Chapter VIII: Part 8

That Roses held over the Fume of Sulphur, may quickly by it be depriv'd of their Colour, and have as much of their Leaves, as the Fume works upon, burn'd pale, is an Experiment, that divers others have tried, as well as I. But (_Pyrophilus_) it may seem somewhat strange to one that has never consider'd the Compounded nature of Brimstone, That, whereas the Fume of Sulphur will, as we have said, Whiten the Leaves of Roses; That Liquor, which is commonly call'd Oyl of Sulphur _per Campanam_, because it is suppos'd to be made by the Condensation of these Fumes in Glasses shap't like Bells, into a Liquor, does powerfully heighten the Tincture of Red Roses, and make it more Red and Vivid, as we have easily tried by putting some Red-Rose Leaves, that had been long dried, (and so had lost much of their Colour) into a Vial of fair Water. For a while after the Affusion of a convenient Quantity of the Liquor we are speaking of, both the Leaves themselves, and the Water they were Steep'd in, discover'd a very fresh and lovely Colour.

_EXPERIMENT XXIV._

It may (_Pyrophilus_) somewhat serve to Illustrate, not only the Doctrine of _Pigments_, and of _Colours_, but divers other Parts of the _Corpuscular Philosophy_; as that explicates Odours, and many other things, not as the Schools by Aery Qualities, but by Real, though extremely Minute Bodies; to examine, how much of a Colourless Liquor, a very small Parcel of a Pigment may Imbue with a _discernable_ Colour. And though there be scarce any thing of Preciseness to be expected from such Trials, yet I presum'd, that (at least) I should be able to show a much further Subdivision of the Parts of Matter into _Visible_ Particles, than I have hitherto found taken notice of, and than most men would imagine; no Body, that I know of, having yet attempted to reduce this Matter to any Measure.

The Bodies, the most promising for such a purpose, might seem to be the Metalls, especially Gold, because of the Multitude, and Minuteness of its Parts, which might be argu'd from the incomparable Closeness of its Texture: But though we tried a Solution of Gold made in _Aqua Regia_ first, and then in fair Water; yet in regard we were to determine the Pigment we imploy'd, not by _Bulk_ but _Weight_, and because also, that the Yellow Colour of Gold is but a faint one in Comparison of the deep Colour of _Cochineel_, we rather chose this to make our Trials with. But among divers of these it will suffice to set down one, which was carefully made in Vessels conveniently Shap'd; (and that in the presence of a Witness, and an Assistant) the Sum whereof I find among my _Adversaria_, Registred in the following Words. To which I shall only premise, (to lessen the wonder of so strange a diffusion of the Pigment) That _Cochineel_ will be better Dissolv'd, and have its Colour far more heightn'd by Spirit of Urine, than (I say not by common Water, but) by Rectify'd Spirit of Wine it self.

The Note I spoke off is this. [One Grain of _Cochineel_ dissolv'd in a pretty Quantity of Spirit of Urine, and then dissolv'd further by degrees in fair Water, imparted a discernable, though but a very faint Colour, to about six Glass-fulls of Water, each of them containing about forty three Ounces and an half, which amounts to above a hundred twenty five thousand times its own Weight.]

_EXPERIMENT XXV._

It may afford a considerable Hint (_Pyrophilus_) to him, that would improve the Art of Dying, to know what change of Colours may be produc'd by the three several sorts of Salts already often mention'd, (some or other of which may be procur'd in Quantity at reasonable Rates) in the Juices, Decoctions, Infusions, and (in a word) the more soluble parts of Vegetables. And, though the design of this Discourse be the Improvement of Knowledge, not of Trades: yet thus much I shall not scruple to intimate here, That the Blew Liquors, mention'd in the twentieth and one and twentieth Experiments, are far from being the only Vegetable Substances, upon which Acid, Urinous, and Alcalizate Salts have the like Operations to those recited in those two Experiments. For Ripe _Privet Berries_ (for instance) being crush'd upon White Paper, though they stain it with a Purplish Colour, yet if we let fall on some part of it two or three drops of Spirit of Salt, and on the other part a little more of the Strong Solution of Pot-ashes, the former Liquor immediately turn'd that part of the Thick juice or Pulp, on which it fell, into a lovely Red, and the latter turn'd the other part of it into a delightfull Green. Though I will not undertake, that those Colours in that Substance shall not be much more Orient, than Lasting; and though (_Pyrophilus_) this Experiment may seem to be almost the same with those already deliver'd concerning Syrrup of Violets, and the Juice of Blew-bottles, yet I think it not amiss to take this Occasion to inform you, that this Experiment reaches much farther, than perhaps you yet imagine, and may be of good Use to those, whom it concerns to know, how Dying Stuffs may be wrought upon by Saline Liquors. For, I have found this Experiment to succeed in so many Various Berries, Flowers, Blossoms, and other finer Parts of Vegetables, that neither my Memory, nor my Leisure serves me to enumerate them. And it is somewhat surprizing to see, by how Differingly-colour'd Flowers, or Blossoms, (for example) the Paper being stain'd, will by an Acid Spirit be immediately turn'd Red, and by any _Alcaly_ or any Urinous Spirit turn'd Green; insomuch that ev'n the crush'd Blossoms of _Meserion_, (which I gather'd in Winter and frosty Weather) and those of Pease, crush'd upon White Paper, how remote soever their Colours be from Green, would in a moment pass into a deep Degree of that Colour, upon the Touch of an Alcalizate Liquor. To which let us add, That either of those new Pigments (if I may so call them) may by the Affusion of enough of a contrary Liquor, be presently chang'd from Red into Green, and from Green into Red, which Observation will hold also in Syrrup of Violets, Juices of Blew-bottles, &c.

_Annotation._

After what I have formerly deliver'd to evince, That there are many Instances, wherein new Colours are produc'd or acquir'd by Bodies, which _Chymists_ are wont to think destitute of Salt, or to whose change of Colours no new Accession of Saline Particles does appear to contribute, I think we may safely enough acknowledge, that we have taken notice of so many Changes made by the Intervention of Salts in the Colours of Mix'd Bodies, that it has lessen'd our Wonder, That though _many Chymists_ are wont to ascribe the Colours of Such Bodies to their Sulphureous, and _the rest_ to their Mercurial Principle; yet _Paracelsus_ himself directs us in the Indagation of Colours, to have an Eye principally upon Salts, as we find in that passage of his, wherein he takes upon him to Oblige his Readers much by Instructing them, of what things they are to expect the Knowledge from each of the three distinct Principles of Bodies. _Alias_ (says he) _Colorum similis ratio est: De quibus brevem institutionem hanc attendite, quod scilicet colores omnes ex Sale prodeant. Sal enim dat colorem, dat Balsamum._[19] And a little beneath. _Iam natura Ipsa colores protrathit ex sale, cuique speciei dans illum, qui ipsi competit_, &c. After which he concludes; _Itaque qui rerum omnium corpora cognoscere vult, huic opus est, ut ante omnia cognoscat Sulphur, Ab hoc, qui desiderat novisse Colores is scientiam istorum petat à Sale, Qui scire vult Virtutes, is scrutetur arcana Mercurii. Sic nimirum fundamentum hauserit Mysteriorum, in quolibet crescenti indagandorum, prout natura cuilibet speciei ea ingessit_. But though _Paracelsus_ ascribes to each of his belov'd Hypostatical Principles, much more than I fear will be found to belong to it; yet if we please to consider Colours, not as _Philosophers_, but as _Dyers_, the concurrence of Salts to the striking and change of Colours, and their Efficacy, will, I suppose, appear so considerable, that we shall not need to quarrel much with _Paracelsus_, for ascribing in this place (for I dare not affirm that he uses to be still of one Mind) the Colours of Bodies to their Salts, if by Salts he here understood, not only Elementary Salts, but such also as are commonly taken for Salts, as Allom, Crystals of Tartar, Vitriol, &c. because the Saline principle does chiefly abound in them, though indeed they be, as we elsewhere declare, mix'd Bodies, and have most of them, besides what is Saline, both Sulphureous, Aqueous, and Gross or Earthy parts.

[19] Paracelsus de Mineral. tract. 1. pag. m. 243

But though (_Pyrophilus_) I have observ'd a Red and Green to be produc'd, the former, by Acid Salts, the later by Salts not Acid, in the express Juices of so many differing Vegetable Substances, that the Observation, if persued, may prove (as I said) of good Use: yet to show you how much e'vn these Effects depend upon the particular Texture of Bodies, I must subjoyn some cases wherein I (who am somewhat backwards to admit Observations for Universal) had the Curiosity to discover, that the Experiments would not Uniformly succeed, and of these Exceptions, the chief that I now remember, are reducible to the following three.

_EXPERIMENT XXVI._

And, (first) I thought fit to try the Operation of Acid Salts upon Vegetable Substances, that are already and by their own Nature Red. And accordingly I made Trial upon Syrrup of Clove-july-flowers, the clear express'd Juice of the succulent Berries of _Spina Cervina_, or Buckthorn (which I had long kept by me for the sake of its deep Colour) upon Red Roses, Infusion of Brazil, and divers other Vegetable Substances, on some of which crush'd (as is often mention'd) upon White Paper, (which is also to be understood in most of these Experiments, if no Circumstance of them argue otherwise) Spirit of Salt either made no considerable Change, or alter'd the Colour but from a Darker to a Lighter Red. How it will succeed in many other Vegetable Juices, and Infusions of the same Colour, I have at present so few at hand, that I must leave you to find it out your self. But as for the Operation of the other sorts of Salts upon these Red Substances, I found it not very Uniform, some Red, or Reddish Infusions, as of Roses, being turn'd thereby into a dirty Colour, but yet inclining to Green. Nor was the Syrrup of Clove-july-flowers turn'd by the solution of Pot-ashes to a much better, though somewhat a Greener, Colour. Another sort of Red Infusions was by an _Alcaly_ not turn'd into a Green, but advanc'd into a Crimson, as I shall have occasion to note ere long. But there were other sorts, as particularly the lovely Colour'd juice of Buckthorn Berries, that readily pass'd into a lovely Green.

_EXPERIMENT XXVII._

Among other Vegetables, which we thought likely to afford Exceptions to the General Observation about the differing Changes of Colours produc'd by Acid and Sulphureous Salts, we thought fit to make Trial upon the Flowers of _Jasmin_, they being both White as to Colour, and esteem'd to be of a more Oyly nature than other Flowers. Whereupon having taken the White parts only of the Flowers, and rubb'd them somewhat hard with my Finger upon a piece of clean Paper, it appear'd very little Discolour'd. Nor had Spirit of Salt, wherewith I moisten'd one part of it, any considerable Operation upon it. But Spirit of Urine, and somewhat more effectually a strong Alcalizate Solution, did immediately turn the almost Colourless Paper moisten'd by the Juice of the _Jasmin_, not as those Liquors are wont to do, when put upon the Juices of other Flowers, of a good Green, but of a Deep, though somewhat Greenish Yellow, which Experiment I did afterwards at several times repeat with the like success. But it seems not that a great degree of Unctuousness is necessary to the Production of the like Effects, for when we try'd the Experiment with the Leaves of those purely White Flowers that appear about the end of Winter, and are commonly call'd _Snow drops_, the event, was not much unlike that, which, we have been newly mentioning.

_EXPERIMENT XXVIII._

Another sort of Instances to show, how much changes of Colour effected by Salts, depend upon the particular Texture of the Colour'd Bodies, has been afforded me by several _Yellow_ Flowers, and other Vegetables, as Mary-gold Leaves, early Prim-roses, fresh Madder, &c. For being rubb'd upon White Paper, till they imbued it with their Colour, I found not, that by the addition of Alcalizate Liquors, nor yet by that of an Urinous Spirit, they would be turn'd either Green or Red: nor did so Acid a Spirit, as that of Salt, considerably alter their Colour, save that it seem'd a little to Dilute it. Only in some early Prim-roses it destroy'd the greatest part of the Colour, and made the Paper almost White agen. And Madder also afforded some thing peculiar, and very differing from what we have newly mention'd: For having gather'd Some Roots of it, and, (whilst they were recent) express'd upon White Paper the Yellow Juice, an Alcalizate Solution drop'd upon it did not turn it either Green or White, but Red. And the bruis'd Madder it self being drench'd with the like Alcalizate Solution, exchang'd also its Yellowishness for a Redness.

_An admonition touching the four preceding Experiments._

Having thus (_Pyrophilus_) given you divers Instances, to countenance the General observation deliver'd in the twenty fifth Experiment, and divers Exceptions whereby it ought to be Limited; I must leave the further Inquiry into these Matters to your own Industry. For not remembring at present many of those other Trials, long since made to satisfie my self about Particulars, and not having now the Opportunity to repeat them, I must content my Self to have given you the Hint, and the ways of prosecuting the search your Self; and only declare to you in general, that, As I have made many Trials, unmention'd in this Treatise, whose Events were agreeable to those mention'd in the twenty fifth Experiment, so (to name now no other Instances) what I have try'd with Acid and Sulphureous Salts upon the Pulp of Juniper Berries, rubb'd upon White Paper, inclines me to think, That among that vast Multitude, and strange Variety of Plants that adorn the face of the Earth, perhaps many other Vegetables may be found, on which such _Menstruums_ may not have such Operations, as upon the Juice of Violets, Pease-blossoms, &c. no nor upon any of those three other sorts of Vegetables, that I have taken notice of in the three fore-going Experiments. It sufficiently appearing ev'n by these, that the effects of a Salt upon the Juices of particular Vegetables do very much depend upon their particular Textures.

_EXPERIMENT XXIX._

It may be of some Use towards the discovery of the nature of these Changes, which the Alimental Juice receives in some Vegetables, according to the differing degrees of their Maturity, and according to the differing kinds of Plants of the same Denomination, to observe what Operation Acid, Urinous, and Alcalizate Salts will have upon the Juices of the several sorts of the Vegetable substances I have been mentioning.

To declare my meaning by an Example, I took from the same Cluster, one Blackberry full Ripe, and another that had not yet gone beyond a Redness, and rubbing apiece of white Paper, with the former, I observ'd, that the Juice adhering to it was of adark Reddish Colour, full of little Black Specks; and that this Juice by a drop of a strong _Lixivium_, was immediately turn'd into a Greenish Colour deep enough, by as much Urinous Spirit into a Colour much of Kin to the former, though somewhat differing, and fainter; and by a drop of Spirit of Salt into a fine and lightsome Red: where as the Red Berry being in like manner rubb'd upon Paper, left on it a Red Colour, which was very little alter'd by the Acid Spirit newly nam'd, and by the Urinous and Lixiviate Salts receiv'd changes of Colour differing from those that had been just before produc'd in the dark Juice of the Ripe Blackberry.

I remember also, that though the Infusion of Damask-Roses would as well, though not so much, as that of Red, be heightned by Acid Spirits to an intense degree of Redness, and by Lixiviate Salts be brought to a Darkish Green; yet having for Trials sake taken a Rose, whose Leaves, which were large and numerous, like those of a Province Rose, were perfectly Yellow, though in a Solution of Salt of Tartar, they afforded a Green Blewish Tincture, yet I did not by an Acid Liquor obtain a Red one; all that the Saline Spirit I imploy'd, perform'd, being (if I much misremember not) to Dilute Somewhat the Yellowness of the Leaves. I would also have tried the Tincture of Yellow Violets, but could procure none. And if I were in those Islands of _Banda_, which are made Famous as well as Rich, by being the almost only places, where Cloves will prosper, I should think it worth my Curiosity to try, what Operation the three differing Kinds of Salts, I have so often mention'd, would have upon the Juice of this Spice, (express'd at the several Seasons of it) as it grows upon the Tree. Since good Authors inform us, (of what is remarkable) that these whether Fruits, or Rudiments of Fruits, are at first _White_, afterward _Green_, and then _Reddish_, before they be beaten off the Tree, after which being Dry'd before they are put up, they grow _Blackish_ as we see them. And one of the recentest _Herbarists_ informs us, that the Flower grows upon the top of the Clove it self, consisting of four small Leaves, like a Cherry Blossom, but of an excellent _Blew_. But (_Pyrophilus_) to return to our own Observations, I shall add, that I the rather choose, to mention to you an Example drawn from Roses, because that though I am apt to think, as I elsewhere advertise, that something may be guess'd at about some of the Qualities of the Juices of Vegetables, by the Resemblance or Disparity that we meet with in the Changes made of their Colours, by the Operation of the same kinds of Salts; yet that those Conjectures should be very warily made, may appear among other things, by the Instance I have chosen to give in Roses. For though, (as I formerly told you) the Dry'd Leaves, both of the Damask, and of Red ones, give a Red Tincture to Water sharpen'd with Acid Salts, yet the one sort of Leaves is known to have a Purgative faculty,[20] and the other are often, and divers ways, imploy'd for Binding.

[20] See _Parkinson_ Th. Boran. Trib. 9. cap. 26.

And I also choose (_Pyrophilus_) to subjoyn this twenty ninth Experiment to those that precede it, about the change of the Colours of Vegetables by Salts, for these two reasons: The first, that you may not easily entertain Suspitions, if in the Trials of an Experiment of some of the Kinds formerly mention'd, you should meet with an Event somewhat differing from what my Relations may have made you expect. And the second, That you may hereby be invited to discern, that it may not be amiss to take notice of the particular Seasons wherein you gather the Vegetables which in Nicer Experiments you make use of. For, it I were not hindred both by haste and some justifiable Considerations, I could perhaps add considerable Instances, to those lately deliver'd, for the making out of this Observation; but for certain reasons I shall at present substitute a remarkable passage to be met with in that Laborious Herbarist Mr. _Parkinson_, where treating of the Virtues of the (already divers times mention'd) Buckthorn Berries, he subjoyns the following account of several Pigments that are made of them, not only according to the several ways of Handling them, but according to the differing Seasons of Maturity, at which they are Gather'd; _Of these Berries_, (says he) _are made three several sorts of Colours as they shall be gather'd, that is, being gather'd while they are Green, and kept Dry, are call'd Sapberries, which being steep'd into some Allom-water, or fresh bruis'd into Allom-water, they give a reasonable fair Yellow Colour which Painters use for their Work, and Book-binders to Colour the edges of Books, and Leather-dressers to Colour Leather, as they use also to make a Green Colour, call'd Sap-green, taken from the Berries when they are Black, being bruis'd and put into a Brass or Copper Kettle or Pan, and there suffer'd to abide three or four_ _Days, or a little heated upon the Fire, and some beaten Allom put unto them, and afterwards press'd forth, the Juice or Liquor is usually put in great Bladders tied with strong thred at the Head and hung up untill it be Dry, which is dissolv'd in Water or Wine, but Sack_ (he affirms) _is the best to preserve the Colour from Starving, (as they call it) that is, from Decaying, and make it hold fresh the longer. The third Colour (where of none_ (says he) _that I can find have made mention but only_ Tragus_) is a Purplish Colour, which is made of the Berries suffer'd to grow upon the Bushes untill the middle or end of_ November, _that they are ready to drop from the Trees._

And, I remember (_Pyrophilus_) that I try'd, with a success that pleas'd me well enough, to make such a kind of Pigment, as Painters call Sap-green, by a way not unlike that, deliver'd here by our Author, but I cannot now find any thing relating to that matter among my loose Papers. And my Trials were made so many years ago, that I dare not trust my Memory for Circumstances, but will rather tell you, that in a noted Colour-shop, I brought them by Questions to confess to me, that they made their Sap-green much after the ways by our _Botanist_ here mention'd. And on this occasion I shall add an Observation, which though it does not strictly belong to this place, may well enough be mention'd here, namely, that I find by an account given us by the Learned _Clusius_, of _Alaternus_, that ev'n the Grosser Parts of the same Plant, are some of them one Colour, and some another; For speaking of that Plant, he tells us, that the _Portugalls_ use the Bark to Dye their Nets into a Red Colour, and with the Chips of the Wood, which are Whitish, they Dye a Blackish Blew.

_EXPERIMENT XXX._

Among the Experiments that tend to shew that the change of Colours in Bodies may proceed from the Vary'd Texture of their Parts, and the consequent change of their Disposition to Reflect or Refract the Light, that sort of Experiments must not be left unmention'd, which is afforded us by Chymical Digestions. For, if _Chymists_ will believe several famous Writers about what they call the Philosophers Stone, they must acknowledge that the same Matter, seald up Hermetically in a Philosophical Egg, will by the continuance of Digestion, or if they will have it so (for it is not Material in our case which of the two it be) of Decoction, run through a great Variety of differing Colours, before it come to that of the Noblest _Elixir_; whether that be Scarlet, or Purple, or what ever other Kind of Red. But without building any thing on so Obtruse and Questionable an Operation, (which yet may be pertinently represented to those that believe the thing) we may observe, that divers Bodies digested in carefully-clos'd Vessels, will in tract of time, change their Colour: As I have elsewhere mention'd my having observ'd ev'n in Rectify'd Spirit of Harts-horn, and as is evident in the Precipitations of Amalgams of Gold, and Mercury, without Addition, where by the continuance of a due Heat the Silver-Colour'd Amalgam is reduc'd into a shining Red Powder. Further Instances of this Kind you may find here and there in divers places of my other Essays. And indeed it has been a thing, that has much contributed to deceive many _Chymists_, that there are more Bodies than one, which by Digestion will be brought to exhibit that Variety and Succession of Colours, which they imagine to be Peculiar to what they call the _True matter of the Philosophers_. But concerning this, I shall referr you to what you may elsewhere find in the Discourse written touching the passive Deceptions of _Chymists_, and more about the Production of Colours by Digestion you will meet with presently. Wherefore I shall now make only this Observation from what has been deliver'd, That in these Operations there appears not any cause to attribute the new Colours emergent to the Action of a new Substantial form, nor to any Increase or Decrement of either the Salt, Sulphur, or Mercury of the Matter that acquires new Colours: For the Vessels are clos'd, and these Principles according to the _Chymists_ are Ingenerable and Incorruptible; so that the Effect seems to proceed from hence, that the Heat agitating and shuffling the Corpuscles of the Body expos'd to it, does in process of time so change its Texture, as that the Transposed parts do Modifie the incident Light otherwise, than they did when the Matter appear'd of another Colour.

_EXPERIMENT XXXI._

Among the several changes of Colour, which Bodies acquire or disclose by Digestion, it it very remarkable, that _Chymists_ find a Redness rather than any other Colour in most of the Tinctures they Draw, and ev'n in the more Gross Solutions they make of almost all Concretes, that abound either with Mineral or Vegetable Sulphur, though the _Menstruum_ imploy'd about these Solutions or Tinctures be never so Limpid or Colourless.

This we have observ'd in I know not how many Tinctures drawn with Spirit of Wine from _Jalap_, _Guaicum_, and several other Vegetables; and not only in the Solutions of _Amber_, _Benzoin_, and divers other Concretes made with the same _Menstruum_, but also in divers Mineral Tinctures. And, not to urge that familiar Instance of the Ruby of Sulphur, as _Chymists_ upon the score of its Colour, call the Solution of Flowers of Brimstone, made with the Spirit of Turpentine, nor to take notice of other more known Examples of the aptness of Chymical Oyls, to produce a Red Colour with the Sulphur they extract, or dissolve; not to insist (I say) upon Instances of this nature, I shall further represent to you, as a thing remarkable, that, both Acid and Alcalizate Salts, though in most other cases of such contrary Operations, in reference to Colours, will with many Bodies that abound with Sulphureous, or with Oyly parts, produce a Red; as is manifest partly in the more Vulgar Instances of the Tinctures, or Solutions of Sulphur made with _Lixiviums_, either of Calcin'd Tartar or Pot-ashes, and other Obvious examples, partly by this, that the true Glass of Antimony extracted with some Acid Spirits, with or without Wine, will yield a Red Tincture, and that I know an Acid Liquor, which in a moment will turn Oyl of Turpentine into a deep Red. But among the many Instances I could give you of the easie Production of Redness by the Operation of Saline Spirit, as well as of Spirit of Wine; I remember two or three of those I have tried, which seem remarkable enough to deserve to be mention'd to you apart.

_EXPERIMENT XXXII._

But before we set them down, it will not perhaps appear impertinent to premise;

That there seems to be a manifest Disparity betwixt Red Liquors, so that some of them may be said to have a Genuine Redness in comparison of others, that have a Yellowish Redness: For if you take (for example) a good Tincture of _Chochineel_, dilute it never so much with fair Water, you will not (as far as I can judge by what I have tried) be able to make it a Yellow Liquor. Insomuch that a Single drop of a rich Solution of _Cochineel_ in Spirit of Urine, being Diluted with above an Ounce of fair Water, exhibited no Yellowishness at all, but a fair (though somewhat faint) Pinck or Carnation; and even when _Cochineel_ was by degrees Diluted much beyond the newly mention'd Colour, by the way formerly related to you in the twenty fourth Experiment, I remember not, that there appear'd in the whole Trial any Yellow. But if you take Balsom of Sulphur (for Instance) though it may appear in a Glass, where it has a good Thickness, to be of a deep Red, yet if you shake the Glass, or pour a few drops on a sheet of White Paper, spreading them on it with your Finger, the Balsom that falls back along the sides of the Glass, and that which stains the Paper, will appear Yellow, not Red. And there are divers Tinctures, such as that of Amber made with Spirit of Wine, (to name now no more) that will appear either Yellow or Red, according as the Vessels that they fill, are Slender or Broad.

_EXPERIMENT XXXIII._

But to proceed to the Experiments I was about to deliver; _First_; Oyl or Spirit of Turpentine, though clear as fair Water, being Digested upon the purely White Sugar of Lead, has, in a short time, afforded us a high Red Tincture, that some Artists are pleas'd to call the Balsom of _Saturn_, which they very much (and probably not altogether without cause) extoll as an excellent Medicine in divers Outward affections.

_EXPERIMENT XXXIV._

_Next_, take of common Brimstone finely powdred five Ounces, of Sal-Armoniack likewise pulveriz'd an equal weight, of beaten Quick-lime six Ounces, mix these Powders exquisitely, and Distill them through a Retort plac'd in Sand by degrees of Fire, giving at length as intense a Heat as you well can in Sand, there will come over (if you have wrought well) a Volatile Tincture of Sulphur, which may probably prove an excellent Medicine, and should have been mention'd among the other Preparations of Sulphur, which we have elsewhere imparted to you, but that it is very pertinent to our present Subject, The change of Colours. For though none of the Ingredients be Red, the Distill'd Liquor will be so: and this Liquor if it be well Drawn, will upon a little Agitation of the Vial first unstop'd (especially if it be held in a Warmer hand) lend forth a copious Fume, not Red, like that of Nitre, but White; And sometimes this Liquor may be so Drawn, that I remember, not long since, I took pleasure to observe in a parcel of it, that Ingredients not Red, did not only yield by Distillation a Volatile Spirit that was Red, but though that Liquor did upon the bare opening of the Bottle it was kept in, drive us away with the plenty and sulphureous sent of a White steam which it sent forth, yet the Liquor it self being touch'd by our Fingers, did immediately Dye them Black.

_EXPERIMENT XXXV._

The third and _last_ Experiment I shall now mention to shew, how prone Bodies abounding in Sulphureous parts are to afford a Red Colour, is one, wherein by the Operation of a Saline Spirit upon a White or Whitish Body, which according to the _Chymists_ should be altogether Sulphureous, a Redness may be produc'd, not (as in the former Experiments) slowly, but in the twinkling of an Eye. We took then of the Essential Oyl of Anniseeds, which has this Peculiarity, that in Cold weather it loses its Fluidity and the greatest part of its Transparency, and looks like a White or Whitish Oyntment, and near at hand seems to consist of a Multitude of little soft Scales: Of this Coagulated Stuff we spread a little with a Knife upon a piece of White Paper, and letting fall on it, and mixing with it a drop or two of Oyl of Vitriol, immediately (as we fore-saw) there emerg'd together with some Heat and Smoak, a Blood-Red Colour, which therefore was in a trice produc'd by two Bodies, whereof the one had but a Whitish Colour, and the other (if carefully rectify'd) had no Colour at all.

_EXPERIMENT XXXVI._

But on this Occasion (_Pyrophilus_) we must add once for all, that in many of the above-recited Experiments, though the changes of Colour happen'd as we have mention'd them: yet the emergent or produc'd Colour is oft times very subject to Degenerate, both quickly and much. Notwithstanding which, since the Changes, we have set down, do happen presently upon the Operation of the Bodies upon each other, or at the times by us specify'd; _that_ is sufficient both to justifie our Veracity, and to shew what we Intend; it not being Essential to the Genuineness of a Colour to be Durable. For a fading Leaf, that is ready to Rot, and moulder into Dust, may have as true a Yellow, as a Wedge of Gold, which so obstinately resists both Time and Fire. And the reason, why I take occasion from the former Experiment to subjoyn this general Advertisement, is, that I have several times observ'd, that the Mixture resulting from the Oyls of Vitriol, and of Anniseeds, though it acquire a thicker consistence than either of the Ingredients had, has quickly lost its Colour, turning in a very short time into a dirty Gray, at least in the Superficial parts, where 'tis expos'd to the Air; which last Circumstance I therefore mention, because that, though it seem probable, that this Degeneration of Colours may oft times and in divers cases proceed from the further Action of the Saline Corpuscles, and the other Ingredients upon one another, yet in many cases much of the Quick change of Colours seems ascribeable to the Air, as may be made probable by several reasons: The first whereof may be fetcht from the newly recited Example of the two Oyls; The next may be, that we have sometimes observ'd long Window-Curtains of light Colours, to have that part of them, which was expos'd to the Air, when the Window was open, of one Colour, and the lower part, that was sheltred from the Air by the Wall, of another Colour: And the third Argument may be fetch'd from divers Observations, both of others, and our own; For of that Pigment so well known in Painters Shops, by the name of _Turnsol_, our Industrious _Parkinson_, in the particular account he gives of the Plant that bears it, tells us also, That _the Berries when they are at their full Maturity, have within them between the outer Skin and the inward Kirnel or Seed, a certain Juice or Moisture, which being rubb'd upon Paper or Cloath, at the first appears of a fresh and lovely Green Colour, but presently changeth into a kind of Blewish Purple, upon the Cloath or Paper, and the same Cloath afterwards wet in Water, and wrung forth, will Colour the Water into a Claret Wine Colour, and these_ (concludes he) _are those Raggs of Cloath, which are usually call'd_ Turnsol _in the Druggists or Grocers Shops_[21]. And to this Observation of our _Botanist_ we will add an Experiment of our own, (made before we met with That) which, though in many Circumstances, very differing, serves to prove the same thing; for having taken of the deeply Red Juice of _Buckthorn_ Berries, which I bought of the Man that uses to sell it to the Apothecaries, to make their Syrrup _de Spina Cervina_, I let some of it drop upon a piece of White Paper, and having left it there for many hours, till the Paper was grown dry again, I found what I was inclin'd to suspect, namely, That this Juice was degenerated from a deep Red to a dirty kind of Greyish Colour, which, in a great part of the stain'd Paper seem'd not to have so much as an Eye of Red: Though a little Spirit of Salt or dissolv'd _Alcaly_ would turn this unpleasant Colour (as formerly I told you it would change the not yet alter'd Juice) into a Red or Green. And to satisfie my self, that this Degeneration of Colour did not proceed from the Paper, I drop'd some of the deep Red or Crimson Juice upon a White glaz'd Tile, and suffering it to dry on there, I found that ev'n in that Body, on which it could not Soak, and by which it could not be Wrought, it nevertheless lost its Colour. And these Instances (_Pyrophilus_) I am the more carefull to mention to you, that you may not be much Surpris'd or Discourag'd, if you should sometimes miss of performing punctually what I affirm my self to have done in point of changing Colours; since in these Experiments the over-sight or neglect of such little Circumstances, as in many others would not be perhaps considerable, may occasion the mis-carrying of a Trial. And I was willing also to take this occasion of Advertising you in the repeating of the Experiments mention'd in this Treatise, to make use of the Juices of Vegetables, and other things prepar'd for your Trials, as soon as ever they are ready, lest one or other of them grow less fit, if not quite unfit by delay; and to estimate the Event of the Trials by the Change, that is produc'd presently upon the due and sufficient Application of Actives to Passives, (as they speak) because in many cases the effects of such Mixtures may not be lasting, and the newly produc'd Colour may in a little time degenerate. But, (_Pyrophilus_) I forgot to add to the two former Observations lately made about Vegetables, a third of the same Import, made in Mineral substances, by telling you, That the better to satisfie a Friend or two in this particular, I sometimes made, according to some Conjectures of mine, this Experiment; That having dissolv'd good Silver in _Aqua-fortis_, and Precipitated it with Spirit of Salt, upon the first Decanting of the Liquor, the remaining Matter would be purely White; but after it had lain a while uncover'd, that part of it, that was Contiguous to the Air, would not only lose its Whiteness, but appear of a very Dark and almost Blackish Colour, I say that part that was Contiguous to the Air, because if that were gently taken off, the Subjacent part of the same Mass would appear very White, till that also, having continu'd a while expos'd to the Air, would likewise Degenerate. Now whether the Air perform these things by the means of a Subtile Salt, which we elsewhere show it not to be destitute of, or by a peircing Moisture, that is apt easily to insinuate it self into the Pores of some Bodies, and thereby change their Texture, and so their Colour; Or by solliciting the Avolation of certain parts of the Bodies, to which 'tis Contiguous; or by some other way, (which possibly I may elsewhere propose and consider) I have not now the leisure to discourse. And for the same reason, though I could add many other Instances, of what I formerly noted touching the emergency of Redness upon the Digestion of many Bodies, insomuch that I have often seen upon the Borders of _France_ (and probably we may have the like in _England_) a sort of Pears, which digested for some time with a little Wine, in a Vessel exactly clos'd, will in not many hours appear throughout of a deep Red Colour, (as also that of the Juice, wherein they are Stew'd, becomes) but ev'n on pure and white Salt of Tartar, pure Spirit of Wine, as clear as Rock-water, will (as we elsewhere declare) by long Digestion acquire a Redness; Though I say such Instances might be Multiply'd, and though there be some other Obvious changes of Colours, which happen so frequently, that they cannot but be as well Considerable as Notorious; such as is the Blackness of almost all Bodies burn'd in the open Air: yet our haste invites us to resign you the Exercise of enquiring into the Causes of these Changes. And certainly, the reason both _why_ the Soots of such differing Bodies are almost all of them all Black, _why_ so much the greater part of Vegetables should be rather Green than of any other Colour, and particularly (which more directly concerns this place) _why_ gentle Heats do so frequently in Chymical Operations produce rather a Redness than another Colour in digested _Menstruums_, not only Sulphureous, as Spirit of Wine, but Saline, as Spirit of Vinegar, may be very well worth a serious Inquiry; which I shall therefore recommend to _Pyrophilus_ and his Ingenious Friends.

[21] _Parkinson_, Thea. Bot. Trib. 4 cap. 12.

_EXPERIMENT XXXVII._

It may seem somewhat strange, that if you take the Crimson Solution of _Cochineel_, or the Juice of Black Cherries, and of some other Vegetables that afford the like Colour, (which because many take but for a deep Red, we do with them sometimes call it so) and let some of it fall upon a piece of Paper, a drop or two of an Acid Spirit, such as Spirit of Salt, or _Aqua-fortis_, will immediately turn it into a fair Red. Whereas if you make an Infusion of Brazil in fair Water, and drop a little Spirit of Salt or _Aqua-fortis_ into it, that will destroy its Redness, and leave the Liquor of a Yellow, (sometimes Pale) I might perhaps plausibly enough say on this occasion, that if we consider the case a little more attentively, we may take notice, that the action of the Acid Spirit seems in both cases, but to weaken the Colour of the Liquor on which it falls. And so though it destroy Redness in the Tincture of Brazil, as well as produce Red in the Tincture of _Chochineel_, its Operations may be Uniform enough, since as Crimson seems to be little else than a very deep Red, with (perhaps) an Eye of Blew, so some kinds of Red seem (as I have lately noted) to be little else than heightned Yellow. And consequently in such Bodies, the Yellow seems to be but a diluted Red. And accordingly Alcalizate Solutions and Urinous Spirits, which seem dispos'd to Deepen the Colours of the Juices and Liquors of most Vegetables, will not only restore the Solution of _Cochineel_ and the Infusion of Brazil to the Crimson, whence the Spirit of Salt had chang'd them into a truer Red; but will also (as I lately told you) not only heighthen the Yellow Juice of Madder into Red, but advance the Red Infusion of Brazil to a Crimson. But I know not whether it will not be much safer to derive these Changes from vary'd Textures, than certain kinds of Bodies; and you will perhaps think it worth while, that I should add on this occasion, That it may deserve some Speculation, why, notwithstanding what we have been observing, though Blew and Purple seem to be deeper Colours than Red, and therefore the Juices of Plants of either of the two former Colours may (congruously enough to what has been just now noted) be turn'd Red by Spirit of Salt or _Aqua-fortis_, yet Blew Syrrup of Violets and some Purples should both by Oyl of Tartar and Spirit of Urine be chang'd into Green, which seems to be not a deeper but a more diluted Colour than Blew, if not also than Purple.

_EXPERIMENT XXXVIII._

It would much contribute to the History of Colours, if _Chymists_ would in their Laboratories take a heedfull notice, and give us a faithfull account of the Colours observ'd in the Steams of Bodies either Sublim'd or Distill'd, and of the Colours of those Productions of the Fire, that are made up by the Coalition of those Steams. As (for Instance) we observe in the Distilling of pure Salt peter, that at a certain season of the Operation, the Body, though it seem either Crystalline, or White, affords very Red Fumes: whereas though Vitriol be Green or Blew, the Spirit of it is observ'd to come over in Whitish Fumes. The like Colour I have taken notice of in the Fumes of several other Concretes of differing Colours, and Natures, especially when Distill'd with strong Fires. And we elsewhere note, that ev'n Soot, as Black as it is, has fill'd our Receivers with such copious White Fumes, that they seem'd to have had their In-sides wash'd with Milk. And no less observable may be, the Distill'd Liqours, into which such Fumes convene, (for though we will not deny, that by skill and care a Reddish Liqour may be obtain'd from Nitre) yet the common Spirit of it, in the making ev'n of which store of these Red Fumes are wont to pass over into the Receiver, appears not to be at all Red. And besides, that neither the Spirit of Vitriol, nor that of Soot is any thing White; And, besides also, that as far as I have observ'd, most (for I say not all) of the Empyreumatical Oyls of Woods, and other Concretes, are either of a deep Red, or of a Colour between Red and Black; besides this, I say, 'tis very remarkable that notwithstanding that great Variety of Colours to be met with in the Herbs, Flowers, and other Bodies wont to be Distill'd in _Balneo_: yet (as far at least as our common Distillers Experience reacheth) all the Waters and Spirits that first come over by that way of Distillation, leave the Colours of their Concretes behind them, though indeed there be one or two Vegetables not commonly taken notice of, whose Distill'd Liqours I elsewhere observe to carry over the Tincture of the Concrete with them. And as in Distillations, so in Sublimations, it were worth while to take notice of what comes up, in reference to our present scope, by purposely performing them (as I have in some cafes done) in conveniently shap'd Glasses, that the Colour of the ascending Fumes may be discern'd; For it may afford a Naturalist good Information to observe the Congruities or the Differences betwixt the Colours of the ascending Fumes, and those of the _Flowers_, they compose by their Convention. For it is evident, that these _Flowers_, do many of them in point of Colour, much differ, not only from one another, but oft times from the Concretes that afforded them. Thus, (not here to repeat what I formerly noted of the Black Soots of very differingly Colour'd Bodies) though Camphire and Brimstone afford _Flowers_ much of their own Colour, save that those of Brimstone are wont to be a little Paler, than the Lumps that yielded them; yet ev'n of Red _Benzoin_, that sublim'd Substance, which _Chymists_ call its _Flowers_, is wont to be White or Whitish. And to omit other Instances, ev'n one and the same Black Mineral, Antimony, may be made to afford _Flowers_, some of them Red, and some Grey, and, which is more strange, some of them purely White. And 'tis the Prescription of some Glass-men by exquisitely mingling a convenient proportion of Brimstone, Sal-Armoniack, and Quicksilver, and Subliming them, together, to make a Sublimate of an excellent Blew; and though having caus'd the Experiment to be made, we found the produc'd Sublimate to be far from being of a lovely Colour, (as was promis'd) that there and there, it seem'd Blewish, and at least was of a Colour differing enough from either of the Ingredients, which is sufficient for our present purpose. But a much finer Colour is promis'd by some of the Empiricks, that pretend to Secrets, who tell us, that Orpiment, being Sublim'd, will afford among the Parts of it that fly Upward, some little Masses, which, though the Mineral it self be of a good Yellow, will be Red enough to emulate Rubies, both in Colour and Translucency. And this Experiment may, for ought I know, sometimes succeed; for I remember, that having in a small Bolt-head purposely sublim'd some powder'd Orpiment, we could in the Lower part of the Sublimate discern here and there some Reddish Lines, though much of the Upper part of the Sublimate consisted of a matter, which was not alone purely Yellow, but transparent almost like a Powder. And we have also this way obtain'd a Sublimate, the Lower part whereof though it consisted not of Rubies, yet the small pieces of it, which were Numerous enough, were of a pleasant Reddish Colour, and Glitter'd very prettily. But to insist on such kind of Trials and Observations (where the ascending Fumes of Bodies differ in Colour from the Bodies themselves) though it might indeed Inrich the History of Colours, would Robb me of too much of the little time I have to dispatch what I have further to tell you concerning them.

_EXPERIMENT XXXIX_

Take the dry'd Buds (or Blossoms) of the Pomegranate Tree, (which are commonly call'd in the Shops _Balaustiums_) pull off the Reddish Leaves, and by a gentle Ebullition of them in fair Water, or by a competent Infusion of them in like Water well heated, extract a faint Reddish Tincture, which if the Liquor be turbid, you may Clarifie it by Filtrating it Into this, if you pour a little good Spirit of Urine, or some other Spirit abounding in the like sort of Volatile Salts, the Mixture will presently turn of a dark Greenish Colour, but if instead of the fore-mention'd Liquor, you drop into the simple Infusion a little rectify'd Spirit of Sea-Salt, the Pale and almost Colourless Liquor will immediately not only grow more Transparent, but acquire a high Redness, like that of Rich Claret Wine, which so suddenly acquir'd Colour, may as quickly be Destroy'd and turn'd into a dirty Blewish Green, by the affusion of a competent quantity of the above-mention'd Spirit of Urine.

_Annotation._