current.--_Le Genie Civil._
* * * * *
MESSRS. KAPP AND CROMPTON'S MEASURING INSTRUMENTS.
We give herewith, from the _Elektrotechnische Zeitschrift_, a few interesting details in regard to the measuring apparatus of Messrs. Kapp and Crompton.
It is evident that when we use permanent magnets or springs as directing forces in measuring instruments, we cannot count upon an absolute constancy in the indications, as the magnetism of the magnetized pieces, or the tension of the springs, modifies in time. The apparatus require to be regulated from time to time, and hence the idea of substituting electro-magnets for permanent ones.
If we suppose (Fig. 1) a magnetized needle, _n s_, placed between the extremities of a soft iron core, N S, and if we group the circuit in such a way that the current, after traversing the coil, _e e_, of the electro, traverses a circle, _d d_, situated in a plane at right angles with the plane of the needle's oscillation, it is evident that we shall have obtained an apparatus that satisfies the aforesaid conditions. It seems at first sight that in such an instrument the directing force should be constant from the moment the electro was saturated, and it would be possible, were sufficiently thin cores used, to obtain a constancy in the directing magnetic field for relatively feeble intensities. In reality, the actions are more complex. The needle, _n s_, is, in fact, induced to return to its position of equilibrium by two forces, the first of which (the attraction of the poles, N S) rapidly increases with the intensity so as to become quickly and perceptibly constant, while the second (the sum of the elementary electrodynamic actions that are exerted between the spirals, _e e_, and the needle, _n s_) increases proportionally to the intensity of the current. If we represent these two sections graphically by referring the magnetic moments as ordinates and the current intensities as abscissas to two co-ordinate axes (Fig. 2), we shall obtain for the first force the curve, O A B, which, starting from A, becomes sensibly parallel with the axis of X, and for the second the right line, O D. The resultant action is represented by the curve, O E E'_F. It will be seen that this action, far from being constant, increases quite rapidly with the intensity of the current, so that the deflections would become feebler and feebler for strong intensities, of current; and this, as well known, would render the apparatus very defective from a practical point of view.
But the action of the spirals can be annulled without sensibly diminishing the magnetism of the core by arranging a second system of spirals identical with the first, but placed in a plane at right angles therewith, or, more simply still, by having a single system of spirals comprising the coil of the electro-magnet, but distributed in a plane that is oblique with respect to the needle's position of rest. It then becomes possible, by properly modifying such angle of inclination, to obtain a total directing action that shall continue to increase with the intensity, and which, graphically represented, shall give the curve, O G G'_H, for example (Fig. 2).
This arrangement, which is adopted in Mr. Kapp's instruments, gives very good results, as may be easily seen by reference to Figs. 3 and 4, in which the current intensities or differences of potential are referred as ordinates and the degrees of deflection of the needle as abscissas. The unbroken lines represent the curves obtained with the apparatus just described, while the dotted ones give the curve of deflection of an ordinary tangent galvanometer. These curves show that for strong intensities of current Mr. Kapp's instrument is more advantageous than the tangent galvanometer. Mr. Crompton has constructed an amperemeter upon the same principle, which is shown in Fig. 5.--_La Lumiere Electrique._
* * * * *
THE CHEMICAL ACTION OF LIGHT.
Professor A. Vogel, in a communication to the "Sitzungsberichte der Munchener Akademie," brings into prominence the fact that the hemlock plant, which yields coniine in Bavaria, contains none in Scotland. Hence he concludes that solar light plays a part in the generation of the alkaloids in plants. This view is corroborated by the circumstance that the tropical cinchonas, if cultivated in our feebly lighted hothouses, yield scarcely any alkaloids. Prof. Vogel has proved this experimentally. He has examined the barks of cinchona plants obtained from different conservatories, but has not found in any of them the characteristic reaction of quinine. Of course it is still possible that quinine might be discovered in other conservatory-grown cinchonas, especially as the specimens operated upon were not fully developed. But as the reaction employed indicates very small quantities of quinine, it may be safely assumed that the barks examined contained not a trace of this alkaloid, and it can scarcely be doubted that the deficiency of sunlight in our hothouses is one of the causes of the deficiency of quinine.
It will at once strike the reader as desirable that specimens of cinchonas should be cultivated in hothouses under the influence of the electric light, in addition to that of the sun.
If sunlight can be regarded as a factor in the formation of alkaloids in the living plant, it has, on the other hand, a decidedly injurious action upon the quinine in the bark stripped from the tree. On drying such bark in full sunlight the quinine is decomposed, and there are formed dark-colored, amorphous, resin-like masses. In the manufacture of quinine the bark is consequently dried in darkness.
This peculiar behavior of quinine on exposure to sunlight finds its parallel in the behavior of chlorophyl with the direct rays of the sun. It is well known that the origin of chlorophyl in the plant is entirely connected with light, so that etiolated leaves growing in the dark form no chlorophyl. But as soon as chlorophyl is removed from the sphere of vegetable life, a brief exposure to the direct rays of the sun destroys its green color completely.
Prof. A. Vogel conjectures that the formation of tannin in the living plant is to some extent influenced by light. This supposition is supported by the fact that the proportion of tannin in beech or larch bark increases from below upward--that is, from the less illuminated to the more illuminated parts, and this in the proportions of 4:6 and 5:10.
Sunny mountain slopes of a medium height yield, according to wide experience, on an average the pine-barks richest in tannin. In woods in level districts the proportion of tannin is greatest in localities exposed to the light, while darkness seems to have an unfavorable effect. Here, also, we must refer to the observation that leaves exceptionally exposed to the light are relatively rich in tannin.
We may here add that in the very frequent cases where a leaf is shadowed by another in very close proximity, or where a portion of a leaf has been folded over by some insect, the portion thus shaded retains a pale green color, while adjacent leaves, or other portions of the same leaf, assume their yellow, red, or brown autumnal tints. If, as seems highly probable, these tints are due to transformation products of tannin, we may not unnaturally conclude that they will be absent where tannin has not been generated.--_Jour. of Science._
* * * * *
EUTEXIA.[1]
[Footnote 1: Read before the Birmingham Philosophical Society,
January 22, 1885.]
By THOMAS TURNER, Assoc. R.S.M., F.C.S., Demonstrator of Chemistry, Mason College.
There are a number of interesting facts, some of which are known to most persons, and many of them have been long recognized, of which, however, it must be owned that the explanation is somewhat obscure, and the connections existing between them have been but recently pointed out. As an example of this, it is well known that salt water freezes at a lower temperature than fresh water, and hence sea-water may be quite liquid while rivers and ponds are covered with ice. Again, it is noticed that mixtures of salts often have a fusing-point lower than that of either of the constituent salts, and of this fact we often take advantage in fluxing operations. Further, it is well known that certain alloys can be prepared, the melting-points of which are lower than the melting-point of either of the constituent metals alone. Thus, while potassium melts at 62.5° C., and sodium at about 98°, an alloy of these metals is fluid at ordinary temperatures, and fusible metal melts below the temperature of boiling water, or more than 110° lower than the melting-point of tin, the most fusible of the three metals which enter into the composition of this alloy. But though these and many similar facts have been long known, it is but recently, owing largely to the labors of Dr. Guthrie, that fresh truths have been brought to light, and a connection shown to exist throughout the whole which was previously unseen, though we have still to acknowledge that at present there is much at the root of the matter which is but imperfectly understood. Still Dr. Guthrie proves a relationship to exist between the several facts we have previously mentioned, and also between a number of other phenomena which at first sight appear to be equally isolated and unexpected, and we are asked to regard them all as examples of what he has called "eutexia."
We may define a eutectic substance as a body composed of two or more constituents, which constituents are in such proportion to one another as to give to the resultant compound body a minimum temperature of liquefaction--that is, a lower temperature of liquefaction than that given by any other proportion.[2] It will be seen at once by this definition that the temperature of liquefaction of a eutectic substance is lower than the temperature of liquefaction of either or any of the constituents of the mixture. And, further, it is plain that those substances only can be eutectic which we can obtain both as liquid and solid, and hence the property of eutexia is closely connected with solution.
[Footnote 2: Guthrie, _Phil. Mag._ [5], xvii., p. 462.]
Following in the natural divisions adopted by Dr. Guthrie, we may consider eutexia in three aspects:
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Scientific American Supplement, No. 508, September 26, 1885Chapter M: Meizel's Reciprocating Exhauster
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