Chapter III: Front Matter (3)

Now, it is found that when the four corners of such a structure are occupied by four separate atoms or groups, or when (as the expression goes) the body contains an “asymmetrical carbon atom,” if the substance or one of its derivations can be obtained in a crystalline form, the crystals are also asymmetric, _i.e._, arc develops a face which is the mirror-reflection of a similar face developed on the other variety; and if a beam of polarized light be passed through the solution of the substance, its plane is rotated to the left if one variety be used, and, if the other, to the right. This hypothesis of LeBel’s and Van’t Hoff’s has had an enormous influence on the progress of organic chemistry. By its means Fischer, now professor at Berlin, has explained the reason of the existence of the enormous number of bodies analogous to grape and cane sugar, and has prepared many new varieties; and it appears likely that the terpenes, a class of bodies allied to turpentine, and comprising most of the substances to which the odor of flowers is due, may thereby find their explanation. It may be mentioned in passing that Pasteur, having found that ordinary mould destroyed one variety of tartaric acid rather than the other in a mixture of the two, and made use of this observation in order to prepare the unattached variety in a state of purity, was led to study the action of organisms more or less resembling mould; and that this has led to the development of the science of bacteriology, which has had an enormous influence on our views regarding fermentation in general, and guides the work of our physicians, our surgeons (witness Lister’s antiseptic treatment), our sanitary engineers in their estimate of the purity of drinking-water and of the disposal of sewage, of our manufacturers of beer and spirits, of wine-growers, and more recently of farmers. All these processes depend upon the action of organisms in producing chemical changes, whether in the tissues of the body, causing or curing disease, or in the production of flavored alcohol from sugar, or in the manufacture of butter and cheese, or in preparing the land for the reception of crops. We also owe to the genius of Van’t Hoff the most important advance of recent times in the region of physical chemistry. It has been observed by Raoult, professor at Grenoble, that the freezing-point of a solvent as a general rule is lowered to the same extent if there be dissolved in it quantities of substances proportional to their molecular weights. Thus, supposing 1.80 grams of grape-sugar be dissolved in 100 grams of water and the solution cooled below 0° with constant stirring, ice separates suddenly in thin spicules, and the temperature rises to −0.185°. If 3.42 grams of cane-sugar be similarly dissolved in 100 grams of water, the freezing-point of the solution is again −0.185°. Now, 1.80 and 3.42 are respectively the hundredth part of the molecular weights of grape-sugar (C6H12O6) and cane-sugar (C12H22O11). Similarly, Raoult found that quantities proportional to molecular weights dissolved in a solvent depress the vapor pressure of that solvent equally, or, what comes to the same thing, raise its boiling-point by an equal number of degrees. But ordinary salts, such as sodium chloride, potassium nitrate, etc., dissolved in water, give too great a depression of the freezing-point and too high a boiling-point. Next, it has been observed by botanists, Devries, Pfeffer, and others, who had examined the ascent of sap in plants, that if a vessel of unglazed porcelain, so treated as to cause a film of cupric ferrocyanide (a slimy red compound) to deposit in the pores of its walls, be filled with a weak (about 1 per cent.) solution of sugar or similar substance, and plunged in a vessel of pure water, water entered through the pores. By attaching a monometer to the porous vessel the pressure exerted by the entering water could be measured. Such pressure was termed “osmotic pressure,” referring to the “osmosis” or passage through the walls of the vessel. Such prepared walls are permeable freely to water, but not to sugar or similar bodies. Van’t Hoff pointed out that the total pressure registered is proportional to the amount of substance in solution, and that it is proportional to the absolute temperature, and he showed, besides, that the pressure exerted by the sugar molecules is the same as that which would be exerted at the same temperature were an equal number of molecules of hydrogen to occupy the same volume as the sugar solution. This may be expressed by stating that when in dilute solution sugar molecules behave _as if_ they were present in the gaseous state. Here again, however, it was noticed that salts tended to give a higher pressure; it was difficult to construct a semi-permeable diaphragm, however, which would resist the passage of salt molecules, while allowing those of water to pass freely. Lastly, Arrhenius, of Stockholm, had shown that the conductivity of salt solutions for electricity may be explained on the assumption that when a salt, such as KNO3 is dissolved in water, it dissociates into portions similar in number and kind to those it would yield if electrolyzed (and if no secondary reactions were to take place). Such portions (K and NO3, for example) had been named ions by Faraday. The conductivity of such solutions becomes greater, per unit of dissolved salt, the weaker the solution, until finally a limit is reached, after which further dilution no longer increases conductivity. Now Van’t Hoff united all these isolated observations and showed their bearing on each other. Stated shortly, the hypothesis is as follows: When a substance is dissolved in a large quantity of a solvent, its molecules are separated from each other to a distance comparable with that which obtains in gases. They are, therefore, capable of independent action; and when placed in a vessel the walls of which are permeable to the solvent, but not to the dissolved substance (“semi-permeable membrane”), the imprisoned molecules of the latter exert pressure on the interior surface of these walls as if they were gaseous. Van’t Hoff showed the intimate connection between this phenomenon and the depression of freezing-point and the use of vapor pressure already alluded to. He pointed out further that the exceptions to this behavior, noticed in the case of dissolved salts, are due to their “electric dissociation,” or “ionization,” as it is now termed; and that in a sufficiently dilute solution of potassium nitrate, for example, the osmotic pressure, and the correlated depression of freezing-point and rise of boiling-point, are practically equal to what would be produced were the salt to be split into its ions, K and NO3. These views were vigorously advocated by Ostwald, professor at Leipzig, in his _Zeitschrift für physikalische Chemie_, and he and his pupils have done much to gather together facts in confirmation of this theory, and in extending its scope.

It must be understood that the ions K and NO3 are not, strictly speaking, atoms; they are _charged_ atoms; the K retains a +, and the NO3 a − charge. On immersing into the solution the poles of a battery, one charged + and the other −, the + K atoms are attracted to the − pole, and are there discharged; as soon as they lose their charge they are free to act on the water, when they liberate their equivalent of hydrogen. Similarly, the − NO3 groups are discharged at the + pole, and abstract hydrogen from the water, liberating an equivalent quantity of oxygen. Thus the phenomenon of electrolysis, so long a mysterious process, finds a simple explanation. The course of ordinary chemical reactions is also readily realized when viewed in the light of this theory. Take, for example, the ordinary equation:

AgNO3.Aq + NaCl.Ag = AgCl + NaNO3.Aq;

_i.e._, solutions of silver nitrate and sodium chloride give a precipitate of silver chloride, leaving sodium nitrate in solution. By the new views, such an equation must be written:

+ − + − + −
Ag.Aq + NO3.Aq + Na.Aq + Cl.Aq = AgCl + Na.Aq + NO3.Aq.

The compound, silver chloride, being insoluble in water, is formed by the union of the ions Ag and Cl, and their consequent discharge, forming an electrically neutral compound; while the sodium ions, charged positively together with the NO3 ions, negatively charged, remain in solution.

One more application of the principle may be given. Many observers—Andrews, Favre, and Silbermann, but especially Julius Thomsen, of Copenhagen, and M. Berthelot, of Paris—have devoted much labor and time to the measurement of the heat evolved during chemical reactions. Now, while very different amounts of heat are evolved when chlorine, bromine, or iodine combine respectively with sodium or potassium, the number of heat units evolved on neutralizing sodium or potassium hydroxide with hydrochloric, hydrobromic, hydriodic, or nitric acids is always about 13,500. How can this fact be explained? It finds its explanation as follows: These acids and bases are ionized in solution as shown in the equation:

+ − + − + −
H.Aq + Cl.Aq. + Na.Aq + OH.Aq = H.OH + Na.Aq + Cl.Aq.

Water is the only compound formed; and it is produced by the union of the hydrogen-ion originally belonging to the acid, and the OH or hydroxyl-ion originally belonging to the base. No further change has occurred; hence the uniform evolution of heat by the interaction of equivalent quantities of these acids and bases.

It now remains to give a short account of the greatest generalization which has as yet been made in chemistry. It has been termed the “Periodic Arrangement of the Elements.”

In 1864 Newlands, of London, and Lothar Meyer, late of Tübingen, found that by arranging the elements in the order of their atomic weights certain regularities were to be observed between each element, and in general the eighth in succession from it, in the order of their numerical value. Such similar elements formed groups or quantities; while the elements separating them belong to a _period_, hence the name “periodic arrangement.” Commencing with lithium, a light, lustrous metal found in silicate in certain minerals, we have the following series:

Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
7 9.2 11 12 14 16 19 20

Sodium Magnesium Aluminum Silicon Phosphorus Sulphur Chlorine Argon
23 24.3 27 28 31 34 35.5 40

and so on. It is unnecessary to point out in detail the resemblances between the elements which stand in the vertical columns; but it may be stated that the resemblance extends also to the formulas and properties of their compounds. Thus the chlorides of lithium and sodium are each white soluble salts, of the formulas LiCl and NaCl; oxides of magnesium and of beryllium are both insoluble white earthy powders, MgO and BeO (GeO), and so on. Newlands, in his preliminary sketch, termed this order the “Law of Octaves,” and predicted the existence of certain undiscovered elements which should occupy unfilled positions in the table. Mendeléef, professor at St. Petersburg, in 1869 amplified and extended these relations; and he and Meyer pointed out that the volume occupied by equal numbers of atoms of such elements underwent a periodic variation when the elements are classified as above. The prediction of undiscovered elements was made by Mendeléef in a more assured manner; and in several cases they have been realized. Thus what Mendeléef called “ekaboron” has since been discovered by Lecoq de Boisbandron and named, patriotically, “gallium”; Mendeléef’s “eka-silicon” is now known as “germanium,” discovered by Winkler; and “eka-aluminum” is now Cléve’s “scandium.” Moreover, the atomic weights of cæsium, beryllium, molybdenium, and mercury have been altered so that they fit the periodic table; and further research has justified the alteration.

The valency of these elements increases from right to left, as will be seen by inspection of the following series:

LiCl BeCl3 BCl3 CCl4 NH4Cl
Na2O MgO B2O3 SiO2 PCl3
Monad. Dyad. Triad. Tetrad. Triad and Pentad.

OH2 FH Ne——
SO3 Cl(OH)O3 A——
Dyad and Hexad. Monad and Heptad. No valency.

The elements of no valency are of recent discovery. In 1894 Lord Rayleigh had determined the density of the nitrogen of the atmosphere, having separated from it the oxygen and carbon dioxide which is mixed with nitrogen in air. He found it to be of somewhat higher density than that obtainable from ammonia and other compounds of nitrogen. In conjunction with Ramsay he investigated atmospheric nitrogen; it was absorbed either by a method devised by Cavendish, or by making it combine with magnesium at a red heat. They found that the unabsorbable residue possessed an unknown spectrum, and that its density was nearly 20. To this new gas they gave the name “argon,” or inactive, seeing that all attempts to cause it to enter into combination had failed. In 1895 Ramsay, searching for possible combinations of argon in minerals, experimented with one which had been previously examined by Hillebrand, of Baltimore, and obtained from it helium, a gas of density 2, possessing a spectrum which had been previously discovered in 1868 in the chromosphere of the sun, by Jannsen, of Paris, and named helium by Frankland and Lockyer. Subsequent liquefaction of crude argon by means of liquid air, prepared by a process invented simultaneously by Linde and Hampson, gave a residue which was named by its discoverers, Ramsay and Travers, “neon.” Liquid argon has yielded two other gases also, “krypon” and “xenon.” These elements form a separate group in the Periodic Table, commencing with helium, with atomic weight, 4; neon, 20; argon, 40; krypon, 82; and xenon, 128. They all agree in being mono-atomic, _i.e._, their molecules consist of single atoms; and they have no tendency to form compounds, _i.e_., they possess no valency.

In this sketch of the progress of chemistry during the century which has just passed, attention has been paid chiefly to the progress of thought. Allusions must, however, be made to the applications of chemistry to industrial purposes. The development of the soda industry, the preparation of carbonate of soda and caustic from common salt—initiated in France by LeBlanc (1742–1806)—has been developed by Tennant, in Scotland, and Muspeath and Gossage, and by Hargreaves, Weldon, and Maetea, in England; this process has at present a serious rival in the ammonia-soda process, developed by Solway, in Belgium, and by Brunner and Mond, in England. The main action of sulphuric acid, so long associated with the alkali process, has made enormous strides during the present century, but is still, in the main, the original process of causing sulphur dioxide in presence of water to absorb the oxygen of the air through nitric oxide. But the saving of the oxides of nitrogen through the invention of a sulphuric acid power by Gay-Lussac, known by his name, and the re-utilization of these oxides in the “Glover” power, invented by John Glover, of Newcastle, have greatly lessened the cost of the acid. Concentration of the acid in iron vessels is now common, the cost of platinum or of fragile glass vessels being thereby saved. The desulphurization of iron and the removal of silicon, carbon, and phosphorus by Bessemer’s process, modified by Thomas and Gilchrist through the introduction of a “basic magnesia lining” for the convertors, has made it possible to obtain pure iron and steel from ores previously regarded as of little value.

The use of artificial manures, prepared by mixing refuse animal matters with tetra-hydrogen, calcium phosphate, and nitrate of soda, or sulphate of ammonia, first introduced by Liebig, has created a revolution in agricultural methods and in the weight of crops obtainable from a given area of soil. The influence of manures on crops has been fully studied by Lawes and Gilbert for more than fifty years in their experimental farm at Rothampstead. The most remarkable advances which have been made, however, are due to cheap electric current. The electrolysis of alumina, dissolved in fused cryolite to obtain aluminum, an operation carried out at Schaffhausen-on-the-Rhine, and at the Falls of Foyers, in Scotland; the electro-deposition of pure copper for electric wires and cables, electro-silvering, gilding, and nickelling, all these are instances where decomposition of a compound by the electric current has led to important industrial results. At present soda and chlorine are being manufactured by the electrolysis of salt solution contained in rocking trays, one of the electrodes being mercury, by the Castner-Kellner process. This manufacture is being carried on at Niagara, as well as in England. But electricity as a heating agent finds ever-extending application. Louis Moisson, professor at Paris, led the way by utilizing the enormous heat of the ore in his electric furnace, thereby, among other interesting reactions, manufacturing diamonds, small, it is true, though none the less real. The use of electricity as a heating agent has received new applications. Phosphorus is now made by distilling a mixture of phosphates of lime and alumina with coke; a new polishing agent has been found in “carborundum,” a compound of carbon and silicon, produced by heating in an electric furnace a mixture of sand and coke; and cyanide of potassium, almost indispensable for the extraction of gold from ores poor in gold, is now manufactured by heating a mixture of carbon and carbonate of barium in an electric furnace in a current of carbon monoxide. These are but some of the instances in which electricity has been adopted as an agent in effecting chemical changes; and it may be confidently predicted that the earlier years of the twentieth century will witness a great development in this direction. It may be pointed out that the later developments of industrial chemistry owe their success entirely to the growth of chemical theory; and it is obvious that that nation which possesses the most competent chemists, theoretical and practical, is destined to succeed in the competition with other nations for commercial supremacy and all its concomitant advantages.

WILLIAM RAMSAY.

ARCHÆOLOGY

To write of the progress of archæology in this century is scarcely possible, as the idea of the subject was unknown a hundred years ago; it is, therefore, the whole history of its opening and development that we have to deal with. The conception of the history of man being preserved to us in material facts, and not only in written words, was quite disregarded until the growth of geology had taught men to read nature for themselves, instead of trusting to the interpretations formed by their ancestors. Even down to the present the academic view is that classical archæology is more important than other branches, because it serves to illustrate classical literature. Looked at as archæology, it is, on the contrary, the least important branch, because we already know so much more of the classical ages than we do of others.

It is only within the present generation that it has been realized that wherever man has lived he has left the traces of his action, and that a systematic and observant study of those remains will interpret to us what his life was, what his abilities and tastes were, and the extent and nature of his mind. Literature is but one branch of the archæology of the higher races; another—equally important for the understanding of man—is art; these two give the highest and most complex and characteristic view of the nature of a race. At the opposite end of the scale are the rudest stone weapons which remain as the sole traces of the savages who used them. These highest and lowest evidences of mind, and all that lies between them, are the domain of archæology.

We now purpose to review the growth of archæology in contact with geology, where it concerns man as the last of the links of life on the globe; and then to notice the archæology of each country in turn, as it leads on to the times of historical record, and so passes down to modern times.

A century ago the world of thought was divided between the old and new ideas very differently from what is now the case. Then there stood on one side the idea of a special creation of an individual man, at 4000 B. C.; the compression of all human history into a prehistoric age of about three thousand years, and a fairly logical solution of most of the difficulties of understanding in a comfortable teleology. On the other hand stood many who felt the inherent improbability of such solutions of the problem of life, and who were feeling their way to some more workable theory on the basis of Laplace, Lamarck, Erasmus Darwin, and others; vaguely mingling together questions of physics, geology, archæology, anthropology, and theology, each of which we now see must be treated on its own basis, and be decided on internal evidence, before we can venture to let it affect our judgment on other points.

The great new force which thrust itself in to divide and decide on these questions is the scientific study of man and his works. Strangely shaped flints had been noticed, but no one had any knowledge of their age. One such, when found with the bones of a mammoth, was attributed to the Roman age, because no person could have brought elephants into Britain except some Roman general. The argument was excellent and irrefutable until geology found plenty more remains of the mammoth and showed that it was here long before the Romans. It was less than half a century ago that our eyes began to open to the abundant remains of flint-using man. Then a single rude stone weapon was an unexplained curiosity; now an active collector will put together his tens of thousands of specimens, will know exactly where they were found, their relation of age and of purpose, and their bearing on the history of man.

Not only have worked flint implements been found in the river gravels of France and England, where they were first noticed in the middle of this century, but also in most parts of Europe, in Egypt on the high desert, in Somaliland, at the Cape of Good Hope, in India, America, and other countries; and the most striking feature is the exact similarity in form wherever they have been found. So precisely do the same types recur, so impossible would it be to say from its form whether a flint had been found in Europe, Asia, or Africa, that it appears as if the art of working had spread from some single centre over the rest of the world. This is especially the case with the river-gravel flints—the earlier class—usually called Paleolithic. Soon after the general division had been made between polished stone-work of the later or Neolithic times, found on the surface, and the rough chipped work of the earlier or Paleolithic times, found in geological deposits, a further sub-division was made by separating the Paleolithic age into that of the river gravels and that of the cave-dwellers. The latter has again been divided into three classes by French writers, named, from their localities, _Mousterien_, _Solutrien_, _Magdalenien_; and, though these classes may be much influenced by locality, they probably have some difference of age between them.

And now within the last few years a still earlier kind of workmanship has been recognized in flints found in England on the high hills in Kent. Though at first much disputed, the human origin of the forms is now generally acknowledged, and they show a far ruder ability than even the most massive of the Paleolithic forms. The position also of these flints, in river deposits lying on the highest hills some six hundred feet above the present rivers, shows that the whole of the valleys has been excavated since they were deposited, and implies a far greater age than any of the gravel beds of the Paleolithic ages.

We, therefore, have passed now at the beginning of this century to a far wider view of man’s history, and classify his earlier ages in Europe thus:

First—Eolithic: Rudest massive flints from deposits 600 feet up.

Second—Paleolithic: Massive flints from gravels 200 feet up and
less (Achuleen).

Third—Paleolithic—Cave-dwellers: Flints like the preceding and
flakes (Mousterien).

Fourth—Paleolithic—Cave-dwellers: Flints well worked and finely
shaped (Solutrien).

Fifth—Paleolithic—Cave-dwellers: Abundant bone working and
drawing (Magdalenien).

Sixth—Neolithic: Polished flint working, pastoral and
agricultural man.

What time these periods cover nothing yet proves. The date of 4000 B. C. for man’s appearance, with which belief the nineteenth century started, has been pushed back by one discovery after another. Estimates of from 10,000 to 200,000 years have been given from various possible clews. In Egypt an exposure of 7000 years or more only gives a faint brown tint to flints lying side by side with Paleolithic flints that are black with age. I incline to think that 100,000 years B. C. for the rise of the second class, and 10,000 B. C. for the rise of the sixth class will be a moderate estimate.

Passing now from Paleolithic man of the latest geological times whose works lie under the deposit of ages, to Neolithic man of surface history whose polished stone tools lie on the ground, we find also how greatly views have changed. For ages past metal-using man has looked on the beautifully polished or chipped weapons of his forefathers as “thunderbolts,” possessing magic powers, and he often mounted the smaller ones to wear as charms. At the beginning of this century well-finished stone weapons were only preserved as curiosities which might belong to some remote age, but without any definite ideas about them. The recognition of long ages of earlier unpolished stone work has now put these more elaborate specimens to a comparatively late period, and yet they are probably older than the date to which our forefathers placed the creation of man.

The beginning of a more intelligent knowledge of such things was laid by the systematic excavations of the burial mounds scattered over the south of England, which was done in the early part of this century by Sir Richard Colt Hoare. A solid basis of facts was laid, which began to supersede the romances woven by Stukeley and others in the last century. Gradually more exact methods of search were introduced, and in the last thirty years Canon Greenwell has done much, and General Pitt Rivers has established a standard of accurate and complete work with perfect recording, which is the highest development of archæological study. These and other researches have opened up the life of Neolithic man to us, and we see that he was much as modern man, if compared with the earlier stage of man as a hunter. The Neolithic man made pottery, spun and wove linen, constructed enormous earthworks both for defence and for burial, and systematically made his tools of the best material he could obtain by combined labor in mining. The extensive flint-mines in chalk districts of England show long-continued labor; and the perfect form and splendid finish of many of the stone weapons show that skilled leisure could be devoted to them, and that æsthetic taste had been developed. The large camps prove that a thorough tribal organization prevailed, though probably confined to small clans.

About the middle of the century a new type of dwelling began to be explored—the lake dwelling; this system of building towns upon piles in lakes had the great advantage of protection from enemies and wild beasts, and a constant supply of food in the fish that could be hooked from the water below. Though such settlements were first found in the Swiss lakes, and explored there by Keller, they have since been found in France, Hungary, Italy, Holland, and the British Isles. The earlier settlements of this form belong to the Neolithic age, but only in central Europe. In these earliest lake dwellings weaving was known, and the cultivation of flax, grapes, and other fruit and corn; while the usual domestic animals were kept and cattle were yoked to the plough; pottery was abundant, and was often ornamented with geometric patterns. The type of man was round-headed. Following the Neolithic lake dwellings came those of the Bronze age, and as the bronze objects are similar to those found in other kinds of dwellings we shall notice them in the Bronze age in general. The type of man was longer-headed than in the earlier lake settlement. The domestication of animals shows an advance; the horse was common, and the dog, ox, pig, and sheep were greatly improved. Pottery was better made and elaborately decorated, often with strips of tin-foil.

The Bronze age marks a great step in man’s history. In many countries the use of copper, hardened by arsenic or oxide, was common for long before the alloy of copper and tin was used. In other countries, where the use of metals was imported, copper only appears as a native imitation of the imported bronze. Hence there is a true age of copper in lands where the use of metals has grown. It must by no means be supposed that copper excluded the use of flint; it was not until bronze became common that flint was disused. The existence of a Bronze age was first formulated, as distinct from a Stone age, about seventy years ago; and the existence of a Copper age has been much disputed in the last thirty years, but has only been proved clearly ten years ago, in Egypt.

In the eighteenth century the bronze weapons found in England were attributed to the Romans by some writers, though others, with more reason, argued that they were British. In the first year of the century began the comparative study of such weapons with reference to modern savage products. The development of the metal forms from stone prototypes was pointed out in 1816; the tracing out of the succession of the forms and the modes of use appeared in 1847. Further study cleared up the details, and within the last twenty years the full knowledge of the Bronze age in other countries has left no question as to the general facts of the sequence of its history. In each type of tool and weapon there appears first a very simple form imitated from the stone implements which were earlier used. Gradually the facilities given by the casting and toughness of the metal were used, and the forms were modified; ornamentation was added, and thin work in embossed patterns gave the stiffness and strength which had been attained before by massive forms. The general types are the axe—first a plain slip of metal, later developed with a socket; then the chisel, gouge, sickle, knife, dagger, sword, spear, and shield; personal objects, as pins, necklets, bracelets, ear-rings, buttons, buckles, and domestic caldrons and cups. Most of these forms were found together, all worn out and broken, in the great bronze-founder’s hoard at Bologna.

Lastly in the prehistory of Europe comes the Iron age, which so much belongs to the historical period that we can best consider it in noticing separate countries.

From the recent discoveries in Egypt we can gain some idea of the date of these periods. We ventured to assign about 10,000 B. C. for the rise of the Neolithic or polished-stone period (it may very possibly be earlier); the beginning of the use of copper may be placed about 5000 B. C.; the beginning of bronze was perhaps 3000 or 2000 B. C., as its free use in Egypt is not till 1600 B. C.; and the use of iron beginning about 1000 B. C., probably in Armenia, spreading thence through Europe until it reached Italy, perhaps 700 years B. C., and Britain about 400 B. C. Such is the briefest outline of the greater part of the history of man, massed together in one general term of “prehistoric,” before we reach the little fringe of history nearest to our own age. The whole of this knowledge results from the work of the century.

We now turn to the historical ages of each of the principal countries, to review what advance has been made even where a basis of written record has come down to us, equally accessible in all recent times.

EGYPT

At the beginning of the century Egypt was a land of untouched and inexplicable mystery; the hieroglyphics were wondered at, and puzzled over, without any idea of how they were to be read, whether as symbols or as letters. The history was entirely derived from the confused accounts of Greek authors, the lists remaining of Manetho’s history, written about 260 B. C., and the allusions in the Bible. The attempt to make everything fit to the ideas of the Greeks, and to make everything refer to the Biblical history, greatly retarded the understanding of the monuments, and is scarcely overcome yet. The first great step forward was when an inscription was found at Rosetta, in 1799, written in two methods, the monumental hieroglyphic and the popular demotic, along with a Greek version. By 1802 some groups of each writing had been translated. Young identified more signs, and Gell, by 1822, could successfully apportion three-quarters of the signs to the Greek words. The next step was to apply the modern Coptic language, descended from the ancient Egyptian, to the reading of the words. Gell had been doing so, but it needed a student of Coptic—Champollion—to carry this out thoroughly, as he did in 1821–32. Since then advance in reading has been only a matter of detail, not requiring any new principles.

The knowledge of the art began with the admiration for the debased work of Roman times, the principal interest at the beginning of the century. Then the excavations among the Rameside monuments at Thebes, about 1820–30, took attention back to the age of 1500–1000 B. C. The work of Lepsius, and later of Mariette, from 1840–80, opened men’s eyes to the splendid work of the early dynasties, about 4000–3000 B. C. And lastly the excavations of 1893–99 have fascinated scholars by a view of the rise of the civilization and the prehistoric period before 5000 B. C.

Throughout the greater part of the century the archæology of Egypt lay untouched; all attention was given to the language; and even Gardner Wilkinson’s fine view of the civilization (1837) depended largely on Greek authors, and had no perspective of history in tracing changes and development. It is only in the last ten or fifteen years that any exact knowledge has been acquired about the rise and progress of the various arts of life; this study now enables us to date the sculpture, metal work, pottery, and other art products as exactly as we can those of the Middle Ages.

The view that we now have of the rise and decay of this great civilization and its connection with other lands is more complete and far-reaching than that of any other country. In the early undated age, before the monarchy which began about 4800 B. C., a flourishing civilization was spread over upper Egypt. Towns were built of brick, as in later times; clothing was made of woven linen and of leather; pottery was most skilfully formed, without the potter’s wheel, hand-made, yet of exquisite regularity and beauty of outline, while the variety of form is perhaps greater than in any other land; stone vases were made entirely by hand, without a lathe, as perfect in form as the pottery, and of the hardest rocks, as diorite and granite; wood was carved for furniture; the art of colored glazing was common, and was even applied to glazing over large carvings in rock crystal; ornaments and beads were wrought of various stones and precious metals; ivory combs with carved figures adorned the hair; ivory spoons were used at the table; finely formed weapons and tools of copper served where strength was needful, while more useful were flint knives and lances which were wrought with a miraculous finish that has never been reached by any other people; and games were played with dainty pieces made of hard stone and of ivory. But all this tasteful skill of 6000–5000 B. C. had its negative side; in the artistic copying of nature the mechanical skill of these people carried them a very little way; their figures and heads of men and animals are strangely crude. And they had no system of writing, although marks were commonly used. They always buried the body doubled up, and often preserved the head and hands separately. Commerce was already active, and large rowing-galleys carried the wares of different countries around the Mediterranean. These people were the same as the modern Kabyle, of Algeria, and akin to the South European races, but with some negro admixture. Our whole knowledge of this age has only been gained within the last five years.

At about 5000 B. C. there poured into Egypt a very different people, probably from the Red Sea. Having far more artistic taste, a commoner use of metals, a system of writing already begun, and a more organized government, these fresh people started a new civilization in Egypt; adopting readily the art and skill of the earlier race, they formed by their union the peculiar culture known as Egyptian, a type which lasted for four thousand years. The same foundation of a type is seen in the bodily structure; the early historical people had wider heads and more slender noses than the prehistoric, but from 4000 B. C. down to Roman times the form shows no change.

From this union of two able races came one of the finest peoples ever seen, the Egyptians of the old kingdom, 4500—3500 B. C. Full of grand conceptions, active, able, highly mechanical, and yet splendid artists, they have left behind them the greatest masses of building, the most accurate workmanship and exquisite sculptures in the grand pyramids and tombs of their cemeteries. They perfected the art of organizing combined labor on the immense public works. In all these respects no later age or country has advanced beyond this early ability. The moral character and ideas are preserved to us in the writings of these people; and we there read of the ability, reserve, steadfastness, and kindliness which we see reflected in the lifelike portraiture of that age.

After a partial decay about 3000 B. C. this civilization blossomed out again nobly in the twelfth dynasty about 2600 B. C.; though the works of this age hardly reach the high level of the earlier times, yet they are finer than anything that followed them. At this period more contact with other countries is seen; both Syria and the Mediterranean were known, though imperfectly.

To this succeeded another decadence, sealed by the disaster of the foreign invasion of the Hyksos. But this was thrown off by the rise of a third age of brilliance—the eighteenth dynasty, 1500 B. C.—which, though inferior to early times in its highest work, yet shines by the widespread of art and luxury throughout the upper classes. Magnificence became fashionable, and the lower classes contented themselves with most barefaced imitations of costly wares. Foreign islands came closely in contact with Egypt. The ships of the Syrian coast and Cyprus continually traded to and fro, exchanging silver, copper, and precious stones for the gold of Egypt. Greece also traded its fine pottery of the Mycenæan age for the showy necklaces of gold and the rings and amulets with names of Pharaohs. Egypt then dominated the shores of the western Mediterranean, the plains of the Euphrates, and the fertile Soudan. But this power and wealth led to disaster. Like Rome, later on, she could not resist the temptation to live on plunder; heavy tribute of corn was exacted, large numbers were employed in unproductive labor, and national disaster was the natural consequence. Egypt never recovered the dominion or the splendor that were hers in this age. Of this period some slight notions are given us from literary remains in the Bible and Greek authors; but archæology is, so far, our only practical guide, as in the earlier ages. The great temples and monuments of the eighteenth-twentieth dynasties (1600–1100 B. C.) bear hundreds of historical inscriptions, the tombs are covered with scenes of private life, the burials and the ruins of towns furnish us with all the objects of daily use. This age is one of the fullest and richest in all history, and hardly any other is better known even in Greece or Italy. Yet all this has been brought to light in the century, and the knowledge of the foreign relations of Egypt is entirely the result of the last fifteen years.

The final thousand years of the civilization of Egypt is checkered with many changes; sometimes independent, as in the ages of Shishak of Necho, and of the Ptolemies; at other times a prey to Ethiopians, Persians, Greeks, or Romans. Its arts and crafts show a constant decay, and there was but little left to resist the influence of Greek taste and design, which ran a debased course in the country. There was, however, a spread of manufactures and of cheap luxuries into lower and lower classes; and the wealth of the country accumulated under the beneficent rule of the earlier Ptolemies (300–200 B. C.).

The principal discoveries about these later ages have been in the papyri, which have been largely found during the last twenty years. The details of the government and life of the country in the Ptolemaic (305–30 B. C.) and Roman (30 B. C.–640 A. D.) periods have been cleared up; and many prizes of classical literature have also been recovered. The archæology of the Middle Ages in Egypt has also been studied. Many of the Arabic buildings have been recently cleaned and put in good condition, and the splendid collection of manuscripts in Cairo has opened a view of the beautiful art of the thirteenth-fifteenth centuries so closely akin to what was done in Europe at the same time.

Egypt is, then, before all other lands, the country of archæology. A continuous history of seven thousand years, with abundant remains of every period to illustrate it, and a rich prehistoric age before that, give completeness to the study and the fullest value to archæological research.

MESOPOTAMIA

The valley of the Euphrates might well rival that of the Nile if it were scientifically explored, but unhappily all the excavation has been done solely with a view to inscription and sculpture, and no proper record has been made, nor have any towns been examined, the only work being in palaces and temples.

The earliest study on the ground was by Rich (1818–20), who gathered some few sculptures and formed an idea of Assyrian art. The French Consul, Botta, excavated Khorsabad (founded 700 B. C.) in 1834–35, and Layard excavated Nimrud in 1845–47; these were both Assyrian sites. The older Babylonian civilization was touched at Erech by Loftus, in 1849–52; and this age has attracted the most important excavations made since, at Tello by Sarzec (1876–81), and at Nippur by Peters and Haynes, of Philadelphia, during the last few years.

The cuneiform characters were absolutely unexplained until Grotefend, in 1800, resolved several of them by taking inscriptions which he presumed might contain names of Persian kings and comparing them alongside of the known names; thus—without a single fixed point to start from—he tried a series of hypotheses until he found one which fitted the facts. Bournouf (in 1836) and Lassen (1836–44) rectified and completed the alphabet. But the cuneiform signs were used to write many diverse languages, as the Roman alphabet is used at present; and the short Persian alphabet was only a fraction of the great syllabary of six hundred signs used for Assyrian. Rawlinson had independently made out the Persian alphabet, using the Zend and Sanskrit for the language. He next, from the trilingual Behistun inscription in Persian, Assyrian, and Vannic, resolved the long Assyrian syllabary, using Hebrew for the language. Since then other more obscure languages written in cuneiform have been worked with more or less success; the most important is the Turanian language, used by the earlier inhabitants of Babylonia before the Semitic invasion; this is recorded by many syllabaries and dictionaries, and translations compiled by the literary Semitic kings.

The general view of the civilization which has been obtained by these labors of the century shows it to have been more important to the world than any other. Cuneiform was the literary script of the world for at least six thousand years, the only medium of writing from the Mediterranean to the Indian Ocean. The Babylonian culture was almost certainly the source of the oldest present civilization—that of China. And the arts were developed probably even earlier than in Egypt. The first inhabitants were called Sumirian (or river folk) in distinction from the Accadian (or highland) people, who came from Elam down into the Euphrates valley, bringing with them the use of writing. Their earliest writing was of figure symbols (like the Egyptian and Hittite); but as in the valley clay tablets were the only material for writing, the figures became gradually transformed into groups of straight lines and spots impressed on the clay; hence the signs were formalized into what we call cuneiform. The Semitic invaders were using cuneiform characters by about 3000 B. C.

The early civilization was intensely religious, the main buildings being the temples, which were placed on enormous piles of brick-work. The sculpture was at a high level in the time of Naram-Sinn, about 3750 B. C.; and yet below his ruins at Nippur there are no less than thirty-five feet depth of earlier ruins, which must extend back to 6000 or 7000 B. C. In early times stone implements were used alongside of copper and bronze, as we find in Egypt 4000 B. C. Pottery was well made, and also reliefs in terra-cotta. Personal ornaments of engraved gems and gold-work were common.

The main landmarks in the later time of this civilization are the Elamite invasion of Kudur-nan-khundi (2280 B. C.) which upset the Semitic rulers, and the Assyrian invasion of Tiglath-Adar (1270 B. C.), after which interest centres in the Assyrian kingdom and its development of the Mesopotamian culture which it borrowed. The main buildings of the Assyrian kings were their enormous palaces, the mass of which was of unbaked bricks, faced with alabaster slabs; such were the works of Assurnazir-pal (Nimrud, 880 B. C.), Sargon (Khorsabad, 710 B. C.), Sennacherib and Assurbani-pal (Kouyunjik, 700 B. C.). The later, Assyrian, form of the civilization was to the earlier Chaldean much what Rome was to Greece, a rather clumsy borrower, who laboriously preserved the literature and art. Some of the Assyrian sculpture of animals is, however, perhaps unsurpassed for vivid action. The systematic libraries, containing copies of all the older literature for general study, were most creditable, though the Assyrian himself composed nothing better than chronicles. Nearly all that we possess of Babylonian religion, and much of the history, is in the copies scrupulously made from the ancient tablets by the Assyrian scribes, who noted every defect in the original with critical fidelity.

The Mesopotamian civilization has left its mark on the modern world. Its religion greatly influenced Hebrew, and thence Christian, thought, the psalms, for instance, being a Babylonian form of piety. Its science fixed the signs of the zodiac, the months of the year, the days of the week, and the division of the circle in degrees, all of which are now universal. And its art, carried by the Phœnicians, was copied by the Greeks and Etruscans, and thus passed on into modern design.

SYRIA

The knowledge of Palestine was but slight, and of northern Syria nothing to speak of, a century ago. Travellers with some scientific ability, such as Robinson (1838 and 1852), De Saulcy (1853), and Van de Velde (1854), greatly extended our view and led up to the splendid survey by the Palestine Exploration Fund (1866 and on), which exhausted the surface study of the land. The more archæological work of excavation was begun at Jerusalem (1867–70), and resumed (1892–99) at Lachish, Jerusalem, etc. The topographical results are all important, and leave nothing to be done until excavation can be freely applied; and the small amount of digging yet done has fixed the varieties of pottery back to 2000 B. C. and given some early architecture. But the ruins of Syria, and indeed of Turkey in general, are practically yet untouched. The discovery (1868) of the inscription of Mesha, King of Moab (896 B. C.), opened a new prospect of research which cannot yet be entered upon. In the north of Syria nothing has been done except the German work at Singerli, from which came an Aramean inscription of about 740 B. C. And in the south a large number of early inscriptions of the Arabian dynasties, reaching back some centuries B. C., have been copied; but there, also, excavation is impossible.

The main new light from Syria has been on the Hittite power. Burckhardt, in 1812, had noticed a new kind of hieroglyph at Hamath. After several ineffective copies, Wright made casts of the stones in 1872. Several other such inscriptions have been found, and from these and the Egyptian and Assyrian references to the Hittites we now realize that they were a northern people, with a great capital on the Euphrates, at Karkhemish, and ruling over nearly all Syria and Asia Minor. Little has yet been fixed about the writing; a few signs are read and some have passed into the Cypriote alphabet. A striking proof of the spread of Babylonian culture is seen in the tablets found in Egypt at Tel-el-Amarna in 1887, which show that all the correspondence between Egypt and Syria in the fifteenth century B. C. was carried on in cuneiform. These hundreds of letters give a vivid picture of life in Syria at that early date.

GREECE

The revival of interest in Greek civilization was at first purely literary, and remained so during two or three centuries. But during the last century various travellers and residents abroad made collections which awoke an interest in the art; and though most of these collectors were content with merely showy sculpture, greatly restored and falsified for the market, yet some—such as Hamilton—took a real archæological interest in the unearthing and collecting of ancient art. The condition of study at the end of the eighteenth century was that many private men of wealth had bought large quantities of sculpture which was but little understood, and looked on more from a decorative than a scientific point of view, while there were the beginnings of a serious appreciation of it which had been just laid down by Winckelmann.

The nineteenth century opened with a grand work of publishing the principal treasures of classical art in England, which was finally issued in 1809 by Payne, Knight, and Townley; this marks the highest point of the dilettante collecting spirit, which was soon eclipsed by truer knowledge. Hitherto the best sculpture had hardly been known but at second hand through Roman copies; a closer acquaintance began with the travels of Dodwell, Gell, and Leake, all in the first decade of the century. The free opening of the British Museum, in 1805, and the accumulation there of all the best collections within the first quarter of the century, also served to educate a public taste. The first struggle of scientific and artistic knowledge against the dilettante spirit was over the Elgin marbles; by 1816 they were accepted as the masterpieces which all later criticism has proved them to be. The Æginetan and Phigaleian sculptures, brought to Munich and London, helped also to show the nobility of early Greek art; so that the last two generations have had a canon of taste to rely upon, the value of which cannot be overestimated.

Following on this noble foundation, other collectors worked in Greece and Asia Minor, and the British Museum profited by the labors of Burgon, Fellows, and Woodhouse between 1840 and 1860. The diplomatically supported work of Newton on the Mausoleum (1857–58), and Wood at Ephesus (1863–75), filled out our knowledge of the middle period of Greek art (350 B. C.). Comparatively little has been done since then by England, but the activity of the Germans at Olympia has given us the only original masterpiece that is known—the Hermes of Praxiteles (350 B. C.), and their work at Pergamon revealed the great altar belonging to the later age (180 B. C.). The excavations at Athens (in 1886) have produced the impressive statues dedicated to Athene about 520 B. C., which reveal the noble rise of Attic sculpture. But attention during the last quarter-century has been largely fixed upon the earlier ages. The discoveries of Schliemann at Hissarlik (Troy, 1870–82), Mycenæ (1876), Orchomenos (1880–81), and Tiryns (1884), opened a new world of thought and research. Though at first bitterly attacked, it is now agreed that these discoveries show us the civilization of Greece between 2000 and 1000 B. C. Lastly, during ten years past Egypt has provided the solid chronology for prehistoric Greece by discoveries of trade between the two countries.