Chapter II: Part 2
At this unexpected objection, not only _Themistius_, but the rest of the company appear'd not a little surpriz'd; but after a while _Philoponus_ conceiving his opinion, as well as that of _Aristotle_, concern'd in that Objection, You cannot sure (sayes he to _Carneades_) propose this Difficulty; not to call it Cavill, otherwise then as an Exercise of wit, and not as laying any weight upon it. For how can that be separated from a thing that was not existent in it. When, for instance, a Refiner mingles Gold and Lead, and exposing this Mixture upon a Cuppell to the violence of the fire, thereby separates it into pure and refulgent Gold and Lead (which driven off together with the Dross of the Gold is thence call'd _Lithargyrium Auri_) can any man doubt that sees these two so differing substances separated from the Mass, that they were existent in it before it was committed to the fire.
I should (replies _Carneades_) allow your Argument to prove something, if, as Men see the Refiners commonly take before hand both Lead and Gold to make the Mass you speak of, so we did see Nature pull down a parcell of the Element of Fire, that is fancy'd to be plac'd I know not how many thousand Leagues off, contiguous to the Orb of the Moon, and to blend it with a quantity of each of the three other Elements, to compose every mixt Body, upon whose Resolution the Fire presents us with Fire, and Earth, and the rest. And let me add, _Philoponus_, that to make your Reasoning cogent, it must be first prov'd, that the fire do's only take the Elementary Ingredients asunder, without otherwise altering them. For else 'tis obvious, that Bodies may afford substances which were not pre-existent in them; as Flesh too long kept produces Magots, and old Cheese Mites, which I suppose you will not affirm to be Ingredients of those Bodies. Now that fire do's not alwayes barely separate the Elementary parts, but sometimes at least alter also the Ingredients of Bodies, if I did not expect ere long a better occasion to prove it, I might make probable out of your very Instance, wherein there is nothing Elementary separated by the great violence of the Refiners fire: the Gold and Lead which are the two Ingredients separated upon the _Analysis_ being confessedly yet perfectly mixt Bodies, and the Litharge being Lead indeed; but such Lead as is differing in consistence and other Qualities from what it was before. To which I must add that I have sometimes seen, and so questionlesse have you much oftener, some parcells of Glasse adhering to the Test or Cuppel, and this Glass though Emergent as well as the Gold or Litharge upon your Analysis, you will not I hope allow to have been a third Ingredient of the Mass out of which the fire produc'd it.
Both _Philoponus_ and _Themistius_ were about to reply, when _Eleutherius_ apprehending that the Prosecution of this Dispute would take up time, which might be better employ'd, thought fit to prevent them by saying to _Carneades_: You made at least half a Promise, when you first propos'd this Objection, that you would not (now at least) insist on it, nor indeed does it seem to be of absolute necessity to your cause, that you should. For though you should grant that there are Elements, it would not follow that there must be precisely four. And therefore I hope you will proceed to acquaint us with your other and more considerable Objections against _Themistius's_ Opinion, especially since there is so great a Disproportion in Bulke betwixt the Earth, Water and Air, on the one part, and those little parcells of resembling substances, that the fire separates from _Concretes_ on the other part, that I can scarce think that you are serious, when to lose no advantage against your Adversary, you seem to deny it to be rational, to conclude these great simple Bodies to be the Elements, and not the Products of compounded ones.
What you alledge (replies _Carneades_) of the Vastness of the Earth and Water, has long since made me willing to allow them to be the greatest and chief Masses of Matter to be met with here below: But I think I could shew You, if You would give me leave, that this will prove only that the Elements, as You call them, are the chief Bodies that make up the neighbouring part of the World, but not that they are such Ingredients as every mixt Body must consist of. But since You challenge me of something of a Promise, though it be not an entire one, Yet I shall willingly perform it. And indeed I intended not when I first mention'd this Objection, to insist on it at present against _Themistius_, (as I plainly intimated in my way of proposing it:) being only desirous to let you see, that though I discern'd my Advantages, yet I was willing to forego some of them, rather then appear a rigid Adversary of a Cause so weak, that it may with safety be favourably dealt with. But I must here profess, and desire You to take Notice of it, that though I pass on to another Argument, it is not because I think this first invalid. For You will find in the Progress of our Dispute, that I had some reason to question the very way of Probation imploy'd both by Peripateticks and Chymists, to evince the being and number of the Elements. For that there are such, and that they are wont to be separated by the Analysis made by Fire, is indeed taken for granted by both Parties, but has not (for ought I know) been so much as plausibly attempted to be proved by either. Hoping then that when we come to that part of our Debate, wherein Considerations relating to this Matter are to be treated of, you will remember what I have now said, and that I do rather for a while suppose, then absolutely grant the truth of what I have question'd, I will proceed to another Objection.
And hereupon _Eleutherius_ having promis'd him not to be unmindfull, when time should serve, of what he had declar'd.
I consider then (sayes _Carneades_) in the next place, that there are divers Bodies out of which _Themistius_ will not prove in haste, that there can be so many Elements as four extracted by the Fire. And I should perchance trouble him if I should ask him what Peripatetick can shew us, (I say not, all the four Elements, for that would be too rigid a Question, but) any one of them extracted out of Gold by any degree of Fire whatsoever. Nor is Gold the only Bodie in Nature that would puzzle an _Aristotelian_, that is no more [Errata: (that is no more)] to analyze by the Fire into Elementary Bodies, since, for ought I have yet observ'd, both Silver and calcin'd _Venetian_ Talck, and some other Concretes, not necessary here to be nam'd, are so fixt, that to reduce any of them into four Heterogeneous Substances has hitherto prov'd a Task much too hard, not only for the Disciples of _Aristotle_, but those of _Vulcan_, at least, whilst the latter have employ'd only Fire to make the _Analysis_.
The next Argument (continues _Carneades_) that I shall urge against _Themistius's_ Opinion shall be this, That as there are divers Bodies whose _Analysis_ by Fire cannot reduce them into so many Heterogeneous Substances or Ingregredients [Transcriber's Note: Ingredients] as four, so there are others which may be reduc'd into more, as the Blood (and divers other parts) of Men and other Animals, which yield when analyz'd five distinct Substances, Phlegme, Spirit, Oyle, Salt and Earth, as Experience has shewn us in distilling Mans Blood, Harts-Horns, and divers other Bodies that belonging to the Animal-Kingdom abound with not uneasily sequestrable Salt.
THE
SCEPTICAL CHYMIST:
OR
CHYMICO-PHYSICAL
Doubts & Paradoxes,
Touching the
EXPERIMENTS
WHEREBY
VULGAR SPAGYRISTS
Are wont to Endeavour to Evince their
SALT, SULPHUR
AND
MERCURY,
TO BE
The True Principles of Things.
_Utinam jam tenerentur omnia, & inoperta ac confessa Veritas esset! Nihil ex Decretis mutaremus. Nunc Veritatem cum eis qui docent, quaerimus._ Sen.
_LONDON,_
Printed for _J. Crooke_, and are to be sold at the Ship in St. _Pauls_ Church-Yard. 1661.
THE
SCEPTICAL CHYMIST.
_The First Part._
I am (sayes _Carneades_) so unwilling to deny _Eleutherius_ any thing, that though, before the rest of the Company I am resolv'd to make good the part I have undertaken of a Sceptick; yet I shall readily, since you will have it so, lay aside for a while the Person of an Adversary to the Peripateticks and Chymists; and before I acquaint you with my Objections against their Opinions, acknowledge to you what may be (whether truly or not) tollerably enough added, in favour of a certain number of Principles of mixt Bodies, to that grand and known Argument from the _Analysis_ of compound Bodies, which I may possibly hereafter be able to confute.
And that you may the more easily Examine, and the better Judge of what I have to say, I shall cast it into a pretty number of distinct Propositions, to which I shall not premise any thing; because I take it for granted, that you need not be advertis'd, that much of what I am to deliver, whether for or against a determinate number of Ingredients of mix'd Bodies, may be indifferently apply'd to the four Peripatetick Elements, and the three Chymical Principles, though divers of my Objections will more peculiarly belong to these last nam'd, because the Chymical _Hypothesis_ seeming to be much more countenanc'd by Experience then the other, it will be expedient to insist chiefly upon the disproving of that; especially since most of the Arguments that are imploy'd against it, may, by a little variation, be made to conclude, at least as strongly against the less plausible, _Aristotelian_ Doctrine.
To proceed then to my Propositions, I shall begin with this. That
[Sidenote: Propos. I.]
_It seems not absurd to conceive that at the first Production of mixt Bodies, the Universal Matter whereof they among other Parts of the Universe consisted, was actually divided into little Particles of several sizes and shapes variously mov'd._
This (sayes _Carneades_) I suppose you will easily enough allow. For besides that which happens in the Generation, Corruption, Nutrition, and wasting of Bodies, that which we discover partly by our _Microscopes_ of the extream littlenesse of even the scarce sensible parts of Concretes; and partly by the Chymical Resolutions of mixt Bodies, and by divers other Operations of Spagyrical Fires upon them, seems sufficiently to manifest their consisting of parts very minute and of differing Figures. And that there does also intervene a various local Motion of such small Bodies, will scarce be denied; whether we chuse to grant the Origine of Concretions assign'd by _Epicurus_, or that related by _Moses_. For the first, as you well know, supposes not only all mixt Bodies, but all others to be produc'd by the various and casual occursions of Atomes, moving themselves to and fro by an internal Principle in the Immense or rather Infinite _Vacuum_. And as for the inspir'd Historian, He, informing us that the great and Wise Author of Things did not immediately create Plants, Beasts, Birds, &c. but produc'd them out of those portions of the pre-existent, though created, Matter, that he calls Water and Earth, allows us to conceive, that the constituent Particles whereof these new Concretes were to consist, were variously moved in order to their being connected into the Bodies they were, by their various Coalitions and Textures, to compose.
But (continues _Carneades_) presuming that the first Proposition needs not be longer insisted on, I will pass on to the second, and tell you that
[Sidenote: Propos. II.]
_Neither is it impossible that of these minute Particles divers of the smallest and neighbouring ones were here and there associated into minute Masses or Clusters, and did by their Coalitions constitute great store of such little primary Concretions or Masses as were not easily dissipable into such Particles as compos'd them._
To what may be deduc'd, in favour of this Assertion, from the Nature of the Thing it self, I will add something out of Experience, which though I have not known it used to such a purpose, seems to me more fairly to make out that there May be Elementary Bodies, then the more questionable Experiments of Peripateticks and Chymists prove that there Are such. I consider then that Gold will mix and be colliquated not only with Silver, Copper, Tin and Lead, but with Antimony, _Regulus Martis_ and many other Minerals, with which it will compose Bodies very differing both from Gold, and the other Ingredients of the resulting Concretes. And the same Gold will also by common _Aqua Regis_, and (I speak it knowingly) by divers other _Menstruums_ be reduc'd into a seeming Liquor, in so much that the Corpuscles of Gold will, with those of the _Menstruum_, pass through Cap-Paper, and with them also coagulate into a Crystalline Salt. And I have further try'd, that with a small quantity of a certain Saline Substance I prepar'd, I can easily enough sublime Gold into the form of red Crystalls of a considerable length; and many other wayes may Gold be disguis'd, and help to constitute Bodies of very differing Natures both from It and from one another, and neverthelesse be afterward reduc'd to the self-same Numerical, Yellow, Fixt, Ponderous and Malleable Gold it was before its commixture. Nor is it only the fixedst of Metals, but the most fugitive, that I may employ in favour of our Proposition: for Quicksilver will with divers Metals compose an _Amalgam_, with divers _Menstruums_ it seems to be turn'd into a Liquor, with _Aqua fortis_ will be brought into either a red or white Powder or precipitate, with Oyl of Vitriol into a pale Yellow one, with Sulphur it will compose a blood-red and volatile Cinaber, with some Saline Bodies it will ascend in form of a Salt which will be dissoluble in water; with _Regulus_ of Antimony and Silver I have seen it sublim'd into a kinde of Crystals, with another Mixture I reduc'd it into a malleable Body, into a hard and brittle Substance by another: And some there are who affirm, that by proper Additaments they can reduce Quicksilver into Oyl, nay into Glass, to mention no more. And yet out of all these exotick Compounds, we may recover the very same running Mercury that was the main Ingredient of them, and was so disguis'd in them. Now the Reason (proceeds _Carneades_) that I have represented these things concerning Gold and Quicksilver, is, That it may not appear absurd to conceive, that such little primary Masses or Clusters, as our Proposition mentions, may remain undissipated, notwithstanding their entring into the composition of various Concretions, since the Corpuscle of Gold and Mercury, though they be not primary Concretions of the most minute Particles or matter, but confessedly mixt Bodies, are able to concurre plentifully to the composition of several very differing Bodies, without losing their own Nature or Texture, or having their cohaesion violated by the divorce of their associated parts or Ingredients.
Give me leave to add (sayes _Eleutherius_) on this occasion, to what you now observ'd, that as confidently as some Chymists, and other modern Innovators in Philosophy are wont to object against the Peripateticks, That from the mixture of their four Elements there could arise but an inconsiderable variety of compound Bodies; yet if the _Aristotelians_ were but half as well vers'd in the works of Nature as they are in the Writings of their Master, the propos'd Objection would not so calmly triumph, as for want of Experiments they are fain to suffer it to do. For if we assigne to the Corpuscles, whereof each Element consists, a peculiar size and shape, it may easily enough be manifested, That such differingly figur'd Corpuscles may be mingled in such various Proportions, and may be connected so many several wayes, that an almost incredible number of variously qualified Concretes may be compos'd of them. Especially since the Corpuscles of one Element may barely, by being associated among themselves, make up little Masses of differing size and figure from their constituent parts: and since also to the strict union of such minute Bodies there seems oftentimes nothing requisite, besides the bare Contact of a great part of their Surfaces. And how great a variety of _Phaenomena_ the same matter, without the addition of any other, and only several ways dispos'd or contexed, is able to exhibit, may partly appear by the multitude of differing Engins which by the contrivances of skilful Mechanitians, and the dexterity of expert Workmen, may be made of Iron alone. But in our present case being allow'd to deduce compound Bodies from four very differently qualified sorts of matter, he who shall but consider what you freshly took notice of concerning the new Concretes resulting from the mixture of incorporated Minerals, will scarce doubt but that the four Elements mannag'd by Natures Skill may afford a multitude of differing Compounds.
I am thus far of your minde (sayes _Carneades_) that the _Aristotelians_ might with probability deduce a much greater number of compound Bodies from the mixture of their four Elements, than according to their present _Hypothesis_ they can, if instead of vainly attempting to deduce the variety and properties of all mixt Bodies from the Combinations and Temperaments of the four Elements, as they are (among them) endowd with the four first Qualities, they had endeavoured to do it by the Bulk and Figure of the smallest parts of those supposed Elements. For from these more Catholick and Fruitfull Accidents of the Elementary matter may spring a great variety of Textures, upon whose Account a multitude of compound Bodies may very much differ from one another. And what I now observe touching the four Peripatetick Elements, may be also applyed, _mutatis mutandis_, (as they speak) to the Chymical Principles. But (to take notice of that by the by) both the one and the other, must, I fear, call in to their assistance something that is not Elementary, to excite or regulate the motion of the parts of the matter, and dispose them after the manner requisite to the Constitution of particular Concretes. For that otherwise they are like to give us but a very imperfect account of the Origine of very many mixt Bodies, It would, I think, be no hard matter to perswade you, if it would not spend time, and were no Digression, to examine, what they are wont to alledge of the Origine of the Textures and Qualities of mixt Bodies, from a certain substantial Form, whose Origination they leave more obscure than what it is assum'd to explicate.
But to proceed to a new Proposition.
[Sidenote: Propos. III.]
_I shall not peremptorily deny, that from most of such mixt Bodies as partake either of Animal or Vegetable Nature, there may by the Help of the Fire, be actually obtain'd a determinate number (whether Three, Four or Five, or fewer or more) of Substances, worthy of differing Denominations._
Of the Experiments that induce me to make this Concession, I am like to have occasion enough to mention several in the prosecution of my Discourse. And therefore, that I may not hereafter be oblig'd to trouble You and my self with needless Repetitions, I shall now only desire you to take notice of such Experiments, when they shall be mention'd, and in your thoughts referre them hither.
To these three Concessions I have but this Fourth to add, That
[Sidenote: Propos. IV.]
_It may likewise be granted, that those distinct Substances, which Concretes generally either afford or are made up of, may without very much Inconvenience be call'd the Elements or Principles of them._
When I said, _without very much Inconvenience_, I had in my Thoughts that sober Admonition of _Galen_, _Cum de re constat, de verbis non est Litigandum_. And therefore also I scruple not to say _Elements_ or _Principles_, partly because the Chymists are wont to call the Ingredients of mixt Bodies, _Principles_, as the _Aristotelians_ name them _Elements_; I would here exclude neither. And, partly, because it seems doubtfull whether the same Ingredients may not be call'd _Principles_? as not being compounded of any more primary Bodies: and _Elements_, in regard that all mix'd Bodies are compounded of them. But I thought it requisite to limit my Concession by premising the words, _very much_, to the word _Inconvenience_, because that though the Inconvenience of calling the distinct Substances, mention'd in the Proposition _Elements_ or _Principles_, be not very great, yet that it is an Impropriety of Speech, and consequently in a matter of this moment not to be altogether overlook'd, You will perhaps think, as well as I, by that time you shall have heard the following part of my Discourse, by which you will best discern what Construction to put upon the former Propositions, and how far they may be look'd upon, as things that I concede as true, and how far as things I only represent as specious enough to be fit to be consider'd.
And now _Eleutherius_ (continues _Carneades_) I must resume the person of a Sceptick, and as such, propose some part of what may be either dislik't, or at least doubted of in the common _Hypothesis_ of the Chymists: which if I examine with a little the more freedom, I hope I need not desire you (a Person to whom I have the Happinesse of being so well known) to look upon it as something more suitable to the Employment whereto the Company has, for this Meeting, doom'd me; then either to my Humour or my Custom.
Now though I might present you many things against the Vulgar Chymical Opinion of the three Principles, and the Experiments wont to be alledg'd as Demonstrations of it, yet those I shall at present offer you may be conveniently enough comprehended in four Capital Considerations; touching all which I shall only premise this in general, That since it is not my present Task so much to assert an _Hypothesis_ of my own, as to give an Account wherefore I suspect the Truth of that of the Chymists, it ought not to be expected that all my Objections should be of the most cogent sort, since it is reason enough to Doubt of a propos'd Opinion, that there appears no cogent Reason for it.
To come then to the Objections themselves; I consider in the first place, That notwithstanding what common Chymists have prov'd or taught, it may reasonably enough be Doubted, how far, and in what sence, Fire ought to be esteem'd the genuine and universal Instrument of analyzing mixt Bodies.
This Doubt, you may remember, was formerly mention'd, but so transiently discours'd of, that it will now be fit to insist upon it; And manifest that it was not so inconsiderately propos'd as our Adversaries then imagin'd.
But, before I enter any farther into this Disquisition, I cannot but here take notice, that it were to be wish'd, our Chymists had clearly inform'd us what kinde of Division of Bodies by Fire must determine the number of the Elements: For it is nothing near so easy as many seem to think, to determine distinctly the Effects of Heat, as I could easily manifest, if I had leasure to shew you how much the Operations of Fire may be diversify'd by Circumstances. But not wholly to pass by a matter of this Importance, I will first take notice to you, that _Guajacum_ (for Instance) burnt with an open Fire in a Chimney, is sequestred into Ashes and Soot, whereas the same Wood distill'd in a Retort does yield far other Heterogeneities, (to use the _Helmontian_ expression) and is resolv'd into Oyl, Spirit, Vinager, Water and Charcoal; the last of which to be reduc'd into Ashes, requires the being farther calcin'd then it can be in a close Vessel: Besides having kindled Amber, and held a clean Silver Spoon, or some other Concave and smooth Vessel over the Smoak of its Flame, I observ'd the Soot into which that Fume condens'd, to be very differing from any thing that I had observ'd to proceed from the steam of Amber purposely (for that is not usual) distilled _per se_ in close Vessels. Thus having, for Tryals sake, kindled Camphire, and catcht the Smoak that copiously ascended out of the Flame, it condens'd into a Black and unctuous Soot, which would not have been guess'd by the Smell or other Properties to have proceeded from Camphire: whereas having (as I shall otherwhere more fully declare) expos'd a quantity of that Fugitive Concrete to a gentle heat in a close Glass-Vessel, it sublim'd up without seeming to have lost any thing of its whiteness, or its Nature, both which it retain'd, though afterwards I so encreased the Fire as to bring it to Fusion. And, besides Camphire, there are divers other Bodies (that I elsewhere name) in which the heat in close Vessels is not wont to make any separation of Heterogeneities, but only a comminution of Parts, those that rise first being Homogeneal with the others, though subdivided into smaller Particles: whence Sublimations have been stiled, _The Pestles of the Chymists_. But not here to mention what I elsewhere take notice of, concerning common Brimstone once or twice sublim'd, that expos'd to a moderate Fire in Subliming-Pots, it rises all into dry, and almost tastless, Flowers; Whereas being expos'd to a naked Fire it affords store of a Saline and Fretting Liquor: Not to mention this, I say, I will further observe to you, that as it is considerable in the _Analysis_ of mixt Bodies, whether the Fire act on them when they are expos'd to the open Air, or shut up in close Vessels, so is the degree of Fire by which the _Analysis_ is attempted of no small moment. For a milde _Balneum_ will sever unfermented Blood (for Instance) but into Phlegme and _Caput mortuum_, the later whereof (which I have sometimes had) hard, brittle, and of divers Colours, (transparent almost like Tortoise-shell) press'd by a good Fire in a Retort yields a Spirit, an Oyl or two, and a volatile Salt, besides a [Errata: another] _Caput mortuum_. It may be also pertinent to our present Designe, to take notice of what happens in the making and distilling of Sope; for by one degree of Fire the Salt, the Water and the Oyl or Grease, whereof that factitious Concrete is made up, being boyl'd up together are easily brought to mingle and incorporate into one Mass; but by another and further degree of Heat the same Mass may be again divided into an oleagenous, an aqueous, a Saline, and an Earthy part. And so we may observe that impure Silver and Lead being expos'd together to a moderate Fire, will thereby be colliquated into one Mass, and mingle _per minima_, as they speak, whereas a much vehementer Fire will drive or carry off the baser Metals (I mean the Lead, and the Copper or other Alloy) from the Silver, though not, for ought appears, separate them from one another. Besides, when a Vegetable abounding in fixt Salt is analyz'd by a naked Fire, as one degree of Heat will reduce it into Ashes, (as the Chymists themselves teach us) so, by only a further degree of Fire, those Ashes may be vitrified and turn'd into Glass. I will not stay to examine how far a meere Chymist might on this occasion demand, If it be lawful for an _Aristotelian_ to make Ashes, (which he mistakes for meere Earth) pass for an Element, because by one degree of Fire it may be produc'd, why a Chymist may not upon the like Principle argue, that Glass is one of the Elements of many Bodies, because that also may be obtain'd from them, barely by the Fire? I will not, I say, lose time to examine this, but observe, that by a Method of applying the Fire, such similar Bodies may be obtain'd from a Concrete, as Chymists have not been able to separate; either by barely burning it in an open Fire, or by barely distilling it in close Vessels. For to me it seems very considerable, and I wonder that men have taken so little notice of it, that I have not by any of the common wayes of Distillation in close Vessels, seen any separation made of such a volatile Salt as is afforded us by Wood, when that is first by an open Fire divided into Ashes and Soot, and that Soot is afterwards plac'd in a strong Retort, and compell'd by an urgent Fire to part with its Spirit, Oyl and Salt; for though I dare not peremptorily deny, that in the Liquors of _Guajacum_ and other Woods distill'd in Retorts after the common manner, there may be Saline parts, which by reason of the Analogy may pretend to the name of some kinde of volatile Salts; yet questionless there is a great disparity betwixt such Salts and that which we have sometimes obtain'd upon the first Distillation of Soot (though for the most part it has not been separated from the first or second Rectification, and sometimes not till the third) For we could never yet see separated from Woods analyz'd only the vulgar way in close vessels any volatile Salt in a dry and Saline form, as that of Soot, which we have often had very Crystalline and Geometrically figur'd. And then, whereas the Saline parts of the Spirits of _Guajacum_, &c. appear upon distillation sluggish enough, the Salt of Soot seems to be one of the most volatile Bodies in all Nature; and if it be well made will readily ascend with the milde heat of a Furnace, warm'd only by the single Wieck of a Lamp, to the top of the highest Glass Vessels that are commonly made use of for Distillation: and besides all this, the taste and smell of the Salt of Soot are exceeding differing from those of the Spirits of _Guajacum_, &c. and the former not only smells and tastes much less like a vegetable Salt, than like that of Harts-horn, and other Animal Concretes; but in divers other Properties seems more of Kinne to the Family of Animals, than to that of vegetable Salts, as I may elsewhere (God permitting) have an occasion more particularly to declare. I might likewise by some other Examples manifest, That the Chymists, to have dealt clearly, ought to have more explicitly and particularly declar'd by what Degree of Fire, and in what manner of Application of it, they would have us Judge a Division made by the Fire to be a true _Analysis_ into their Principles, and the Productions of it to deserve the name of Elementary Bodies. But it is time that I proceed to mention the particular Reasons that incline me to Doubt, whether the Fire be the true and universal Analyzer of mixt Bodies; of which Reasons what has been already objected may pass for one.
In the next place I observe, That there are some mixt Bodies from which it has not been yet made appear, that any degree of Fire can separate either Salt or Sulphur or Mercury, much less all the Three. The most obvious Instance of this Truth is Gold, which is a Body so fix'd, and wherein the Elementary Ingredients (if it have any) are so firmly united to each other, that we finde not in the operations wherein Gold is expos'd to the Fire, how violent soever, that it does discernably so much as lose of its fixednesse or weight, so far is it from being dissipated into those Principles, whereof one at least is acknowledged to be Fugitive enough; and so justly did the Spagyricall Poet somewhere exclaim,
_Cuncta adeo miris illic compagibus harent._
And I must not omit on this occasion to mention to you, _Eleutherius_, the memorable Experiment that I remember I met with in _Gasto Claveus_,[2] who, though a Lawyer by Profession, seems to have had no small Curiosity and Experience in Chymical affairs: He relates then, that having put into one small Earthen Vessel an Ounce of the most pure Gold, and into another the like weight of pure Silver, he plac'd them both in that part of a Glass-house Furnace wherein the Workmen keep their Metal, (as our English Artificers call their Liquid Glass) continually melted, and that having there kept both the Gold and the Silver in constant Fusion for two Moneths together, he afterwards took them out of the Furnace and the Vessels, and weighing both of them again, found that the Silver had not lost above a 12th part of its weight, but the Gold had not of his lost any thing at all. And though our Author endeavours to give us of this a Scholastick Reason, which I suppose you would be as little satisfied with, as I was when I read it; yet for the matter of Fact, which will serve our present turne, he assures us, that though it be strange, yet Experience it self taught it him to be most true.
[Footnote 2: _Gasto Claveus_ Apolog. Argur. & Chrysopera.]
And though there be not perhaps any other Body to be found so perfectly fix'd as Gold, yet there are divers others so fix'd or compos'd, at least of so strictly united parts, that I have not yet observ'd the Fire to separate from them any one of the Chymists Principles. I need not tell you what Complaints the more Candid and Judicious of the Chymists themselves are wont to make of those Boasters that confidently pretend, that they have extracted the Salt or Sulphur of Quicksilver, when they have disguis'd it by Additaments, wherewith it resembles the Concretes whose Names are given it; whereas by a skilful and rigid _Examen_, it may be easily enough stript of its Disguises, and made to appear again in the pristine form of running Mercury. The pretended Salts and Sulphurs being so far from being Elementary parts extracted out of the Bodie of Mercurie, that they are rather (to borrow a terme of the Grammarians) De-compound Bodies, made up of the whole Metal and the _Menstruum_ or other Additaments imploy'd to disguise it. And as for Silver, I never could see any degree of Fire make it part with any of its three Principles. And though the Experiment lately mentioned from _Claveus_ may beget a Suspition that Silver may be dissipated by Fire, provided it be extreamly violent and very lasting: yet it will not necessarily follow, that because the Fire was able at length to make the Silver lose a little of its weight, it was therefore able to dissipate it into its Principles. For first I might alledge that I have observ'd little Grains of Silver to lie hid in the small Cavities (perhaps glas'd over by a vitrifying heat) in Crucibles, wherein Silver has been long kept in Fusion, whence some Goldsmiths of my Acquaintance make a Benefit by grinding such Crucibles to powder, to recover out of them the latent particles of Silver. And hence I might argue, that perhaps _Claveus_ was mistaken, and imagin'd that Silver to have been driven away by the Fire, that indeed lay in minute parts hid in his Crucible, in whose pores so small a quantity as he mist of so ponderous a Bodie might very well lie conceal'd.
But Secondly, admitting that some parts of the Silver were driven away by the violence of the Fire, what proof is there that it was either the Salt, the Sulphur, or the Mercury of the Metal, and not rather a part of it homogeneous to what remain'd? For besides, that the Silver that was left seem'd not sensibly alter'd, which probably would have appear'd, had so much of any one of its Principles been separated from it: We finde in other Mineral Bodies of a less permanent nature than Silver, that the Fire may divide them into such minute parts, as to be able to carry them away with its self, without at all destroying their Nature. Thus we see that in the refining of Silver, the Lead that is mix'd with it (to carry away the Copper or other ignoble Mineral that embases the Silver) will, if it be let alone, in time evaporate away upon the Test; but if (as is most usual amongst those that refine great quantities of Metals together) the Lead be blown off from the Silver by Bellowes, that which would else have gone away in the Form of unheeded steams, will in great part be collected not far from the Silver, in the Form of a darkish Powder or Calx, which, because it is blown off from Silver, they call Litharge of Silver. And thus _Agricola_[3] in divers places informs us, when Copper, or the Oare of it is colliquated by the violence of the Fire with _Cadmia_, the Sparks that in great multitudes do fly upwards do, some of them, stick to the vaulted Roofs of the Furnaces, in the form of little and (for the most part) White Bubbles, which therefore the Greeks, and, in Imitation of them, our Drugsters call _Pompholix_: and others more heavy partly adhere to the sides of the Furnace, and partly (especially if the Covers be not kept upon the Pots) fall to the Ground, and by reason of their Ashy Colour as well as Weight were called by the same Greeks [Greek: spodos], which, I need not tell you, in their Language signifies Ashes. I might add, that I have not found that from Venetian Talck (I say Venetian, because I have found other kinds of that Mineral more open) from the _Lapis Ossifragus_, (which the Shops call _Ostiocolla_) from _Muscovia_ Glass, from pure and Fusible Sand, to mention now no other Concretes; those of my Acquaintance that have try'd have been able by the Fire to separate any one of the Hypostatical Principles, which you will the less scruple to believe, if you consider that Glass may be made by the bare Colliquation of the Salt and Earth remaining in the Ashes of a burnt Plant, and that yet common Glass, once made, does so far resist the violence of the Fire, that most Chymists think it a Body more undestroyable then Gold it self. For if the Artificer can so firmly unite such comparative gross Particles as those of Earth and Salt that make up common Ashes, into a Body indissoluble by Fire; why may not Nature associate in divers Bodies the more minute Elementary Corpuscles she has at hand too firmly to let them be separable by the Fire? And on this Occasion, _Eleutherius_, give me leave to mention to you two or three sleight Experiments, which will, I hope, be found more pertinent to our present Discourse, than at first perhaps they will appear. The first is, that, having (for Tryals sake) put a quantity of that Fugitive Concrete, Camphire, into a Glass Vessel, and plac'd it in a gentle Heat, I found it (not leaving behinde, according to my Estimate, not so much as one Grain) to sublime to the Top of the Vessel into Flowers: which in Whiteness, Smell, &c. seem'd not to differ from the Camphire it self. Another Experiment is that of _Helmont_, who in several places affirms, That a Coal kept in a Glass exactly clos'd will never be calcin'd to Ashes, though kept never so long in a strong Fire. To countenance which I shall tell you this Tryal of my own, That having sometimes distilled some Woods, as particularly Box, whilst our _Caput mortuum_ remain'd in the Retort, it continued black like Charcoal, though the Retort were Earthen, and kept red-hot in a vehement Fire; but as soon as ever it was brought out of the candent Vessel into the open Air, the burning Coals did hastily degenerate or fall asunder, without the Assistance of any new Calcination, into pure white Ashes. And to these two I shall add but this obvious and known Observation, that common Sulphur (if it be pure and freed from its Vinager) being leasurely sublim'd in close Vessels, rises into dry Flowers, which may be presently melted into a Bodie of the same Nature with that which afforded them. Though if Brimstone be burnt in the open Air it gives, you know, a penetrating Fume, which being caught in a Glass-Bell condenses into that acid Liquor called Oyl of Sulphur _per Campanam_. The use I would make of these Experiments collated with what I lately told you out of _Agricola_ is this, That even among the Bodies that are not fixt, there are divers of such a Texture, that it will be hard to make it appear, how the Fire, as Chymists are wont to imploy it, can resolve them into Elementary Substances. For some Bodies being of such a Texture that the Fire can drive them into the cooler and less hot part of the Vessels wherein they are included, and if need be, remove them from place to place to fly the greatest heat, more easily than it can divorce their Elements (especially without the Assistance of the Air) we see that our Chymists cannot Analyze them in close Vessels, and of other compound Bodies the open Fire can as little separate the Elements. For what can a naked Fire do to Analyze a mixt Bodie, if its component Principles be so minute, and so strictly united, that the Corpuscles of it need less heat to carry them up, than is requisite to divide them into their Principles. So that of some Bodies the Fire cannot in close Vessels make any _Analysis_ at all, and others will in the open Air fly away in the Forms of Flowers or Liquors, before the Heat can prove able to divide them into their Principles. And this may hold, whether the various similar parts of a Concrete be combin'd by Nature or by Art; For in factitious _Sal Armoniack_ we finde the common and the Urinous Salts so well mingled, that both in the open Fire, and in subliming Vessels they rise together as one Salt, which seems in such Vessels irresoluble by Fire alone. For I can shew you _Sal Armoniack_ which after the ninth Sublimation does still retain its compounded Nature. And indeed I scarce know any one Mineral, from which by Fire alone Chymists are wont to sever any Substance simple enough to deserve the name of an Element or Principle. For though out of native Cinnaber they distill Quicksilver, and though from many of those Stones that the Ancients called _Pyrites_ they sublime Brimstone, yet both that Quicksilver and this Sulphur being very often the same with the common Minerals that are sold in the Shops under those names, are themselves too much compounded Bodies to pass for the Elements of such. And thus much, _Eleutherius_, for the Second Argument that belongs to my First Consideration; the others I shall the lesse insist on, because I have dwelt so long upon this.
[Footnote 3: _Agricola_ de Natura Fossil. Lib. 9. Cap. 11. & 12.]
Proceed we then in the next place to consider, That there are divers Separations to be made by other means, which either cannot at all, or else cannot so well be made by the Fire alone. When Gold and Silver are melted into one Mass, it would lay a great Obligation upon Refiners and Goldsmiths to teach them the Art of separating them by the Fire, without the trouble and charge they are fain to be at to sever them. Whereas they may be very easily parted by the Affusion of Spirit of Nitre or _Aqua fortis_ (which the French therefore call _Eau de Depart_:) so likewise the Metalline part of Vitriol will not be so easily and conveniently separated from the Saline part even by a violent Fire, as by the Affusion of certain Alkalizate Salts in a liquid Form upon the Solution of Vitriol made in common water. For thereby the acid Salt of the Vitriol, leaving the Copper it had corroded to joyn with the added Salts, the Metalline part will be precipitated to the bottom almost like Mud. And that I may not give Instances only in De-compound Bodies, I will add a not useless one of another kinde. Not only Chymists have not been able (for ought is vulgarly known) by Fire alone to separate true Sulphur from Antimony; but though you may finde in their Books many plausible Processes of Extracting it, yet he that shall make as many fruitlesse Tryals as I have done to obtain it by, most of them will, I suppose, be easily perswaded, that the Productions of such Processes are Antimonial Sulphurs rather in Name than Nature. But though Antimony sublim'd by its self is reduc'd but to a volatile Powder, or Antimonial Flowers, of a compounded Nature like the Mineral that affords them: yet I remember that some years ago I sublim'd out of Antimony a Sulphur, and that in greater plenty then ever I saw obtain'd from that Mineral, by a Method which I shall therefore acquaint you with, because Chymists seem not to have taken notice of what Importance such Experiments may be in the Indagation of the Nature, and especially of the Number of the Elements. Having then purposely for Tryals sake digested eight Ounces of good and well powder'd Antimony with twelve Ounces of Oyl of Vitriol in a well stopt Glas-Vessel for about six or seven Weeks; and having caus'd the Mass (grown hard and brittle) to be distill'd in a Retort plac'd in Sand, with a strong Fire; we found the Antimony to be so opened, or alter'd by the _Menstruum_ wherewith it had been digested, That whereas crude Antimony, forc'd up by the Fire, arises only in Flowers, our Antimony thus handled afforded us partly in the Receiver, and partly in the Neck and at the Top of the Retort, about an Ounce of Sulphur, yellow and brittle like common Brimstone, and of so Sulphureous a smell, that upon the unluting the Vessels it infected the Room with a scarce supportable stink. And this Sulphur, besides the Colour and Smell, had the perfect Inflamability of common Brimstone, and would immediately kindle (at the Flame of a Candle) and burn blew like it. And though it seem'd that the long digestion wherein our Antimony and _Menstruum_ were detain'd, did conduce to the better unlocking of the Mineral, yet if you have not the leasure to make so long a Digestion, you may by incorporating with powder'd Antimony a convenient Quantity of Oyl of Vitriol, and committing them immediately to Distillation, obtain a little Sulphur like unto the common one, and more combustible than perhaps you will at first take notice of. For I have observ'd, that though (after its being first kindled) the Flame would sometimes go out too soon of its self, if the same Lump of Sulphur were held again to the Flame of a Candle, it would be rekindled and burn a pretty while, not only after the second, but after the third or fourth accension. You, to whom I think I shewed my way of discovering something of Sulphureous in Oyl of Vitriol, may perchance suspect, _Eleutherius_, either that this Substance was some Venereal Sulphur that lay hid in that Liquor, and was by this operation only reduc'd into a manifest Body; or else that it was a compound of the unctuous parts of the Antimony, and the Saline ones of the Vitriol, in regard that (as _Gunther_[4] informs us) divers learned men would have Sulphur to be nothing but a mixture made in the Bowels of the Earth of Vitriolate Spirits and a certain combustible Substance. But the Quantity of Sulphur we obtain'd by Digestion was much too great to have been latent in the Oyl of Vitriol. And that Vitriolate Spirits are not necessary to the Constitution of such a Sulphur as ours, I could easily manifest, if I would acquaint you with the several wayes by which I have obtain'd, though not in such plenty, a Sulphur of Antimony, colour'd and combustible like common Brimstone. And though I am not now minded to discover them, yet I shall tell you, that to satisfie some Ingenious Men, that distill'd Vitriolate Spirits are not necessary to the obtaining of such a Sulphur as we have been considering, I did by the bare distillation of only Spirit of Nitre, from its weight of crude Antimony separate, in a short time, a yellow and very inflamable Sulphur, which, for ought I know, deserves as much the name of an Element, as any thing that Chymists are wont to separate from any Mineral by the Fire. I could perhaps tell you of other Operations upon Antimony, whereby That may be extracted from it, which cannot be forc'd out of it by the Fire; but I shall reserve them for a fitter Opportunity, and only annex at present this sleight, but not impertinent Experiment. That whereas I lately observed to you, that the Urinous and common Salts whereof _Sal Armoniack_ consists, remain'd unsever'd by the Fire in many successive Sublimations, they may be easily separated, and partly without any Fire at all, by pouring upon the Concrete finely powder'd, a Solution of Salt of Tartar, or of the Salt of Wood-Ashes; for upon your diligently mixing of these you will finde your Nose invaded with a very strong smell of Urine, and perhaps too your Eyes forc'd to water by the same subtle and piercing Body that produces the stink; both these effects proceeding from hence, that by the Alcalizate Salt, the Sea Salt that enter'd the composition of the _Sal Armoniack_ is mortify'd and made more fixt, and thereby a divorce is made between it and the volatile Urinous Salt, which being at once set at liberty, and put into motion, begins presently to fly away, and to offend the Nostrils and Eyes it meets with by the way. And if the operation of these Salts be in convenient Glasses promoted by warmth, though but by that of a Bath, the ascending Steams may easily be caught and reduc'd into a penetrant Spirit, abounding with a Salt, which I have sometimes found to be separable in a Crystalline Form. I might add to these Instances, that whereas Sublimate, consisting, as you know, of Salts & Quicksilver combin'd and carried up together by Heat, may be Sublim'd, I know not how often, by a like degree of Fire, without suffering any divorce of the component Bodies, the Mercury may be easily sever'd from the adhering Salts, if the Sublimate be distill'd from Salt of Tartar, Quick Lime, or such Alcalizate Bodies. But I will rather observe to you, _Eleutherius_, what divers ingenious men have thought somewhat strange; that by such an Additament that seems but only to promote the Separation, there may be easily obtain'd from a Concrete that by the Fire alone is easily divisible into all the Elements that Vegetables are suppos'd to consist of, such a similar Substance as differs in many respects from them all, and consequently has by many of the most Intelligent Chymists been denied to be contain'd in the mixt Body. For I know a way, and have practis'd it, whereby common Tartar, without the addition of any thing that is not perfectly a Mineral except Salt-petre, may by one Distillation in an Earthen Retort be made to afford good store of real Salt, readily dissoluble in water, which I found to be neither acid, nor of the smell of Tartar, and to be almost as volatile as Spirit of Wine it self, and to be indeed of so differing a Nature from all that is wont to be separated by Fire from Tartar, that divers Learned Men, with whom I discours'd of it, could hardly be brought to beleeve, that so fugitive a Salt could be afforded by Tartar, till I assur'd it them upon my own Knowledge. And if I did not think you apt to suspect me to be rather too backward than too forward to credit or affirm unlikely things, I could convince you by what I have yet lying by me of that anomalous Salt.
[Footnote 4: Lib. 1. Observat. Cap. 6.]
The Fourth thing that I shall alledge to countenance my first Consideration is, That the Fire even when it divides a Body into Substances of divers Consistences, does not most commonly analyze it into Hypostatical Principles, but only disposes its parts into new Textures, and thereby produces Concretes of a new indeed, but yet of a compound Nature. This Argument it will be requisite for me to prosecute so fully hereafter, that I hope you will then confess that 'tis not for want of good Proofs that I desire leave to suspend my Proofs till the _Series_ of my Discourse shall make it more proper and seasonable to propose them.
It may be further alledg'd on the behalf of my First Consideration, That some such distinct Substances may be obtain'd from some Concretes without Fire, as deserve no less the name of Elementary, than many that Chymists extort by the Violence of the Fire.
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The Sceptical ChymistChapter II: Part 2
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