Chapter I (3)

(324.) Nothing can be more desirable than that every possible facility and encouragement should be afforded for such researches, and indeed to the pursuits of the enlightened resident or traveller in every department of science, by the representatives of our national authority wherever our power extends. By these only can our knowledge of the actual state of the surface of the globe, and that of the animals and vegetables of the ancient continents and seas, be extended and perfected, while more complete information than we at present possess of the habits of those actually existing, and the influence of changes of climate, food, and circumstances, on them, may be expected to render material assistance to our speculations respecting those which have become extinct.

CHAP. IV.

OF THE EXAMINATION OF THE MATERIAL CONSTITUENTS OF THE WORLD.

_Mineralogy._

(325.) The consideration of the history and structure of our globe, and the examination of the fossil contents of its strata, lead us naturally to consider the materials of which it consists. The history of these materials, their properties as objects of philosophical enquiry, and their application to the useful arts and the embellishments of life, with the characters by which they can be certainly distinguished one from another, form the object of mineralogy, taken in its most extended sense.

(326.) There is no branch of science which presents so many points of contact with other departments of physical research, and serves as a connecting link between so many distant points of philosophical speculation, as this. To the geologist, the chemist, the optician, the crystallographer, the physician, it offers especially the very elements of their knowledge, and a field for many of their most curious and important enquiries. Nor, with the exception of chemistry, is there any which has undergone more revolutions, or been exhibited in a greater variety of forms. To the ancients it could scarcely be said to be at all known, and up to a comparatively recent period, nothing could be more imperfect than its descriptions, or more inartificial and unnatural than its classification. The more important minerals in the arts, indeed, those used for economical purposes and those from which metals were extracted, had a certain degree of attention paid to them, for the sake of their utility and commercial value, and the precious stones for that of ornament. But until their crystalline forms were attentively observed and shown to be determinate characters on which dependence could be placed, no mineralogist could give any correct account of the real distinction between one mineral and another.

(327.) It was only, however, when chemical analysis had acquired a certain degree of precision and universal applicability that the importance of mineralogy as a science began to be recognized, and the connection between the external characters of a stone and its ingredient constituents brought into distinct notice. Among these characters, however, none were found to possess that eminent distinctness which the crystalline form offers; a character, in the highest degree geometrical, and affording, as might be naturally supposed, the strongest evidence of its necessary connection with the intimate constitution of the substance. The full importance of this character was, however, not felt until its connection with the texture or cleavage of a mineral was pointed out, and even then it required numerous and striking instances of the critical discernment of Haüy and other eminent mineralogists in predicting from the measurements of the angles of crystals which had been confounded together that differences would be found to exist in their chemical composition, all which proved fully justified in their result before the essential value of this character was acknowledged. This was no doubt in great measure owing to the high importance set by the German mineralogists on those external characters of touch, sight, weight, colour, and other sensible qualities, which are little susceptible, with the exception of weight, of exact determination, and which are subject to material variations in different specimens of the same mineral. By degrees, however, the necessity of ascribing great weight to a character so definite was admitted, especially when it was considered that the same step which pointed out the intimate connection of external form with internal structure furnished the mineralogist with the means of reducing all the forms of which a mineral is susceptible under one general type, or primitive form, and afforded grounds for an elegant theoretical account of the assumption of definite figures _ab initio_.

(328.) A simple and elegant invention of Dr. Wollaston, the reflecting goniometer, gave a fresh impulse to that view of mineralogy which makes the crystalline form the essential or leading character, by putting it in the power of every one, by the examination of even the smallest portion of a broken crystal, to ascertain and verify that essential character on which the identity of a mineral in the system of Haüy was made to depend. The application of so ready and exact a method speedily led to important results, and to a still nicer discrimination of mineral species than could before be attained; and the confirmation given to these results by chemical analysis stamped them with a scientific and decided character which they have retained ever since.

(329.) Meanwhile the progress made in chemical analysis had led to the important conclusion that every chemical compound susceptible of assuming the solid state assumed with it a determinate crystalline form; and the progress of optical science had shown that the fundamental crystalline form, in the case at least of transparent bodies, drew with it a series of optical properties no less curious than important in relation to the affections of light in its passage through such substances. Thus, in every point of view, additional importance became added to this character; and the study of the crystalline forms of bodies in general assumed the form of a separate and independent branch of science, of which the geometrical forms of the mineral world constituted only a particular case. Mineralogy, however, as a branch of natural history, remains still distinct either from optics or crystallography. The mineralogist is content, and thinks he has performed his task, if not as a natural historian at least as a classifier and arranger, if he only gives such a characteristic description of a mineral as shall effectually distinguish it from every other, and shall enable any one who may encounter such a body in any part of the world to impose on it its name, assign it a place in his system, and turn to his books for a further description of all that the chemist, the optician, the lapidary, or the artist, may require to know. Still this is no easy matter: the laborious researches of the most eminent mineralogists can hardly yet be said to have effectually accomplished it; and its difficulty may be appreciated by the small number of simple minerals, or minerals of perfectly definite and well-marked characters, which have been hitherto made out. Nor can this indeed be wondered at, when we consider that by far the greater portion of the rocks and stones which compose the external crust of the globe consists of nothing more than the accumulated _detritus_ of older rocks, in which the fragments and powder of an infinite variety of substances are mingled together, in all sorts of varying proportions, and in such a way as to defy separation. Many of these rocks, however, so compounded, occur with sufficient frequency and uniformity of character to have acquired names and to have been usefully applied; indeed, in the latter respect, minerals of this description far surpass all the others. As objects of natural history, therefore, they are well worthy of attention, however difficult it may be to assign them a place in any artificial arrangement.

(330.) This paucity of simple minerals, however, is probably rather apparent than real, and in proportion as the researches of the chemist and crystallographer shall be extended throughout nature, they will no doubt become much more numerous. Indeed, in the great laboratories of nature it can hardly be doubted that almost every kind of chemical process is going forwards, by which compounds of every description are continually forming. Accordingly, it is remarked, that the lavas and ejected scoriæ of volcanoes are receptacles in which mineral products previously unknown are constantly discovered, and that the primitive formations, as they are called in geology, which bear no marks of having been produced by the destruction of others, are also remarkable for the beauty and distinctness of character of their minerals.

(331.) The great difficulty which has been experienced in attempts to classify mineral substances by their chemical constituents has arisen from the observed presence, in some specimens of minerals bearing that general resemblance in other respects as well as agreement in form which would seem to entitle them to be considered as alike, of ingredients foreign to the usual composition of the species, and that occasionally in so large a proportion as to render it unjustifiable to refer their occurrence to accidental impurities. These cases, as well as some anomalies observed in the classification of minerals by their crystalline forms, which seemed to show that the same substance might occasionally appear under two distinct forms, as well as some remarkable coincidences between the forms of substances quite distinct from each other in a chemical point of view, have within a recent period given rise to a branch of the science of crystallography of a very curious and important nature. The _isomorphism_ of certain groups of chemical elements has already afforded us an example illustrative of the manner in which inductions sometimes receive unexpected verifications (see 180.). The laws and relations thus brought to light are among the most curious and interesting parts of modern science, and seem likely in their further developement to afford ample scope for the exercise of chemical and mineralogical research. They have already afforded innumerable fine examples of that important step in science by which anomalies disappear, and occasional incongruities become reconciled under more general expressions of physical laws, and thus unite in affording support to those very views which they promised, when first observed, to overset. Nothing, indeed, can be more striking than to see the very ingredient which every previous chemist and mineralogist would agree to disregard and reject as a mere casual impurity brought forward and appealed to in support of a theory expressly directed to the object of rescuing science from the imputation of disregarding, under any circumstances, the plain results of direct experiment.

_Chemistry._

(332.) The laws which concern the intimate constitution of bodies, not as respects their _structure_ or the manner in which their parts are put together, but as regards their _materials_ or the ingredients of which those parts are composed, form the objects of chemistry. A solid body may be regarded as a fabric, more or less regularly and artificially constructed, in which the materials and the workmanship may be separately considered, and in which, though the latter be ruined and confounded by violence, the former remain unchanged in their nature, though differently arranged. In liquid or aërial bodies, too, though there prevails a less degree of difference in point of structure, and a greater facility of dispersion and dissipation, than in solids, yet an equal diversity of _materials_ subsists, giving to them properties differing extremely from each other.

(333.) The inherent activity of matter is proved not only by the production of motion by the mutual attractions and repulsions of distant or contiguous masses, but by the changes and apparent transformations which different substances undergo in their sensible qualities by mere mixture. If water be added to water, or salt to salt, the effect is an increase of quantity, but no change of quality. In this case, the mutual action of the particles is entirely mechanical. Again, if a blue powder and a yellow one, each perfectly dry, be mixed and well shaken together, a green powder will be produced; but this is a mere effect arising in the eye from the intimate mixture of the yellow and blue light separately and independently reflected from the minute particles of each; and the proof is had by examining the mixture with a microscope, when the yellow and blue grains will be seen separate and each quite unaltered. If the same experiment be tried with coloured liquids, which are susceptible of mixing without chemical action, a compound colour is likewise produced, but no examination with magnifiers is in that case sufficient to detect the ingredients; the reason obviously being, the excessive minuteness of the parts, and their perfect intermixture, produced by agitating two liquids together. From the mixture of two powders, extreme patience would enable any one, by picking out with a magnifier grain after grain, to separate the ingredients. But when liquids are mixed, no mechanical separation is any longer practicable; the particles are so minute as to elude all search. Yet this does not hinder us from regarding such a compound as still a mere mixture, and its properties are accordingly intermediate between those of the liquids mixed. But this is far from being the case with all liquids. When a solution of potash, for example, and another of tartaric acid, each perfectly liquid, are mixed together in proper proportions, a great quantity of a solid saline substance falls to the bottom of the containing vessel, which is quite different from either potash or tartaric acid, and the liquid from which it subsided offers no indications by its taste or other sensible qualities of the ingredients mixed, but of something totally different from either. It is evident that this is a phenomenon widely different from that of mere mixture; there has taken place a great and radical change in the intimate nature of the ingredients, by which a new substance is produced which had no existence before. And it has been produced by the _union_ of the ingredients presented to each other; for when examined it is found that nothing has been _lost_, the weight of the whole mixture being the sum of the weights mixed. Yet the potash and tartaric acid have disappeared entirely, and the weight of the new product is found to be exactly equal to that of the tartaric acid and potash employed, taken together, abating a small portion held in solution in the liquid, which may be obtained however by evaporation. They have therefore combined, and adhere to one another with a cohesive force sufficient to form a solid out of a liquid; a force which has thus been called into action by merely presenting them to each other in a state of solution.

(334.) It is the business of chemistry to investigate these and similar changes, or the reverse of such changes, where a single substance is resolved into two or more others, having different properties from it, and from each other, and to enquire into all the circumstances which can influence them; and either determine, modify, or suspend their accomplishment, whether such influence be exercised by heat or cold, by time and rest, or by agitation or pressure, or by any of those agents of which we have acquired a knowledge, such as electricity, light, magnetism, &c.

(335.) The wonderful and sudden transformations with which chemistry is conversant, the violent activity often assumed by substances usually considered the most inert and sluggish, and, above all, the insight it gives into the nature of innumerable operations which we see daily carried on around us, have contributed to render it the most popular, as it is one of the most extensively useful, of the sciences; and we shall, accordingly, find none which have sprung forward, during the last century, with such extraordinary vigour, and have had such extensive influence in promoting corresponding progress in others. One of the chief causes of its popularity is, perhaps, to be sought for in this, that it is, of all the sciences, perhaps, the most completely an experimental one; and even its theories are, for the most part, of that generally intelligible and readily applicable kind, which demand no intense concentration of thought, and lead to no profound mathematical researches. The simple process of inductive generalization, grounded on the examination of numerous facts, all of them presenting considerable intrinsic interest, has sufficed, in most instances, to lead, by a clear and direct road, to its highest laws yet known. But, on the other hand, these laws, when stated, are not yet fully sufficient to lead us, except in very limited cases, to a deductive knowledge of particulars never before examined, at least, not without great caution, and constant appeal to experiment as a check on our reasoning; so that we are justified in regarding the _axioms_ of chemistry, the true handles of deductive reasoning, as still unknown, and, perhaps, likely long to remain so. This is no fault of its cultivators, who have comprised in their list the highest and most varied talents and industry, but of the inherent complexity of the subject, and the infinite multitude of causes which are concerned in the production of every, even the simplest, chemical phenomenon.

(336.) The history of chemistry (on which, however, we are not about to enlarge,) is one of great interest to those who delight to trace the steps by which mankind advance to the discovery of truth through a series of mistakes and failures. It may be divided, 1st, into the period of the alchemists, a lamentable epoch in the annals of intellectual wandering; 2dly, that of the phlogistic doctrines of Beccher and Stahl, in which, as if to prove the perversity of the human mind, of two possible roads the wrong was chosen; and a theory obtained universal credence on the strength of an induction, valid as such, but wrongly interpreted, which is negatived, _in every instance_, by an appeal to the balance. This, too, happened, not by reason of unlucky coincidences, or individual oversights, but of necessity, and from an inherent defect of the theory itself, which thus impeded the progress of the science, as far as a science of experiment can be impeded by a false theory, by perplexing its cultivators with the appearance of contradictions in their experiments where none really subsisted, by destroying all their confidence in the numerical exactness of their own results, and by involving the subject in a mist of visionary and hypothetical causes in place of the true acting principles. Thus, in the combustion of any substance which is incapable of flying away in fumes, an increase of weight takes place,--the ashes are heavier than the fuel. Whenever this was observed, however, it was passed carelessly over as arising from the escape of phlogiston, or the principle of inflammability, which was considered as being either the element of fire itself, or in some way combined with it, and thus essentially _light_. It is now known that the increase of weight is owing to the absorption of, and combination with, a quantity of a peculiar ingredient called _oxygen_, from the air, a principle essentially _heavy_. So far as weight is concerned, it makes no difference whether a body having weight enters, or one having levity escapes; but there is this plain difference in a philosophical point of view, that oxygen is a real producible substance, and phlogiston is no such thing: the former is a _vera causa_, the latter an hypothetical being, introduced to account for what the other accounts for much better.

(337.) The third age of chemistry--that which may be called emphatically modern chemistry--commenced (in 1786) when Lavoisier, by a series of memorable experiments, extinguished for ever this error, and placed chemistry in the rank of one of the exact sciences,--a science of number, weight, and measure. From that epoch to the present day it has constantly advanced with an accelerated progress, and at this moment may be regarded as more progressive than ever. The principal features in this progress may be comprised under the following general heads:--

1. The discovery of the proximate, if not the ultimate, elements
of all bodies, and the enlargement of the list of known
elements to its present extent of between fifty and sixty
substances.

2. The developement of the doctrine of latent heat by Black,
with its train of important consequences, including the
scientific theory of the steam-engine.

3. The establishment of Wenzel’s law of definite proportions on
his own experiments, and those of Richter, a discovery
subsequently merged in the more general wording and better
development of Dalton’s atomic theory.

4. The precise determination of the atomic weights of the
different chemical elements, mainly due to the astonishing
industry of Berzelius, and his unrivalled command of chemical
resources, as well as to the researches of the other chemists
of the Swedish and German school.

5. The assimilation of gases and vapours, by which we are led
to regard the former, universally, as particular cases of
the latter, a generalization resulting chiefly from the
experiments of Faraday on the condensation of the gases,
and those of Gay-Lussac and Dalton, on the laws of their
expansion by heat compared with that of vapours.

6. The establishment of the laws of the combination of gases and
vapours by definite volumes, by Gay-Lussac.

7. The discovery of the chemical effects of electricity, and
the decomposing agency of the Voltaic pile, by Nicholson
and Carlisle; the investigation of the laws of such
decompositions, by Berzelius and Hisinger: the decomposition
of the alkalies by Davy, and the consequent introduction into
chemistry of new and powerful agents in their metallic bases.

8. The application of chemical analysis to all the objects of
organized and unorganized nature, and the discovery of
the ultimate constituents of all, and the proximate ones
of organic matter, and the recognisance of the important
distinctions which appear to divide these great classes of
bodies from each other.

9. The applications of chemistry to innumerable processes in the
arts, and among other useful purposes to the discovery of the
essential medical principles in vegetables, and to important
medicaments in the mineral kingdom.

10. The establishment of the intimate connection between
chemical composition and crystalline form, by Haüy
and Vauquelin, with the successive rectifications the
statement of that connection has undergone in the hands of
Mitscherlich, Rose, and others, with the progress of chemical
and crystallographical knowledge.

(338.) To pursue these several heads into detail would lead us into a treatise on chemistry; but a few remarks on one or two of them, as they bear upon the general principles of all scientific enquiry, will not be irrelevant. And first, then, with reference to the discovery of new elements, it will be observed, that philosophical chemistry no more aims at determining the one essential element out of which all matter is framed--the one ultimate principle of the universe--than astronomy at discovering the origin of the planetary movements in the application of a determinate projectile force in a determinate direction, or geology at ascending to the creation of the earth. There may be such an element. Some singular relations which have been pointed out in the atomic weights of bodies seem to suggest to minds fond of speculation that there is; but philosophical chemistry is content to wait for some striking fact, which may either occur unexpectedly or be led to by the slow progress of enlarged views, to disclose to us its existence. Still, the multiplication of so-considered elementary bodies has been considered by some as an inconvenience. We confess we do not coincide with this view. Whatever they be, the obstinacy with which they resist decomposition shows that they are ingredients of a very high and primary importance in the economy of nature; and such as, in any state of science, it would be indispensably necessary to be perfectly familiar with. Like particular theorems in geometry, which, though not rising to the highest point of generality, have yet their several scopes and ranges of extensive application, they must be well and perfectly understood in all their bearings. Should we ever arrive at an analysis of these bodies, the chemical properties of the new elements which will then come into view will be known only by our knowledge of these, or of other compounds of the same class, which they may be capable of forming. Not but that such an analysis would be a most important and indeed triumphant achievement, and change the face of chemistry; but it would undo nothing that has been done, and render useless no point of knowledge which we have yet arrived at.

(339.) The atomic theory, or the law of definite proportions, which is the same thing presented in a form divested of all hypothesis, after the laws of mechanics, is, perhaps, the most important which the study of nature has yet disclosed. The extreme simplicity which characterizes it, and which is itself an indication, not unequivocal, of its elevated rank in the scale of physical truths, had the effect of causing it to be announced at once by Mr. Dalton, in its most general terms, on the contemplation of a few instances[53], without passing through subordinate stages of painful inductive ascent by the intermedium of subordinate laws, such as, had the contrary course been pursued by him, would have been naturally preparatory to it, and such as would have led others to it by the prosecution of Wenzel’s and Richter’s researches, had they been duly attended to. This is, in fact, an example, and a most remarkable one, of the effect of that natural propensity to generalize and simplify (noticed in 171.), which, if it occasionally leads to over-hasty conclusions, limited or disproved by further experience, is yet the legitimate parent of many of our most valuable and soundest results. Instances like this, where great and, indeed, immeasurable steps in our knowledge of nature are made at once, and almost without intellectual effort, are well calculated to raise our hopes of the future progress of science, and, by pointing out the simplest and most obvious combinations as those which are actually found to be agreeable to the harmony of creation, to hold out the cheering prospect of difficulties diminishing as we advance, instead of thickening around us in increasing complexity.

(340.) A consequence of this immediate presentation of the law of definite proportions in its most general form is, that its subordinate laws--those which limit its generality in particular cases, which diminish the number of combinations abstractly possible, and restrain the indiscriminate mixture of elements,--remain to be discovered. Some such limitations have, in fact, been traced to a certain extent, but by no means so far as the importance of the subject requires; and we have here abundant occupation for chemists for some time.

(341.) The determination of the atomic weights of the chemical elements, like that of other standard physical data, with the utmost exactness, is in itself a branch of enquiry not only of the greatest importance, but of extreme difficulty. Independent of the general reasons for desiring accuracy in this respect, there is one peculiar to the subject. It has been suggested (by Dr. Prout), and strongly insisted on (by Dr. Thomson), that all the numbers representing these weights, constituting a scale of great extent, in which the extremes already known are in proportion to each other, as 1 to upwards of 200, are simple even multiples of the least of them. If this be really the case, it opens views of such importance as to justify any degree of labour and pains in the verification of the law as a purely inductive one. But in the actual state of chemical analysis, with all deference to such high authority, we confess it appears to us to stand in great need of further confirmation, since it seems doubtful whether such accuracy has yet been attained as to enable us to answer positively for a fraction not exceeding the three or four hundredth part of the whole quantity to be determined: at least the results of the first experimenters, obtained with the greatest care, differ often by a greater amount; and this degree of exactness, at least, would be required to verify the law satisfactorily in the higher parts of the scale.

(342.) The mere agitation of such a question, however, points out a class of phenomena in physical science of a remote and singular kind, and of a very high and refined order, which could never become known but in an advanced state of science, not only practical, but theoretical,--we mean, such as consist in observed relations among the _data_ of physics, which show them to be quantities not _arbitrarily_ assumed, but depending on laws and causes which they may be the means of at length disclosing. A remarkable instance of such a relation is the curious law which Bode observed to obtain in the progression of the magnitudes of the several planetary orbits. This law was interrupted between Mars and Jupiter, so as to induce him to consider a planet as wanting in that interval;--a deficiency long afterwards strangely supplied by the discovery of _four_ new planets in that very interval, all of whose orbits conform in dimension to the law in question, within such moderate limits of error as may be due to causes independent of those on which the law itself ultimately rests.[54]

(343.) Neither is it irrelevant to our subject to remark, that the progress which has been made in this department of chemistry, and the considerable exactness actually attainable in chemical analysis, have been owing, in great measure, to a circumstance which might at first have been hardly considered likely to exercise much influence on the progress of a science,--the discovery of platina. Without the resources placed at the ready disposal of chemists by this invaluable metal, it is difficult to conceive that the multitude of delicate analytical experiments which have been required to construct the fabric of existing knowledge could have ever been performed. This, among many such lessons, will teach us that the most important uses of natural objects are not those which offer themselves to us most obviously. The chief use of the moon for man’s immediate purposes remained unknown to him for five thousand years from his creation. And, since it cannot but be that innumerable and most important uses remain to be discovered among the materials and objects already known to us, as well as among those which the progress of science must hereafter disclose, we may hence conceive a well-grounded expectation, not only of constant increase in the physical resources of mankind, and the consequent improvement of their condition, but of continual accessions to our power of penetrating into the arcana of nature, and becoming acquainted with her highest laws.

CHAP. V.

OF THE IMPONDERABLE FORMS OF MATTER.

_Heat._

(344.) One of the chief agents in chemistry, on whose proper application and management the success of a great number of its enquiries depends, and many of whose most important laws are disclosed to us by phenomena of a chemical nature, is HEAT. Although some of its effects are continually before our eyes as matters of the most common occurrence, insomuch that there is scarcely any process in the useful arts and manufactures which does not call for its intervention, and although, independent of this high utility, and the proportionate importance of a knowledge of its nature and laws, it presents in itself a subject of the most curious speculation; yet there is scarcely any physical agent of which we have so imperfect a knowledge, whose intimate nature is more hidden, or whose laws are of such delicate and difficult investigation.

(345.) The word heat generally implies the sensation which we experience on approaching a fire; but, in the sense it carries in physics, it denotes the cause, whatever it be, of that sensation, and of all the other phenomena which arise on the application of fire, or of any other heating cause. We should be greatly deceived if we referred only to sensation as an indication of the presence of this cause. Many of those things which excite in our organs, and especially of those of taste, a sensation of heat, owe this property to chemical stimulants, and not at all to their being actually _hot_. This error of judgment has produced a corresponding confusion of language, and hence had actually at one period[55] crept into physical philosophy a great many illogical and absurd conclusions. Again, there are a number of chemical agents, which, from their corroding, blackening, and dissolving, or drying up the parts of some descriptions of bodies, and producing on them effects not generally unlike (though intrinsically very different from) those produced by heat, are said, in loose and vulgar language, to burn them; and this error has even become rooted into a prejudice, by the fact that some of these agents are capable of becoming actually and truly _hot_ during their action on moist substances, by reason of their combination with the water the latter contain. Thus, quicklime and oil of vitriol both exercise a powerful corrosive action on animal and vegetable substances, and both become violently hot by their combination with water. They are, therefore, set down in vulgar parlance as substances of a hot nature; whereas, in their relations to the physical cause of heat, they agree with the generality of bodies similarly constituted.

(346.) The nature of heat has hitherto been chiefly studied under the general heads of--

1st, Its sources, or the phenomena which it usually accompanies.

2d, Its communication from its sources to substances capable of
receiving it, and from these to others, with a view to
discover the laws which regulate its distribution through
space or through the bodies which occupy it.

3d, Its effects, on our senses, and on the bodies to which it is
communicated in its various degrees of intensity, by which,
means are afforded us of measuring these degrees.

4th, Its intimate relations to the atoms of matter, as exhibited
in its capability of acquiring a latent state under certain
circumstances, and of entering into something like chemical
combinations.

(347.) The most obvious sources of heat are, the sun, fire, animal life, fermentations, violent chemical actions of all kinds, friction, percussion, lightning, or the electric discharge, in whatever manner produced, the sudden condensation of air, and others, so numerous, and so varied, as to show the extensive and important part it has to perform in the economy of nature. The discoveries of chemists, however, have referred most of these to the general head of chemical combination. Thus, fire, or the combustion of inflammable bodies, is nothing more than a violent chemical action attending the combination of their ingredients with the oxygen of the air. Animal heat is, in like manner, referable to a process bearing no remote analogy to a slow combustion, by which a portion of carbon, an inflammable principle existing in the blood, is united with the oxygen of the air in respiration; and thus carried off from the system: fermentation is nothing more than a decomposition of chemical elements loosely united, and their re-union in a more permanent state of combination. The analogy between the sun and terrestrial fire is so natural as to have been chosen by Newton to exemplify the irresistible force of an inference derived from that principle. But the nature of the sun and the mode in which its wonderful supply of light and heat is maintained are involved in a mystery which every discovery that has been made either in chemistry or optics, so far from elucidating, seems only to render more profound. Friction as a source of heat is well known: we rub our hands to warm them, and we grease the axles of carriage-wheels to prevent their setting fire to the wood; an accident which, in spite of this precaution, does sometimes happen. But the effect of friction, as a means of producing heat with little or no consumption of materials, was not fully understood till made the subject of direct experiment by count Rumford, whose results appear to have established the extraordinary fact, that an unlimited supply of heat may be derived by friction from the same materials. Condensation, whether of air by pressure, or of metals by percussion, is another powerful source of heat. Thus, iron may be so dexterously hammered as to become red-hot, and the rapid condensation of a confined portion of air will set tinder on fire.

(348.) The most violent heats known are produced by the concentration of the solar rays by burning glasses,--by the combustion of oxygen and hydrogen gases mixed in the exact proportion in which they combine to produce water,--and by the discharge of a continued and copious current of electricity through a small conductor. As these three sources of heat are independent of each other, and each capable of being brought into action in a very confined space, there seems no reason why they might not all three be applied at once at the same point, by which means, probably, effects would be produced infinitely surpassing any hitherto witnessed.

(349.) Heat is communicated either by _radiation_ between bodies at a distance, or by _conduction_ between bodies in contact, or between the contiguous parts of one and the same body. The laws of the radiation of heat have been studied with great attention, and have been found to present strong analogies with that of light in some points, and singular differences in others. Thus, the heat which accompanies the sun’s rays comports itself, in all respects, like light; being subject to similar laws of reflection, refraction, and even of polarization, as has been shown by Berard. Yet they are not identical with each other; Sir William Herschel having shown, by decisive experiments, verified by those of Sir H. Englefield, that there exist in a solar beam both rays of heat which are not luminous, and rays of light which have no heating power.

(350.) The heat, radiated by terrestrial fires, and by bodies _obscurely_ hot, by whatever means they have acquired their heat (even by exposure to the sun’s rays), differs very materially from solar heat in their power of penetrating transparent substances. This singular and important difference was first noticed by Mariotte, and afterwards made the subject of many curious and interesting experiments by Scheele, who found that terrestrial heat, or that radiated from fires or heated bodies, is intercepted and detained by glass or other transparent bodies, while solar heat is not; and that, being so detained, it heats them: which the latter, as it passes freely through them, is incapable of doing. The more recent researches of Delaroche, however, have shown that this detention is complete only when the temperature of the source of heat is low; but that, as that temperature is higher, a portion of the heat radiated acquires a power of penetrating glass; and that the quantity which does so bears continually a larger and larger proportion to the whole, as the heat of the radiant body is more intense. This discovery is very important, as it establishes a community of nature between solar and terrestrial heat; while at the same time it leads us to regard the actual temperature of the sun as far exceeding that of any earthly flame.

(351.) A variety of theories have been framed to account for these curious phenomena; but the subject stands rather in need of further elucidation from experiment, and is one which merits, and will probably amply repay, the labours of those who may hereafter devote their attention to it. The theory of the radiation of heat, in general, which seems to agree best with the known phenomena, is that of M. Prevost, who considers all bodies as constantly radiating out heat in all directions, and receiving it by a similar means of communication from others, and thus tending, in any space filled, wholly or in part, with bodies at various temperatures, to establish an equilibrium or equality of heat in all parts. The application of this idea to the explanation of the phenomenon of dew we have already seen (see 167.). The laws of such radiation, under various circumstances, have been lately investigated in a beautiful series of experiments on the cooling of bodies by their own radiation in vacuo, by Messrs. Dulong and Petit, which offer some of the best examples in science of the inductive investigation of quantitative laws.

(352.) The communication of heat between bodies in contact, or between the different parts of the same body, is performed by a process called conduction. It is, in fact, only a particular case of radiation, as has been explained above (217.); but a case _so_ particular as to require a separate and independent investigation of its laws. The most important consideration introduced into the enquiry by this peculiarity is that of time. The communication of heat by conduction is performed, for the most part, with extreme slowness, while that performed by direct radiation is probably not less rapid than the propagation of light itself. The analysis of the delicate and difficult points which arise in the investigation of this subject in its reduction to direct geometrical treatment has been executed with admirable success by the late Baron Fourrier, whose recent lamented death has deprived science of an ornament it could ill spare, thinned as its ranks have been within the last few years. This acute philosopher and profound mathematician has developed, in a series of elaborate memoirs presented to the French Institute, the laws of the communication of heat through the interior of solid masses, placed under the influence of any external heating and cooling causes, and has in particular applied his results to the conditions on which the maintenance of the actual observed temperature on the earth’s surface depends; to the possible influence of a supposed central heat on our climates; and to the determination of the actual amount of the heat, derived to us from the sun, or at least that portion of it on which the difference of the seasons depends.

(353.) The principal effects of heat are the sensations of warmth or cold consequent on its entry or egress into or out of our bodies; the dilatation it causes in the dimensions of all substances in which it is accumulated; the changes of state it produces in the melting of solids, and the conversion of them and of liquids into vapour; and the chemical changes it performs by actual decompositions effected in the intimate molecules of various substances, especially those of which vegetables and animals are composed; to which we may add, the production of electric phenomena under certain circumstances in the contact of metals, and the developement of electric polarity in crystallised substances.

(354.) Cold has been considered by some as a positive quality, the effect of a cause antagonist to that of heat; but this idea seems now (with perhaps a single exception) to be universally abandoned. The sensation of cold is as easily explicable by the passage of heat outwards through the surface of the body as that of heat by its ingress from without; and the experiments cited in proof of a radiation of cold are all perfectly explained by Prevost’s theory of reciprocal interchange. It is remarkable, however, how very limited our means of producing intense cold are, compared with those we possess of effecting the accumulation of heat in bodies. This is one of the strongest arguments adducible in favour of the doctrines of those who maintain the possibility of exhausting the heat of a body altogether, and leaving it in a state absolutely devoid of it. But we ought to consider, that the known methods of generating heat chiefly turn on the production of chemical combinations: we may easily conceive, therefore, that, to obtain equally powerful corresponding frigorific effects, we ought to possess the means of effecting a disunion equally extensive and rapid between such elements, actually combined, as have already produced heat by their union. This, however, we can only accomplish by engaging them in combinations still more energetic, that is to say, in which we may reasonably expect more heat to be produced by the new combination than would be destroyed or abstracted by the proposed decomposition. Chemistry, however, (unaided by electric agency,) affords no means of suddenly breaking the union of two elements, and presenting _both_ in an uncombined state. A certain analogy to such disunion, however, and its consequences, may be traced in the sudden expansion of condensed gases from a liquid state into vapour, which is the most powerful source of cold known.

(355.) The dilatation of bodies by heat forms the subject of that branch of science called pyrometry. There is no body but is capable of being penetrated by heat, though some with greater, others with less rapidity; and being so penetrated, all bodies (with a very few exceptions, and those depending on very peculiar circumstances,) are dilated by it in bulk, though with a great diversity in the amount of dilatation produced by the same degree of heat. Of the several forms of natural bodies, gases and vapours are observed to be most dilatable; liquids next, and solids least of all. The dilatation of solids has been made a subject of repeated and careful measurement by several experimenters; among whom, Smeaton, Lavoisier, and Laplace, are the principal. The remarkable discovery of the unequal dilatation of crystallised bodies by Mitscherlich has already been spoken of. (266.) That of gases and vapours was examined about the same time by Dalton and Gay-Lussac, who both arrived independently at the conclusion of an equal dilatability subsisting in them all, which constitutes one of the most remarkable points in their history.

(356.) The dilatation of air by heat affords, perhaps, the most unexceptionable means known of measuring degrees of heat. The thermometer, as originally constructed by Cornelius Drebell, was an air thermometer. Those now in common use measure accessions of heat not by the degree of dilatation of air but of mercury. It has been shown, by the researches of Dulong and Petit, that its indications coincide exactly with that of the air-thermometer in moderate temperatures; though at very elevated ones they exhibit a sensible, and even considerable, deviation. By this instrument, which owes its present convenience and utility to the happy idea of Newton, who first thought of fixing determinate points on its scale, we are enabled to estimate, or at least identify, the degrees of heat; and thereby to investigate with accuracy the laws of its communication and its other properties. Were we sure that equal additions of heat produced equal increments of dimension in any substance, the indications of a thermometer would afford a true and secure _measure_ of the quantity present; but this is so far from being the case, that we are nearly in total ignorance on this important point; a circumstance which throws the greatest difficulty in the way of all theoretical reasoning, and even of experimental enquiry. The laws of the dilatation of liquids, in consequence of this deficiency of necessary preliminary knowledge, are still involved in great obscurity, notwithstanding the pains which have been bestowed on them by the elaborate experiments and calculations of Gilpin, Blagden, Deluc, Dalton, Gay-Lussac, and Biot.

(357.) The most striking and important of the effects of heat consist, however, in the liquefaction of solid substances, and the conversion of the liquids so produced into vapour. There is no solid substance known which, by a sufficiently intense heat, may not be melted, and finally dissipated in vapour; and this analogy is so extensive and cogent, that we cannot but suppose that all those bodies which are liquid under ordinary circumstances, owe their liquidity to heat, and would freeze or become solid if their heat could be sufficiently reduced. In many we see this to be the case in ordinary winters; for some, severe frosts are requisite; others freeze only with the most intense artificial colds; and some have hitherto resisted all our endeavours; yet the number of these last is few, and they will probably cease to be exceptions as our means of producing cold become enlarged.

(358.) A similar analogy leads us to conclude that all aëriform fluids are merely liquids kept in the state of vapour by heat. Many of them have been actually condensed into the liquid state by cold accompanied with violent pressure; and as our means of applying these causes of condensation have improved, more and more refractory ones have successively yielded. Hence we are fairly entitled to extend our conclusion to those which we have not yet been able to succeed with; and thus we are led to regard it as a general fact, that the liquid and aëriform or vaporous states are entirely dependent on _heat_; that were it not for this cause, there would be nothing but solids in nature; and that, on the other hand, nothing but a sufficient intensity of heat is requisite to destroy the cohesion of every substance, and reduce all bodies, first to liquids, and then into vapour.

(359.) But solids, themselves, by the abstraction of heat shrink in dimension, and at the same time become harder, and more brittle; yielding less to pressure, and permitting less separation between their parts by tension. These facts, coupled with the greater compressibility of liquids, and the still greater of gases, strongly induce us to believe that it is heat, and heat alone, which holds the particles of all bodies at that distance from each other which is necessary to allow of compression; which in fact gives them their elasticity, and acts as the antagonist force to their mutual attraction, which would otherwise draw them into actual contact, and retain them in a state of absolute immobility and impenetrability. Thus we learn to regard heat as one of the great maintaining powers of the universe, and to attach to all its laws and relations a degree of importance which may justly entitle them to the most assiduous enquiry.

(360.) It was first ascertained by Dr. Black that when heat produces the liquefaction of a solid, or the conversion of a liquid into vapour, the liquid or the vapour resulting is no _hotter_ than the solid or liquid from which it was produced, though a great deal of heat has been expended in producing this effect, and has actually entered into the substance.

(361.) Hence he drew the conclusion that it has become _latent_, and continues to exist in the product, maintaining it in its new state, without increasing its temperature. He further proved, that when the vapour condenses, or the liquid freezes, this latent heat is again given out from it. This great discovery, with its natural and hardly less important concomitant, that of the difference of specific heats in different bodies, or the different quantities of heat they require to raise their temperature equally, are the chief reasons for regarding heat as a material substance in a more decided manner than light, with which in its radiant state it holds so close an analogy.

(362.) The subject of latent heat has been far less attentively studied than its great practical importance would appear to demand, when we consider that it is to this part of physical science that the theory of the steam-engine is mainly referable, and that material improvements may not unreasonably be expected in that wonderful instrument, from a more extended knowledge than we possess of the latent heats of different vapours. This is not the case, however, with the subject of specific heat, which was followed up immediately after its first promulgation with diligence by Irvine; and, after a brief interval, by Lavoisier and Laplace, as well as by our countryman Crawfurd, who determined the specific heats of many substances, both solid and liquid. After a considerable period of inactivity, the subject was again resumed by Delaroche and Berard, and subsequently by Dulong and Petit: the result of whose investigations has been the inductive establishment of one of those simple and elegant physical laws which carry with them, if not their own evidence, at least their own recommendation to our belief, as being in unison with every thing we know of the harmony of nature. The law to which we allude is this:--that the atoms of all the simple chemical elements have exactly the same capacity for heat, or are all equally heated or cooled by equal accessions or abstractions of heat. It is only among laws like this that we can expect to find a clew capable of guiding us to a knowledge of the true nature of heat, and its relations to ponderable matter.

_Magnetism and Electricity._