Chapter V: Introduction (3)

Garnets that are found in metamorphic rocks such as schists were formed when great forces squeezed and heated rocks far below the earth’s surface. This heat and pressure caused elements in the rocks to join together into different combinations to form new minerals, such as garnets. Garnets that occur scattered through igneous rocks, such as some pegmatites and granites, cooled and crystallized from hot, igneous fluids when the rocks themselves formed.

Most Texas garnets are not transparent. A few, however, are clear enough to be used as gemstones. These can be cut, polished, and mounted in rings, brooches, bracelets, and earrings. Although some garnet is widely used as an abrasive, none from Texas has been produced for this purpose.

Gneiss

Gneiss is a metamorphic rock that has parallel layers or bands. Some gneiss is made up of the same minerals (chiefly feldspar and quartz) as granite, and it is then called _granite gneiss_. Several of the other kinds of gneiss are known as _mica gneiss_, _conglomerate gneiss_, _gabbro gneiss_, and _hornblende gneiss_. In order to be a gneiss, a metamorphic rock has to have bands or layers. These bands may be either straight or wavy and either wide or narrow. In most gneisses, you will find a layer made up of long or flat mineral grains next to a layer made up of the grains of an entirely different mineral. The bands may show color differences, too. For example, a pink layer made up of feldspar grains may be found next to a black layer made up of hornblende grains. The mineral grains interlock as they do in igneous rocks, and they are generally large enough to be seen without a magnifying glass.

Gneiss can form from an igneous rock, such as granite, or from a sedimentary rock, such as sandstone. Heat, fluids, and pressures below the earth’s surface change these rocks into gneiss.

Gneiss that formed during Precambrian time is now seen at the surface in both west Texas and central Texas. In west Texas, it occurs principally in the Van Horn area of Culberson and Hudspeth counties. In central Texas, it is found in Blanco, Burnet, Gillespie, Llano, and Mason counties of the Llano uplift area.

One of the Llano uplift rocks is called the Valley Spring Gneiss. It generally has a light color (much of it is pinkish), and it is believed to have once been a sandstone. Another gneiss of this area, the Big Branch Gneiss, which has a medium to dark gray color, occurs in northern Gillespie and Blanco counties and is an altered igneous rock. Some of the Texas gneiss rocks are suitable for use as building stones.

Gold

Gold commonly occurs in nature as a single element—gold—but much native gold has a small amount of some other element, such as silver, copper, or iron, mixed with it.

Native gold is a shiny, yellow, metallic mineral that does not tarnish, and it leaves a shiny, golden-yellow streak when you rub it across a streak plate. If silver is present, the color and streak have a lighter shade. Pure gold is extremely heavy—its specific gravity is 19.3. Because it is malleable, this mineral will flatten into a thin sheet when hammered. It is ductile enough to be drawn out into wires. Gold is also soft—a pocket knife will scratch it easily. When it is to be used for ornaments and jewelry, gold is usually mixed with other metal, such as silver, copper, nickel, or palladium, to make it harder. The amount of gold that is present is then indicated by _carats_ (or _karats_). Pure gold is 24 carats. If you have a gold ring that has _14 K_ stamped inside it, you know that it is made of a mixture of 14 parts gold and 10 parts of other metal.

Gold commonly occurs in nature as plates, scales, or grains. Some of the grains are large enough to be called _nuggets_. It also is found in a wire-like shape described as _filiform_, it occurs in a network, called _reticulate_, and it can have a branching and fern-like shape, described as _dendritic_. Gold is not often found as individual crystals.

Several other minerals, such as pyrite, chalcopyrite, and mica, are sometimes mistaken for gold. None of these, however, is malleable and ductile, and none is nearly as heavy as gold. Pyrite and chalcopyrite have dark-colored streaks unlike that of gold. Mica cleaves so perfectly that it can be split into thin, flat sheets, but gold has no cleavage at all.

The best places to look for gold are in areas near igneous rocks and along the creeks and rivers that drain these areas. It is thought that most gold originally was carried up from molten igneous rock by hot solutions. The solutions moved into cracks and other openings in nearby rocks and deposited the gold, commonly along with quartz. Later, some of these gold-bearing rocks weathered away. The gold that the rocks contained either remained at the spot or was washed into creeks and rivers. These transported accumulations of loose gold are called _placer deposits_.

No really important gold deposit has ever been found in Texas, although traces and small amounts have been reported in several areas. A little gold has been found in the Llano uplift area of central Texas. It occurs in quartz veinlets that cut through some of the Precambrian metamorphic rocks of Llano, Mason, northeastern Gillespie, and west-central Burnet counties. Many years ago, a small amount of gold was mined northeast of Llano in Llano County from the Heath mine. Some gold also has been found in sands and gravels along streams, such as along Sandy Creek and its tributaries, in parts of this Llano uplift area.

In the Trans-Pecos country of west Texas, small amounts of gold have been found in the Van Horn area of Culberson and Hudspeth counties, in the Quitman Mountains district of Hudspeth County, and in the country around Shafter in Presidio County. Most of the small quantity of gold that was mined in west Texas was obtained as a by-product from the Presidio mine in the Shafter district (described with silver minerals on p. 90).

Small amounts of gold have been reported from other parts of Texas. Some of these localities are in Eocene Tertiary sandstones in the Gulf Coastal Plain, in Cretaceous limestones in Irion, Uvalde, and Williamson counties, and in sand and gravel in Howard and Taylor counties. None of these deposits has been found to have any commercial value.

Granite

Granite is an intrusive igneous rock that is made up chiefly of crystalline grains or crystals of quartz and a feldspar mineral, such as orthoclase or microcline. Several other minerals, including mica and hornblende, may also be present.

All of the mineral grains in granite are about the same size, and you can distinguish them without using a magnifying glass. A granite may be coarse grained, medium grained, or fine grained. When you examine this rock, you will see that its grains are not cemented but interlocked like the pieces of a jigsaw puzzle. The color of granite, which is pink, red, gray, or brownish, depends chiefly on the color of its feldspar grains.

Most granites formed from hot, molten magma that slowly cooled and hardened far below the earth’s surface. Because of this slow cooling, fairly large mineral grains were formed.

Granites are now seen at the surface in several areas of Texas. They were gradually uncovered as the areas became higher and the overlying rocks slowly weathered away. One of these areas is the Llano uplift of central Texas where the granites occur in Blanco, Burnet, Gillespie, Llano, and Mason counties. These granites formed during Precambrian time and are believed to be about a billion years old. (Scientists are now able to determine the age of some rocks accurately by very precisely measuring the relative amounts of isotopes produced by decay of radioactive minerals.)

Granites also appear at the surface in the Trans-Pecos country of west Texas. Some of these areas include the Franklin Mountains of El Paso County, the Quitman Mountains of Hudspeth County, the Chisos Mountains of Brewster County, and the Chinati Mountains of Presidio County.

Red, pink, and gray granites from quarries in the Llano uplift area are widely used as building stones and monument stones. A large quarry at Granite Mountain just west of Marble Falls in Burnet County has supplied pink granite for buildings in many parts of the United States. The Texas Capitol building and several other State buildings in Austin are made of this granite.

Graphite

Graphite is a mineral that is made up of a single element—carbon. (_Diamond_, although it does not look at all like graphite, is a crystalline form of carbon.) Graphite is a steel-gray or black mineral that commonly has a metallic luster. It is not heavy and is extremely soft. Graphite will soil your fingers and leave a black mark on paper. This mineral cleaves perfectly in one direction and splits into thin flakes that feel greasy.

To help distinguish graphite from _molybdenite_, a mineral it resembles, you can use a shiny, glazed surface, such as is found on a saucer or a plate, to test its streak. When rubbed across this kind of surface, graphite will leave a black streak, but molybdenite will leave a greenish one.

Graphite commonly occurs as scales, as sheet-like layers, or as compact masses. It may be found mixed with clay or other impurities, and it then looks dull and earthy. Crystals of graphite, which are seldom found, are 6-sided and flat.

Graphite occurs in Llano, Burnet, and other counties in the Llano uplift area of central Texas. One of the Nation’s most important graphite mines is located in the Clear Creek area several miles northwest of Burnet in Burnet County. Some graphite has also been mined near Lone Grove in Llano County. In addition, a graphite schist, obtained south of Llano in Llano County, has been used as a filtering material.

All of this graphite occurs in extremely old Precambrian graphite schist rocks that we now see at the surface in this part of Texas. It is believed that the schists were once ancient sedimentary rocks, such as shales, which contained organic matter. Long ago, great forces below the earth’s surface altered these rocks. When this happened, the organic material that they contained changed into the mineral we know as graphite.

Graphite has a number of uses. It is mixed with clay to make the pencil lead that we use for writing. It serves as a lubricant, either alone or mixed with oil, grease, or water. In addition, graphite is used to make generator brushes, stove and shoe polish, and special paints. Because it can stand great heat without melting, some graphite is mixed with clay to make the pots or crucibles that hold molten metals.

Grossularite. _See_ Garnet.

Gypsite. _See_ Gypsum.

Gypsum

Gypsum is a hydrous calcium sulfate. This mineral is normally colorless or white, but impurities cause it to appear gray, brownish, yellowish, or reddish. It is transparent or translucent and is not heavy. When you rub gypsum across a streak plate, it leaves a white streak. This mineral is so soft that a fingernail scratches it easily. Gypsum occurs in several varieties.

The colorless, glassy, and transparent variety of gypsum is called _selenite_. It is found as cleavable masses and as crystals that are prism-shaped or flat and diamond-shaped. It is not uncommon for two crystals to be joined together so that they have a swallow-tail shape—these crystals are _twinned_. Groups of flat selenite crystals arranged together so that they resemble flowers are called _rosettes_. Many of these have been found in Nolan County.

Gypsum has four directions of cleavage. One of these directions is so perfect that some selenite splits into thin, clear sheets that may be mistaken for mica; other selenite cleavage fragments may be mistaken for calcite. You can distinguish selenite sheets from calcite by testing their hardness (selenite is softer) and by putting a drop or two of dilute hydrochloric acid on them. The acid will fizz and bubble on calcite but not on the selenite gypsum. There is also a quick way to distinguish the thin selenite cleavage fragments from mica. After you carefully bend a thin sheet of mica, it will snap back to its original shape without breaking. Selenite gypsum, however, is not elastic. It will bend, but it will break if you try to straighten it again.

Selenite is found in cracks and cavities in rocks. Good crystals have been collected at Gyp Hill, a salt dome southeast of Falfurrias in Brooks County, and some selenite has been mined there. Selenite crystals also occur scattered through clays, particularly along creek banks, in Lee, Fayette, Bastrop, and several other counties.

Another variety of gypsum is known as _fibrous gypsum_. It is made up of slender, brittle, needle-like fibers that fill the cracks in some rocks. If fibrous gypsum has a silky or pearly luster, it is called _satin spar_. One of the places where satin spar occurs is in Permian rocks in Hardeman County.

Most of the fibrous gypsum and selenite is formed by solutions. Some of these solutions develop when underground waters, seeping through rocks, pick up and dissolve minerals that contain sulfur (such as pyrite). This dissolved material changes the water into very weak sulfuric acid. When the sulfuric acid meets calcium carbonate (as in limestone or calcite), it combines with the calcium to form the gypsum.

A massive, fine-grained, and translucent variety of gypsum, known as _alabaster_, is used for articles such as lamp bases, statuettes, vases, and book-ends.

A loose, earthy, crumbly variety of gypsum, called _gypsite_, is ordinarily found mixed with other materials, such as clay, sand, and soil. It occurs either at or near the surface of the ground. Gypsite is found in Culberson, Reeves, and other counties in west Texas.

A massive, granular variety of gypsum, called _rock gypsum_, may occur in large deposits. This is the gypsum that is used for making products such as plaster, wallboard, and some cements.

Deposits of rock gypsum are found both underground and at the surface in Texas. Surface deposits occur in Permian rocks in several counties to the east of the Texas High Plains. They also occur in the area between the Pecos River and the Delaware and Apache Mountains in Culberson and Reeves counties. Some of the other surface deposits are found near the Malone Mountains in Hudspeth County and in Lower Cretaceous rocks in Gillespie and Menard counties. Rock gypsum has been mined from the deposits in Fisher, Gillespie, Hardeman, Hudspeth, and Nolan counties. It also has been produced from the cap-rock at Hockley salt dome in Harris County.

Gypsum and another mineral, anhydrite, have very nearly the same composition. Both are calcium sulfates. Gypsum, however, contains water of crystallization, and anhydrite does not. It is likely that most of the rock-gypsum deposits of Texas originally were beds of anhydrite. By absorbing water that seeped through it, the anhydrite changed into gypsum.

Halite

Halite, sodium chloride, is the table salt you sprinkle on food for seasoning. This mineral ordinarily is white or colorless, but other materials cause it to be tinted red, blue, gray, brown, or green. When you rub halite across a streak plate, it leaves a white streak.

Because halite cleaves in three directions, all at right angles to each other, the cleavage fragments are shaped like cubes. You can see some of them by looking at a few grains of table salt through a magnifying glass.

Halite has a salty taste and dissolves easily in water. It also is transparent to translucent and has a glassy luster. This mineral is soft enough for a copper penny to scratch it. Halite commonly occurs as cubic crystals and as granular or compact masses.

In addition to its use as table salt, much halite goes to make soda ash, chlorine, and other chemicals. A few of its other uses are in leather making, meat packing, and food canning.

Texas has large underground deposits of halite. These deposits, known as _rock salt_, occur in the Permian subsurface basin of west Texas and in the salt domes of the Gulf Coastal Plain. The Permian basin, which extends under parts of west Texas, New Mexico, Oklahoma, Colorado, and Kansas, is now completely filled with sediments. It appears level and flat when you travel across it and does not look at all like a basin or a valley. During Permian time, however, this area was covered by a salty sea. As the sea gradually dried up, the dissolved material that it contained was deposited as thick beds of halite, anhydrite, and other minerals. Later, these minerals were covered by sedimentary rocks which were deposited on top of them. Now, the minerals are found many hundreds of feet below the surface. In Hutchinson, Mitchell, Ward, and Yoakum counties, some of this Permian basin salt has been produced (as brine) from wells that have been drilled into it.

The Gulf Coastal Plain salt domes are huge and almost circular columns of halite, some of which are more than 2 miles wide. Some are less than 300 feet below the surface, but most of them are much deeper. These salt columns pushed upward many thousands of feet from great, deeply buried salt deposits. The halite is mined from shafts dug into the Hockley salt dome in Harris County and into the Grand Saline salt dome in Van Zandt County. Salt brines are produced from wells drilled into several salt domes of this area.

At the surface in Texas, halite occurs in salt lakes in Crane and Hudspeth counties and in alkali lakes on the High Plains. It is found also on the shores of bays and lagoons in Cameron, Kenedy, Kleberg, and Willacy counties, and it occurs at springs and seepages in various places in the State.

Hematite

Hematite, iron oxide, the chief ore of iron, is found in many places in Texas but not in large deposits. This mineral may have a metallic luster and appear reddish brown, dark brown, steel gray, or black or it may occur as a soft, red, earth-like material called _red ocher_.

Most metallic hematite is too hard for a pocket knife to scratch, but quartz or a steel file will scratch it. Hematite is fairly heavy, for it has a specific gravity of 5.26. This mineral has no cleavage, but some specimens show three directions of parting that are almost at right angles to each other. A great help in identifying hematite is the dark reddish-brown streak it leaves when you rub it across a streak plate.

Some hematite occurs as rounded masses that resemble kidneys or bunches of grapes (then called _kidney ore_); it also is found as flat crystals. Most of the Texas hematite occurs as granular or compact masses. One of these massive varieties is composed of shiny scales or plates and is called _micaceous_ or _specular hematite_. This variety has been found in Hudspeth County and in northeastern Mason County. Hematite also commonly occurs as cementing material in many Texas sandstones.

Some hematite is formed by the alteration of magnetite, another iron mineral. This hematite is known as _martite_, and some of it still has the crystal shape (an octahedron or a dodecahedron) that belonged to the magnetite. Most of the hematite found in the Llano uplift area of central Texas is believed to be altered magnetite. In this central Texas area, some massive, granular martite has been mined at the Gamble prospect, a few miles southeast of Fredonia in northeastern Mason County, where it occurs as layers in Precambrian gneiss.

Small deposits of hematite occur in other parts of Texas, too. Some of the west Texas localities include Sierra Blanca, the Quitman Mountains, and the Carrizo Mountains of Hudspeth County and the area around Shafter in Presidio County.

Hollandite. _See_ Manganese Minerals.

Hyalite. _See_ Opal.

Jasper. _See_ Quartz.

Kaolin. _See_ Clay.

Limestone

Limestone is a sedimentary rock made up chiefly of calcite, a calcium-carbonate mineral. This rock also commonly contains grains of quartz, clay minerals, the mineral dolomite, or other materials. If a large amount of dolomite is present, the rock is called _dolomitic limestone_. In some limestones, the mineral grains are too small to be distinguished from each other without a magnifying glass or a microscope, but in other limestones, the individual mineral grains are easily seen.

Pure limestone is white, but if it contains clay or plant or animal matter it is light gray, dark gray, or black. Limestone also may be some shade of yellow, brown, or red. It is fairly soft and can be scratched with a knife. Because this rock contains calcite, an easy chemical test will help identify it: a drop or two of dilute hydrochloric acid will quickly fizz and bubble when placed on the limestone.

Limestones form in fresh water, such as in lakes, but most of them form in the seas. As some earlier-formed rocks are weathered, the calcium minerals that they contain are dissolved. Creeks and rivers carry this dissolved material to the sea. There, small animals, such as corals, crinoids, sponges, and foraminifers, take the dissolved material out of the water to build their calcium carbonate shells. Plants, such as algae, can take calcium carbonate out of solution too, and it collects on them. Shells, shell fragments, and plant remains accumulate on the sea floor, forming limy deposits that later become limestone.

Limestones also originate in a slightly different way. When the temperature and chemical composition of the water permit, calcium carbonate precipitates as millions of tiny grains of calcite and forms a limy mud that is converted to limestone. Many limestones contain shell or plant fragments in addition to these tiny grains of calcite.

There are several special kinds of limestone. If the rock is made up of many little rounded calcite grains that resemble fish eggs, it is called _öolitic limestone_. Another limestone, _chalk_, is soft, white, and fine grained. It consists mostly of tiny shell fragments and fine-grained calcite. _Coquina_ is a porous limestone made up of loosely cemented shells and shell fragments. Another special kind of limestone, known as _lithographic limestone_, because it can be used in printing, is smooth, firm, and hard. Its mineral grains are too small to be recognized without a microscope. This kind of limestone breaks with a smooth, sometimes curved, fracture. Still another variety, _pulverulent limestone_, is loose, soft, powdery, and white. It occurs in the Lower Cretaceous Edwards Limestone in Williamson and Bell counties of central Texas. Some of this limestone is used to polish rice grains, and it is added to livestock feeds to provide calcium for the animals.

Much limestone is found at the surface in Texas in Cambrian, Ordovician, Mississippian, Pennsylvanian, Permian, and Cretaceous formations. If you will look at numbers 5, 6, 9, 10, and 11 on the Texas geologic map (pp. 4-5), you will see that these strata appear at the surface in central, north-central, and Trans-Pecos Texas.

Limestone has many important uses. Much Texas limestone is crushed and used as a road-building material and as an aggregate that is mixed with cement to make concrete. Farmers in some areas improve their crops by adding limestone to the soil. Limestone also is sent to the iron furnaces in east Texas to be used in the production of pig iron and steel.

Some of the Texas limestones are heated to a fairly high temperature in order to change them into _lime_ (calcium oxide). Industry uses a large amount of lime in making chemicals, steel, glass, paper, and other products. Builders use it to make plasters, mortars, and stuccos. At plants in Comal, Johnson, Travis, and Williamson counties, lime is made from Cretaceous limestones.

Another important use of limestone is in making _portland cement_. The limestone is mixed with clay or shale, and the mixture is burned in a kiln until it just begins to melt. Then it is allowed to cool. Next, it is finely ground and in order to keep the finished cement from hardening or setting too quickly when it is used, a _retarder_, such as gypsum, is added. A number of cement-manufacturing plants in Texas use Cretaceous limestones, shales, and clays.

Many of the Texas limestones make excellent building stones. Some of them are quarried from Pennsylvanian and Cretaceous formations in north-central Texas and from Lower Cretaceous formations in counties near the Llano uplift of central Texas. A large quarry on the Williamson-Travis County line near Cedar Park in central Texas has supplied Cretaceous limestone for many buildings and monuments in the United States and Canada.

Limonite

Limonite is not really a definite mineral but is a mixture of iron oxides containing water. It is believed to be closely related to an iron mineral called _goethite_. Some limonite may be dull and earthy with the appearance of brownish-yellow or rusty brown clay. This variety is so soft that a fingernail will scratch it easily.

Other limonite has a dark brown or black color and a metallic or almost metallic luster. A copper penny will not scratch it, but a steel file will. This kind of limonite may have a shiny black surface that resembles glossy lacquer. The property that will help you most in identifying limonite is the rusty, yellowish-brown streak it leaves when rubbed across a streak plate.

Limonite has no cleavage and no crystal shape of its own. But crystals of other iron minerals, such as pyrite and magnetite, alter to form limonite. It then occurs with a crystal shape that originally belonged to one of these other minerals. (Such false forms of minerals are called _pseudomorphs_.) Limonite also occurs as layers in rocks, as hollow or solid concretions, or as coatings on other minerals. It is found mixed with minerals such as clays and serves as the cementing material in some sandstones.

Limonite is found in many localities in Texas including Blanco, Brewster, Burnet, Llano, and San Saba counties. The most important limonite deposits in Texas, however, are in the eastern part of the State, particularly in Anderson, Cass, Cherokee, Henderson, Marion, Morris, Nacogdoches, Smith, and Upshur counties.

The east Texas limonite deposits occur mainly in Weches sedimentary rocks. These rocks, which were deposited in the sea during Eocene Tertiary time, contain clay along with greensands. (Greensands are small, soft grains that contain _glauconite_, a mineral composed of iron, silicon, and several other elements.) Later, as the sea retreated, these sediments became a part of the land. Waters seeping through the sediments changed into weak solutions of carbonic and sulfuric acid that dissolved the iron out of some of the greensands. When conditions were favorable, this iron was re-deposited as an iron-carbonate mineral called _siderite_. Siderite was changed to limonite by weathering. Some siderite is still found in east Texas, and it is also mined along with the limonite as an iron ore.

East Texas iron ore has been mined from time to time ever since about 1855, and records show that a number of local iron furnaces once operated. The brown iron ore (as the limonite is also called) now is mined from open pits in Cass, Cherokee, and Morris counties.

This ore, after being washed, goes into blast furnaces at Lone Star (near Daingerfield) and at Houston. In the blast furnaces the ore is changed into metallic iron by mixing it with coke (made from coal) and limestone and blowing in blasts of hot air.

To make steel, the iron from the blast furnace (called _pig iron_) is put into open-hearth furnaces together with scrap iron, limestone, and other materials. This mixture is heated and melted together to get rid of unwanted substances. Then other elements, such as molybdenum, manganese, or nickel, are added to make steel with the right strength and toughness.

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Hot Gases
Blast Furnace
Iron Ore
Limestone
Coke
Fire Brick lining
Steel Plate covering
3550°F
Hot Air Blast
Slag
Slag Ladle
Molten Iron
Iron Ladle

Steel mills alongside the furnaces in Texas turn out many products, such as steel plates for oil tanks, ships, and tank cars and steel beams for framework in buildings and bridges. Some of their other products include pipes for the oil and chemical industries and wire for nails and fencing material.

Lithographic Limestone. _See_ Limestone.

Llanite

Llanite is a unique rock that is found only in Llano County in central Texas. This intrusive igneous rock is made up of easily seen crystals and grains of quartz and feldspar that are scattered through a brown-colored mass of extremely small mineral grains. The quartz is beautiful, sky-blue, and opal-like; the feldspar has a rusty pink color. (Because the quartz looks like opal, this rock often is called _opaline granite_.) The mineral grains that make up the brown-colored mass are so tiny that they can be identified only with a microscope. They are quartz, feldspar, mica, fluorite, and apatite.

Llanite formed during Precambrian time. Molten rock material forced its way upward into cracks that cut across granite and schist rocks while the rocks were still far underground. This hot magma remained in the cracks where it cooled and hardened to form long, narrow, wall-like masses (called _dikes_) of llanite. We can see some of the llanite dikes exposed at the earth’s surface to the north and northeast of Llano in Llano County because the overlying rocks have weathered away.

Llanite has been quarried from one of the dikes west of Babyhead in northern Llano County. Because llanite is both attractive and strong, it has been used as an ornamental stone and as a monument stone.

Magnetite

Magnetite, iron oxide, is a black, metallic mineral with an outstanding physical property: it is magnetic—fragments of magnetite readily cling to a magnet. It also leaves a black streak when rubbed across a streak plate. Although this mineral is too hard to be scratched by the average pocket knife, a steel file will scratch it. Magnetite is fairly heavy—it has a specific gravity of 5.18.

Magnetite occurs as compact or granular masses, as scattered grains, and as crystals. Most of the crystals are octahedrons, but some dodecahedrons are found. Magnetite helps make up a part of many metamorphic and igneous rocks, and it also occurs as tiny crystals and grains in some sands, sandstones, and other sedimentary rocks.

Open-Hearth Furnace
Scrap metal
Alloying Elements
Limestone
Furnace Interior
Live Fuel Burner
Air pre-heated

Most of the magnetite that has been found in Texas occurs in Precambrian gneiss and schist rocks of the Llano uplift area of central Texas, particularly in Llano County and in eastern Mason County. It occurs as thin layers, as thick lens-shaped deposits, and as scattered grains in the rocks. Probably at least a billion years ago these gneisses and schists were sedimentary rocks, such as shales and sandstones. Some geologists believe that these rocks could have contained iron sediments (perhaps in the form of _glauconite_). Great forces below the earth’s surface crumpled and squeezed the sedimentary rocks and changed them into the metamorphic schist and gneiss rocks we see today. As this happened, the iron sediments in the rocks were changed into magnetite.

At least some of the magnetite in this area (such as the deposit at Iron Mountain in Llano County) probably had a different sort of origin. Molten igneous rock material containing iron could have moved up into cracks in the ancient sedimentary rocks. Then the magnetite formed from this iron material when the igneous and sedimentary rocks were changed into the schists and gneisses of today.

None of the Llano and Mason County magnetite deposits is really very large. Nevertheless, prospecting and a little mining have been carried on from time to time at several deposits in this area. At Iron Mountain, which is about 12 miles northwest of Llano in Llano County, magnetite has been mined from open pits. Although magnetite is commonly used as a source of iron, the magnetite from this deposit was used as a heavy concrete aggregate.

Malachite. _See_ Copper Minerals.

Manganese Minerals (Braunite, Hollandite, Pyrolusite)

Although manganese does not occur alone in nature as a native element, it makes up a part of many minerals and compounds. This element has an important use in steel making, where it helps rid the steel of unwanted substances, such as oxygen and sulfur, and, in addition, it is used to make tough, hard, manganese steel for armor plate, railroad tracks, safes, and steam shovels. Manganese has various uses outside the steel industry. It is added to copper and nickel to make alloys, it is used in the manufacture of dry-cell batteries, and (as manganese sulfate) it is used as a fertilizer.

Manganese minerals and compounds, such as _braunite_, _hollandite_, _pyrolusite_, and _wad_, occur in several counties in Texas. No large, commercial deposits have been found here.

Some manganese compounds and minerals are covered with a soft, sooty black material that will soil your fingers. This can help you recognize these minerals; however, a few non-manganese minerals, such as some chalcocite, also have a black coating that soils your fingers in a similar way.

One of the manganese minerals, _braunite_, is a complex oxide of manganese that contains silica. It has a submetallic luster and is dark steel-gray or black. When rubbed across a streak plate, it leaves a steel-gray or a black streak. This mineral is too hard to be scratched by a pocket knife, but a piece of quartz or a steel file will scratch it. Braunite has a specific gravity of 4.75 to 4.82. It has four directions of cleavage that are parallel to the faces of a pyramid.

In the Spiller mine, about 15 miles northeast of Mason in Mason County, masses of braunite occur as lens-shaped layers in Precambrian gneiss and quartzite rocks. This braunite may have formed from another manganese mineral (possibly manganese garnet) that was exposed at the earth’s surface after the overlying rocks eroded away. As this other mineral weathered, it may have altered into braunite, or the braunite could have been deposited from solutions emanating from hot magmas before the great thickness of overlying rock was removed.

The mineral variety _hollandite_ is a rare manganate of manganese and barium. It has a metallic luster, and its color is silvery gray or black. When you rub it across a streak plate, hollandite leaves a black streak. It has a specific gravity of 4.7 to 5. Hollandite is rather hard, but a steel file will scratch it.

Hollandite occurs in western Jeff Davis County in west Texas at what is called the Mayfield prospect. Here, it is found as rounded masses that occur in a vein near a large fault in Lower Cretaceous limestone rocks.

Other manganese compounds, _pyrolusite_ and _wad_, are found in several important deposits near the Pecos River in western Val Verde County. _Pyrolusite_ is a manganese dioxide mineral. It is black, opaque, and so soft that it rubs off on your fingers like soot. Pyrolusite may be granular and massive or may be powdery. It also occurs as a fern-like coating on rocks. _Wad_ is not really a mineral but is an impure, dull-black or brownish-black mixture of manganese oxide, water, and other substances. It can be soft enough to soil your fingers, or it can be too hard to scratch with a pocket knife. Wad occurs in earthy or compact masses or in crusts or stains on rocks.

In Val Verde County, the wad and pyrolusite are found mixed with soil, clay, gravel, sand, and plant remains. This material fills cracks in Lower Cretaceous limestones, it is scattered through gravels, and it is deposited in low places at the surface. The manganese in these deposits came from limestone rocks that have since weathered away. Rainwater trickled into these rocks and dissolved the manganese minerals they contained. This manganese was washed down toward the Pecos River and was deposited as wad and pyrolusite.

Marble

Marble is a metamorphic rock made up chiefly of sparkling grains of calcite or dolomite, but other minerals may be present. The marble may be fine grained, medium grained, or coarse grained; commonly, all the mineral grains are about the same size.

Marble may be of uniform color, banded, spotted, or streaked. If it is made up only of pure calcite or dolomite, the marble is white. If, however, it contains carbonaceous material, such as graphite, it is grayish or black. Limonite impurities cause the marble to be yellowish brown, and manganese oxides and hematite give it a brownish, pinkish, or reddish color.

Marble is a rather soft rock, and you can scratch it easily with a pocket knife. A few drops of dilute hydrochloric acid will bubble and fizz readily on calcite marble; on dolomite marble, it may fizz slightly.

Marble forms from limestone or from dolomite rock. Heat and pressure below the earth’s surface cause the calcite and dolomite mineral grains in these rocks to recrystallize. A fine-grained limestone can be changed into a coarse-grained calcite marble. The marble is not made up of new and different minerals, but it has a new texture unlike that of the limestone. (To a builder, the word _marble_ has another meaning. He considers rocks such as unaltered limestone, unaltered dolomite, or even serpentine to be marble, if they will take a high polish.)

Metamorphic marbles occur at the surface in central Texas and in west Texas. Some of the west Texas occurrences are in the Van Horn area of Culberson and Hudspeth counties and in the Big Bend area of Brewster County. In central Texas, Precambrian marbles are found in Burnet, Gillespie, Llano, and Mason counties of the Llano uplift area. Many of them are suitable for use as monument and building stones. Some of the Llano County marble is quarried and used as granules for roofs and as terrazzo chips for making colorful floors (described with serpentine on p. 88).

Martite. _See_ Hematite.

Mica

Mica is not just one mineral but is the name given to a group of similar minerals. The mica minerals are easy to recognize. Because they have perfect cleavage in one direction, they split into thin, flat sheets. You can see through some mica sheets, and they are elastic enough to be bent back and forth. (Another mineral, selenite gypsum, also will split into thin, flat, transparent sheets, but selenite sheets break when you bend them.)

Basal Cleavage

Two of the mica minerals that you are most likely to find in Texas are _muscovite_ and _biotite_. Both these minerals are potassium-aluminum silicates, and biotite, in addition, contains magnesium and iron. In general, muscovite is light colored, that is, it has a light brown, yellow, or green tint, or is colorless, and biotite is dark colored, commonly dark green, brown, or black. These minerals have glassy or pearly lusters and are rather soft—a copper penny scratches them. The specific gravity of biotite is 2.8 to 3.2, and that of muscovite is 2.76 to 3.1.

Mica minerals occur in igneous rocks, such as granite and pegmatite, and in metamorphic rocks, such as schist and gneiss. They also are found as tiny flakes in some sandstones, limestones, and other sedimentary rocks. Most of the Texas mica is found in the Llano uplift area (particularly in Llano County) and in the Mica Mine area. (The Mica Mine area is in the Van Horn Mountains about 15 miles south of Van Horn in west Texas.) In both these areas, the mica minerals occur mostly in Precambrian pegmatites and mica schists.

The gleaming mica schists were once igneous rocks or sedimentary rocks such as sandstones and shales. Long ago, great forces beneath the earth’s surface changed the rocks into mica schists. The mica that is found in pegmatites formed from hot fluids of igneous origin when the pegmatite rock itself was formed.

Clusters of mica in the pegmatites are called _books_, because the thin sheets into which the mica splits look like pages. Some muscovite books up to 8 inches across are found in the Mica Mine area of the Van Horn Mountains.

The books or sheets of muscovite mica that occur in pegmatites are especially valuable to industry. Muscovite can stand great heat without melting, it is tough, it splits into thin sheets, and it lets very little heat and electricity pass through. Because of these properties, muscovite is used in fuses and as insulators in heating elements of electric irons and toasters. (Biotite is not used, because the iron it contains makes it a conductor of electricity.) Sheet muscovite also is widely used by the electronics industry as a non-conducting material in the manufacture of tubes and other products.

Both muscovite and biotite from mica schist rocks, as well as scrap pieces of sheet mica from pegmatites, are ground into flakes or powder. This ground-up mica has many uses, ranging from a powder coating for automobile inner-tubes to Christmas tree “snow.”

Only a small amount of mica has been mined in Texas. A fair grade of sheet mica occurs in the pegmatites at Mica Mine in west Texas, but the deposit is not large. In the pegmatites of the Llano uplift area of central Texas, no sheet mica has been found that is considered good enough for the requirements of industry. Mica suitable for grinding, however, is found in both these Texas areas.

Micaceous Hematite. _See_ Hematite.

Microcline. _See_ Feldspar.

Milky Quartz. _See_ Quartz.

Muscovite. _See_ Mica.

Native Silver. _See_ Silver Minerals.

Obsidian and Vitrophyre

Obsidian is a dark, glassy-looking igneous rock. Most obsidian contains the same chemical elements as granite and rhyolite, since all three of these rocks can form from the same type of molten rock material. Obsidian, however, has no separate minerals, because its chemical elements are not combined in an orderly way. It is a natural glass.

Because it is a glass, we know that obsidian forms very quickly. One way for it to form is from the sudden cooling of hot, molten lava that flows out of volcanoes. If the lava cools and hardens before the separate minerals can crystallize, it becomes a natural glass, such as obsidian.

This rock is smooth and shiny. Most of it is black, but some can be dark green or dark brown. Obsidian allows light to pass through it, and it breaks with a curved, conchoidal fracture. The broken edges are very sharp.

Another glassy igneous rock that forms from fast-cooling lava is _vitrophyre_. It looks like obsidian except that it has crystals or crystalline mineral grains (which may be light colored) scattered through the dark glassy material.

Obsidian and vitrophyre are found in the Big Bend area of Brewster and Presidio counties in west Texas. They occur with other igneous rocks that formed there during Tertiary time.

The Indians who long ago roamed this area used the smooth, shiny vitrophyre and obsidian to make some of their arrowheads and scrapers. Today, rock collectors pick up these attractive rocks for their collections, and some of them cut and polish obsidian and vitrophyre for use as gemstones.

Onyx. _See_ Quartz.

Öolitic Limestone. _See_ Limestone.

Opal

Opal is like hardened jelly or gelatin. It has no crystalline inner structure and no crystal shape of its own—it is amorphous. This mineral has almost the same chemical composition as quartz. Both are silicon dioxides (silica), but opal, in addition, contains water.

Opal can be almost any color—red, yellow, blue, brown, gray, white—or it can be colorless. It is transparent or translucent and appears glassy, resinous, greasy, or dull. Opal has a specific gravity of 1.9 to 2.2—this mineral is a little lighter than quartz. It also is softer than quartz. A copper penny will not scratch opal, but quartz will. Opal has a white streak and a curved, conchoidal fracture but no cleavage.

Opal occurs in a number of places in Texas. In the Trans-Pecos country of west Texas, it fills cracks and cavities in some of the extrusive igneous rocks. It occurs on the High Plains of northwest Texas, and it is found in Tertiary formations of the Gulf Coastal Plain where it occurs as masses that fill cracks and cavities in sedimentary rocks, as the cementing material in some sandstones (such as in the Catahoula sandstone), and as opalized wood.

Much opal forms from underground waters that contain silicon. These solutions move through the rocks and deposit the opal in them.

Opal is found in a number of varieties. Some show a beautiful, lustrous play of colors that comes from inside the specimens. These varieties are known as _precious opal_ and are prized as gemstones. In Texas, some precious opal is found near Alpine in Brewster County. It has a milky white to bluish-white color, is translucent, and shows a fiery orange, red, blue, and green play of colors.

The variety known as _common opal_ shows no play of colors. It may be white, gray, bluish, reddish, greenish, or yellowish, and it is only slightly translucent. It is found in Brewster, Jeff Davis, Presidio, and other counties of the Trans-Pecos country of west Texas. It occurs also around some of the wet-weather (playa) lakes on the Texas High Plains. In the Gulf Coastal Plain, common opal is found with chalcedony (a variety of quartz) in Tertiary formations. A south Texas locality sometimes visited by collectors is near Freer in Duval County.

A clear, commonly rounded, variety of opal that looks like ice is called _hyalite_. Two areas in which it has been found are in Presidio County in west Texas and in Llano County in central Texas.

A variety of petrified wood, called _opalized wood_, is opal that replaced the fibers of a piece of wood. Wood opal is found at a number of places in the Gulf Coastal Plain. It occurs there in Tertiary formations within about 20 miles of the boundary line between areas 2 and 3 shown on the geologic map (pp. 4-5).

A soft opaline material called _diatomite_, or _diatomaceous earth_, is made up chiefly of the skeletons of diatoms—tiny, one-celled plants that live in fresh or salt water. These little plants are able to take silica from the water to make opal skeletons for themselves. When the diatom skeletons collect at the bottom of a lake or sea, they form the light, crumbly, white, gray, or cream-colored deposit of impure opal known as diatomite. Industry uses this material as a filter, as insulation, as an abrasive, and as a filler.

Diatomite formed in ancient lakes on the Texas High Plains during late Tertiary (Pliocene) and early Quaternary (Pleistocene) times. It is found in Armstrong, Crosby, Dickens, Ector, Hartley, and Lamb counties.

Opaline Granite. _See_ Llanite.

Orthoclase. _See_ Feldspar.

Pegmatite

Pegmatites occur in igneous rock areas, and most geologists consider them intrusive igneous rocks. They are made up of crystals and crystalline mineral grains that fit together—the grains are interlocked. The crystals and grains in pegmatites are larger than those of surrounding rocks, and some are huge, even larger than a man. However, there is a wide range of grain sizes in pegmatite.

Some pegmatites cut through igneous or metamorphic rocks in such a way that they resemble walls (called _dikes_). Others are found as veins, as flat masses, or as odd-shaped bodies in rocks. Many pegmatites occur in granites and contain feldspar, quartz, mica, and other minerals, as granite does. Some pegmatites occur with other kinds of igneous rocks and contain the same minerals as these rocks. A few pegmatites contain rare and unusual minerals.

Many geologists believe that pegmatites form from hot fluids of igneous origin that are left after other igneous rocks, such as granite, have already formed. These left-over fluids contain large amounts of aluminum, potassium, silicon, sodium, and several other elements. While the granite or other rocks are still far underground, this material pushes up into them, and may even partly dissolve them. Then it slowly cools and hardens into pegmatite. It is believed that, later, more fluids move into cracks in some pegmatites. This new material adds other minerals to the pegmatites and alters some of those minerals already there.

Some of the pegmatites we now see at the surface in Texas are probably about a billion years old. They formed during Precambrian time and occur with other extremely old rocks. One well-known Texas pegmatite area is the Mica Mine district of west Texas. It is about 15 miles south of Van Horn in the Van Horn Mountains of Culberson and Hudspeth counties. Another pegmatite area is in the Llano uplift of central Texas. These central Texas pegmatites occur in Burnet, Gillespie, Llano, and Mason counties.

Large crystals and grains of feldspar, mica, and quartz are found in the pegmatites of both these areas. A small amount of mica has been mined from the west Texas pegmatites, and feldspar has been produced from the central Texas pegmatites.

An extremely rare and unusual pegmatite occurs in the Llano uplift area at Baringer Hill, which is west of Burnet in Llano County. This pegmatite was once on the bank of the Colorado River, but when Buchanan Dam was built, the area was flooded. The Baringer Hill pegmatite now lies beneath the water of Lake Buchanan. Many rare minerals, which contain beryllium, cerium, thorium, uranium, yttrium, zirconium, and a number of other elements, occur in this pegmatite. Some of these minerals, such as those containing yttrium and zirconium, glow or incandesce when they are heated. During the early part of this century, before the area was flooded, several of the yttrium minerals were mined and used in making lamp mantles.

Pitchblende. _See_ Uranium Minerals.

Precious Opal. _See_ Opal.

Pulverulent Limestone. _See_ Limestone.

Pumicite. _See_ Volcanic Ash.

Pyrite

Pyrite is a shiny, pale golden-yellow or brassy-yellow metallic mineral. This mineral, an iron disulfide, is so often mistaken for gold that it is widely known by the nickname _fool’s gold_.

Except for their similar color and luster, pyrite and gold are really very different. When you rub pyrite across a streak plate, it leaves a black, a greenish-black, or a brownish-black streak, but the streak of gold is gold-colored. Pyrite is too hard for the average pocket knife to scratch, but a knife will scratch gold easily. Pyrite is brittle and readily breaks, but gold is malleable and flattens out when hit with a hammer. Pyrite is only about 5 times as heavy as an equal volume of water, but pure gold is over 19 times as heavy. And pyrite may have a brown or a multicolored tarnish on it, but gold never tarnishes.

Pyrite is a common mineral and is found in many of the igneous, metamorphic, and sedimentary rocks of Texas. It may be scattered through the rocks, or it may fill cracks and cavities in them. This mineral occurs as granular and compact masses, as rounded masses, or as crystals. The crystals are commonly cubes, pyritohedrons, or octahedrons. In some crystals, the shapes are combined (such as a cube with an octahedron or two pyritohedrons grown through each other). You may notice that the sides of some cubes and pyritohedrons have fine, parallel grooves (called _striae_ or _striations_) on them.

Pyrite originates in a number of different ways. Some of it forms, along with other minerals in igneous rocks, from hot magmas. It also forms in metamorphic rocks by the same processes that produce these rocks. Some of the pyrite in limestone and other sedimentary rocks is formed when the rocks themselves are deposited by seas or streams. Pyrite also is deposited by the hot fluids that are given off by magmas. These fluids travel up into cracks and other openings in rocks and then form pyrite as well as other minerals. Much pyrite forms in still another way. As water seeps through rocks, it dissolves some of the iron minerals that they contain. When, under certain conditions, these iron solutions mix with hydrogen sulfide (this is the gas that makes some water smell like rotten eggs), pyrite is formed.

Pyrite alters easily. Because of this, most builders carefully check the limestone, granite, marble, or whatever other building stone they plan to use to be sure that it does not contain large amounts of pyrite. When exposed to the weather, pyrite changes to limonite and causes an unsightly rust stain.

Pyrite is used as a source of sulfur, and it is produced for this purpose in several states. In Texas, however, no pyrite deposits have been found that are large enough to be mined.

Pyrolusite. _See_ Manganese Minerals.

Quartz

Quartz, silicon dioxide, is one of the most common minerals. It is glassy, waxy, greasy, or dull and is transparent or translucent. Pure quartz is colorless, but impurities make some varieties white, black, or a shade of red, yellow, blue, violet, or brown. Quartz is a hard mineral. It scratches window glass and cannot be scratched by a pocket knife or even by a steel file. It has a specific gravity of 2.65. The curved, conchoidal fracture shown by many specimens helps identify it.

Quartz is plentiful in Texas. It occurs in igneous rocks, such as granite, llanite, and pegmatite; in metamorphic rocks, such as quartzite, schist, and gneiss; and in sedimentary rocks, such as some sandstone, conglomerate, and breccia.

Quartz is found as crystals and as masses. Some of the masses are coarsely crystalline, but some are made up of extremely small crystalline particles called _cryptocrystalline_ quartz. Some of the cryptocrystalline varieties of quartz found in Texas are chalcedony, chert, and jasper. Some of the coarsely crystalline varieties found here are amethyst, milky quartz, rose quartz, smoky quartz, and rock crystal.