Chapter IV: The Various States of Matter

Sec. 1. The Statics of Fluids: Researches of Andrews, Cailletet, and others on liquid and gaseous states-- Amagat's experiments--Van der Waals' equation--Discovery of corresponding states--Amagat's superposed diagrams--Exceptions to law--Statics of mixed fluids-- Kamerlingh Onnes' researches--Critical Constants-- Characteristic equation of fluid not yet ascertainable.

Sec. 2. The Liquefaction of Gases and Low Temperatures: Linde's, Siemens', and Claude's methods of liquefying gases--Apparatus of Claude described--Dewar's experiments--Modification of electrical properties of matter by extreme cold: of magnetic and chemical-- Vitality of bacteria unaltered--Ramsay's discovery of rare gases of atmosphere--Their distribution in nature--Liquid hydrogen--Helium.

Sec. 3. Solids and Liquids: Continuity of Solid and Liquid States--Viscosity common to both--Also Rigidity-- Spring's analogies of solids and liquids--Crystallization --Lehmann's liquid crystals--Their existence doubted --Tamman's view of discontinuity between crystalline and liquid states.

Sec. 4. The Deformation of Solids: Elasticity-- Hoocke's, Bach's, and Bouasse's researches--Voigt on the elasticity of crystals--Elastic and permanent deformations--Brillouin's states of unstable equilibria--Duhem and the thermodynamic postulates-- Experimental confirmation--Guillaume's researches on nickel steel--Alloys.

CHAPTER V

SOLUTIONS AND ELECTROLYTIC DISSOCIATION

Sec. 1. Solution: Kirchhoff's, Gibb's, Duhem's and Van t'Hoff's researches.

Sec. 2. Osmosis: History of phenomenon--Traube and biologists establish existence of semi-permeable walls--Villard's experiments with gases--Pfeffer shows osmotic pressure proportional to concentration-- Disagreement as to cause of phenomenon.

Sec. 3. Osmosis applied to Solution: Van t'Hoff's discoveries--Analogy between dissolved body and perfect gas--Faults in analogy.

Sec. 4. Electrolytic Dissociation: Van t'Hoff's and Arrhenius' researches--Ionic hypothesis of--Fierce opposition to at first--Arrhenius' ideas now triumphant --Advantages of Arrhenius' hypothesis--"The ions which react"--Ostwald's conclusions from this--Nernst's theory of Electrolysis--Electrolysis of gases makes electronic theory probable--Faraday's two laws--Valency-- Helmholtz's consequences from Faraday's laws.