Chapter I: Part 1
Worlds Within Worlds:
The Story of Nuclear Energy
Volume 3
Nuclear Fission · Nuclear Fusion · Beyond Fusion
by Isaac Asimov
United States Atomic Energy Commission
Office of Information Services
Library of Congress Catalog Card Number 75-189477
1972
_Nothing in the history of mankind has opened our eyes to the possibilities of science as has the development of atomic power. In the last 200 years, people have seen the coming of the steam engine, the steamboat, the railroad locomotive, the automobile, the airplane, radio, motion pictures, television, the machine age in general. Yet none of it seemed quite so fantastic, quite so unbelievable, as what man has done since 1939 with the atom ... there seem to be almost no limits to what may lie ahead: inexhaustible energy, new worlds, ever-widening knowledge of the physical universe._ Isaac Asimov
Nuclear energy is playing a vital role in the life of every man, woman, and child in the United States today. In the years ahead it will affect increasingly all the peoples of the earth. It is essential that all Americans gain an understanding of this vital force if they are to discharge thoughtfully their responsibilities as citizens and if they are to realize fully the myriad benefits that nuclear energy offers them.
The United States Atomic Energy Commission provides this booklet to help you achieve such understanding.
UNITED STATES ATOMIC ENERGY COMMISSION
Dr. James R. Schlesinger, Chairman
James T. Ramey
Dr. Clarence E. Larson
William O. Doub
Dr. Dixy Lee Ray
ISAAC ASIMOV received his academic degrees from Columbia University and is Associate Professor of Biochemistry at the Boston University School of Medicine. He is a prolific author who has written over 100 books in the past 18 years, including about 20 science fiction works, and books for children. His many excellent science books for the public cover subjects in mathematics, physics, astronomy, chemistry, and biology, such as _The Genetic Code_, _Inside the Atom_, _Building Blocks of the Universe_, _Understanding Physics_, _The New Intelligent Man’s Guide to Science_, and _Asimov’s Biographical Encyclopedia of Science and Technology_. In 1965 Dr. Asimov received the James T. Grady Award of the American Chemical Society for his major contribution in reporting science progress to the public.
CONTENTS
VOLUME 1
Introduction 5
Atomic Weights 6
Electricity 11
Units of Electricity 11
Cathode Rays 13
Radioactivity 17
The Structure of the Atom 25
Atomic Numbers 30
Isotopes 35
Energy 47
The Law of Conservation of Energy 47
Chemical Energy 50
Electrons and Energy 54
The Energy of the Sun 55
The Energy of Radioactivity 57
VOLUME 2
Mass and Energy 69
The Structure of the Nucleus 75
The Proton 75
The Proton-Electron Theory 76
Protons in Nuclei 80
Nuclear Bombardment 82
Particle Accelerators 86
The Neutron 92
Nuclear Spin 92
Discovery of the Neutron 95
The Proton-Neutron Theory 98
The Nuclear Interaction 101
Neutron Bombardment 107
VOLUME 3
Nuclear Fission 117
New Elements 117
The Discovery of Fission 122
The Nuclear Chain Reaction 127
The Nuclear Bomb 131
Nuclear Reactors 141
Nuclear Fusion 146
The Energy of the Sun 146
Thermonuclear Bombs 148
Controlled Fusion 150
Beyond Fusion 158
Antimatter 158
The Unknown 163
Reading List 165
NUCLEAR FISSION
New Elements
In 1934 Enrico Fermi began his first experiments involving the bombardment of uranium with neutrons—experiments that were to change the face of the world.
Fermi had found that slow neutrons, which had very little energy, were easily absorbed by atomic nuclei—more easily than fast neutrons were absorbed, and certainly more easily than charged particles were.
Often what happened was that the neutron was simply absorbed by the nucleus. Since the neutron has a mass number of 1 and an atomic number of 0 (because it is uncharged), a nucleus that absorbs a neutron remains an isotope of the same element, but increases its mass number.
For instance, suppose that neutrons are used to bombard hydrogen-1, which then captures one of the neutrons. From a single proton, it will become a proton plus a neutron; from hydrogen-1, it will become hydrogen-2. A new nucleus formed in this way will be at a higher energy and that energy is emitted in the form of a gamma ray.
Sometimes the more massive isotope that is formed through neutron absorption is stable, as hydrogen-2 is. Sometimes it is not, but is radioactive instead. Because it has added a neutron, it has too many neutrons for stability. The best way of adjusting the matter is to emit a beta particle (electron). This converts one of the neutrons into a proton. The mass number stays the same but the atomic number increases by one.
The element rhodium, for example, which has an atomic number of 45, has only 1 stable isotope, with a mass number of 103. If rhodium-103 (45 protons, 58 neutrons) absorbs a neutron, it becomes rhodium-104 (45 protons, 59 neutrons), which is not stable. Rhodium-104 emits a beta particle, changing a neutron to a proton so that the nuclear combination becomes 46 protons and 58 neutrons. This is palladium-104, which is stable.
As another example, indium-115 (49 protons, 66 neutrons) absorbs a neutron and becomes indium-116 (49 protons, 67 neutrons), which gives off a beta particle and becomes tin-116 (50 protons, 66 neutrons), which is stable.
There are over 100 isotopes that will absorb neutrons and end by becoming an isotope of an element one higher in the atomic number scale. Fermi observed a number of these cases.
Having done so, he was bound to ask what would happen if uranium were bombarded with neutrons. Would its isotopes also be raised in atomic number—in this case from 92 to 93? If that were so it would be very exciting, for uranium had the highest atomic number in the entire scale. Nobody had ever discovered any sample of element number 93, but perhaps it could be formed in the laboratory.
In 1934, therefore, Fermi bombarded uranium with neutrons in the hope of obtaining atoms of element 93. Neutrons were absorbed and whatever was formed did give off beta particles, so element 93 should be there. However, four different kinds of beta particles (different in their energy content) were given off and the matter grew very confusing. Fermi could not definitely identify the presence of atoms of element 93 and neither could anyone else for several years. Other things turned up, however, which were even more significant.
Before going on to these other things, however, it should be mentioned that undoubtedly element 93 was formed even though Fermi couldn’t clearly demonstrate the fact. In 1939 the American physicists Edwin Mattison McMillan (1907- ) and Philip Hauge Abelson (1913- ), after bombarding uranium atoms with slow neutrons, were able to identify element 93. Since uranium had originally been named for the planet, Uranus, the new element beyond uranium was eventually named for the planet Neptune, which lay beyond Uranus. Element 93 is therefore called “neptunium”.
What happened was exactly what was expected. Uranium-238 (92 protons, 146 neutrons) added a neutron to become uranium-239 (92 protons, 147 neutrons), which emitted a beta particle to become neptunium-239 (93 protons, 146 neutrons).
In fact, neptunium-239 also emitted a beta particle so it ought to become an isotope of an element even higher in the atomic number scale. This one, element 94, was named “plutonium” after Pluto, the planet beyond Neptune. The isotope, plutonium-239, formed from neptunium-239, was only feebly radioactive, however, and it was not clearly identified until 1941.
The actual discovery of the element plutonium came the year before, however, when neptunium-238 was formed. It emitted a beta particle and became plutonium-238, an isotope that was radioactive enough to be easily detected and identified by Glenn Theodore Seaborg (1912- ), and his co-workers, who completed McMillan’s experiments when he was called away to other defense research.
Neptunium and plutonium were the first “transuranium elements” to be produced in the laboratory, but they weren’t the last. Over the next 30 years, isotopes were formed that contained more and more protons in the nucleus and therefore had higher and higher atomic numbers. At the moment of writing, isotopes of every element up to and including element 105 have been formed.
A number of these new elements have been named for some of the scientists important in the history of nuclear research. Element 96 is “curium”, named for Pierre and Marie Curie; element 99 is “einsteinium” for Albert Einstein; and element 100 is “fermium” for Enrico Fermi.
Element 101 is “mendelevium” for the Russian chemist Dmitri Mendeléev, who early in 1869 was the first to arrange the elements in a reasonable and useful order. Element 103 is “lawrencium” for Ernest O. Lawrence. “Rutherfordium” for Ernest Rutherford has been proposed for element 104.
And “hahnium” for Otto Hahn (1879-1968), a German physical chemist whose contribution we will come to shortly, has been proposed for element 105.
Neptunium, however, was not the first new element to be created in the laboratory. In the early 1930s, there were still 2 elements with fairly low atomic numbers that had never been discovered. These were the elements with atomic numbers 43 and 61.
In 1937, though, molybdenum (atomic number 42) had been bombarded with neutrons in Lawrence’s laboratory in the United States. It might contain small quantities of element 43 as a result. The Italian physicist Emilio Segrè (1905- ), who had worked with Fermi, obtained a sample of the bombarded molybdenum and indeed obtained indications of the presence of element 43. It was the first new element to be manufactured by artificial means and was called “technetium” from the Greek word for “artificial”.
The technetium isotope that was formed was radioactive. Indeed, all the technetium isotopes are radioactive. Element 61, discovered in 1945 and named “promethium”, also has no stable isotopes. Technetium and promethium are the only elements with atomic numbers less than 84 that do not have even a single stable isotope.
The Discovery of Fission
But let us get back to the bombardment of uranium with neutrons research that Fermi had begun. After he had reported his work, other physicists repeated it and also got a variety of beta particles and were also unable to decide what was going on.
One way to tackle the problem was to add to the system some stable element that was chemically similar to the tiny traces of radioactive isotopes that might be produced through the bombardment of uranium. Afterwards the stable element could probably be separated out of the mixture and the trace of radioactivity would, it was hoped, be carried along with it. The stable element would be a “carrier”.
Among those working on the problem were Otto Hahn and his Austrian co-worker, the physicist Lise Meitner (1878-1968). Among the potential carriers they added to the system was the element, barium, which has an atomic number of 56. They found that a considerable quantity of the radioactivity did indeed accompany the barium when they separated that element out of the system.
A natural conclusion was that the isotopes producing the radioactivity belonged to an element that was chemically very similar to barium. Suspicion fell at once on radium (atomic number 88), which was very like barium indeed as far as chemical properties were concerned.
Lise Meitner, who was Jewish, found it difficult to work in Germany, however, for it was then under the rule of the strongly anti-Semitic Nazi regime. In March 1938 Germany occupied Austria, which became part of the German realm. Meitner was no longer protected by her Austrian citizenship and had to flee the country and go to Stockholm, Sweden. Hahn remained in Germany and continued working on the problem with the German physical chemist Fritz Strassman (1902- ).
Although the supposed radium, which possessed the radioactivity, was very like barium in chemical properties, the two were not entirely identical. There were ways of separating them, and Hahn and Strassman busied themselves in trying to accomplish this in order to isolate the radioactive isotopes, concentrate them, and study them in detail. Over and over again, however, they failed to separate the barium and the supposed radium.
Slowly, it began to seem to Hahn that the failure to separate the barium and the radioactivity meant that the isotopes to which the radioactivity belonged had to be so much like barium as to be nothing else _but_ barium. He hesitated to say so, however, because it seemed unbelievable.
If the radioactive isotopes included radium, that was conceivable. Radium had an atomic number of 88, only four less than uranium’s 92. You could imagine that a neutron being absorbed by a uranium nucleus might make the latter so unstable as to cause it to emit 2 alpha particles and become radium. Barium, however, had an atomic number of 56, only a little over half that of uranium. How could a uranium nucleus be made to turn into a barium nucleus unless it more or less broke in half? Nothing like that had ever been observed before and Hahn hesitated to suggest it.
While he was nerving himself to do so, however, Lise Meitner, in Stockholm, receiving reports of what was being done in Hahn’s laboratory and thinking about it, decided that unheard-of or not, there was only one explanation. The uranium nucleus _was_ breaking in half.
Actually, when one stopped to think of it (after getting over the initial shock) it wasn’t so unbelievable at that. The nuclear force is so short-range, it barely reaches from end to end of a large nucleus like that of uranium. Left to itself, it holds together most of the time, but with the added energy of an entering neutron, we might imagine shock waves going through it and turning the nucleus into something like a quivering drop of liquid. Sometimes the uranium nucleus recovers, keeps the neutron, and then goes on to beta-particle emission. And sometimes the nucleus stretches to the point where the nuclear force doesn’t quite hold it together. It becomes a dumbbell shape and then the electromagnetic repulsion of the two halves (both positively charged) breaks it apart altogether.
It doesn’t break into equal halves. Nor does it always break at exactly the same place, so that there were a number of different fragments possible (which was why there was so much confusion). Still, one of the more common ways in which it might break would be into barium and krypton. (Their respective atomic numbers, 56 and 36, would add up to 92.)
Meitner and her nephew, Otto Robert Frisch (1904- ), who was in Copenhagen, Denmark, prepared a paper suggesting that this was what was happening. It was published in January 1939. Frisch passed it on to the Danish physicist Niels Bohr (1885-1962) with whom he was working. The American biologist William Archibald Arnold (1904- ), who was also working in Copenhagen at the time, suggested that the splitting of the uranium nucleus into halves be called “fission”, the term used for the division-in-two of living cells. The name stuck.
In January 1939, just about the time Meitner and Frisch’s paper was published, Bohr had arrived in the United States to attend a conference of physicists. He carried the news of fission with him. The other physicists attending the conference heard the news and in a high state of excitement at once set about studying the problem. Within a matter of weeks, the fact of uranium fission was confirmed over and over.
One striking fact about uranium fission was the large amount of energy it released. In general, when a very massive nucleus is converted to a less massive one, energy is released because of the change in the mass defect, as Aston had shown in the 1920s. When the uranium nucleus breaks down through the ordinary radioactive processes to become a less massive lead nucleus, energy is given off accordingly. When, however, it breaks in two to become the much less massive nuclei of barium and krypton (or others in that neighborhood) much more energy is given off.
It quickly turned out that uranium fission gave off something like ten times as much nuclear energy per nucleus than did any other nuclear reaction known at the time.
Even so, the quantity of energy released by uranium fission was only a tiny fraction of the energy that went into the preparation of the neutrons used to bring about the fission, if each neutron that struck a uranium atom brought about a single fission of that 1 atom.
Under those conditions, Rutherford’s suspicion that mankind would never be able to tap nuclear energy probably still remained true. (He had been dead for 2 years at the time of the discovery of fission.)
However, those were not the conditions.
The Nuclear Chain Reaction
Earlier in this history, we discussed chain reactions involving chemical energy. A small bit of energy can ignite a chemical reaction that would produce more than enough energy to ignite a neighboring section of the system, which would in turn produce still more—and so on, and so on. In this way the flame of a single match could start a fire in a leaf that would burn down an entire forest, and the energy given off by the burning forest would be enormously higher than the initial energy of the match flame.
Might there not be such a thing as a “nuclear chain reaction”? Could one initiate a nuclear reaction that would produce something that would initiate more of the same that would produce something that would initiate still more of the same and so on?
In that case, a nuclear reaction, once started, would continue of its own accord, and in return for the trifling investment that would serve to start it—a single neutron, perhaps—a vast amount of breakdowns would result with the delivery of a vast amount of energy. Even if it were necessary to expend quite a bit of energy to produce the 1 neutron that would start the chain reaction, one would end with an enormous profit.
What’s more, since the nuclear reaction would spread from nucleus to nucleus with millionths-of-a-second intervals, there would be, in a very brief time, so many nuclei breaking down that there would be a vast explosion. The explosion was sure to be millions of times as powerful as ordinary chemical explosions involving the same quantity of exploding material, since the latter used only the electromagnetic interaction, while the former used the much stronger nuclear interaction.
The first to think seriously of such a nuclear chain reaction was the Hungarian physicist Leo Szilard (1898-1964). He was working in Germany in 1933 when Adolf Hitler came to power and, since he was Jewish, he felt it would be wise to leave Germany. He went to Great Britain and there, in 1934, he considered certain new types of nuclear reactions that had been discovered.
In these, it sometimes happened that a fast neutron might strike a nucleus with sufficient energy to cause it to emit 2 neutrons. In that way the nucleus, absorbing 1 neutron and emitting 2, would become a lighter isotope of the same element.
But what would happen if each of the 2 neutrons that emerged from the original target nucleus struck new nuclei and forced the emission of a pair of neutrons from each. There would now be a total of 4 neutrons flying about and if each struck new nuclei there would next be 8 neutrons and so on. From the initial investment of a single neutron there might soon be countless billions initiating nuclear reactions.
Szilard, fearing the inevitability of war and fearing further that the brutal leaders of Germany might seek and use such a nuclear chain reaction as a weapon in warfare, secretly applied for a patent on a device intending to make use of such a nuclear chain reaction. He hoped to turn it over to the British Government, which might then use its possession as a way of restraining the Nazis and keeping the peace.
However, it wouldn’t have worked. It took the impact of a very energetic neutron to bring about the emission of 2 neutrons. The neutrons that then emerged from the nucleus simply didn’t have enough energy to keep things going. (It was like trying to make wet wood catch fire.)
But what about uranium fission? Uranium fission was initiated by slow neutrons. What if uranium fission also produced neutrons as well as being initiated by a neutron? Would not the neutrons produced serve to initiate new fissions that would produce new neutrons and so on endlessly?
It seemed very likely that fission produced neutrons and indeed, Fermi, at the conference where fission was first discussed, suggested it at once. Massive nuclei possessed more neutrons per proton than less massive ones did. If a massive nucleus was broken up into 2 considerably less massive ones, there would be a surplus of neutrons. Suppose, for instance, uranium-238 broke down into barium-138 and krypton-86. Barium-138 contains 82 neutrons and krypton-86 50 neutrons for a total of 132. The uranium-238 nucleus, however, contains 146 neutrons.
The uranium fission process was studied at once to see if neutrons were actually given off and a number of different physicists, including Szilard, found that they were.
Now Szilard was faced with a nuclear chain reaction he was certain would work. Only slow neutrons were involved and the individual nuclear breakdowns were far more energetic than anything else that had yet been discovered. If a chain reaction could be started in a sizable piece of uranium, unimaginable quantities of energy would be produced. Just 1 gram of uranium, undergoing complete fission, would deliver the energy derived from the total burning of 3 tons of coal and would deliver that energy in a tiny fraction of a second.
Szilard, who had come to the United States in 1937, clearly visualized the tremendous explosive force of something that would have to be called a “nuclear bomb”. Szilard dreaded the possibility that Hitler might obtain the use of such a bomb through the agency of Germany’s nuclear scientists.
Partly through Szilard’s efforts, physicists in the United States and in other Western nations opposed to Hitler began a program of voluntary secrecy in 1940, to avoid passing along any hints to Germany. What’s more, Szilard enlisted the services of two other Hungarian refugees, the physicists Eugene Paul Wigner (1902- ) and Edward Teller (1908- ) and all approached Einstein, who had also fled Germany and come to America.
Einstein was the most prestigious scientist then living and it was thought a letter from him to the President of the United States would be most persuasive. Einstein signed such a letter, which explained the possibility of a nuclear bomb and urged that the United States not allow a potential enemy to come into possession of it first.
Largely as a result of this letter, a huge research team was put together in the United States, to which other Western nations also contributed, with but one aim—to develop the nuclear bomb.
The Nuclear Bomb
Although the theory of the nuclear bomb seemed clear and simple, a great many practical difficulties stood in the way. In the first place, if only uranium atoms underwent fission a supply of uranium had at least to be obtained in pure form, for if the neutrons struck nuclei of elements other than uranium, they would simply be absorbed and removed from the system, ending the possibility of a chain reaction. This alone was a heavy task, since there had been so little use for uranium in quantity that there was almost no supply in existence and no experience in how to purify it.
Secondly, the supply of uranium might have to be a large one, for neutrons didn’t necessarily enter the first uranium atom they approached. They moved about here and there, making glancing collisions, and travelling quite a distance, perhaps, before striking head-on and entering a nucleus. If in that time they had passed outside the lump of uranium, they were useless.
Albert Einstein
Old Grove Rd.
Nassau Point
Peconic, Long Island
August 2nd, 1939
F.D. Roosevelt,
President of the United States,
White House
Washington, D.C.
Sir:
Some recent work by E. Fermi and L. Szilard, which has been communicated to me in manuscript, leads me to expect that the element uranium may be turned into a new and important source of energy in the immediate future. Certain aspects of the situation which has arisen seem to call for watchfulness and, if necessary, quick action on the part of the Administration. I believe therefore that it is my duty to bring to your attention the following facts and recommendations:
In the course of the last four months it has been made probable—through the work of Joliot in France as well as Fermi and Szilard in America—that it may become possible to set up a nuclear chain reaction in a large mass of uranium, by which vast amounts of power and large quantities of new radium-like elements would be generated. Now it appears almost certain that this could be achieved in the immediate future.
This new phenomenon would also lead to the construction of bombs, and it is conceivable—though much less certain—that extremely powerful bombs of a new type may thus be constructed. A single bomb of this type, carried by boat and exploded in a port, might very well destroy the whole port together with some of the surrounding territory. However, such bombs might very well prove to be too heavy for transportation by air.
The United States has only very poor ores of uranium in moderate
quantities. There is some good ore in Canada and the former
Czechoslovakia, while the most important source of uranium is Belgian
Congo.
In view of this situation you may think it desirable to have some
permanent contact maintained between the Administration and the group
of physicists working on chain reactions in America. One possible way
of achieving this might be for you to entrust with this task a person
who has your confidence and who could perhaps serve in an inofficial
capacity. His task might comprise the following:
a) to approach Government Departments, keep them informed of the
further development, and put forward recommendations for Government
action, giving particular attention to the problem of securing a
supply of uranium ore for the United States;
b) to speed up the experimental work, which is at present being
carried on within the limits of the budgets of University
laboratories, by providing funds, if such funds be required, through
his contacts with private persons who are willing to make
contributions for this cause, and perhaps also by obtaining the
co-operation of industrial laboratories which have the necessary
equipment.
I understand that Germany has actually stopped the sale of uranium
from the Czechoslovakian mines which she has taken over. That she
should have taken such early action might perhaps be understood on the
ground that the son of the German Under-Secretary of State, von
Weizsäcker, is attached to the Kaiser-Wilhelm-Institut in Berlin where
some of the American work on uranium is now being repeated.
Yours very truly,
(Albert Einstein)
As the quantity of uranium within which the fission chain reaction was initiated grew larger, more and more of the neutrons produced found a mark and the fission reaction would die out more and more slowly. Finally, at some particular size—the “critical size”—the fission reaction did not die at all, but maintained itself, with enough of the neutrons produced finding their mark to keep the nuclear reaction proceeding at a steady rate. At any greater size the nuclear reaction would accelerate and there would be an explosion.
It wasn’t even necessary to send neutrons into the uranium to start the process. In 1941 the Russian physicist Georgii Nikolaevich Flerov (1913- ) found that every once in a while a uranium atom would undergo fission without the introduction of a neutron. Occasionally the random quivering of a nucleus would bring about a shape that the nuclear interaction could not bring back to normal and the nucleus would then break apart. In a gram of ordinary uranium, there is a nucleus undergoing such “spontaneous fission” every 2 minutes on the average. Therefore, enough uranium need only be brought together to surpass critical size and it will explode within seconds, for the first nucleus that undergoes spontaneous fission will start the chain reaction.
First estimates made it seem that the quantity of uranium needed to reach critical size was extraordinarily great. Fully 99.3% of the metal is uranium-238, however, and, as soon as fission was discovered, Bohr pointed out that there were theoretical reasons for supposing that it was the uranium-235 isotope (making up only 0.7% of the whole) that was the one undergoing fission. Investigation proved him right. Indeed, the uranium-238 nucleus tended to absorb slow neutrons without fission, and to go on to beta-particle production that formed isotopes of neptunium and plutonium. In this way uranium-238 actually interfered with the chain reaction.
In any quantity of uranium, the more uranium-235 present and the less uranium-238, the more easily the chain reaction would proceed and the lower the critical size needed. Vast efforts were therefore made to separate the 2 isotopes and prepare uranium with a higher than normal concentration of uranium-235 (“enriched uranium”).
Of course, there was no great desire for a fearful explosion to get out of hand while the chain reaction was being studied. Before any bomb could be constructed, the mechanism of the chain reaction would have to be studied. Could a chain reaction capable of producing energy (for useful purposes as well as for bombs) be established? To test this, a quantity of uranium was gathered in the hope that a _controlled_ chain reaction of uranium fission could be established. For that purpose, control rods of a substance that would easily absorb neutrons and slow the chain reaction were used. The metal, cadmium, served admirably for this purpose.
Then, too, the neutrons released by fission were pretty energetic. They tended to travel too far too soon and get outside the lump of uranium too easily. To produce a chain reaction that could be studied with some safety, the presence of a moderator was needed. This was a supply of small nuclei that did not absorb neutrons readily, but absorbed some of the energy of collision and slowed down any neutron that struck it. Nuclei such as hydrogen-2, beryllium-9, or carbon-12 were useful moderators. When the neutrons produced by fission were slowed, they travelled a smaller distance before being absorbed in their turn and the critical size would again be reduced.
Toward the end of 1942 the initial stage of the project reached a climax. Blocks of graphite containing uranium metal and uranium oxide were piled up in huge quantities (enriched uranium was not yet available) in order to approach critical size. This took place under the stands of a football stadium at the University of Chicago, with Enrico Fermi (who had come to the United States in 1938) in charge.[1]
The large structure was called an “atomic pile” at first because of the blocks of graphite being piled up. The proper name for such a device, and the one that was eventually adopted, was, however, “nuclear reactor”.
On December 2, 1942, calculations showed that the nuclear reactor was large enough to have reached critical size. The only thing preventing the chain reaction from sustaining itself was the cadmium rods that were inserted here and there in the pile and that were soaking up neutrons.
One by one the cadmium rods were pulled out. The number of uranium atoms undergoing fission each second rose and, finally, at 3:45 p.m., the uranium fission became self-sustaining. It kept going on its own (with the cadmium rods ready to be pushed in if it looked as though it were getting out of hand—something calculations showed was not likely).
News of this success was announced to Washington by a cautious telephone call from Arthur Holly Compton (1892-1962) to James Bryant Conant (1893- ). “The Italian navigator has landed in the new world”, said Compton. Conant asked, “How were the natives?”, and the answer was, “Very friendly”.
This was the day and moment when the world entered the “nuclear age”. For the first time, mankind had constructed a device in which the nuclear energy being given off was greater than the energy poured in. Mankind had tapped the reservoirs of nuclear energy and could put it to use. Had Rutherford lived but 6 more years, he would have seen how wrong he was to think it could never be done.
The people of earth remained unaware of what had taken place in Chicago and physicists continued to work toward the development of the nuclear bomb.
Enriched uranium was successfully prepared. Critical sizes were brought low enough to make a nuclear bomb small enough to be carried by plane to some target. Suppose one had 2 slabs of enriched uranium, each below critical size, but which were above critical size if combined. And suppose an explosive device were added that, at some desired moment, could be set off in such a way that it would drive 1 slab of enriched uranium against the other. There would be an instant explosion of devastating power. Or suppose the enriched uranium were arranged in loosely packed pieces to begin with so that the flying neutrons were in open air too often to maintain the chain reaction. A properly arranged explosion might compress the uranium into a dense ball. Neutron absorption would become more efficient and again, an explosion would follow.
On July 16, 1945, a device that would result in a nuclear explosion was set up near Alamogordo, New Mexico, with nervous physicists watching from a safe distance. It worked perfectly; the explosion was tremendous.
By that time Nazi Germany had been defeated, but Japan was still fighting. Two more devices were prepared. After a warning, one was exploded over the Japanese city of Hiroshima on August 6, 1945, and the other over Nagasaki 2 days later. The Japanese government surrendered and World War II came to an end.
It was with the blast over Hiroshima that the world came to know it was in the nuclear age and that the ferocious weapon of the nuclear bomb existed. (The popular name for it at the time was “atomic bomb” or “A-bomb”.)
During the war, German scientists may have been trying to develop a nuclear bomb, but, if so, they had not yet succeeded at the time Germany met its final defeat. Soviet physicists, under Igor Vasilievich Kurchatov (1903-1960), were also working on the problem. The dislocation of the war, which inflicted much more damage on the Soviet Union than on the United States, kept the Soviet effort from succeeding while it was on. However, since the Soviets were among the victors, they were able to continue after the war.
In 1949 the Soviets exploded their first nuclear bomb. In 1952 the British did the same; in 1960, the French; and in 1964, the Chinese.
Although many nuclear bombs have been exploded for test purposes, the two over Hiroshima and Nagasaki have been the only ones used in time of war.
Nor need nuclear bombs be considered as having destructive potential only. There is the possibility that, with proper precautions, they might be used to make excavations, blast out harbors or canals, break up underground rock formations to recover oil or other resources, and in other ways do the work of chemical explosives with far greater speed and economy. It has even been suggested that a series of nuclear bomb explosions might be used to hurl space vehicles forward in voyages away from earth.
Nuclear Reactors
The development of the nuclear chain reaction was not in the direction of bombs only. Nuclear reactors designed for the controlled production of useful energy multiplied in number and in efficiency since Fermi’s first “pile”. Many nations now possess them, and they are used for a variety of purposes.[2]
In 1954 the first nuclear submarine the USS _Nautilus_ was launched by the United States. Its power was obtained entirely from a nuclear reactor, and it was not necessary for it to rise to the surface at short intervals in order to recharge its batteries. Nuclear submarines have crossed the Arctic Ocean under the ice cover, and have circumnavigated the globe without surfacing.
In 1959 both the Soviet Union and the United States launched nuclear-powered surface vessels. The Soviet ship was the icebreaker, _Lenin_, and the American ship was a merchant vessel, the NS _Savannah_.
In the 1950s nuclear reactors were also used as the source of power for the production of electricity for civilian use. The Soviet Union built a small station of this sort in 1954, which had a capacity of 5,000 kilowatts. The British built one of 92,000 kilowatt capacity, which they called Calder Hall. The first American nuclear reactor for civilian use began operation at Shippingport, Pennsylvania, in 1958. It was the first really full-scale civilian nuclear power plant in the world.
The world appeared to have far greater sources of energy than had been expected. The “fossil fuels”—coal, oil and natural gas—were being used at such a rate that many speculated that the gas and oil would be gone in decades and the coal in centuries. Was it possible that uranium might now serve as a new source that would last indefinitely?
It was rather disappointing that it was uranium-235 which underwent fission, because that isotope made up only 0.7% of the uranium that existed. If uranium-235 were all we had and all we ever could have, the energy supply of the world would still be rather too limited.
There were other possible “nuclear fuels”, however. There was plutonium-239, which would also fission under neutron bombardment. It had an ordinary half-life (for a radioactive change in which it gave off alpha particles) of 24,300 years, which is long enough to make it easy to handle.
But how can plutonium-239 be formed in sufficient quantities to be useful? After all, it doesn’t occur in nature. Surprisingly, that turned out to be easy. Uranium-238 atoms will absorb many of the neutrons that are constantly leaking out of the reactor and will become first neptunium-239 and then plutonium-239. The plutonium, being a different element from the uranium, can be separated from uranium and obtained in useful quantities.
Such a device is called a “breeder reactor” because it breeds fuel. Indeed, it can be so designed to produce more plutonium-239 than the uranium-235 it uses up, so that you actually end up with more nuclear fuel than you started with. In this way, all the uranium on earth (and not just uranium-235) can be considered potential nuclear fuel.
The first breeder reactor was completed at Arco, Idaho, in August 1951, and on December 20 produced the very first electricity on earth to come from nuclear power. Nevertheless, breeder reactors for commercial use are still a matter for the future.[3]
Another isotope capable of fissioning under neutron bombardment is uranium-233. It does not occur in nature, but was formed in the laboratory by Seaborg and others in 1942. It has a half-life of 162,000 years. It can be formed from naturally occurring thorium-232. Thorium-232 will absorb a neutron to become thorium-233. Then 2 beta particles are given off so that the thorium-233 becomes first protactinium-233 and then uranium-233.
If a thorium shell surrounds a nuclear reactor, fissionable uranium-233 is formed within it and is easily separated from the thorium. In this way, thorium is also added to the list of earth’s potential nuclear fuels.[4]
If all the uranium and thorium in the earth’s crust (including the thin scattering of those elements through granite, for instance) were available for use, we might get up to 100 times as much energy from it as from all the coal and oil on the planet. Unfortunately, it is very unlikely that we will ever be able to make use of all the uranium and thorium. It is widely and thinly spread through the crustal rocks and much of it could not be extracted without using up more energy than would be supplied by it once isolated.
Another problem rests with the nature of the fission reaction. When the uranium-235 nucleus (or plutonium-239 or uranium-233) undergoes fission, it breaks up into any of a large number of middle-sized nuclei that are radioactive—much more intensely radioactive than the original fuel. (It was from among these “fission products” that isotopes of element 61 were first obtained in 1945. Coming from the nuclear fire, it reminded its discoverers of Prometheus, who stole fire from the sun in the Greek myths, and so it was called “promethium”.)
The fission products still contain energy and some of them can be used in lightweight “nuclear batteries”. Such nuclear batteries were first built in 1954. Some batteries, using plutonium-238 rather than fission products, have been put to use in powering artificial satellites over long periods.
Unfortunately, only a small proportion of the fission products can be put to profitable use. Most must be disposed of. They are dangerous because the radiations they give off are deadly and cannot be detected by the ordinary senses. They are very difficult to dispose of safely, and they must not be allowed to get into the environment, especially since some of them remain dangerous for decades or even centuries.
NUCLEAR FUSION
The Energy of the Sun
As it happens, though, nuclear fission is not the only route to useful nuclear energy.
Aston’s studies in the 1920s had shown that it was the middle-sized nuclei that were most tightly packed. Energy would be given off if middle-sized nuclei were produced from either extreme. Not only would energy be formed by the breakup of particularly massive nuclei through fission, but also through the combination of small nuclei to form larger ones (“nuclear fusion”).
In fact, from Aston’s studies it could be seen that, mass for mass, nuclear fusion would produce far more energy than nuclear fission. This was particularly true in the conversion of hydrogen to helium; that is, the conversion of the individual protons of 4 separate hydrogen nuclei into the 2-proton—2-neutron structure of the helium nucleus. A gram of hydrogen, undergoing fusion to helium, would deliver some fifteen times as much energy as a gram of uranium undergoing fission.
As early as 1920, the English astronomer Arthur Stanley Eddington (1882-1944) had speculated that the sun’s energy might be derived from the interaction of subatomic particles. Some sort of nuclear reaction seemed, by then, to be the most reasonable way of accounting for the vast energies constantly being produced by the sun.
The speculation became more plausible with each year. Eddington himself studied the structure of stars, and by 1926 had produced convincing theoretical reasons for supposing that the center of the sun was at enormous densities and temperatures. A temperature of some 15,000,000 to 20,000,000°C seemed to characterize the sun’s center.
At such temperatures, atoms could not exist in earthly fashion. Held together by the sun’s strong gravitational field, they collided with such energy that all or almost all their electrons were stripped off, and little more than bare nuclei were left. These bare nuclei could approach each other much more closely than whole atoms could (which was why the center of the sun was so much more dense than earthly matter could be). The bare nuclei, smashing together at central-sun temperatures, could cling together and form more complex nuclei. Nuclear reactions brought about by such intense heat (millions of degrees) are called “thermonuclear reactions”.
As the 1920s progressed further studies of the chemical structure of the sun showed it to be even richer in hydrogen than had been thought. In 1929 the American astronomer Henry Norris Russell (1877-1957) reported evidence that the sun was 60% hydrogen in volume. (Even this was too conservative; 80% is considered more nearly correct now.) If the sun’s energy were based on nuclear reactions at all, then it had to be the result of hydrogen fusion. Nothing else was present in sufficient quantity to be useful as a fuel.
More and more was learned about the exact manner in which nuclei interacted and about the quantity of energy given off in particular nuclear reactions. It became possible to calculate what might be going on inside the sun by considering the densities and temperatures present, the kind and number of different nuclei available, and the quantity of energy that must be produced. In 1938 the German-American physicist Hans Albrecht Bethe (1906- ) and the German astronomer Carl Friedrich von Weizsäcker (1912- ) independently worked out the possible reactions, and hydrogen fusion was shown to be a thoroughly practical way of keeping the sun going.
Thanks to the high rate of energy production by thermonuclear reactions and to the vast quantity of hydrogen in the sun, not only has it been possible for the sun to have been radiating energy for the last 5,000,000,000 years or so, but it will continue to radiate energy in the present fashion for at least 5,000,000,000 years into the future.
Even so, the sheer quantity of what is going on in the sun is staggering in earthly terms. In the sun 650,000,000 tons of hydrogen are converted into helium every second, and in the process each second sees the disappearance of 4,600,000 tons of mass.
Thermonuclear Bombs
Could thermonuclear reactions be made to take place on earth? The conditions that exist in the center of the sun would be extremely difficult to duplicate on the earth, so there was a natural search for any kind of nuclear fusion that would produce similar energies to those going on in the sun but which would be easier to bring about.
There are 3 hydrogen isotopes known to exist. Ordinary hydrogen is almost entirely hydrogen-1, with a nucleus made up of a single proton. Small quantities of hydrogen-2 (deuterium) with a nucleus made up of a proton plus a neutron also exist and such atoms are perfectly stable.
In 1934 Rutherford, along with the Australian physicist Marcus Laurence Elwin Oliphant (1901- ) and the Austrian chemist Paul Harteck (1902- ) sent hydrogen-2 nuclei flying into hydrogen-2 targets and formed hydrogen-3 (also called “tritium” from the Greek word for “third”) with a nucleus made up of a proton plus 2 neutrons. Hydrogen-3 is mildly radioactive.
Hydrogen-2 fuses to helium more easily than hydrogen-1 does and, all things being equal, hydrogen-2 will do so at lower temperatures than hydrogen-1. Hydrogen-3 requires lower temperatures still. But even for hydrogen-3 it still takes millions of degrees.
Hydrogen-3, although the easiest to be forced to undergo fusion, exists only in tiny quantities.
Hydrogen-2, therefore, is the one to pin hopes on especially in conjunction with hydrogen-3. Only 1 atom out of every 6000 hydrogen atoms is hydrogen-2, but that is enough. There exists a vast ocean on earth that is made up almost entirely of water molecules and in each water molecule 2 hydrogen atoms are present. Even if only 1 in 6000 of these hydrogen atoms is deuterium that still means there are about 35,000 billion tons of deuterium in the ocean.
What’s more, it isn’t necessary to dig for that deuterium or to drill for it. If ocean water is allowed to run through separation plants, the deuterium can be extracted without very much trouble. In fact, for the energy you could get out of it, deuterium from the oceans, extracted by present methods and without allowing for future improvement, would be only one-hundredth as expensive as coal.
The deuterium in the world’s ocean, if allowed to undergo fusion little by little, would supply mankind with enough energy to keep us going at the present rate for 500,000,000,000 years. To be sure, to make deuterium fusion practical, it may be necessary to make use of rarer substances such as the light metal lithium. This will place a sharper limit on the energy supply but even if we are careful, fusion would probably supply mankind with energy for as long as mankind will exist.
Then, too, there would seem to be no danger of hydrogen fusion plants running out of control. Only small quantities of deuterium would be in the process of fusion at any one time. If anything at all went wrong, the deuterium supply could be automatically cut off and the fusion process, with so little involved, would then stop instantly. Moreover, there would be less reason to worry about atomic wastes, for the most dangerous products—hydrogen-3 and neutrons—could be easily taken care of.
It seems ideal, but there is a catch. However clear the theory, before a fusion power station can be established some practical method must be found to start the fusion process, which means finding some way for attaining temperatures in the millions of degrees.
One method for obtaining the necessary temperature was known by 1945. An exploding fission bomb would do it. If, somehow, the necessary hydrogen-2 was combined with a fission bomb, the explosion would set off a fusion reaction that would greatly multiply the energy released. You would have in effect a “thermonuclear bomb”. (To the general public, this was commonly known as a “hydrogen bomb” or an “H-bomb”.)
In 1952 the first fusion device was exploded by the United States in the Marshall Islands. Within months, the Soviet Union had exploded one of its own and in time thermonuclear bombs thousands of times as powerful as the first fission bomb over Hiroshima were built and exploded.
All thermonuclear bombs have been exploded only for test purposes. Even testing seems to be dangerous, however, at least if it is carried on in the open atmosphere. The radioactivity liberated spreads over the world and may do slow but cumulative damage.
Controlled Fusion
However effective a fusion bomb may be in liberating vast quantities of energy, it is not what one has in mind when speaking of a fusion power station. The energy of a fusion bomb is released all at once and its only function is that of utter destruction. What is wanted is the production of fusion energy at a low and steady rate—a rate that is under the control of human operators.
The sun, for instance, is a vast fusion furnace 866,000 miles across, but it is a controlled one—even though that control is exerted by the impersonal laws of nature. It releases energy at a very steady and very slow rate. (The rate is not slow in human terms, of course, but stars sometimes do release their energy in a much more cataclysmic fashion. The result is a “supernova” in which for a short time a single star will increase its radiation to as much as a trillion times its normal level.)
The sun (or any star) going at its normal rate is controlled and steady in its output because of the advantage of huge mass. An enormous mass, composed mainly of hydrogen, compresses itself, through its equally enormous gravitational field, into huge densities and temperatures at its center, thus igniting the fusion reaction—while the same gravitational field keeps the sun together against its tendency to expand.
There is, as far as scientists know, no conceivable way of concentrating a high gravitational field in the absence of the required mass, and the creation of controlled fusion on earth must therefore be done without the aid of gravity. Without a huge gravitational force we cannot simultaneously bring about sun-center densities and sun-center temperatures; one or the other must go.
On the whole, it would take much less energy to aim at the temperatures than at the densities and would be much more feasible. For this reason, physicists have been attempting, all through the nuclear age, to heat thin wisps of hydrogen to enormous temperature. Since the gas is thin, the nuclei are farther apart and collide with each other far fewer times per second. To achieve fusion ignition, therefore, temperatures must be considerably higher than those at the center of the sun. In 1944 Fermi calculated that it might take a temperature of 50,000,000° to ignite a hydrogen-3 fusion with hydrogen-2 under earthly conditions, and 400,000,000° to ignite hydrogen-2 fusion alone. To ignite hydrogen-1 fusion, which is what goes on in the sun (at a mere 15,000,000°), physicists would have to raise their sights to beyond the billion-degree mark.
This would make it seem almost essential to use hydrogen-3 in one fashion or another. Even if it can’t be prepared in quantity to begin with, it might be formed by neutron bombardment of lithium, with the neutrons being formed by the fusion reaction. In this way, you would start with lithium and hydrogen-2 plus a little hydrogen-3. The hydrogen-3 is formed as fast as it is used up. Although in the end hydrogen is converted to helium in a controlled fusion reaction as in the sun, the individual steps in the reaction under human control are quite different from those in the sun.
Still, even the temperatures required for hydrogen-3 represent an enormous problem, particularly since the temperature must not only be reached, but must be held for a period of time. (You can pass a piece of paper rapidly through a candle flame without lighting it. It must be held in the flame for a short period to give it a chance to heat and ignite.)
The English physicist John David Lawson (1923- ) worked out the requirements in 1957. The time depended on the density of the gas. The denser the gas, the shorter the period over which the temperature had to be maintained. If the gas is about one hundred-thousand times as dense as air, the proper temperature must be held, under the most favorable conditions, for about one thousandth of a second.
Comments
Log in to leave a comment.
Worlds Within Worlds: The Story of Nuclear Energy, Volume 3 (of 3)Chapter I: Part 1
0%37 min left in chapter