Chapter X: TECHNOLOGY.--Alkali Manufactories.--Present aspect of the (4)
For example, it is now known that three products--gas, oil, and salt or brine--lie within natural receptacles formed by the rock strata in the order of their weight. This law, as has well been said, forms the foundation of all successful boring experiments, and the search for natural fuel, therefore, becomes as easy and as reliable a duty as that for artesian water or for coal. The great oil fever of the West was attended at first, as Professor M'Gee tells us, with much waste of the product. Wells were sunk everywhere, and the oil overflowed the land, tainting the rivers, poisoning the air, and often driving out the prospectors from the field of discovery. In Baku accidents and catastrophes have, similarly, been of frequent occurrence. We read of petroleum flowing from the ground in jets 200 feet high, and as thick as a man's body; we learn how it swept away the huge cranes and other machinery, and how, as it flowed away from the orifices, its course was marked by the formation of rivers of oil many miles in length.
In America the pressure of rock gas has burst open stills weighing over a ton, and has rushed through huge iron tanks and split open the pipes wherewith it was sought to control its progress. The roar of this great stream of natural gas was heard for miles around as it escaped from the outlet, and when it was ignited the pillar of flame illumined the surrounding country over a radius extending in some cases to forty miles. It is clear that man having tapped the earth's stores of natural fuel, stood in danger of having unloosed a monster whose power he seemed unable to control. Yet, as the sequel will show, science has been able to tackle with success the problems of mastering the force and of utilizing the energy which are thus locked up within the crust of the globe.
As regards the chemistry of rock gas, we may remark in the first place that this natural product ranks usually as light carbureted hydrogen gas. In this respect it is not unlike the marsh gas with which everyone is familiar, which is found bubbling up from swamps and morasses, and which constitutes the "will o' the wisp" of romance. In rock gas, marsh gas itself is actually found in the proportion of about 93 per cent. The composition of marsh gas is very simple. It consists of the two elements carbon and hydrogen united in certain proportions, indicated chemically by the symbol CH4. We find, in fact, that rock gas possesses a close relationship, chemically speaking, with many familiar carbon compounds, and of these latter, petroleum itself, asphaltum, coal, jet, graphite or plumbago, and even the diamond itself--which is only crystallized carbon after all--are excellent examples.
The differences between these substances really consist in the degree of fixing of the carbon or solid portion of the product, as it were, which exists. Thus in coal and jet the carbon is of stable character, such as we might expect to result from the slow decomposition of vegetable matter, and the products of this action are not volatile or liable to be suddenly dissociated or broken up. On the other hand, when we deal with the _hydrocarbons_ as they are called, in the shape of rock gas, naphtha, petroleum, tar, asphaltum, and similar substances, we see how the carbon has become subordinated to the hydrogen part of the compounds, with the result of rendering them more or less unstable in their character. As Professor M'Gee has shown us, there is in truth a graduated series leading us from the marsh gas and rock gas as the lightest members of this class of compounds onward through the semi-gaseous naphtha to the fluid petroleum, the semi-fluid tar, the solid asphaltum, and the rigid and brittle substance known as albertite, with other and allied products. Having said so much regarding the chemistry of the fuels of the future, we may now pass to consider their geological record. A somewhat curious distribution awaits the man of science in this latter respect. Most readers are aware that the geologists are accustomed to classify rocks, according to their relative age, into three great groups, known respectively as the primary, secondary, and tertiary periods. In the secondary period we do not appear to meet with the fuels of the future, but as far back as the Devonian or old Red Sandstone period, and in the still older Silurian rocks, stores of gas and petroleum abound. In the latest or tertiary period, again, we come upon nearly all the forms of fuels we have already specified.
The meaning of this geological distribution of the fuels is entirely fortuitous. Dr. M'Gee tells us that as their formation depended on local conditions (such as plant growth), and as we have no means of judging why such local conditions occurred within any given area, so must we regard the existence of fuel products in particular regions as beyond explanation. Of one point, however, we are well assured, namely that the volume of the fuels of the future is developed in an inverse proportion to their geological age. The proportionate volume, as it has been expressed, diminishes progressively as the geological scale is descended. Again, the weight of the fuels varies directly with their age; for it is in the older formation of any series that we come upon the oils and tars and asphaltum, while the marsh gas exists in later and more recently formed deposits. Further geological research shows us that the American gas fields exist each as an inverted trough or dome, a conformation due, of course, to the bending and twisting of the rocks by the great underground heat forces of the world. The porous part of the dome may be sandstone or limestone, and above this portion lie shales, which are the opposite of porous in texture. The dome, further, contains gas above, naphtha in the middle, and petroleum below, while last of all comes water, which is usually very salt. In the Indiana field, however, we are told that the oils lie near the springing or foundation of the arch of the dome, and at its crown gas exists, and overlies brine.
A very important inquiry, in relation to the statement that upon the products whose composition and history have just been described the fuel supply of the future will depend, consists in the question of the extent and duration of these natural gas and oil reservoirs. If we are beginning to look forward to a time when our coal supply will have been worked out, it behooves us to ask whether or not the supply of natural gas and oil is practically illimitable. The geologist will be able to give the coming man some degree of comfort on this point, by informing him that there seems to be no limit to the formation of the fuel of the future.
Natural gas is being manufactured to-day by nature on a big scale. Wherever plant material has been entombed in the rock formations, and wherever its decomposition proceeds, as proceed it must, there natural gas is being made. So that with the prospect of coal becoming as rare as the dodo itself, the world, we are told by scientists, may still regard with complacency the failure of our ordinary carbon supply. The natural gases and oils of the world will provide the human race with combustible material for untold ages--such at least is the opinion of those who are best informed on the subject. For one thing, we are reminded that gas is found to be the most convenient and most economical of fuels. Rock gas is being utilized abroad even now in manufacturing processes. Dr. M'Gee says that even if the natural supply of rock gas were exhausted to-morrow, manufacturers of glass, certain grades of iron, and other products would substitute an artificial gas for the natural product rather than return to coal. He adds that "enormous waste would thereby be prevented, the gas by which the air of whole counties in coke-burning regions is contaminated would be utilized, and the carbon of the dense smoke clouds by which manufacturing cities are overshadowed would be turned to good account." So that, as regards the latter point, even Mr. Ruskin with his horror of the black smoke of to-day and of the disfigurement of sky and air might become a warm ally of the fuel of the future. The chemist in his laudation of rock gas and allied products is only re-echoing, when all is said and done, the modern eulogy pronounced on ordinary coal gas as a cooking and heating medium.
We are within the mark when we say that the past five years alone have witnessed a wonderful extension in the use of gas in the kitchen and elsewhere. It would be singular, indeed, if we should happen to be already anticipating the fuel of the future by such a practice. Whether or not this is the case, it is at least satisfactory for mankind to know that the mother earth will not fail him when he comes to demand a substitute for coal. I may be too early even to think of the day of extinction; but we may regard that evil day with complacency in face of the stores of fuel husbanded for us within the rock foundations of our planet.--_Glasgow Herald._
* * * * *
PORTABLE ELECTRIC LIGHT.
The famous house of MM. Sautter, Lemonnier & Co. takes a conspicuous part in the Paris exhibition, and from the wide range of its specialties exhibits largely in three important branches of industry: mechanics, electricity, and the optics of lighthouses and projectors. In these three branches MM. Sautter, Lemonnier & Co. occupy a leading position in all parts of the world.
The invention of the aplanetic projector, due to Col. Mangin, was a clever means of overcoming difficulties, practically insurmountable, that were inseparable from the construction of parabolic mirrors; this contributed chiefly to the success of MM. Sautter, Lemonnier & Co. in this direction. The firm has produced more than 1,500 of these apparatus, representing a value of nearly £500,000, for the French and other governments.
Besides the great projector, which forms the central and crowning object of the exhibit of MM. Sautter, Lemonnier & Co. in the machinery hall, the firm exhibits a projector 90 centimeters in diameter mounted on a crane traveling on wheels, in the pavilion of the War Department. The lamp used for this apparatus has a luminous value of 6,000 carcels, with a current of 100 amperes; the amplifying power of the mirror is 2,025, which gives an intensity of ten millions to twelve millions of carcels to the beam.
Projectors used for field work are mounted on a portable carriage, which also contains the electric generator and the motor driving it.
It consists of a tubular boiler (Dion, Bouton & Trepardoux system). This generator is easily taken to pieces, cleaned, and repaired, and steam can be raised to working pressure in 20 minutes. The mechanical and electrical part of the apparatus consists of a Parsons turbo-motor, of which MM. Sautter, Lemonnier & Co. possess the license in France for application to military and naval purposes. The speed of the motor is 9,000 revolutions per minute, and the dynamo is driven direct from it; at this speed it gives a current of 100 amperes with and from 55 to 70 volts; the intensity of the light is from 5,500 to 6,000 carcels. The carriage upon which the whole of this apparatus is mounted is carried on four wheels, made of wood with gun metal mountings. These are more easy to repair when in service than if they were wholly of iron. The weight of the carriage is three tons.--_Engineering._
* * * * *
ELECTRIC MOTOR FOR ALTERNATING CURRENTS.
Prof. Galileo Ferraris, of Turin, who has carefully studied alternating currents and secondary transformers, has constructed a little motor based upon an entirely new principle, which is as follows: If we take two inductive fields developed by two bobbins, the axes of which cut each other at right angles, and a pole placed at the vertex of the angle, this pole will be subjected to the simultaneous action of the two bobbins, and the resultant of the magnetic actions will be represented in magnitude and direction by the diagonal of the parallelogram, two consecutive sides of which have for their length the intensity of the two fields, and for their direction the axes of the two bobbins.
If into each of these bobbins we send alternating currents having between one bobbin and the other a difference of phase of 90°, the extremity of the resultant will describe a circle having for its center the vertex of the right angle.
If, instead of a fixed pole, we use a metal cylinder movable on its axis, we shall obtain a continuous rotatory motion of this part, and the direction of the movement will change when we interchange the difference of phase in the exciting currents. This rotatory movement is not due to the Foucault currents, for the metal cylinder may consist of plates of iron insulated from each other.
In order to realize the production of these fields, several means can be employed: The current is sent from an alternating current machine into the primary circuit of a transformer and thence into one of the bobbins, the other being supplied by means of the secondary current of the transformer. A resistance introduced into the circuit will produce the required difference of phase, and the equality of the intensities of the fields will be obtained by multiplying the number of turns of the secondary wire on the bobbin. Moreover, the two bobbins may be supplied by the secondary current of a transformer by producing the difference of phase, as in the first case.
In the motor constructed by Prof. Ferraris the armature consisted of a copper cylinder measuring 7 centimeters in diameter and 15 centimeters in length, movable on its axis. The inductors were formed of two groups of two bobbins. The bobbins which branched off from the primary circuit of a Gaulard transformer, and were connected in series, comprised 196 spirals with a resistance of 13 ohms; the bobbins comprising the secondary circuit were coupled in parallel, and had 504 spirals with 3.43 ohms resistance. In order to produce the difference of phase, a resistance of 17 ohms was introduced into the second circuit, when the dynamo produced a current of 9 amperes with 80 inversions per second. Under these conditions the available work measured on the axis of the motor was found for different speeds: Revolutions per minute: 262--400--546--650--722--770. Watts measured at the brake: 1.32--2.12--2.55--2.77--2.55--2.40. The maximum rendering corresponds to a speed of rotation of 650 revolutions, and Prof. Ferraris attributes the loss of work for higher speeds to the vibrations to which the machine is exposed. At present the apparatus is but a laboratory one.--_Bulletin International de l'Electricite._
* * * * *
THE ELECTRIC AGE.
By CHARLES CARLETON COFFIN.
The application of electricity for our convenience and comfort is one of the marvels of the age. Never in the history of the world has there been so rapid a development of an occult science. Prior to 1819 very little was known in regard to magnetism and electricity. During that year Oersted discovered that an electric current would deflect a magnetic needle, thus showing that there was some relationship between electric and magnetic force. A few months later, Arago and Sir Humphry Davy, independently of each other, discovered that by coiling a wire around a piece of iron, and passing an electric current through it, the iron would possess for the time being all the properties of a magnet. In 1825 William Sturgeon, of London, bent a piece of wire in the form of the letter U, wound a second wire around it, and, upon connecting it with a galvanic battery, discovered that the first wire became magnetic, but lost its magnetic property the moment the battery was disconnected. The idea of a telegraphic signal came to him, but the electric impulse, through his rude apparatus, faded out at a distance of fifty feet. In 1830 Prof. Joseph Henry, of this country, constructed a line of wire, one and a half miles in length, and sent a current of electricity through it, ringing a bell at the farther end. The following year Professor Faraday discovered magnetic induction. This, in brief, is the genesis of magnetic electricity, which is the basis of all that has been accomplished in electrical science.
The first advance after these discoveries was in the development of the electric telegraph--the discovery in 1837, by the philosopher Steinhill, that the earth could serve as a conductor, thus requiring but one wire in the employment of an electric current. Simultaneously came Morse's invention of the mechanism for the telegraph in 1844, foreshadowed by Henry in the ringing of bells, thus transmitting intelligence by sound. Four years later, in 1848, Prof. M. G. Farmer, still living in Eliot, Me., attached an electro-magnet to clockwork for the striking of bells to give an alarm of fire. The same idea came to William F. Channing. The mechanism, constructed simply to illustrate the idea by Professor Farmer, was placed upon the roof of the Court House in Boston, and connected with the telegraph wire leading to New York, and an alarm rung by the operator in that city. The application of electricity for giving definite information to firemen was first made in Boston, and it was my privilege to give the first alarm on the afternoon of April 12, 1852.
At the close of the last century, Benjamin Thompson, born in Woburn, Mass., known to the world as Count Rumford, was in the workshop of the military arsenal of the King of Bavaria in Munich, superintending the boring of a cannon. The machinery was worked by two horses. He was surprised at the amount of heat which was generated, for when he threw the borings into a tumbler filled with cold water, it was set to boiling, greatly to the astonishment of the workmen. Whence came the heat? What was heat? The old philosopher said that it was an element. By experiment he discovered that a horse working two hours and twenty minutes with the boring machinery would heat nineteen pounds of water to the boiling point. He traced the heat to the horse, but with all his acumen he did not go on with the induction to the hay and oats, to the earth, the sunshine and rain, and so get back to the sun. One hundred years ago there was no chemical science worthy of the name, no knowledge of the constitution of plants or the properties of light and heat. The old philosophers considered light and heat to be fluids, which passed out of substances when they were too full. Count Rumford showed that motion was convertible into heat, but did not trace the motion to its source, so far as we know, in the sun.
It is only forty-six years since Professor Joule first demonstrated the mutual relations of all the manifestations of nature's energy. Thirty-nine years only have passed since he announced the great law of the convertibility of force. He constructed a miniature churn which held one pound of water, and connected the revolving paddle of the churn with a wheel moved by a pound weight, wound up the weight, and set the paddle in motion. A thermometer detected the change of temperature and a graduated scale marked the distance traversed by the descending weight. Repeated experiments showed that a pound weight falling 772 feet would raise the temperature of water one degree, and that this was an unvarying law. This was transferring gravitation to heat, and the law held good when applied to electricity, magnetism, and chemical affinity, leading to the conclusion that they were severally manifestations of one universal power.--_Congregationalist._
* * * * *
EARLY ELECTRIC LIGHTING.
The opening of the new station of the Electric Lighting Co., of Salem, Mass., was recently celebrated with appropriate festivities.
Among the letters of regret from those unable to attend the opening was the following from Prof. Moses G. Farmer:
"ELIOT, Me., Aug. 5, 1889.
"_To the Salem Electric Lighting Company, Charles H. Price, President_:
"GENTLEMEN: It would give me great pleasure to accept your kind invitation to be present at the opening of your new station in Salem on the 8th of this present August.
"It is now thirty years since the first dwelling house in Salem was lighted by electricity. That little obscure dwelling, 11 Pearl Street, formerly owned by 'Pa' Webb, had the honor to be illuminated by the effulgent electric beam during every evening of July, 1859, as some of your honored residents, perhaps, well remember. Mr. George D. Phippen can doubtless testify to one or more evenings; Mr. Wm. H. Mendell, of Boston, can also add his testimony; dozens of others could also do the same, had not some of them already passed to the 'great beyond,' among whom I well recollect the interest taken by the late and honored Henry L. Williams, Mr. J. G. Felt, and I do not know how many others. I well remember reading some of the very finest print standing with my back to the front wall and reading by the light of a 32 candle power lamp on the northernmost end of the mantel piece in the parlor; very possibly the hole in which the lamp was fastened remains to this day. In a little closet in the rear sleeping room was a switch which could be turned in one direction and give a beautiful glow light, while if turned in the other direction, it instantly gave as beautiful a dark. My then 12 year old daughter used to surprise and please her visitors by suddenly turning on and off the 'glim.' It is not well to despise the day of small things, for although the dynamo had not at that date put in an appearance, and though I used thirty-six Smee cells of six gallons capacity each, yet I demonstrated then and there that the incandescent electric light was a possibility, and although I innocently remarked to the late Samuel W. Bates, of Boston, who with his partner, Mr. Chauncey Smith, furnished so generously in the interest of science, not wholly without hope of return, the funds for the experiment, that it 'did not take much zinc,' and though Mr. Bates as naively replied, 'I notice that it takes some silver, though,' still it was then and there heralded as the coming grand illuminant for the dwelling. I am thankful to have lived to see my predictions partly fulfilled.
"During the early fifties I published a statement something like this: 'One pound of coal will furnish gas enough to maintain a candle light for fifteen hours. One pound of gas (the product of five pounds of coal) will, in a good fishtail gas burner, furnish one candle light for seventy-five hours. One pound of coal burned in a good furnace, under a good boiler, driving a good steam engine, turning a good magneto-electric machine, will give a candle light for one thousand hours. But if all the energy locked up in one pound of pure carbon could be wholly converted into light, it would maintain one candle light for more than one and a half years.'
"So, gentlemen, _nil desperandum_; there is still room for improvement. Let your motto be 'Excelsior.' Possibly you may have already extracted from one-fifteenth to one-twelfth of the energy stored in the pound of carbon, but hardly more. Go on, go on, and bring it so cheap as to reach the humblest dwelling when you shall celebrate the centennial of the opening of your new station.
"I do most sincerely regret that I cannot be with you in the flesh. I am, like Ixion of old, confined to a wheel (chair in my case), cannot walk, cannot even stand; hence, owing to the impairment of my understanding (???), I must wish you all the enjoyments of the evening, and gladly content myself that you have made so much possible.
"Very truly yours, MOSES G. FARMER."
* * * * *
THE MODERN THEORY OF LIGHT.[1]
[Footnote 1: Being the general substance of a lecture to the
Ashmolean Society in the University of Oxford, on Monday, June
3, 1889. [Reprinted from the _Liverpool University College
Magazine_.]]
By Prof. OLIVER LODGE.
To persons occupied in other branches of learning, and not directly engaged in the study of physical science, some rumor must probably have traveled of the stir and activity manifest at the present time among the votaries of that department of knowledge.
It may serve a useful purpose if I try and explain to outsiders what this stir is mainly about, and why it exists. There is a proximate and there is an ultimate cause. The proximate cause is certain experiments exhibiting in a marked and easily recognizable way the already theoretically predicted connection between electricity and light. The ultimate cause is that we begin to feel inklings and foretastes of theories, wider than that of gravitation, more fundamental than any theories which have yet been advanced; theories which if successfully worked out will carry the banner of physical science far into the dark continent of metaphysics, and will illuminate with a clear philosophy much that is at present only dimly guessed. More explicitly, we begin to perceive chinks of insight into the natures of electricity, of ether, of elasticity, and even of matter itself. We begin to have a kinetic theory of the physical universe.
We are living, not in a Newtonian, but at the beginning of a perhaps still greater Thomsonian era. Greater, not because any one man is probably greater than Newton,[2] but because of the stupendousness of the problems now waiting to be solved. There are a dozen men of great magnitude, either now living or but recently deceased, to whom what we now know toward these generalizations is in some measure due, and the epoch of complete development may hardly be seen by those now alive. It is proverbially rash to attempt prediction, but it seems to me that it may well take a period of fifty years for these great strides to be fully accomplished. If it does, and if progress goes on at anything like its present rate, the aspect of physical science bequeathed to the latter half of the twentieth century will indeed excite admiration, and when the populace are sufficiently educated to appreciate it, will form a worthy theme for poetry, for oratorios, and for great works of art.
[Footnote 2: Though, indeed, a century hence it may be premature
to offer an opinion on such a point.]
To attempt to give any idea of the drift of progress in all the directions which I have hastily mentioned, to attempt to explain the beginnings of the theories of elasticity and of matter, would take too long, and might only result in confusion. I will limit myself chiefly to giving some notion of what we have gained in knowledge concerning electricity, ether, and light. Even that is far too much. I find I must confine myself principally to light, and only treat of the others as incidental to that.
For now well nigh a century we have had a wave theory of light; and a wave theory of light is quite certainly true. It is directly demonstrable that light consists of waves of some kind or other, and that these waves travel at a certain well-known velocity, seven times the circumference of the earth per second, taking eight minutes on the journey from the sun to the earth. This propagation in time of an undulatory disturbance necessarily involves a medium. If waves setting out from the sun exist in space eight minutes before striking our eyes, there must necessarily be in space some medium in which they exist and which conveys them. Waves we cannot have unless they be waves in something.
No ordinary medium is competent to transmit waves at anything like the speed of light; hence the luminiferous medium must be a special kind of substance, and it is called the ether. The _luminiferous_ ether it used to be called, because the conveyance of light was all it was then known to be capable of; but now that it is known to do a variety of other things also, the qualifying adjective may be dropped.
Wave motion in ether, light certainly is; but what does one mean by the term wave? The popular notion is, I suppose, of something heaving up and down, or, perhaps, of something breaking on the shore in which it is possible to bathe. But if you ask a mathematician what he means by a wave, he will probably reply that the simplest wave is
y = a sin (p t - n x),
and he might possibly refuse to give any other answer.
And in refusing to give any other answer than this, or its equivalent in ordinary words, he is entirely justified; that is what is meant by the term wave, and nothing less general would be all-inclusive.
Translated into ordinary English the phrase signifies "a disturbance periodic both in space and time." Anything thus doubly periodic is a wave; and all waves, whether in air as sound waves, or in ether as light waves, or on the surface of water as ocean waves, are comprehended in the definition.
What properties are essential to a medium capable of transmitting wave motion? Roughly we may say two--_elasticity_ and _inertia_. Elasticity in some form, or some equivalent of it, in order to be able to store up energy and effect recoil; inertia, in order to enable the disturbed substance to overshoot the mark and oscillate beyond its place of equilibrium to and fro. Any medium possessing these two properties can transmit waves, and unless a medium possesses these properties in some form or other, or some equivalent for them, it may be said with moderate security to be incompetent to transmit waves. But if we make this latter statement, one must be prepared to extend to the terms elasticity and inertia their very largest and broadest signification, so as to include any possible kind of restoring force and any possible kind of persistence of motion respectively.
These matters may be illustrated in many ways, but perhaps a simple loaded lath or spring in a vise will serve well enough. Pull aside one end, and its elasticity tends to make it recoil; let it go, and its inertia causes it to overshoot its normal position; both causes together cause it to swing to and fro till its energy is exhausted. A regular series of such springs at equal intervals in space, set going at regular intervals of time one after the other, gives you at once a wave motion and appearance which the most casual observer must recognize as such. A series of pendulums will do just as well. Any wave-transmitting medium must similarly possess some form of elasticity and of inertia.
But now proceed to ask what is this ether which in the case of light is thus vibrating? What corresponds to the elastic displacement and recoil of the spring or pendulum? What corresponds to the inertia whereby it overshoots its mark? Do we know these properties in the ether in any other way?
The answer, given first by Clerk Maxwell, and now reiterated and insisted on by experiments performed in every important laboratory in the world, is:
The elastic displacement corresponds to electrostatic charge (roughly speaking, to electricity).
The inertia corresponds to magnetism.
This is the basis of the modern electro-magnetic theory of light. Now let me illustrate electrically how this can be.
The old and familiar operation of charging a Leyden jar--the storing up of energy in a strained dielectric, any electrostatic charging whatever--is quite analogous to the drawing aside of our flexible spring. It is making use of the elasticity of the ether to produce a tendency to recoil. Letting go the spring is analogous to permitting a discharge of the jar--permitting the strained dielectric to recover itself, the electrostatic disturbance to subside.
In nearly all the experiments of electrostatics, ethereal elasticity is manifest.
Next consider inertia. How would one illustrate the fact that water, for instance, possesses inertia--the power of persisting in motion against obstacles--the power of possessing kinetic energy? The most direct way would be to take a stream of water and try suddenly to stop it. Open a water tap freely and then suddenly shut it. The impetus or momentum of the stopped water makes itself manifest by a violent shock to the pipe, with which everybody must be familiar. The momentum of water is utilized by engineers in the "water ram."
A precisely analogous experiment in electricity is what Faraday called "the extra current." Send a current through a coil of wire round a piece of iron, or take any other arrangement for developing powerful magnetism, and then suddenly stop the current by breaking the circuit. A violent flash occurs if the stoppage is sudden enough, a flash which means the bursting of the insulating air partition by the accumulated electro-magnetic momentum.
Briefly, we may say that nearly all electro-magnetic experiments illustrate the fact of ethereal inertia.
Now return to consider what happens when a charged conductor (say a Leyden jar) is discharged. The recoil of the strained dielectric causes a current, the inertia of this current causes it to overshoot the mark, and for an instant the charge of the jar is reversed; the current now flows backward and charges the jar up as at first; back again flows the current, and so on, charging and reversing the charge with rapid oscillations until the energy is all dissipated into heat. The operation is precisely analogous to the release of a strained spring or to the plucking of a stretched string.
But the discharging body thus thrown into strong electrical vibration is embedded in the all-pervading ether, and we have just seen that the ether possesses the two properties requisite for the generation and transmission of waves--viz., elasticity and inertia or density; hence, just as a tuning fork vibrating in air excites aerial waves or sound, so a discharging Leyden jar in ether excites ethereal waves or light.
Ethereal waves can therefore be actually produced by direct electrical means. I discharge here a jar, and the room is for an instant filled with light. With light, I say, though you can see nothing. You can see and hear the spark indeed--but that is a mere secondary disturbance we can for the present ignore--I do not mean any secondary disturbance. I mean the true ethereal waves emitted by the electric oscillation going on in the neighborhood of this recoiling dielectric. You pull aside the prong of a tuning fork and let it go; vibration follows and sound is produced. You charge a Leyden jar and let it discharge; vibration follows and light is excited.
It is light just as good as any other light. It travels at the same pace, it is reflected and refracted according to the same laws; every experiment known to optics can be performed with this ethereal radiation electrically produced, and yet you cannot see it. Why not? For no fault of the light; the fault (if there be a fault) is in the eye. The retina is incompetent to respond to these vibrations--they are too slow. The vibrations set up when this large jar is discharged are from a hundred thousand to a million per second, but that is too slow for the retina. It responds only to vibrations between 4,000 billions and 7,000 billions per second. The vibrations are too quick for the ear, which responds only to vibrations between 40 and 40,000 per second. Between the highest audible and the lowest visible vibrations there has been hitherto a great gap, which these electric oscillations go far to fill up. There has been a great gap simply because we have no intermediate sense organ to detect rates of vibration between 40,000 and 4,000,000,000,000,000 per second. It was, therefore, an unexplored territory. Waves have been there all the time in any quantity, but we have not thought about them nor attended to them.
It happens that I have myself succeeded in getting electric oscillations so slow as to be audible. The lowest I have got at present are 125 per second, and for some way above this the sparks emit a musical note; but no one has yet succeeded in directly making electric oscillations which are visible, though indirectly every one does it when they light a candle.
Here, however, is an electric oscillator, which vibrates 300 million times a second, and emits ethereal waves a yard long. The whole range of vibrations between musical tones and some thousand million per second is now filled up.
These electro-magnetic waves have long been known on the side of theory, but interest in them has been immensely quickened by the discovery of a receiver or detector for them. The great though simple discovery by Hertz of an "electric eye," as Sir W. Thomson calls it, makes experiments on these waves for the first time easy or even possible. We have now a sort of artificial sense organ for their appreciation--an electric arrangement which can virtually "see" these intermediate rates of vibration.
The Hertz receiver is the simplest thing in the world--nothing but a bit of wire or a pair of bits of wire adjusted so that when immersed in strong electric radiation they give minute sparks across a microscopic air gap.
The receiver I have here is adapted for the yard-long waves emitted from this small oscillator; but for the far longer waves emitted by a discharging Leyden jar an excellent receiver is a gilt wall paper or other interrupted metallic surface. The waves falling upon the metallic surface are reflected, and in the act of reflection excite electric currents, which cause sparks. Similarly, gigantic solar waves may produce auroræ; and minute waves from a candle do electrically disturb the retina.
The smaller waves are, however, far the most interesting and the most tractable to ordinary optical experiments. From a small oscillator, which may be a couple of small cylinders kept sparking into each other end to end by an induction coil, waves are emitted on which all manner of optical experiments can be performed.
They can be reflected by plain sheets of metal, concentrated by parabolic reflectors, refracted by prisms, concentrated by lenses. I have at the college a large lens of pitch, weighing over three hundredweight, for concentrating them to a focus. They can be made to show the phenomenon of interference, and thus have their wave length accurately measured. They are stopped by all conductors and transmitted by all insulators. Metals are opaque, but even imperfect insulators such as wood or stone are strikingly transparent, and waves may be received in one room from a source in another, the door between the two being shut.
The real nature of metallic opacity and of transparency has long been clear in Maxwell's theory of light, and these electrically produced waves only illustrate and bring home the well known facts. The experiments of Hertz are in fact the apotheosis of that theory.
Thus, then, in every way Maxwell's 1865 brilliant perception of the real nature of light is abundantly justified; and for the first time we have a true theory of light, no longer based upon analogy with sound, nor upon a hypothetical jelly or elastic solid.
Light is an electro-magnetic disturbance of the ether. Optics is a branch of electricity. Outstanding problems in optics are being rapidly solved now that we have the means of definitely exciting light with a full perception of what we are doing and of the precise mode of its vibration.
It remains to find out how to shorten down the waves--to hurry up the vibration until the light becomes visible. Nothing is wanted but quicker modes of vibrations. Smaller oscillators must be used--very much smaller--oscillators not much bigger than molecules. In all probability--one may almost say certainly--ordinary light is the result of electric oscillation in the molecules of hot bodies, or sometimes of bodies not hot--as in the phenomenon of phosphorescence.
The direct generation of _visible_ light by electric means, so soon as we have learnt how to attain the necessary frequency of vibration, will have most important practical consequences.
Speaking in this university, it is happily quite unnecessary for me to bespeak interest in a subject by any reference to possible practical applications. But any practical application of what I have dealt with this evening is apparently so far distant as to be free from any sordid gloss of competition and company promotion, and is interesting in itself as a matter of pure science.
For consider our present methods of making artificial light; they are both wasteful and ineffective.
We want a certain range of oscillation, between 7,000 and 4,000 billion vibrations per second; no other is useful to us, because no other has any effect upon our retina; but we do not know how to produce vibrations of this rate. We can produce a definite vibration of one or two hundred or thousand per second; in other words, we can excite a pure tone of definite pitch; and we can demand any desired range of such tones continuously by means of bellows and a keyboard. We can also (though the fact is less well known) excite momentarily definite ethereal vibrations of some million per second, as I have explained at length; but we do not at present seem to know how to maintain this rate quite continuously. To get much faster rates of vibration than this we have to fall back upon atoms. We know how to make atoms vibrate; it is done by what we call "heating" the substance, and if we could deal with individual atoms unhampered by others, it is possible that we might get a pure and simple mode of vibration from them. It is possible, but unlikely; for atoms, even when isolated, have a multitude of modes of vibration special to themselves, of which only a few are of practical use to us, and we do not know how to excite some without also the others. However, we do not at present even deal with individual atoms; we treat them crowded together in a compact mass, so that their modes of vibration are really infinite.
We take a lump of matter, say a carbon filament or a piece of quicklime, and by raising its temperature we impress upon its atoms higher and higher modes of vibration, not transmuting the lower into the higher, but superposing the higher upon the lower, until at length we get such rates of vibration as our retina is constructed for, and we are satisfied. But how wasteful and indirect and empirical is the process. We want a small range of rapid vibrations, and we know no better than to make the whole series leading up to them. It is as though, in order to sound some little shrill octave of pipes in an organ, we are obliged to depress every key and every pedal, and to blow a young hurricane.
I have purposely selected as examples the more perfect methods of obtaining artificial light, wherein the waste radiation is only useless and not noxious. But the old-fashioned plan was cruder even than this; it consisted simply in setting something burning; whereby not the fuel but the air was consumed, whereby also a most powerful radiation was produced, in the waste waves of which we were content to sit stewing, for the sake of the minute--almost infinitesimal--fraction of it which enabled us to see.
Every one knows now, however, that combustion is not a pleasant or healthy mode of obtaining light; but every one does not realize that neither is incandescence a satisfactory and unwasteful method which is likely to be practiced for more than a few decades, or perhaps a century.
Look at the furnaces and boilers of a great steam engine driving a group of dynamos, and estimate the energy expended; and then look at the incandescent filaments of the lamps excited by them, and estimate how much of their radiated energy is of real service to the eye. It will be as the energy of a pitch pipe to an entire orchestra.
It is not too much to say that a boy turning a handle could, if his energy were properly directed, produce quite as much real light as is produced by all this mass of mechanism and consumption of material. There might, perhaps, be something contrary to the laws of nature in thus hoping to get and utilize some specific kind of radiation without the rest, but Lord Rayleigh has shown in a short communication to the British Association at York that it is not so, and that, therefore, we have a right to try to do it.
We do not yet know how, it is true, but it is one of the things we have got to learn.
Any one looking at a common glow-worm must be struck with the fact that not by ordinary combustion, nor yet on the steam engine and dynamo principle, is that easy light produced. Very little waste radiation is there from phosphorescent things in general. Light of the kind able to affect the retina is directly emitted; and for this, for even a large supply of this, a modicum of energy suffices.
Solar radiation consists of waves of all sizes, it is true; but then solar radiation has innumerable things to do besides making things visible. The whole of its energy is useful. In artificial lighting nothing but light is desired; when heat is wanted it is best obtained separately by combustion. And so soon as we clearly recognize that light is an electric vibration, so soon shall we begin to beat about for some mode of exciting and maintaining an electrical vibration of any required degree of rapidity. When this has been accomplished the problem of artificial lighting will have been solved.
* * * * *
ON PURIFICATION OF AIR BY OZONE--WITH AN ACCOUNT OF A NEW METHOD.[1]
[Footnote 1: Paper read in Section C, Domestic Health, at the
Hastings Health Congress, on Friday, May 3, 1889.]
By Dr. B. W. RICHARDSON.
During the time when I was engaged in my preliminary medical studies--for I never admit to this day of being anything less than a medical student--the substance called ozone became the topic of much conversation and speculation. I cannot say that ozone was a discovery of that date, for in the early part of the century Von Marum had observed that when electrical discharges were made through oxygen in a glass cylinder inverted over water, the water rose in the cylinder as if something had either been taken away from the gas, or as if the gas itself had been condensed, and was therefore occupying a smaller space. It had also been observed by many electricians that during a passage of the electric spark through air or oxygen, there was a peculiar emanation or odor which some compared to fresh sea air, others to the air after a thunderstorm, when the sky has become very clear, the firmament blue, and the stars, if visible, extremely bright.
But it was not until the time, or about the time, of which I have spoken, 1846-49, that these discovered but unexplained phenomena received proper recognition. The distinguished physicist Schonbein first, if I may so say, isolated the substance which yielded the phenomena, and gave to it the name, by which it has since generally been known, of _ozone_, which means, to emit an odor; a name, I have always thought, not particularly happy, but which has become, practically, so fully recognized and understood, that it would be wrong now to disturb it.
Schonbein made ozone by the action of the electric spark on oxygen. He collected it, he tested its chemical properties, he announced it to be oxygen in a modified form, and he traced its action as an active oxidizer of various substances, and especially of organic substances, even when they were in a state of decomposition.
But Schonbein went further than this. He argued that ozone was a natural part of the atmosphere, and that in places where there was no decomposition, that is to say, in places away from great towns, ozone was present. On the high tower of a cathedral in a big city he discovered ozone; in the city, at the foot of the tower, he found no ozone at the same time. He argued, therefore, that the ozone above was used up in purifying the town below, and so suggested quite a new explanation of the purification of air.
The subject was very soon taken up by English observers, and I remember well a lecture upon it by Michael Faraday, in which that illustrious philosopher, confirming Schonbein, stated that he had discovered ozone freely on the Brighton Downs, and had found the evidence of it diminishing as he approached Brighton, until it was lost altogether in the town itself.
Such was the beginning of our knowledge of ozone, the precise nature of which has not yet been completely made out. At the present time it is held to be oxygen condensed. To use a chemical phrase, the molecule of oxygen, which in the ordinary state is composed of two atoms, is condensed, in ozone, as three atoms. By the electric spark discharged in dry oxygen as much as 15 per cent. may, under proper conditions, be turned into ozone. Ozone has also been found to be heavier than air. Professor Zinno says, that compared with an equal volume of air its density is equal to 1,658, and that it is forty-eight times heavier than hydrogen. Heat decomposes it; at the temperature of boiling water it begins to decompose. In water it is much less soluble than oxygen, and indeed is practically insoluble; when made to bubble through boiling water, it ceases to be ozone. The oxidizing power of ozone is very much greater than that of oxygen, and, according to Saret, when ozone is decomposed, one part of it enters into combination, the other remains simply as oxygen.
It is remarkable that some substances, like turpentine and cinnamon, absorb ozone and combine with it, a simple fact of much greater importance than has ever been attached to it. I found, for instance, that cinnamon which by exposure to the air has been made odorless and, as it is said, "spoiled," can be made to reabsorb ozone and gain a kind of freshness. It is certain also that some substances which are supposed to have disinfecting properties owe what virtues they possess to the presence of ozone.
On some grand scale ozone is formed in the air, and my former friend and colleague, the late Dr. Moffatt, of Hawarden, with whom I wrote a paper on "Meteorology and Disease," read before the Epidemiological Society in 1852-53, described what he designated ozone periods of the atmosphere, connecting these with storms. When the atmospheric pressure is decreasing, when with that there is increasing warmth and moisture, and when south and southwesterly winds prevail, then ozone is active; but when the atmospheric pressure is increasing, when the air is becoming dry and cold, and north and northeasterly winds prevail, then the presence of ozone is less active. These facts have also been put in another way, namely, that the maximum period of ozone occurs when there is greatest evaporation of water from the earth, and the minimum when there is greatest condensation of water on the earth; a theory which tallies well with the idea that ozone is most freely present when electricity is being produced, least present when electricity is in smallest quantity. Mr. Buchan, reporting on the observations of the Scottish Meteorological Society, records that ozone is most abundant from February to June, when the average amount is 6.0; and least from July to January, when the average is 5.7; the maximum, 6.2, being reached in May, and the minimum, 5.3, in November. This same excellent observer states that "ozone is more abundant on the sea coast than inland; in the west than the east of Great Britain; in elevated than in low situations; with southwest than with northeast winds; in the country than in towns; and on the windward than the leeward side of towns."
Recently a very singular hypothesis has been broached in regard to the blue color of the firmament and ozone. It has been observed that when a tube is filled with ozone, the light transmitted through it is of a blue color; from which fact it is assumed that the blue color of the sky is due to the presence of this body in the higher atmospheric strata. The hypothesis is in entire accord with the suggestion of Professor Dove, to which Moffatt always paid the greatest respect, viz., that the source of ozone for the whole of the planet is equatorial, and that the point of development of ozone is where the terrestrial atmosphere raised to its highest altitude, at the equator, expands out north and south in opposite directions toward the two poles, to return to the equator over the earth as the trade winds.
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Scientific American Supplement, No. 717, September 28, 1889Chapter X: TECHNOLOGY.--Alkali Manufactories.--Present aspect of the (4)
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