Chapter II (7)

This great naturalist is convinced that the spar had not been here introduced by infiltration, although that is the very method which he employs to form concretions, not only of spar but of crystal, zeolite, and pyrites, in the closest cavities of the most solid rocks of basaltes. These four substances in this stone were so mixed together that nothing but the fusion of the whole mass could explain the state in which they appeared; but, thinking that such a supposition could not be allowed, this naturalist, like a man of science when his data fail, leaves the matter without any interpretation of his own. This however is what he has not done in the case of basaltes, or that which he mistakes for proper lavas, as I shall have occasion to show.]

Here is an infinite operation, but an operation which is easily performed by the natural arrangement of substances acting freely in a fluid state, and concreting together, each substance, whether more simple or more compound, directing itself by its internal principle of attraction, and affecting mechanically those that are concreting around it.

We see the very same thing happen under our eye, and precisely in the same manner. When a fluid mass of any mineral or metallic substance is made to congeal by sudden cooling on the outside, while the mass within is fluid, a cavity is thus sometimes formed by the contraction of the contained fluid; and in this cavity are found artificial _druzen_, as they may be called, being crystallizations similar to those which the mineral cavities exhibit in such beauty and perfection.

Petrification and consolidation, in some degree, may doubtless be performed, in certain circumstances, by means of the solution of calcareous earth; but the examples given by M. de Luc, of those bodies of lime-stone and agate petrified in the middle of strata of loose or sandy materials, are certainly inexplicable upon any other principle except the fusion of those substances with which the bodies are petrified[35].

[Note 35: Vid. Lettre 28 et Lettre 103. Lettres Physiques et Morales.]

This subject deserves the strictest attention; I propose it as a touchstone for every theory of petrification or perfect consolidation. First, There are found, among argillaceous strata, insulated bodies of iron-stone, perfectly consolidated; secondly, There are found, in strata of chalk and lime-stone, masses of insulated flints; thirdly, There are found, in strata of sea sand, masses of that sand cemented by a siliceous substance; fourthly, In the midst of blocks of sand-stone, there are found masses of loose or pure sand inclosed in crystallised cavities; and in this sand are found insulated masses of crystallised spar, including within them the sand, but without having the sparry or calcareous crystallization disturbed by it. There are also other globular masses of the same kind, where the sparry crystallization is either not to be observed, or appears only partially[36]: And now, lastly, In strata of shell-sand, there are found masses of consolidated lime-stone or marble. In all those cases, the consolidated bodies are perfectly insulated in the middle of strata, in which they must of necessity have been petrified or consolidated; the stratum around the bodies has not been affected by the petrifying substance, as there is not any vestige of it there; and here are examples of different substances, all conspiring to prove one uniform truth. Therefore, a general theory of petrification or consolidation of mineral bodies must explain this distinct fact, and not suffer it any longer to remain a _lusus naturae_.

[Note 36: Mem. de l'Académie Royale des Sciences, an. 1775.]

Let us now consider what it is that we have to explain, upon the supposition of those concretions being formed from a solution. We have, first, To understand what sort of a solution had been employed for the introducing of those various substances; secondly, How those concretions had been formed from such solutions within those bodies of strata; and, lastly, How such concretions could have been formed, without any vestige appearing of the same substance, or of the same operation, in the surrounding part of the stratum. Whatever may be the difficulty of explaining those particular appearances by means of fusion and mechanical force, it is plainly impossible to conceive those bodies formed in those places by infiltration, or any manner of concretion from a state of solution.

Naturalists, in explaining the formation of stones, often use a chemical language which either has no proper meaning, or which will not apply to the subject of mineral operations. We know the chemical process by which one or two stony concretions may be formed among bodies passing from one state to another. When, therefore, a change from a former state of things in mineral bodies is judged by naturalists to have happened, the present state is commonly explained, or the change is supposed to have been made by means of a similar process, without inquiring if this had truly been the case or not. Thus their knowledge of chemistry has led naturalists to reason erroneously, in explaining things upon false principles. It would be needless to give an example of any one particular author in this respect; for, so far as I have seen, it appears to be almost general, every one copying the language of another, and no one understanding that language which has been employed.

These naturalists suppose every thing done by means of solution in the mineral kingdom, and yet they are ignorant of those solvents. They conceive or they imagine concretions and crystallizations to be formed of every different substance, and in every place within the solid body of the earth, without considering how far the thing is possible which they suppose. They are constantly talking of operations which could only take place in the cavities of the earth above the level of the sea, and where the influence of the atmosphere were felt; and yet this is the very place which we have it in our power to examine, and where, besides the stalactite, and one or two more of the same kind, or formed on the same principle, they have never been able to discover one of the many which, according to their theory, ought always to be in action or effect. So far from knowing that general consolidating operation, which they suppose to be exerted in filling up the veins and cavities of the earth by means of the infiltrating water of the surface, they do not seem fully to understand the only operation of this kind which they see. The concretion of calcareous matter upon the surface of the earth is perhaps the only example upon which their theory is founded; and yet nothing can be more against it than the general history of this transaction.

Calcareous matter, the great _vinculum_ of many mineral bodies, is in a perpetual state of dissolution and decay, in every place where the influences of air and water may pervade. The general tendency of this is to dissolve calcareous matter out of the earth, and deliver that solution into the sea. Were it possible to deny that truth, the very formation of stalactite, that operation which has bewildered naturalists, would prove it; for it is upon the general solubility of calcareous matter exposed to water that those cavities are formed, in which may be found such collections of stalactical concretion; and the general tendency of those operations is to waste the calcareous bodies through which water percolates. But how is the general petrifaction or consolidation of strata, below the surface of the sea, to be explained by the general dissolution of that consolidating substance in the earth above that level? Instead of finding a general petrifying or consolidating operation in the part of the earth which we are able to examine, we find the contrary operation, so far at least as relates to calcareous spar, and many other mineral bodies which are decomposed and dissolved upon the surface of the earth.

Thus in the surface of the earth, above the level of the sea, no petrifying operation of a durable nature is found; and, were such an operation there found, it could not be general, as affecting every kind of substance. But, even suppose that such a general operation were found to take place in the earth above the level of the sea, where there might be a circulation of air and percolation of water, How could the strata of the earth below the level of the sea be petrified? This is a question that does not seem to have entered into the heads of our naturalists who attempt to explain petrifaction or mineral concretion from aqueous solutions. But the consolidation of loose and incoherent things, gathered together at the bottom of the sea, and afterwards raised into rocks of various sorts, forms by far the greatest example of petrification or mineral operation of this globe. It is this that must be explained in a mineral theory; and it is this great process of petrifaction to which the doctrine of infiltration, whether for the mechanical purpose of applying cohesive surfaces, or the chemical one of forming crystallizations and concretions, will not by any means apply.

Nothing shows more how little true science has been employed for the explanation of phenomena, than the language of modern naturalists, who attribute, to stalactical and stalagmical operations, every superficial or distant resemblance to those calcareous bodies, the origin of which we know so well. It is not a mere resemblance that should homologate different things; there should be a specific character in every thing that is to be generalised. It will be our business to show that, in the false stalactites, there is not the distinctive character of those water formed bodies to be found.

In the formation of stalactical concretions, besides the incrustation as well as crystallization of the stony substance from the aqueous vehicle by which it had been carried in the dissolved state, we have the other necessary accompanyments of the operation, or collateral circumstances of the case. Such, for example, is that tubular construction of the stalactite, first formed by the concretion of the calcareous substance upon the outside of the pendant gut of water exposed to the evaporation of the atmosphere; we then see the gradual filling up of that pervious tube through which the petrifying water had passed for a certain time; and, lastly, we see the continual accretion which this conducting body had received from the water running successively over every part of it. But among the infinite number of siliceous concretions and crystallizations, as well as those of an almost indefinite variety of other substances, all of which are attributed to solution, there is not the least vestige of any collateral operation, by which the nature of that concretion might be ascertained in the same manner. In all those cases, we see nothing but the concreted substances or their crystallizations; but, no mark of any solvent or incrusting process is to be perceived. On the contrary, almost all, or the greatest part of them, are so situated, and attended with such circumstances, as demonstrate the physical impossibility of that being the manner in which they had been concreted; for, they are situated within close cavities, through which nothing can pervade but heat, electricity, magnetism, etc.; and they fill those cavities more or less, from the thinnest incrustation of crystals to the full content of those cavities with various substances, all regularly concreted or crystallised according to an order which cannot apply to the concretion of any manner of solution.

That there is, in the mineral system, an operation of water which may with great propriety be termed _infiltration_, I make no doubt. But this operation of water, that may be employed in consolidating the strata in the mineral regions, is essentially different from that which is inconsiderately employed or supposed by mineralists when they talk of infiltration; these two operations have nothing in common except employing the water of the surface of the earth to percolate a porous body. Now, the percolation of water may increase the porousness of that body which it pervades, but never can thus change it from a porous to a perfect solid body. But even the percolation of water through the strata deposited at the bottom of the sea, necessarily required, according to the supposition of naturalists, must be refused; for, the interstices of those strata are, from the supposition of the case, already filled with water; consequently, without first removing that stagnant water, it is in vain to propose the infiltration of any fluid from the surface.

This is a difficulty which does not occur in our theory, where the strata, deposited at the bottom of the sea, are to be afterwards heated by the internal fires of the earth. The natural consequence of those heating operations may be considered as the converting of the water contained in the strata into steam, and the expulsion of steam or vapour, by raising it up against the power of gravity, to be delivered upon the surface of the earth and again condensed to the state of water.

Let us now conceive the strata, which had been deposited at the bottom of the sea, as exhausted of their water, and as communicating with the surface of the earth impregnated with water. Here again we have the power of gravity to operate in carrying down water to that place which had been before exhausted by the power of heat; and in this manner, by alternately employing those two great physical agents, we cannot doubt that nature may convey soluble substances from above, and deposit them below for the purpose of consolidating porous bodies, or of filling with saline and earthy matter those interstices which had been originally filled with water, when the strata were deposited at the bottom of the sea. How far any marks of this operation may be perceived, by carefully examining our mines and minerals, I know not; I can only say that, on the contrary, whenever those examined objects were clear and distinct, with the concomitant circumstances, so as to be understood, I have always found the most certain marks of the solid bodies having concreted from the fluid state of fusion. This, however, does not exclude the case of infiltration having been previously employed; and I would intreat mineralists, who have the opportunity of examining the solid parts of the earth, to attend particularly to this distinction. But do not let them suppose that infiltration can be made to fill either the pores or veins of strata without the operation of mineral heat, or some such process by which the aqueous vehicle may be discharged.

Not only are mineral philosophers so inconsiderate, in forming geological theories upon a mere supposition or false analogy, they have even proceeded, upon that erroneous theory, to form a geological supposition for explaining the appearances of strata and other stony masses in employing a particular physical operation, which is, that of _crystallization_[37]. Now crystallization may be considered as a species of elective concretion, by which every particular substance, in passing from a fluid to a solid state, may assume a certain peculiar external shape and internal arrangement of its parts, by which it is often distinguished. But, to suppose the solid mineral structure of the earth explained, like an enigma, by the word _crystallization_, is to misunderstand the science by which we would explain the subject of research; and, to form a general mineral theory thus upon that term, is an attempt to generalise without a reason. For, when it were even admitted that every solid body is crystallised, we thus know no more of the geology of this earth, or understand as little of the general theory of mineral concretion, as we did before;--we cannot, from that, say whether it be by the operation of solution or of fusion which had produced the perceived effect.

[Note 37: Journal de Physique; Avril 1753.]

M. de Carosi has wrote a treatise upon certain petrifactions[38]. In the doctrine of this treatise there is something new or extraordinary. It will therefore be proper to make some observations on it.

[Note 38: Sur la Génération du Silex et du Quartz en partie. Observations faites en Pologne 1783, à Cracovie.]

The object of this treatise is to describe the generation of silex and quartz, with their modifications or compositions, formed within mineral bodies of a different substance. The natural history contained in this little treatise is well described and sufficiently interesting. But It is chiefly in order to examine the means which, according to the theory of this treatise, are employed in petrifying bodies, that I consider it in this place.

The first section of this treatise has for title, _Génération du Caillou et du Quartz de la terre calcaire pure_. It may be worth while to compare the natural history of this part of the earth with the flint and chert found in our chalk and lime-stone countries. I shall therefore transcribe what is worth observing upon that subject (p. 5.).

"Nous rencontrons chez nous dans les parties le plus montagneuses, et les moins couvertes de terreau, ou tout-au plus de sable, entre de purs rochers calcaires une quantité incroyable de cailloux (silex) tant en boules, que veines, couches, et débris. Au premier coup d'oeil l'on s'imagine que ce font des débris de montagnes éloignées, qui y furent amenés par les eaux, mais, en examinant la chose de plus pres, on est convaincu, que ce sont tout au contraire, des parties détachées des montagnes de la contrée. Car il y a sur presque toute l'étendue de nos montagnes calcaires une couche, ou pour mieux dire, un banc composé de plusieurs couches de base calcaire, mais qui ou sont parsemées irrégulièrement de boules, de rognons, de veines, et de petits filons de silex, ou qui contiennent cette pierre en filon, veines, et couches parallèles, et régulièrement disposées. Les boules et rognons de silex y font depuis moins de la grandeur d'une petite noisette, jusqu'au diamètre de plus de six pouces de nôtre mesure. La plupart de ces boules tant qu'elles sont dans l'intérieur caché de la roche vive, et qu'elles n'ont rien souffert de l'impression de l'air, ont, pour l'ordinaire, une croûte de spath calcaire, au moyen de la quelle elles sont accrues à la roche mere; ou pour mieux dire la croûte spatheuse fait l'intermède entre le silex, et la roche calcaire, par où se fait le passage de l'une à l'autre. Mais ceci ne vaut que de boules de silex entièrement formées. C'est dont on peut même se convaincre à la vue, par beaucoup de pierres dont le pavé de la ville de Cracovie est composé. Mais là, ou le silex n'est pas encore entièrement achevé, la croûte spatheuse manque, en revanche on y voit évidemment le passage par degrés successifs de la roche calcaire au silex qui y est contenu, et les nuances de ce passage sont souvent si peu marquées que même les acides minéraux ne suffisent pas à les déterminer, ce n'est que le briquet, qui nous aide à les découvrir. On voit bien ou la pierre calcaire s'enfonce en couleur, l'on s'apperçoit, où sa dureté, ses cassures changent, mais, comme elle y souffre encore quelque impression des acides, l'on ne sauroit déterminer au juste le point, ou elle a déjà plus de la nature du silex, que de celle de la chaux, qu'en la frappant du briquet.

"Tels sont les cailloux en boules et rognons avant leur état de perfection, il y aura même au milieu une partie de pierre calcaire non changée.

"Ceux au contraire, ou la nature à achevé son ouvrage, ont une croûte de chaux endurcie, et sont purement du silex fini, mais de toutes couleurs, d'un grain et d'une texture plus ou moins fine, qui passe assez souvent par degrés dans les différentes variétés du noble silex. Ils ont, pour l'ordinaire, dans leur intérieur une cavité, mais pas toujours au centre, et qui vient apparemment de la consommation de cette partie calcaire qui y resta la dernière, et n'en fut changée ou dissolute et séparée, que lorsque le reste du silex étoit déjà entièrement fini. Ces cavités sont toujours, ou enduites de calcédoine en couche concentriques recouverte de petits cristaux fort brillans et durs de quartz, ou bien seulement de ces derniers-ci. Par-fois il y a aussi du spath calcaire crystallisé, mais cela est extrêmement rare. Quelque-fois enfin ces cavités sont remplies d'une noix de calcédoine. Je n'ai réussi qu'une seule fois en cassant un pareil silex en boule d'y trouver encore le reste de l'eau de crystallisation."

The only remark that I would here make is this, that, if the crystallization of those close cavities in the _silex_ had at any time required water of solution, it must always have required it. But, if there had been water of solution contained in those close cavities, for the crystallization of the various things which are often found within them, How comes it that this water is almost never found? I have good reason to believe that water contained within a solid flint will not make its escape, as does that contained in the _anhydrites_ of Mount _Berico_, which are composed of a porous calcedony. But the siliceous crystallizations within close cavities is a curious subject, which we shall have occasion to examine more particularly in treating of agates. We now proceed to the next section, which is the generation of silex and quartz in marl, (p. 19.)

"Il y a des contrées, chez nous, qui out des étendus assez considérables en long et en large, de montagnes de pierre de marne calcaire, dans lesquelles on rencontre le même phénomène que dans celles de chaux pure; c. a. d. nous y trouvons du silex de différentes variétés, et dans tous les degrés successifs de leur formation, et de leur perfection. Outre cela, nous y voyons encore quelque chose, qui semble nous conduire à la découverte des moyens, dont se sort la nature pour effecteur cette opération, et qui nous étoit caché dans les montagnes de chaux pure: ces bancs de pierre marnesilicieuse, contiennent une partie considérable de pyrites sulfureuses, qui non seulement y forment une grande quantité de petits sillons, mais toute la masse de la montagne est rempli de parcelles souvent presqu'imperceptibles de ce minéral. Ces pyrites sont évidemment des productions du phlogistique et de l'acide contenu dans la montagne.

"L'eau, qui s'y trouve ordinairement en assez grande abondance, en détacha, extraha d'un et l'autre, et les combina après tous les deux ensemble. Cette même eau les dissout derechef, et en fait de nouvelles combinaisons. C'est ce qu'on voit évidemment là, ou la nature, ayant commencé ses opérations, il n'y est resté de la pyrite, qu'une portion de la partie inflammable liée à une base terrestre. Dans ces endroits la marne n'est que fort peu sensible aux acides, et de blanche qu'elle étoit, sa couleur est devenue presque noire. C'est là qu'on observe les différens degrés du changement de la marne en silex, contenant, même encore, par fois, de parties pyritéiques non détruites dans son intérieur. Et comme la nature forme ici, de même, que dans la chaux pure les silex, la plupart en boules ou rognons; comme les différent degrés de métamorphoses de la marne en silex, sont ici beaucoup plus nombreuses que là, de sorte qu'il y a des bandes entières, qui mériteroient plutôt d'être appellés bandes silicieuses, que marneuses; comme il y a, enfin, une grande quantité de pyrites, qu'ailleurs, il est très probable qu'elle se serve là du même moyen qu'ici pour opérer la métamorphose en question.

"Ne nous précipitons, cependant, pas à en tirer plus de conséquences; poursuivons plutôt le fil de notre récit.

"Le silex, qui se trouve ici, est non seulement de différents degrés de perfection, il est de plus d'une espèce. Il y a de la pierre à feu, 2 de la calcédoine, 3 des agathes, et 4 différentes nuances et passages des espèces ordinaires aux fines du silex.

"La pierre à feu, est, ordinairement dans son état de perfection d'un grain assez fin, d'une couleur grise plus ou moins foncée, et même donnant, dans le noirâtre, plus ou moins diaphane; ses cassures sont concentriques ou coquillées, et sa masse est assez compacte. Outre sa conformation ordinaire en boules et rognons, elle fait presque toujours la noix de ursins marins, qui y font en grand nombre, et dont la coquille est le plus souvent, et presque toujours de spath calcaire, même au milieu d'une boule de silex parfait.

"Les calcédoines et agathes de ces couches sont toujours (au moins, je ne les ai pas encore vues autrement) de coraux et autres corps marins pétrifiés. Donc, il faut que les couches de pierres roulées, d'où j'ai tiré ma collection citée plus haut, soyent des débris de montagne» détruites de cette espèce. Il y en a qui sont très parfaites comme celles qui composent ma collection, d'autres méritent plutôt d'être rangées parmi les passages du silex ordinaire, et ses espèces plus fines; d'autres encore sont, en effet, de vraies agathes, mais qui renferment dans leur intérieur plus ou moins de parties non parfaites presque calcaires, qui s'annoncent d'abord par leur couleur blanche, par leur gros grains relativement au reste, par leur opacité, par leur mollesse respective, et souvent même par leur sensibilité pour les acides minéraux. Mais celles, qui sont finies, quoiqu'elles ayent, pour la plupart, une couleur presque noire, ne laissent, cependant, pas d'avoir aussi des teintes plus claires comme brunâtres, verdâtres, rougeâtres, jaunâtres, bleuâtres, tachetées, veinées, etc. Leur clarté n'est pas moins variable, que leur couleur, il y en a de presqu'opaques, comme aussi de presque transparentes, sur tout là, ou la calcédoine prédomine.

"Le quartz s'y trouve comme dans les pierres de la première section, c, a, d, crystallisé, en groupes dans de petites cavités; quelquefois aussi en veines. La calcédoine y est de même, ou bien en mamelons, ou bien en stalactites, lorsqu'elle a de la place pour s'y déposer.

"Un phénomène encore plus curieux que cela est cette belle pyrite sulphureuse jaune, comme de l'or, qui est quelquefois parsemée par tout la substance de pétrifications agathisées, et qui apparemment y fut déposée après la dite métamorphose à la faveur des petits pores, qui y étoient restés ouverts."

I would beg that mineralists, who use such language as this, would consider if it contains a distinct idea of the operation which they would thereby describe, or if it does not contain either a contradiction or an inconceivable proposition. It supposes a calcareous body to be metamorphosed, somehow by means of the mountain acid, into a siliceous body. But, finding many bodies of pyrites contained within that solid flint, it is said, that, when the calcareous body was flintified, there were left in it cavities which were afterwards filled with pyrites. Let us reflect a moment upon this doctrine. These cavities were first open to the outside of the flinty body; but now the pyrites with which they had been filled is insulated in the solid flint. Here three things are required; first, The calcareous body is to be flintified, at the same time leaving the body full of small cavities open to the outside; secondly, These cavities are to be filled with pyrites; lastly, These mineral bodies are to be so inclosed within the flint, as to leave no vestige of the former processes. This marly mountain itself, which had been formed of loose materials gathered together at the bottom of the sea, was first to be filled with pyrites, in various shapes, by means of the phlogistic and the acid of the mountain. Here is proposed to us an operation which is totally unknown, or of which we have no kind of idea. But, let us suppose pyrites formed in this mountain, (of whatever chemical substances), by means of water; Why should water again undo that pyrites, in order to form other concretions? And, Why should the flint be formed first with cavities, and then made solid, after pyrites had been introduced into those cavities of the agate, and, as our author expresses it, _parsemée pour toute la substance?_ Here are suppositions which are not only perfectly gratuitous, but are also inconsistent with any thing that we understand. This is not explaining nature; it is only feigning causes[39].

[Note 39: The description of those insulated siliceous bodies, containing in their closed cavities all the usual concretions of calcedony and crystals, as well as full of small pyrites floating in the solid flint, are extremely interesting to a mineral system, or such a geological theory as should explain the present state of things in those strata that had been formed by deposits of known materials at the bottom of the sea; they are indeed such appearances as may be found, more or less, in all consolidated strata. But it is this author's explanation of that petrifaction which is our present object to consider; and, as he is so particular in giving us his theory upon the subject, it is easy to detect the error of his reasoning. Were those naturalists who explain things only in general, by saying that water is the agent, and infiltration the means employed by nature;--were these naturalists, I say, to give us as particular a description of their process, it would appear as inconsistent with the nature of things as that which we have from this author, who examines nature very minutely, and who sees distinctly that the infiltrating theory is inapplicable for the explanation of those petrifactions.]

The third section has for title, "_Generation du Silex et Quartz de la Pierre Puante_." Here we find an example worthy of being recorded, as contributing to throw great light upon those mineral operations; however, the opinion of our author and mine, upon this subject, differ widely. He proceeds thus:

"Cette pierre n'est, comme chacun le sçait, qu'une pierre calcaire contenant du bitume.

"Nos montagnes n'en contiennent seulement pas de simples couches, mais il y en a même de grandes bancs fort épais.

"Le caillou, ou silex qui s'y génère, forme, tantôt de gros blocs informes, qui occupent des cavités dans l'intérieure des montagnes, tantôt, enfin, en forme de filons.

"J'ai remarqué cette métamorphose sur trois endroits différens, dans chacun des quels la nature a autrement opéré.

"Sur l'un, la pierre puante fait un banc horizontal dans une montagne de pierre calcaire crystalline, ou d'une espèce de marbre, qui contient des couches et filons de métal. Ce banc de pierre puante y fait le toit d'une couche de galène de plomb et de pierre calaminaire, et dans ses cavités et fentes il y a non seulement des blocs de grandeur différente, mais aussi des veines et petites bandes courtes de silex, tant ordinaire, que noble c, a, d, de la pierre à feu, de calcédoine, d'agathes, et même d'une espèce de cornaline jaune et rouge pâle. Je ne m'arrêterai pas à en détailler les variétés, parce qu'elles sont trop accidentelles. Je ne les connois pas même toutes, il s'en faut de beaucoup, parce qu'elles se trouvent dans des anciennes mines négligées, peut être depuis plus d'un siècle, et par conséquent peu accessibles. Je ne doute, cependant pas, que, si l'on pouvoit mieux sonder le terrain, on y trouveroit bien plus encore du peu que j'ai cité. Parmi ce silex, il y a aussi de petites groupes et de petites veines de quartz solide et crystallisé.

"Au second endroit la pierre puante fait un filon, ou si l'on veut, une couche ou bande verticale, qui partage la montagne en deux parties presqu'égales de l'épaisseur de trois aunes à peu près. La montagne, ou cela se voit est aussi une ancienne mine de cuivre et de plomb, consistant en plusieurs variétés de marbre, différent en couleur et en grain, déposées par couches les unes sur les autres. Le filon de silex est formé de feuilles alternatives de pierre puante et de silex, tous les deux de couleur brun de bois à peu prés; mais le silex est plus foncé que sa compagne. Ces feuilles alternatives, consistent d'autres bien plus minces encore, qui souvent n'ont pas l'épaisseur d'une ligne, mais ce qu'il y a de plus curieux, c'est que la même feuille est d'un but de pierre porque, qui, vers le milieu, passe successivement en silex, qui, à son tour, vers l'autre but, qui étoit exposé à l'air repasse par les mêmes gradations en une espèce de tuffe calcaire. Ce qui nous fait voir évidemment la génération et la destruction du silex, même avec une partie des moyens par lesquels elle s'opère. Comme l'endroit de cette découverte n'est accessible qu'à la superficie, je ne saurois dire s'il y a d'autres variétés de silex outre la dite. Il l'est à supposer autant par analogie, que par quelques morceaux qui ont de petites veines transversales d'une espèce de calcédoine, et qui sont, même, sur leur fentes, garnis de petits cristaux de roche. Mais ce qu'il y a de sur c'est que ce filon, parvenu à une certaine profondeur, s'ennoblit et contient du métal, c. a. d. de la galène de plomb, et de la pyrite cuivreuse, j'y en ai trouvés de morceaux, qui en font de preuves incontestables. Le caillou d'ici est un grain fin d'une texture forte, peu transparent, donne beaucoup d'étincelles au briquet, mais ses cassures sont écailleuses.

"La montagne calcaire du troisième lieu a une couche de pierre puante épaisse de plusieurs aunes, qui, derechef contient de petites couches irrégulières et des bandes transversales de silex, qui ont jusques â six pouces passés d'épaisseur. La pierre puante est d'une couleur gris-brune, d'un grain assez fin, et d'un tissu assez dur; ses cassures sont irrégulières, mais plus la pierre s'approche du silex, plus elles donnent dans le coquillé. Le silex ordinaire est d'un brun de bois, d'un grain assez fin, et d'un tissu résistant, et ses cassures sont égales à la pierre porque. Ce n'est pas là la seule variété, il y a, aussi, de la calcédoine et des agathes de couleurs différentes. Même la pierre à feu est assez souvent traversée de veines de calcédoine, de quartz crystallisé, et de spath calcaire blanc en feuilles et en crystaux. Il arrive que la même veine est composée de ces trois espèces de pierres à la fois, de sorte que l'une semble passer dans l'autre, parce que les limites réciproques sont, souvent, assez indistinctes. Il est évident, que le silex est formé de la pierre puante, parce qu'on remarque ici les mêmes phénomènes dont j'ai parlé plus haut, c. a. d. les passages successifs de l'une dans l'autre pierre, tant en montant qu'en descendant."

There is nothing particular in the siliceous mixture in this species of lime-stone, except the vein of that substance. It is evident that this vein, traversing the mountain, had been introduced in the fluid state of fusion. I do not mean to say, that, in this particular case now described, the evidence of that truth peculiarly appears; but that, from the general nature of mineral veins breaking and traversing the solid strata of the globe, no other conclusion can be formed; and that in the particulars of this example there is nothing that could lead us to suppose any other origin to the petrifactions contained in this vein of stinking lime-stone. It is plain, that our author has imagined to himself an unknown manner of executing his mineral metamorphoses. He sees plainly that the common notion of infiltration will not at all explain the evident confusion of those calcareous and siliceous bodies which appear to him to be metamorphosing into each other. Nothing, indeed, can explain those phenomena but a general cause of fluidity; and there is no such general cause besides that of heat or fusion.

But to show how mineralists of great merit, gentlemen who have examined systematically and with some accuracy, may impose upon themselves in reasoning for the explanation of mineral appearances from limited notions of things, and from the supposition of these having been formed where they now are found, that is, upon the surface of the earth, I would beg leave to transcribe what this author has said upon this species of petrifaction. It is not that he is ignorant of what mineralists have already said upon the subject; it is because he sees the incompetency of their explanations in those particular cases; and that he would employ some other more effectual means. (p. 50.)

"Toute terre calcaire à changer dans une autre doit, avant toute chose, être rendue réfractaire ce qui ne peut se faire qu'en la saturant avec un acide. Mais une terre simplement, saturée d'un acide, est d'une réduction fort aisée, vu que l'acide n'y tient pas trop fort, d'ailleurs ce n'est qu'un sel neutre terreux fort facile â dissoudre dans une quantité suffisante d'eau. Or pour rendre cette union plus constante, il faut que la terre alcaline s'assimile intimement à l'acide, ce qui ne se sera jamais sans un intermedeliant, qui homogène les parties de ce nouveau corps, et pour que cela ce fasse il est indispensable, qu'il s'opère une dissolution foncière des parties terrestres de la chaux, qui facilite l'ingress à l'acide, et à l'intermède pour qu'ils s'y lie bien fortement. Supposons qu'il se forme une liqueur savonneuse de l'acide et du phlogistique, que l'air fixe, mis en liberté, ouvre les interstices des parties qui constituent la terre alcaline, qu'apres cela cette liqueur savonneuse ayant l'entrée libre s'assimile à la terre en proportion requise, que l'eau, qui servoit de véhicule dans cette operation, s'évapore successivement, et emporte le superflu des ingrediens, pour qu'il se puisse opérer le rapprochement le plus exacte des parcelles ou molécules homogénées de nouveau corps qu'enfin les molécules les plus pures et les mieux affinées soyent réunies en forme liquide dans des cavités, et que par l'évaporation et séparation de l'eau, ou elles nageoient, il s'en forme des crystaux n'aurons-nous pas une boule de silex, avec de crystaux de quartz dans ses creux intérieurs."

The supposed case is this; a calcareous body is to be metamorphosed into a siliceous nodule, having a cavity within it lined with quartz, crystals, etc. M. de Carosi means to inform us how this may be done. Now, as this process requires no other conditions than those that may be found upon the surface of this earth, the proper way to prove this hypothetical theory, would be to exhibit such a mineral body produced by those means. But, even supposing that such a process were to be exhibited, still it would remain to be explained, how this process, which requires conditions certainly not be found at the bottom of the sea, could be accomplished in that place, where the strata of the earth had been deposited, accumulated, consolidated, and metamorphosed.

This mineral process, which has been now described, will no doubt revolt the opinions of many of our chemists as well as naturalists; and I should not have thought of transcribing it, but as an example of that inconclusive reasoning which prevails in mineralogical writings upon this subject.

But this is not all. We have, upon this occasion, a most remarkable example of the fallaceous views that may be taken of things; and of the danger to science when men of sense and observation form suppositions for the explanation of appearances without that strict conformity with the principles of natural philosophy which is requited on all occasions. Both M. de Carosi, and also M. Macquart[40], to whom our author communicated his ideas and proper specimens, assert, that from their accurate experience, they find calcedony growing daily, not only in the solid body of gypsum, etc. while in the mine, but also in the solid stone when taktn out of the mine, and preserved in their cabinet.

[Note 40: Vid. Essais de Minéralogie par M. Macquart.]

What answer can be made to this positive testimony of these gentlemen, by a person who has not seen any such a thing, and who has not the opportunity of examining the cases in which those naturalists may have perhaps been led into some delusion? Were I however to conjecture upon a subject in which I have not any positive information, I should suppose that some part of the calcedony, like the _oculus mundi_ when dipped in water, may be so transparent, while containing some portion of humidity, that it is not easily distinguishable from the gypsum in which it is concreted; but that in having the humidity evaporated, by being taken out of the mine and exposed to the dry air, those portions of calcedony, which did not before appear, may be perceived by becoming more opaque[41].

[Note 41: From the description given in this treatise, and from the drawings both of M. de Carosi and M. Macquart, I find a very valuable inference to be made, so much the more interesting, as I have not found any example of the like before. This arises from the intimate connection which is here to be perceived between agate and gypsum. Now, upon this principle, that the agate-calcedony had been formed by fusion, a truth which, from the general testimony of minerals, I must presume, it is plain, that those nodules of gypsum had been in the fluid state of fusion among those marly strata, and that the gypseous bodies had been penetrated variously with the siliceous substance of the calcedony.

The description of those siliceous penetrations of gypsum is followed by this conclusion: "En voila assez, je crois pour faire voir que le silex ci-décrit est effectivement une émanation du gypse, et non pas une matière hétérogène amenée d'autre part et déposée, ou nous la voyons." In this instance our author had convinced himself that the calcedony concretions had not been formed, as he and other mineralists had before supposed, by means of infiltration; he has not, however, substituted any thing more intelligible in its stead. I do not pretend that we understand mineral fusion; but only that such mineral fusion is a thing demonstrable upon a thousand occasions; and that thus is to be explained the petrification and consolidation of the porous and naturally incoherent strata of the earth.]

There is, however, a subject in which I can more freely accuse this author of being deceived. This naturalist says, that calcareous stones become silex by a certain chemical operation; and that those flinty bodies, in being exposed upon the surface of the earth, out of their natural bed, are again, by a contrary chemical operation, changed from flint to a calcareous substance. I will give it in his own words, (p. 56.)

"Cela dit, venons au fait. Tout silex progénéré de chaux, détaché de son lieu natal, et exposé aux changemens de saisons, s'amollit, reçoit de crevasses, perd sa transparence, devient, enfin, tout-à-fait opaque, le phlogistique s'en évapore, l'acide en est détaché, lavé, et de terre vitrescible, qu'il étoit, il redevient chaux, comme il étoit auparavant."

Here is no question with regard to mere opinion, but to matter of fact; and, in this case, nothing is more evident, than that upon the surface of this earth, that is, in the examinable parts above the level of the sea, there is no transition either of calcareous bodies into flint, nor of flinty bodies into calcareous substance. Calcareous matter is constantly dissolved by water, when it is exposed to the washing of that fluid; and it is even dissolved out of the most perfect union or combination with siliceous substance, and the most solid composition of an insoluble body, as may be perceived in the decaying of feld-spar. A superficial view of flints, which have come out of a body of chalk, may have created such an opinion, which will not either bear the light of chemical or mineral investigation. The subject of these chalk flints will be minutely examined in its proper place.

Our author has carefully examined the subject of flintification; and the country where he makes his observations would seem to be well disposed for such a research. He has had great opportunity and inclination to examine the subject which he writes upon; and he has given a distinct account of what be has seen. His description of the flintification of sand-stone is extremely interesting. I will therefore transcribe it, both as a valuable portion of natural history, and also in order to contrast this author's opinion, with regard to the means employed by nature in petrifying bodies, and that which I maintain to be the general consolidating operation of the globe. It is Section V. _Generation du Caillou du Silex du Grès, ou Pierre Sablonneuse_.

"Tout grès est susceptible de cette métamorphose quant au grain et quant à la couleur; depuis la bréccia quartzeuse jusqu'à la pierre à rasoir; et depuis le grès blanc jusqu'au brun et presque noirâtre, tient ou non tient, dur, ou presque friable, c'est indifférent, toutes ces variétés donnent du silex, et surtout de la calcédoine, de la cornaline, et des agathes. Quant au ciment je l'y ai toujours remarqué calcaire et faisant effervescence avec les acides dans les endroits de la pierre qui n'étoient point encore changés; et jamais je n'ai vu ce changement dans du grès dont le ciment fut ou quartzeux ou argileux et réfractaire. Ainsi le ciment entre pour quelque chose dans ce changement.

"Le commencement de cette métamorphose paroit (autant que j'ai pu l'observer dans mes débris roulés) se faire par le ciment, qui dissout là, où les agens eurent l'accès libre, rend les grains en quartz mobiles, les emporte, les mêle avec sa masse dense-liquide, les dissout, même en partie, et forme, dans cet état, des veines et de masses calcédonieuse, carneoliques, ou d'une autre espèce de silex, au milieu du grés peu, ou pas du tout, changé. Car autant que je puis voir, ce n'est pas par couches ou veines qu'elle s'opère, mais par boules et masses rond-oblongues. Au commencement ces veines et tâches sont fort minces, et le reste du grés n'est point du tout, ou à peine sensiblement changé hormis qu'il gagne, plus de consistence, à proportion du changement souffert. Mais à mesure que le silex y augmente et se perfectionne, on y apperçoit les degrés par lesquels a passé cette operation. Les nuance du passage d'une pierre à l'autre deviennent plus visibles, les veines et masses de silex grandissent au point, même, qu'il y a jusqu'aux trois quart du grés changé en silex clair comme de l'eau n'ayant que fort peu de grains de sable nageants dans sa masse. Des morceaux de cette espèce sont rares à la vérité, mais j'en ai, cependant, trouvé quelques uns. Ordinairement, dans les beaux morceaux, le silex fait la base, et le sable y est, comme nageant tantôt en grains séparés tantôt en parties et flocons. Dans les pieces moins belles, le sable fait la base, et le silex sert à la fois de ciment, et forme aussi plus ou moins de veines, qui traversent la masse en maintes et maintes directions. Mais si c'est un grès à gros grains, ou de la bréccia, alors le reste prend la nature silicieuse mêlé de sable fin, et les gros grains de quartz restent tels, qu'ils étoient, sans changer. J'ai déjà remarqué que cette métamorphose semble s'opérer, comme celle des cailloux d'origine calcaire en forme approchans la sphérique, il faut encore y a jouter, que j'ai lieu de croire, qu'elle se fasse aussi du dedans en dehors, tout, comme la décomposition se fait du dehors au dedans.

"Il arrive dans cette pierre, comme dans toute autre, qu'il se forme des crystallisations dans les cavités. Lorsqu'elles sont de silex, leur figure est toujours mamelonnée, mais leur eau ou pureté, leur grandeur et leur couleur n'est pas par tout égale. Il y en a qui sont grands, et de la plus pure calcédoine, d'autres sont petits et chaque goutte ou mamelon contient un grain de sable, de facon que cela a l'air d'un grès crystallisé en mamelons ou stalagmitique. D'autres encore sont, de calcédoine, mais recouverts d'une croûte, tantôt blanche qui fait effervescence avec l'acide minéral, et qui est, par conséquent, de nature calcaire; tantôt cette croûte est bleue foncée nuancée de bleu-celeste; tantôt, enfin, elle est noire, mais toutes les deux réfractaires. Outre ces crystallisations silicieuses, il y en a, quoique rarement, de quartzeuses, qui ou forment de petites veines de crystal, ou bien des groupes de crystaux quartzeux, ou qui enfin, enduisent les mamelons de silex."

Our author then makes a specification of the different varieties; after which he continues, p. 69.

"Après tout ceci, l'on conviendra j'espère, que nôtre grais est une pierre bien singulière, et surpassant, à bien des égards, le grais, faussement dit crystallisé, de Fontainebleau. La raison de la figure du grais François est fort évidente, c'est le spath calcaire, qui lui sert de ciment, qui la lui fit prendre; mais qu'est-ce qui opère les métamorphoses racontées dans notre grais siliceux? Seroit-ce son ciment calcaire ou marneux par les mêmes raisons, qui font changer la marne en silex? La chose est très-probable, et je n'en saurois pas même, deviner d'autre. En ce cas la nature auroit un moyen d'opérer par la voie humide, ce que nous faisons dans nos laboratoires en quelque façon, par la voie sèche, c, a, d, de fondre et liquéfier la terre vitrescible, au moyen des alcalis; secret que nous lui avons déjà arraché en partie, en faisant la liqueur silicieuse."

"Je n'ose, cependant, décider pas même hypothétiquement, sur cette matière, pour n'avoir pu observer la nature dans ses ateliers, et parce que je ne possède que des pièces, qui détachées de leur lieu natal, depuis un très long-tems, furent exposées aux intempéries des saisons, où elles peuvent avoir souffert bien de changemens."

There cannot be a more fair exposition of facts; and it is only our author's opinion of this mineral transmutation that I would controvert. I do not pretend to understand the manner of operating that our author here supposes nature to take. I only maintain, that here, as every where in general, the loose and incoherent strata of the globe have been petrified, that is, consolidated, by means of the fusion of their substances; and this I think is confirmed from the accurate description here given of the flintification of sand-stone. Here is described very distinctly an appearance which is very common or general on those occasions; this is the parts or particles of stone floating in the fluid siliceous substance, and there dissolving more or less.

M. de Carosi describes very systematically the generation of silex, calcedony, onyx, and quartz, in calcareous earth, marl, gypsum, sand-stone, and also what he terms _terre glaise, ou de l'Argile_. It is in this last that we find a perfect analogy with what is so frequent in this country of Scotland. These are the agates, calcedonies, calcareous and zeolite nodules, which are found produced in our whin-stone or subterraneous lavas, that is, the amygdaloides of Crondstedt. Naturalists explain the formation of those nodular bodies differently. The Chevalier de Dolomieu supposes these rocks to have been erupted lavas, originally containing cavities; and that these cavities in the solid rock had been afterwards filled and crystallised, by means of infiltration, with the different substances which are found variously concreted and crystallised within the solid rocks. Our author, on the contrary, supposes these formed by a species of chemical transmutation of calcareous and argillaceous earths, which, if not altogether incomprehensible, is at least not in any degree, so far as I know, a thing to be understood.

This is not the place where that subject of these particular rocks, which is extremely interesting, is to be examined. We shall afterwards have occasion to treat of that matter at large. It is sufficient here to observe, that our author finds occasion to generalise the formation of those petrifactions with the flintifications in calcareous and gypseous bodies. When, therefore, the formation of any of them shall be demonstrated, as having taken its origin in the fusion of those substances, this mode of operation, which is generalised in the consolidation of strata, will be properly inferred in all the rest.

Petrifaction is a subject in which mineralogists have perhaps wandered more widely from the truth than in any other part of natural history; and the reason is plain. The mineral operations of nature lie in a part of the globe which is necessarily inaccessible to man, and where the powers of nature act under very different conditions from those which we find take place in the only situation where we can live. Naturalists, therefore, finding in stalactical incrustation a cause for the formation of stone, in many respects analogous to what is found in the strata of the earth, and which had come from the mineral region in a consolidated state, have, without due consideration, attributed to this cause all the appearances of petrifaction or mineral concretion. It has been one of the objects of this work to show that this operation of incrustation, or petrifaction by means of solution, is altogether ineffectual for producing mineral concretions; and that, even were it capable of forming those mineral bodies, yet that, in the solid parts of this earth, formed by a deposit of travelled materials at the bottom of the sea, the conditions necessary to this incrustating process do not take place.