Chapter VII: Part 7

But this brings into my mind, that having sometimes for Curiosity sake, brought a round Vial with a long Neck fill'd with the Tincture of _Lignum Nephriticum_ into the Darken'd Room already often mention'd, and holding it sometimes in, sometimes near the Sun-beams that enter'd at the hole, and sometimes partly in them, and partly out of them, the Glass being held in several postures, and look'd upon from several Neighbouring parts of the Room, disclos'd a much greater Variety of Colours than in ordinary inlightn'd Rooms it is wont to do; exhibiting, besides the usual Colours, a Red in some parts, and a Green in others, besides Intermediate Colours produc'd by the differing Degrees, and odd mixtures of Light and Shade.

By all this You may see, _Pyrophilus_, the reasonableness of what we elsewhere had occasion to mention, when we have divers times told you, that it is usefull to have New Experiments try'd over again, though they were, at first, made by Knowing and Candid Men, such Reiterations of Experiments commonly exhibiting some New Phænomena, detecting some Mistake or hinting some Truth, in reference to them, that was not formerly taken notice of. And some of our friends have been pleas'd to think, that we have made no unusefull addition to this Experiment, by shewing a way, how in a moment our Liquor may be depriv'd of its Blewness, and restor'd to it again by the affusion of a very few drops of Liquors, which have neither of them any Colour at all of their own. And that which deserves some particular wonder, is, that the Cæruleous Tincture of our Wood is subject by the former Method to be Destroy'd or Restor'd, the Yellowish or Reddish Tincture continuing what it was. And that you may see, that Salts are of a considerable use in the striking of Colours, let me add to the many Experiments which may be afforded us to this purpose by the Dyers Trade, this Observation; That as far as we have hitherto try'd, those Liquors in general that are strong of Acid Salts have the Power of Destroying the Blewness of the Infusion of our Wood, and those Liquors indiscriminatly that abound with Sulphureous Salts, (under which I comprehend the Urinous and Volatile Salts of Animal Substances, and the Alcalisate or fixed Salts that are made by Incineration) have the vertue of Restoring it.

_A Corollary of the Tenth Experiment._

That this Experiment, _Pyrophilus_, may be as well Usefull as Delightfull to You, I must mind You, _Pyrophilus_, that in the newly mention'd Observation, I have hinted to You a New and Easie way of Discovering in many Liquors (for I dare not say in all) whether it be an Acid or Sulphureous Salt, that is Predominant; and that such a Discovery is oftentimes of great Difficulty, and may frequently be of great Use, he that is not a Stranger to the various Properties and Effects of Salts, and of how great moment it is to be able to distinguish their Tribes, may readily conceive. But to proceed to the way of trying other Liquors by an Infusion of our Wood, take it briefly thus. Suppose I have a mind to try whether I conjecture aright, when I imagine that Allom, though it be plainly a Mixt Body, does abound rather with Acid than Sulphureous Salt. To satisfie my self herein, I turn my back to the Light, and holding a small Vial full of the Tincture of _Lignum Nephriticum_, which look'd upon in that Position, appears Cæruleous, I drop into it a little of a strong Solution of Allom made in Fair Water, and finding upon the Affusion and shaking of this New liquor, that the Blewness formerly conspicuous in our Tincture does presently vanish, I am thereby incited to suppose, that the Salt Prædominant in Allom belongs to the Family of Sour Salts; but if on the other side I have a mind to examine whether or no I rightly conceive that Salt of Urine, or of Harts-horn is rather of a Saline Sulphureous (if I may so speak) than of an Acid Nature, I drop a little of the Saline Spirit of either into the Nephritick Tincture, and finding that the Cæruleous Colour is rather thereby Deepned than Destroy'd, I collect that the Salts, which constitute these Spirits, are rather Sulphureous than Acid. And to satisfie my self yet farther in this particular, I take a small Vial of fresh Tincture, and placing both it and my self in reference to the Light as formerly, I drop into the Infusion just as much Distill'd Vinegar, or other Acid liquor as will serve to Deprive it of its Blewness (which a few drops, if the Sour Liquor be strong, and the Vial small will suffice to do) then without changing my Posture, I drop and shake into the same Vial a small proportion of Spirit of Hartshorn or Urine, and finding that upon this affusion, the Tincture immediately recovers its Cæruleous Colour, I am thereby confirm'd firm'd in my former Opinion, of the Sulphureous Nature of these Salts. And so, whereas it is much doubted by Some Modern Chymists to what sort of Salt, that which is Prædominant in Quick-lime belongs, we have been perswaded to referr it rather to Lixiviate than Acid Salts, by having observ'd, that though an Evaporated Infusion of it will scarce yield such a Salt, as Ashes and other Alcalizate Bodyes are wont to do, yet if we deprive our Nephritick Tincture of its Blewness by just so much Distill'd Vinegar as is requisite to make that Colour Vanish, the _Lixivium_ of Quick-lime will immediately upon its Affusion recall the Banished Colour; but not so Powerfully as either of the Sulphureous Liquors formerly mention'd. And therefore I allow my self to guess at the _Strength_ of the Liquors examin'd by this Experiment, by the _Quantity_ of them which is sufficient to Destroy or Restore the Cæruleous Colour of our Tincture. But whether concerning Liquors, wherein neither Acid nor Alcalisate Salts are Eminently Prædominant, our Tincture will enable us to conjecture any thing more than that such Salts are not Prædominant in them, I take not upon me to determine here, but leave to further Tryal; For I find not that Spirit of Wine, Spirit of Tartar freed from Acidity, or Chymical Oyl of Turpentine, (although Liquors which must be conceiv'd very Saline, if Chymists have, which is here no place to Dispute, rightly ascrib'd tasts to the Saline Principle of Bodyes,) have any Remarkable Power either to deprive our Tincture of its Cæruleous Colour, or restore it, when upon the Affusion of Spirit of Vinegar it has disappear'd.

_EXPERIMENT XI._

And here I must not omit, _Pyrophilus_, to inform You, that we can shew You even in a Mineral Body something that may seem very near of Kin to the Changeable Quality of the Tincture of _Lignum Nephriticum_, for we have several flat pieces of Glass, of the thickness of ordinary Panes for Windows one of which being interposed betwixt the Eye and a clear Light, appears of a Golden Colour, not much unlike that of the moderate Tincture of our Wood, but being so look'd upon as that the Beams of light are not so much Trajected thorough it as Reflected from it to the Eye, that Yellow seems to degenerate into a pale Blew, somewhat like that of a Turquoise. And what which may also appear strange, is this, that if in a certain posture you hold one of these Plates Perpendicular to the Horizon, so that the Sun-beams shine upon half of it, the other half being Shaded, You may see that the part Shin'd upon will be of a much Diluter Yellow than the Shaded part which will appear much more Richly Colour'd; and if You alter the Posture of the Glass, so that it be not held Perpendicular, but Parallel in reference to the Horizon, You may see, (which perhaps you will admire) the Shaded part look of a Golden Colour, but the other that the Sun shines freely on, will appear considerably Blew, and as you remove any part of the Glass thus held Horizontally into the Sun-beams or Shade, it will in the twinkling of an Eye seem to pass from one of the above mention'd Colours to the other, the Sun-beams Trajected through it upon a sheet of White Paper held near it, do colour it with a Yellow, somewhat bordering upon a Red, but yet the Glass may be so oppos'd to the Sun, that it may upon Paper project a mix'd Colour here and there more inclin'd to Yellow, and here and there more to Blew. The other Phænomena of this odd Glass, I fear it would be scarce worth while to Record, and therefore I shall rather advertise You, _First_ that in the trying of these Experiments with it, you must take notice that one of the sides has either alone, or at least principally its Superficial parts dispos'd to the Reflection of the Blew Colour above nam'd, and that therefore you must have a care to keep that side nearest to the Eye. And next, that we have our selves made Glasses not unfit to exhibit an Experiment not unlike that I have been speaking of, by laying upon pieces of Glass some very finely foliated Silver, and giving it by degrees a much stronger Fire than is requisite or usual for the Tinging of Glasses of other Colours. And this Experiment, not to mention that it was made without a Furnace in which Artificers that Paint Glass are wont to be very Curious, is the more considerable, because, that though a Skilfull Painter could not deny to me that 'twas with Silver he Colour'd his Glasses Yellow; yet he told me, that when to Burn them (as they speak) he layes on the plates of Glass nothing but a _Calx_ of Silver Calcin'd without Corrosive Liquors, and Temper'd with Fair Water, the Plates are Ting'd of a fine Yellow that looks of a Golden Colour, which part soever of it you turn to or from the Light; whereas (whether it be what an Artificer would call Over-doing, or Burning, or else the imploying the Silver Crude that makes the Difference,) we have found more than once, that some Pieces of Glass prepar'd as we have related, though held against the Light they appear'd of a Transparent Yellow, yet look'd on with ones back turn'd to the Light they exhibited an Untransparent Blew.

_EXPERIMENT XII._

If you will allow me, _Pyrophilus_, for the avoiding of Ambiguity, to imploy the Word Pigments, to signifie such prepared materials (as Cochinele, Vermilion, Orpiment,) as Painters, Dyers and other Artificers make use of to impart or imitate particular Colours, I shall be the better understood in divers passages of the following papers, and particularly when I tell you, That the mixing of Pigments being no inconsiderable part of the Painters Art, it may seem an Incroachment in me to meddle with it. But I think I may easily be excus'd (though I do not altogether pass it by) if I restrain my self to the making of a Transient mention of some few of their Practices about this matter; and that only so far forth, as may warrant me to observe to you, that there are but few Simple and Primary Colours (if I may so call them) from whose Various Compositions all the rest do as it were Result. For though Painters can imitate the Hues (though not always the Splendor) of those almost Numberless differing Colours that are to be met with in the Works of Nature, and of Art, I have not yet found, that to exhibit this strange Variety they need imploy any more than _White_, and _Black_, and _Red_, and _Blew_, and _Yellow_; these _five_, Variously _Compounded_, and (if I may so speak) _Decompounded_, being sufficient to exhibit a Variety and Number of Colours, such, as those that are altogether Strangers to the Painters Pallets, can hardly imagine.

Thus (for Instance) Black and White differingly mix'd, make a Vast company of Lighter and Darker Grays.

Blew and Yellow make a huge Variety of Greens.

Red and Yellow make Orange Tawny.

Red with a little White makes a Carnation.

Red with an Eye of Blew, makes a Purple; and by these simple Compositions again Compounded among themselves, the Skilfull Painter can produce what kind of Colour he pleases, and a great many more than we have yet Names for. But, as I intimated above, 'tis not my Design to prosecute this Subject, though I thought it not unfit to take some Notice of it, because we may hereafter have occasion to make use of what has been now deliver'd, to illustrate the Generation of Intermediate Colours; concerning which we must yet subjoyn this Caution, that to make the Rules about the Emergency of Colours, fit to be Relied upon, the Corpuscles whereof the Pigments consist must be such as do not Destroy one anothers Texture, for in case they do, the produced Colour may be very Different from that which would Result from the Mixture of other harmless Pigments of the same Colours, as I shall have Occasion to shew ere long.

_EXPERIMENT XIII._

It may also give much light to an Enquirer into the Nature of Colours, to know that not only in Green, but in many (if not all) other Colours, the Light of the Sun passing through Diaphanous Bodies of differing Hues may be tinged of the same Compound Colour, as if it came from some Painters Colours of the same Denomination, though this later be exhibited by Reflection, and be (as the former Experiment declares) manifestly Compounded of material Pigments. Wherefore to try the Composition of Colours by Trajection, we provided several Plates of Tinged Glass, which being laid two at a time one on the top of another, the Object look'd upon through them both, appear'd of a Compounded Colour, which agrees well with what we have observ'd in the second Experiment, of Looking against the Light through differingly Colour'd Papers. But we thought the Experiment would be more Satisfactory, if we procur'd the Sun-beams to be so Ting'd in their passage through Plates of Glass, as to exhibit the Compounded Colour upon a Sheet of White Paper. And though by reason of the Thickness of the Glasses, the Effect was but Faint, even when the Sun was High and Shin'd forth clear, yet, we easily remedied that by Contracting the Beams we cast on them by means of a Convex Burning-glass, which where it made the Beams much converge Increas'd the Light enough to make the Compounded Colour very manifest upon the Paper. By this means we observ'd, that the Beams trajected through Blew and Yellow compos'd a Green, that an intense and moderate Red did with Yellow make differing degrees of Saffron, and Orange Tawny Colours, that Green and Blew made a Colour partaking of both, such as that which some Latin Writers call _Pavonaceus_, that Red and Blew made a Purple, to which we might add other Colours, that we produc'd by the Combinations of Glasses differingly Ting'd, but that I want proper Words to express them in our Language, and had not when we made the Tryals, the Opportunity of consulting with a Painter, who perchance might have Suppli'd me with some of the terms I wanted.

I know not whether it will be requisite to subjoyn on this Occasion, what I tried concerning Reflections from Colour'd Glasses, and other Transparent Bodies, namely, that having expos'd four or five sorts of them to the Sun, and cast the Reflected Beams upon White Paper held near at hand, the Light appear'd not manifestly Ting'd, but as if it had been Reflected from the Impervious parts of a Colourless Glass, only that Reflected from the Yellow was here and there stain'd with the same Colour, as if those Beams were not all Reflected from the Superficial, but some from the Internal parts of the Glass; upon which Occasion you may take notice, that a Skilfull Tradesman, who makes such Colour'd Glass told me, that where as the Red Pigment was but Superficial, the Yellow penetrated to the very midst of the Plate. But for further Satisfaction, not having the Opportunity to Foliate those Plates, and so turn them into Looking-glasses, we Foliated a Plate of _Muscovy_ Glass, and then laying on it a little Transparent Varnish of a Gold Colour, we expos'd it to the Sun-beams, so as to cast them upon a Body fit to receive them, on which the Reflected Light, appearing, as we expected, Yellow, manifested that Rebounding from the Specular part of the _Selenitis_, it was Ting'd in its return with the Colour of the Transparent Varnish through which it pass'd.

_EXPERIMENT XIV._

After what we have said of the Composition of Colours, it will now be seasonable to annex some Experiments that we made in favour of those Colours, that are taught in the Schools not to be Real, but only Apparent and Phantastical; For we found by Tryals, that these Colours might be Compounded, both with True and Stable Colours, and with one another, as well as unquestionably Genuine and Lasting Colours, and that the Colours resulting from such Compositions, would respectively deserve the same Denominations.

For first, having by the Trajection of the Sun-beams through a Glass-prism thrown an Iris on the Floor, I found that by placing a Blew Glass at a convenient distance betwixt the Prism and the Iris, that part of the Iris that was before Yellow, might be made to appear Green, though not of a Grass Green, but of one more Dilute and Yellowish. And it seems not improbable, that the narrow Greenish List (if I may so call it) that is wont to be seen between the Yellow and Blew parts of the Iris, is made by the Confusion of those two Bordering Colours.

Next, I found, that though the want of a sufficient Liveliness in either of the Compounding Colours, or a light Error in the manner of making the following Tryals, was enough to render some of them Unsuccessfull, yet when all necessary Circumstances were duely observ'd, the Event was answerable to our Expectation and Desire.

And (as I formerly Noted) that Red and Blew compound a Purple, so I could produce this last nam'd Colour, by casting at some Distance from the Glass the Blew part of the Prismatical Iris (as I think it may be call'd for Distinction sake) upon a Lively Red, (for else the Experiment succeeds not so well.) And I remember, that sometimes when I try'd this upon a piece of Red Cloath, _that_ part of the Iris which would have been Blew, (as I try'd by covering that part of the Cloath with a piece of White Paper) and Compounded with the Red, wherewith the Cloath was Imbued before, appear'd of a fair Purple, did, when I came to View it near at hand, look very Odly, as if there were some strange Reflection or Refraction or both made in the Hairs of which that Cloath was composed.

Calling likewise the Prismatical Iris upon a very Vivid Blew, I found that part of it, which would else have been the Yellow, appear Green. (Another somewhat differing Tryal, and yet fit to confirm this, you will find in the fifteenth Experiment.)

But it may seem somewhat more strange, that though the Prismatical Iris being made by the Refraction of Light through a Body that has no Colour at all, must according to the Doctrine of the Schools consist of as purely Emphatical Colours, as may be, yet even these may be Compounded with one another, as well as Real Colours in the Grossest Pigments. For I took at once two Triangular Glasses, and one of them being kept fixt in the same Posture, that the Iris it projected on the Floor might not Waver, I cast on the same Floor another Iris with the other Prism, and Moving it too and fro to bring what part of the second Iris I pleas'd, to fall upon what part of the first I thought fit, we did sometimes (for a small Errour suffices to hinder the Success) obtain by this means a Green Colour in that part of the more Stable Iris, that before was Yellow, or Blew, and frequently by casting those Beams that in one of the Iris's made the Blew upon the Red parts of the other Iris, we were able to produce a lovely Purple, which we can Destroy or Recompose at pleasure, by Severing and Reapproaching the Edges of the two Iris's.

_EXPERIMENT XV._

On this occasion, _Pyrophilus_, I shall add, that finding the Glass-prism to be the usefullest Instrument Men have yet imploy'd about the Contemplation of Colours, and considering that Prisms hitherto in use are made of Glass, Transparent and Colourless, I thought it would not be amiss to try, what change the Superinduction of a Colour, without the Destruction of the Diaphaneity, would produce in the Colours exhibited by the Prism. But being unable to procure one to be made of Colour'd Glass, and fearing also that if it were not carefully made, the Thickness of it would render it too Opacous, I endeavoured to substitute one made of Clarify'd Rosin, or of Turpentine brought (as I elsewhere teach) to the consistence of a Transparent Gum. But though these Endeavours were not wholly lost, yet we found it so difficult to give these Materials their true Shape, that we chose rather to Varnish over an ordinary Prism with some of these few Pigments that are to be had Transparent; as accordingly we did first with Yellow, and then with Red, or rather Crimson, made with Lake temper'd with a convenient Oyl, and the Event was, That for want of good Transparent Colours, (of which you know there are but very few) both the Yellow and the Red made the Glass so Opacous, (though the Pigment were laid on but upon two Sides of the Glass, no more being absolutely necessary) that unless I look'd upon an Inlightned Window, or the Flame of a Candle, or some other Luminous or very Vivid object, I could scarce discern any Colours at all, especially when the Glass was cover'd with Red. But when I did look on such Objects, it appear'd (as I expected) that the Colour of the Pigment had Vitiated or Drown'd some of those which the Prism would according to its wont have exhibited, and mingling with others, Alter'd them: as I remember, that both to my Eyes, and others to whom I show'd it, when the Prism was cover'd with Yellow, it made those Parts of bright Objects, where the Blew would else have been Conspicuous, appear of a light Green. But, _Pyrophilus_, both the Nature of the Colours, and the Degree of Transparency, or of Darkness in the Pigment, besides divers other Circumstances, did so vary the _Phænomena_ of these Tryals, that till I can procure small Colour'd Prisms, or Hollow ones that may be filled with Tincted Liquor, or obtain Some better Pigments than those I was reduc'd to imploy, I shall forbear to Build any thing upon what has been delivered, and shall make no other use of it, than to invite you to prosecute the Inquiry further.

_EXPERIMENT XVI._

And here, _Pyrophilus_, since we are treating of Emphatical Colours, we shall add what we think not unworthy your Observation, and not unfit to afford some Exercise to the Speculative. For there are some Liquors, which though Colourless themselves, when they come to be Elevated, and Dispers'd into Exhalations, exhibit a conspicuous Colour, which they lose again, when they come to be Reconjoyn'd into a Liquor, as good Spirit of _Nitre_; or upon its account strong _Aqua-fortis_, though devoid of all appearance of Redness whilst they continue in the form of a Liquor, if a little Heat chance to turn the Minute parts of them into Vapour, the Steam will appear of a Reddish or deep Yellow Colour, which will Vanish when those Exhalations come to resume the form of Liquor.

And not only if you look upon a Glass half full of _Aqua-fortis_, or Spirit of _Nitre_, and half full of _Nitrous_ steams proceeding from it, you will see the Upper part of the Glass of the Colour freshly mention'd, if through it you look upon the Light. But which is much more considerable, I have tried, that putting _Aqua-fortis_ in a long clear Glass, and adding a little Copper or some such open Metall to it, to excite Heat and Fumes, the Light trajected through those Fumes, and cast upon a sheet of White Paper, did upon that appear of the Colour that the Fumes did, when directly Look'd upon, as if the Light were as well Ting'd in its passage through these Fumes, as it would have been by passing through some Glass or Liquor in which the same Colour was Inherent.

To which I shall further add, that having sometimes had the Curiosity to observe whether the Beams of the Sun near the Horizon trajected through a very Red Sky, would not (though such rednesses are taken to be but Emphatical Colours) exhibit the like Colour, I found that the Beams falling within a Room upon a very White Object, plac'd directly opposite to the Sun, disclos'd a manifest Redness, as if they had pass'd through a Colour'd _Medium_.

_EXPERIMENT XVII._

The emergency, _Pyrophilus_, of Colours upon the Coalition of the Particles of such Bodies as were neither of them of the Colour of that Mixture whereof they are the Ingredients, is very well worth our attentive Observation, as being of good use both Speculative and Practical; For much of the Mechanical use of Colours among Painters and Dyers, doth depend upon the Knowledge of what Colours may be produc'd by the Mixtures of Pigments so and so Colour'd. And (as we lately intimated) 'tis of advantage to the contemplative Naturalist, to know how many and which Colours are Primitive (if I may so call them) and Simple, because it both eases his Labour by confining his most sollicitous Enquiry to a small Number of Colours upon which the rest depend, and assists him to judge of the nature of particular compounded Colours, by shewing him from the Mixture of what more Simple ones, and of what Proportions of them to one another, the particular Colour to be consider'd does result. But because to insist on the Proportions, the Manner and the Effects of such Mixtures would oblige me to consider a greater part of the Painters Art and Dyers Trade, than I am well acquainted with, I confin'd my self to make Trial of _several ways to produce Green_, by the composition of Blew and Yellow. And shall in this place both Recapitulate most of the things I have Dispersedly deliver'd already concerning that Subject, and Recruit them.

And first, whereas Painters (as I noted above) are wont to make Green by tempering Blew and Yellow, both of them made into a soft Consistence, with either Water or Oyl, or some Liquor of Kin to one of those two, according as the Picture is to be Drawn with those they call _water Colours_, or those they term _Oyl Colours_, I found that by choosing fit Ingredients, and mixing them in the form of Dry Powders, I could do, what I could not if the Ingredients were temper'd up with a Liquor; But the Blew and Yellow Powders must not only be finely Ground, but such as that the Corpuscles of the one may not be too unequal to those of the other, lest by their Disproportionate Minuteness the Smaller cover and hide the Greater. We us'd with good success a slight Mixture of the fine Powder of Bise, with that of Orpiment, or that of good Yellow Oker, I say a _slight_ Mixture, because we found that an _exquisite_ Mixture did not do so well, but by lightly mingling the two Pigments in several little Parcels, those of them in which the Proportion and Manner of Mixture was more Lucky, afforded us a good Green.

2. We also learn'd in the Dye-houses, that Cloth being Dy'd Blew with Woad, is afterwards by the Yellow Decoction of _Luteola_ or Woud-wax or Wood-wax Dy'd into a Green Colour.

3. You may also remember what we above Related, where we intimated, that having in a Darkn'd Room taken two Bodies, a Blew and a Yellow, and cast the Light Reflected from the one upon the other, we likewise obtain'd a Green.

4. And you may remember, that we observ'd a Green to be produc'd, when in the same Darkn'd Room we look'd at the Hole at which alone the Light enter'd, through the Green and Yellow parts of a sheet of Marbl'd Paper laid over one another.

5. We found too, that the Beams of the Sun being trajected through two pieces of Glass, the one Blew and the other Yellow, laid over one another, did upon a sheet of White paper on which they were made to fall, exhibit a lovely Green.

6. I hope also, that you have not already forgot, what was so lately deliver'd, concerning the composition of a Green, with a Blew and Yellow; of which most Authors would call the one a _Real_, and the other an _Emphatical_.

7. And I presume, you may have yet fresh in your memory, what the fourteenth Experiment informs you, concerning the exhibiting of a Green, by the help of a Blew and Yellow, that were both of them Emphatical.

8. Wherefore we will proceed to take notice, that we also devis'd a way of trying whether or no Metalline Solutions though one of them at least had its Colour Adventitious, by the mixture of the _Menstruum_ employ'd to dissolve it, might not be made to compound a Green after the manner of other Bodies. And though this seem'd not easie to be perform'd by reason of the Difficulty of finding Metalline Solutions of the Colour requisite, that would mix without Præcipitating each other; yet after a while having consider'd the matter, the first Tryal afforded me the following Experiment. I took a High Yellow Solution of good Gold in _Aqua-Regis_, (made of _Aqua-fortis_, and as I remember half its weight of Spirit of Salt) To this I put a due Proportion of a deep and lovely Blew Solution of Crude Copper, (which I have elsewhere taught to be readily Dissoluble in strong Spirit of Urine) and these two Liquors though at first they seem'd a little to Curdle one another, yet being throughly mingl'd by Shaking, they presently, as had been Conjectur'd, united into a Transparent Green Liquor, which continu'd so for divers days that I kept it in a small Glass wherein 'twas made, only letting fall a little Blackish Powder to the Bottom. The other _Phænomena_ of this Experiment belong not to this place, where it may suffice to take notice of the Production of a Green, and that the Experiment was more than once repeated with Success.

9. And lastly, to try whether this way of compounding Colours would hold ev'n in Ingredients actually melted by the Violence of the Fire, provided their Texture were capable of safely induring Fusion, we caus'd some Blew and Yellow Ammel to be long and well wrought together in the Flame of a Lamp, which being Strongly and Incessantly blown on them kept them in some degree of Fusion, and at length (for the Experiment requires some Patience as well as Skil) we obtain'd the expected Ammel of a Green Colour.

I know not, _Pyrophilus_, whether it be worth while to acquaint you with the ways that came into my Thoughts, whereby in some measure to explicate the first of the mention'd ways of making a Green; for I have sometimes Conjectur'd, that the mixture of the Bise and the Orpiment produc'd a Green by so altering the Superficial Asperity, which each of those Ingredients had apart, that the Light Incident on the mixture was Reflected with differing Shades, as to Quantity, or Order, or both, from those of either of the Ingredients, and such as the Light is wont to be Modify'd with, when it Reflects from Grass, or Leaves, or some of those other Bodies that we are wont to call Green. And sometimes too I have doubted, whether the produced Green might not be partly at least deriv'd from this, That the Beams that Rebound from the Corpuscles of the Orpiment, giving one kind of stroak upon the _Retina_, whose Perception we call Yellow, and the Beams Reflected from the Corpuscles of the Bise, giving another stroak upon the same _Retina_, like to Objects that are Blew, the Contiguity and Minuteness of these Corpuscles may make the Appulse of the Reflected Light fall upon the _Retina_ within so narrow a Compass, that the part they Beat upon being but as it were a Physical point, they may give a Compounded stroak, which may consequently exhibit a Compounded and new Kind of Sensation, as we see that two Strings of a Musical Instrument being struck together, making two Noises that arrive at the Ear at the same time as to Sense, yield a Sound differing from either of them, and as it were Compounded of both; Insomuch that if they be Discordantly ton'd, though each of them struck apart would yield a Pleasing Sound, yet being struck together they make but a Harsh and troublesome Noise. But this not being so fit a place to prosecute Speculations, I shall not insist, neither upon these Conjectures nor any others, which the Experiment we have been mentioning may have suggested to me. And I shall leave it to you, _Pyrophilus_, to derive what Instruction you can from comparing together the Various ways whereby a Yellow and a Blew can be made to Compound a Green. That which I now pretend to, being only to shew that the first of those mention'd ways, (not to take at present notice of the rest) does far better agree with our Conjectures about Colours, than either with the Doctrine of the Schools, or with that of the _Chymists_, both which seem to be very much Disfavour'd by it.

For first, since in the Mixture of the two mention'd Powders I could by the help of a very excellent _Microscope_ (for ordinary ones will scarce serve the turn) discover that which seem'd to the naked Eye a Green Body, to be but a heap of Distinct, though very small Grains of Yellow Orpiment and Blew Bise confusedly enough Blended together, it appears that the Colour'd Corpuscles of either kind did each retain its own Nature and Colour; By which it may be guess'd, what meer Transposition and Juxtaposition of Minute and Singly unchang'd Particles of Matter can do to produce a new Colour; For that this Local Motion and new Disposition of the small parts of the Orpiment did Intervene is much more manifest than it is easie to Explicate how they should produce this new Green otherwise than by the new Manner of their being put together, and consequently by their new Disposition to Modifie the Incident Light by Reflecting it otherwise than they did before they were Mingl'd together.

Secondly, The Green thus made being (if I may so speak) Mechanically produc'd, there is no pretence to derive it from I know not what incomprehensible Substantial Form, from which yet many would have us believe that Colours must flow; Nor does this Green, though a Real and Permanent, not a Phantastical and Vanid Colour, seem to be such an Inherent Quality as they would have it, since not only each part of the Mixture remains unalter'd in Colour, and consequently of a differing Colour from the Heap they Compose, but if the Eye be assisted by a _Microscope_ to discern things better and more distinctly than before it could, it sees not a Green Body, but a Heap of Blew and Yellow Corpuscles.

And in the third place, I demand what either Sulphur, or Salt, or Mercury has to do in the Production of this Green; For neither the Bise nor the Orpiment were indu'd with that Colour before, and the bare Juxtaposition of the Corpuscles of the two Powders that work not upon each other, but might if we had convenient Instruments be separated, unalter'd, cannot with any probability be imagin'd either to Increase or Diminish any of the three Hypostatical Principles, (to which of them soever the _Chymists_ are pleas'd to ascribe Colours) nor does there here Intervene so much as Heat to afford them any colour to pretend, that at least there is made an Extraversion (as the _Helmontians_ speak) of the Sulphur or of any of the two other supposed Principles; But upon this Experiment we have already Reflected enough, if not more than enough for once.

_EXPERIMENT XVIII._

But here, _Pyrophilus_, I must advertise you, that 'tis not every Yellow and every Blew that being mingl'd will afford a Green; For in case one of the Ingredients do not Act only as endow'd with such a Colour, but as having a power to alter the Texture of the Corpuscles of the other, so as to Indispose them to Reflect the Light, as Corpuscles that exhibit a Blew or a Yellow are wont to Reflect it, the emergent Colour may be not Green, but such as the change of Texture in the Corpuscles of one or both of the Ingredients qualifies them to shew forth; as for instance, if you let fall a few Drops of Syrrup of Violets upon a piece of White Paper, though the Syrrup being spread will appear Blew, yet mingling with it two or three Drops of the lately mention'd Solution of Gold, I obtain'd not a Green but a Reddish mixture, which I expected from the remaining Power of the Acid Salts abounding in the Solution, such Salts or Saline Spirits being wont, as we shall see anon, though weakn'd, so to work upon that Syrrup as to change it into a Red or Reddish Colour. And to confirm that for which I allege the former Experiment, I shall add this other, that having made a very strong and high-colour'd Solution of Filings of Copper with Spirit of Urine, though the _Menstruum_ seem'd Glutted with the Metall, because I put in so much Filings that many of them remain'd for divers days Undissolv'd at the Bottom, yet having put three or four Drops of Syrrup of Violets upon White Paper, I found that the deep Blew Solution proportionably mingl'd with this other Blew Liquor did not make a Blew mixture, but, as I expected, a fair Green, upon the account of the Urinous Salt that was in the _Menstruum_.

_EXPERIMENT XIX._

To shew the _Chymists_, that Colours may be made to Appear or Vanish, where there intervenes no Accession or Change either of the Sulphureous, or the Saline, or the Mercurial principle (as they speak) of Bodies: I shall not make use of the Iris afforded by the Glass-prism, nor of the Colours to be seen in a fair Morning in those drops of Dew that do in a convenient manner Reflect and Refract the Beams of Light to the Eye; But I will rather mind them of what they may observe in their own Laboratories, namely, that divers, if not all, Chymical Essential Oyls, as also good Spirit of Wine, being shaken till they have good store of Bubbles, those Bubbles will (if attentively consider'd) appear adorn'd with various and lovely Colours, which all immediately Vanish, upon the relapsing of the Liquor that affords those Bubbles their Skins, into the rest of the Oyl, or Spirit of Wine, so that a Colourless Liquor may be made in a trice to exhibit variety of Colours, and may lose them in a moment without the Accession or Diminution of any of its Hypostatical Principles. And, by the way, 'tis not unworthy our notice, that some Bodies, as well Colourless, as Colour'd, by being brought to a great Thinness of parts, acquire Colours though they had none before, or Colours differing from them they were before endued with: For, not to insist on the Variety of Colours, that Water, made somewhat Glutinous by Sope, acquires, when 'tis blown into such Sphærical Bubbles as Boys are wont to make and play with; Turpentine (though it have a Colour deep enough of its own) may (by being blown into after a certain manner) be brought to afford Bubbles adorn'd with variety of Orient Colours, which though they Vanish after some while upon the breaking of the Bubbles, yet they would in likelihood always exhibit Colours upon their _Superfices_, (though not always the same in the same Parts of them, but Vary'd according to the Incidence of the Sight, and the Position of the Eye) if their Texture were durable enough: For I have seen one that was Skill'd at fashioning Glasses by the help of a Lamp, blowing some of them so strongly as to burst them, whereupon it was found, that the Tenacity of the Metall was such, that before it broke it suffer'd it self to be reduc'd into Films so extremely thin, that being kept clean they constantly shew'd on their Surfaces (but after the manner newly mention'd) the varying Colours of the Rain-bow, which were exceedingly Vivid, as I had often opportunity to observe in some, that I caus'd purposely to be made, to keep by me.

But lest it should be objected, that the above mentioned Instances are drawn from Transparent Liquors, it may possibly appear, not impertinent to add, what I have sometimes thought upon, and several times tried, when I was considering the Opinions of the _Chymists_ about Colours, I took then a Feather of a convenient Bigness and Shape, and holding it at a fit distance betwixt my Eye and the Sun when he was near the Horizon, me thought there appear'd to me a Variety of little Rain-bows, with differing and very vivid Colours, of which none was constantly to be seen in the Feather; the like _Phænomenon_ I have at other times (though not with altogether so good success) produc'd, by interposing at a due distance a piece of Black Ribband betwixt the almost setting Sun and my Eye, not to mention the Trials I have made to the same purpose, with other Bodies.

_EXPERIMENT XX._

Take good Syrrup of Violets, Imprægnated with the Tincture of the flowers, drop a little of it upon a White Paper (for by that means the Change of Colour will be more conspicuous, and the Experiment may be practis'd in smaller Quantities) and on this Liquor let fall two or three drops of Spirit either of Salt or Vinegar, or almost any other eminently Acid Liquor, and upon the Mixture of these you shall find the Syrrup immediatly turn'd Red, and the way of Effecting such a Change has not been unknown to divers Persons who have produc'd the like, by Spirit of Vitriol, or juice of Limmons, but have Groundlessly ascrib'd the Effect to some Peculiar Quality of those two Liquors, whereas, (as we have already intimated) almost any Acid Salt will turn Syrrup of Violets Red. But to improve the Experiment, let me add what has not (that I know of) been hitherto observ'd, and has, when we first shew'd it them, appear'd something strange, even to those that have been inquisitive into the Nature of Colours; namely, that if instead of Spirit of Salt, or that of Vinegar, you drop upon the Syrrup of Violets a little Oyl of Tartar _per Deliquium_, or the like quantity of Solution of Potashes, and rubb them together with your finger, you shall find the Blew Colour of the Syrrup turn'd in a moment into a perfect Green, and the like may be perform'd by divers other Liquors, as we may have occasion elsewhere to Inform you.

_Annotation upon the twentieth Experiment_.

The use of what we lately deliver'd concerning the way of turning Syrrup of Violets, Red or Green, may be this; That, though it be a far more common and procurable Liquor than the Infusion of _Lignum Nephriticum_, it may yet be easily substituted in its Room, when we have a mind to examine, whether or no the Salt predominant in a Liquor or other Body, wherein 'tis Loose and Abundant, belong to the Tribe of _Acid_ Salts or not. For if such a Body turn the Syrrup of a Red or Reddish Purple Colour, it does for the most part argue the Body (especially if it be a distill'd Liquor) to abound with Acid Salt. But if the Syrrup be made Green, that argues the Predominant Salt to be of a Nature repugnant to that of the Tribe of Acids. For, as I find that either Spirit of Salt, or Oyl of Vitriol, or _Aqua-fortis_, or Spirit of Vinegar, or Juice of Lemmons, or any of the Acid Liquors I have yet had occasion to try, will turn Syrrup of Violets, of a _Red_, (or at least, of a _Reddish_ Colour, so I have found, that not only the Volatile Salts of all Animal Substances I have us'd, as Spirit of Harts-horn, of Urine, of Sal-Armoniack, of Blood, &c. but also all the Alcalizate Salts I have imploy'd, as the Solution of Salt of Tartar, of Pot-ashes, of common Wood-ashes, Lime-water, &c. will immediately change the Blew Syrrup, into a perfect Green. And by the same way (to hint that upon the by) I elsewhere show you, both the changes that Nature and Time produce, in the more Saline parts of some Bodies, may be discover'd, and also how ev'n such Chymically prepar'd Bodies, as belong not either to the Animal Kingdome, or to the Tribe of _Alcali's_, may have their new and superinduc'd Nature successfully Examin'd. In this place I shall only add, that not alone the Changing the Colour of the Syrrup, requires, that the Changing Body be more strong, of the Acid, or other sort of Salt that is Predominant in it, than is requisite for the working upon the Tincture of _Lignum Nephriticum_; but that in this is also, the Operation of the formerly mention'd Salts upon our Syrrup, differs from their Operation upon our Tinctures, that in this Liquor, if the Cæruleous Colour be _Destroy'd_ by an Acid Salt, it may be _Restor'd_ by one that is either Volatile, or Lixiviate; whereas in Syrrup of Violets, though one of these contrary Salts will _destroy_ the Action of the other, yet neither of them will _restore_ the Syrrup to its native Blew; but each of them will Change it into the Colour which it self doth (if I may so speak) affect, as we shall have Occasion to show in the Notes on the twenty fifth Experiment.

_EXPERIMENT XXI._

There is a Weed, more known to Plowmen than belov'd by them, whose Flowers from their Colour are commonly call'd _Blew-bottles_, and _Corn-weed_ from their Growing among Corn[18]. These Flowers some Ladies do, upon the account of their Lovely Colour, think worth the being Candied, which when they are, they will long retain so fair a Colour, as makes them a very fine Sallad in the Winter. But I have try'd, that when they are freshly gather'd, they will afford a Juice, which when newly express'd, (for in some cases 'twill soon enough degenerate) affords a very deep and pleasant Blew. Now, (to draw this to our present Scope) by dropping on this fresh Juice, a little Spirit of Salt, (that being the Acid Spirit I had then at hand) it immediately turn'd (as I predicted) into a Red. And if instead of the Sowr Spirit I mingled with it a little strong Solution of an Alcalizate Salt, it did presently disclose a lovely Green; the same Changes being by those differing sorts of Saline Liquors, producible in this _Natural juice_, that we lately mention'd to have happen'd to that _factitious Mixture_, the Syrrup of Violets. And I remember, that finding this Blew Liquor, when freshly made, to be capable of serving in a Pen for an Ink of that Colour, I attempted by moistning one part of a piece of White Paper with the Spirit of Salt I have been mentioning, and another with some Alcalizate or Volatile Liquor, to draw a Line on the leisurely dry'd Paper, that should, e'vn before the Ink was dry, appear partly Blew, partly Red, and partly Green: But though the latter part of the Experiment succeeded not well, (whether because Volatile Salts are too Fugitive to be retain'd in the Paper, and Alcalizate ones are too Unctuous, or so apt to draw Moisture from the Air, that they keep the Paper from drying well) yet the former Part succeeded well enough; the Blew and Red being Conspicuous enough to afford a surprizing Spectacle to those, I acquaint not with (what I willingly allow you to call) the _Trick_.

[18] _Herbarists_ are wont to call this Plant _Cyanus vulgaris minor_.

_Annotation upon the one and twentieth Experiment._

But lest you should be tempted to think (_Pyrophilus_) that Volatile or Alcalizate Salts change Blews into Green, rather upon the score of the easie Transition of the former Colour into the latter, than upon the account of the Texture, wherein most Vegetables, that afford a Blew, seem, though otherwise differing, to be Allied, I will add, that when I purposely dissolv'd Blew Vitriol in fair Water, and thereby imbu'd sufficiently that Liquor with that Colour, a Lixiviate Liquor, and a Urinous Salt being Copiously pour'd upon distinct Parcels of it, did each of them, though perhaps with some Difference, turn the Liquor not Green, but of a deep Yellowish Colour, almost like that of Yellow Oker, which Colour the Precipitated Corpuscles retain'd, when they had Leisurely subsided to the Bottom. What this Precipitated Substance is, it is not needfull now to Enquire in this place, and in another, I have shown you, that notwithstanding its Colour, and its being Obtainable from an Acid _Menstruum_ by the help of Salt of Tartar, it is yet far enough from being the true Sulphur of Vitriol.

_EXPERIMENT XXII._

Our next Experiment (_Pyrophilus_) will perhaps seem to be of a contrary Nature to the two former, made upon Syrrup of Violets, and Juice of Blew-bottles. For as in them by the Affusion of Oyl of Tartar, a Blewish Liquor is made Green, so in this, by the sole Mixture of the same Oyl, a Greenish Liquor becomes Blew. The hint of this Experiment was given us by the practice of some _Italian_ Painters, who being wont to Counterfeit _Ultra-marine Azure_ (as they call it) by Grinding Verdigrease with Sal-Armoniack, and some other Saline Ingredients, and letting them Rot (as they imagine) for a good while together in a Dunghill, we suppos'd, that the change of Colour wrought in the Verdigrease by this way of Preparation, must proceed from the Action of certain Volatile and Alcalizate Salts, abounding in some of the mingled Concretes, and brought to make a further Dissolution of the Copper abounding in the Verdigrease, and therefore we Conjectur'd, that if both the Verdigrease, and such Salts were dissolv'd in fair Water, the small Parts of both being therein more subdivided, and set at liberty, would have better access to each other, and thereby Incorporate much the more suddenly; And accordingly we found, that if upon a strong Solution of good French Verdigrease (for 'tis that we are wont to imploy, as the best) you pour a just quantity of Oyl of Tartar, and shake them well together, you shall immediately see a notable Change of Colour, and the Mixture will grow thick, and not transparent, but if you stay a while, till the Grosser part be Precipitated to, and setled in the Bottom, you may obtain a clear Liquor of a very lovely Colour, and exceeding delightfull to the Eye. But, you must have a care to drop in a competent Quantity of Oyl of Tartar, for else the Colour will not be so Deep, and Rich; and if instead of this Oyl you imploy a clear _Lixivium_ of Pot-ashes, you may have an Azure somewhat Lighter or Paler than, and therefore differing from, the former. And if instead of either of these Liquors, you make use of Spirit of Urine, or of Harts-horn, you may according to the Quantity and Quality of the Spirit you pour in, obtain some further Variety (though scarce considerable) of Cæruleous Liquors. And yet lately by the help of this Urinous Spirit we made a Blew Liquor, which not a few Ingenious Persons, and among them, some, whose Profession makes them very Conversant with Colours, have looked upon with some wonder. But these Azure Colour'd Liquors should be freed from the Subsiding matter, which the Salts of Tartar or Urine precipitate out of them, rather by being Decanted, than by Filtration. For by the latter of these ways we have sometimes found, the Colour of them very much Impair'd, and little Superiour to that of the grosser Substance, that it left in the Filtre.

_EXPERIMENT XXIII._