Skip to content

Chapter C: C C C, fig. 60., is a horizontal section of the furnace over the (3)

Text size

_Mecca balsam, or opobalsam_, is obtained both by incisions of, and by boiling, the branches and leaves of the _Balsamodendron Gileadense_, a shrub which grows in Arabia Felix, Lesser Asia and Egypt. When fresh it is turbid, whitish, becomes, by degrees, transparent; yellow, thickish, and eventually solid. It smells peculiar, but agreeable; tastes bitter and spicy; does not dissolve completely in hot spirit of wine, and contains 10 per cent. of ethereous oil, of the spec. grav. 0·876.

_Japan lac varnish_ flows from incisions in the trunk of the _Rhus Vernix_ (_Melanorrhea usitata_) which is cultivated in Japan, and grows wild in North America. The juice becomes black in the air; when purified, dissolves in very little oil; and, mixed with colouring matter, it constitutes the celebrated varnish of the Japanese.

For Benzoin and Turpentine, see these articles in their alphabetical places.

BANDANNA. A style of calico printing, in which white or brightly coloured spots are produced upon a red or dark ground. It seems to have been practised from time immemorial in India, by binding up firmly with thread, those points of the cloth which were to remain white or yellow, while the rest of the surface was freely subjected to the dyeing operations.

The European imitations have now far surpassed, in the beauty and precision of the design, the oriental patterns; having called into action the refined resources of mechanical and chemical science. The general principles of producing bright figures upon dark grounds, are explained in the article CALICO-PRINTING; but the peculiarities of the Bandanna printing may be conveniently introduced here. In Brande’s Journal for July 1823, I described the Bandanna gallery of Messrs. Monteith at Glasgow, which, when in full action some years ago, might be reckoned the most magnificent and profitable printing apartment in the world. The white spots were produced by a solution of chlorine, made to percolate down through the Turkey red cotton cloth, in certain points, defined and circumscribed by the pressure of hollow lead types in plates, in a hydraulic press. _Fig._ 96., is an elevation of one press; A, the top or entablature; B B, the cheeks or pillars; C, the upper block for fastening the upper lead perforated pattern to; D, the lower block to which the fellow pattern is affixed, and which moves up and down with the piston of the press; E, the piston or ram; F, the sole or base; G, the water-trough, for the discharged or spotted calico to fall into; H, the small cistern, for the aqueous chlorine or liquor-meter, with glass tubes for indicating the height of liquor inside of the cistern; _e e_, glass stopcocks, for admitting the liquor into that cistern from the general reservoir; _f f_, stopcocks for admitting water to wash out the chlorine; _g g_, the pattern lead-plates, with screws for setting the patterns parallel to each other; _m m_, projecting angular pieces at each corner, perforated with a half-inch hole to receive the four guide-pins rising from the lower plate, which serve to secure accuracy of adjustment between the two faces of the lead pattern plates; _h h_, two rollers which seize and pull through the discharged pieces, and deliver them into the water-trough. To the left of D there is a stopcock for filling the trough with water; _l_, is the waste tube for chlorine liquor and water of washing. The contrivance for blowing a stream of air across the cloth, through the pattern tubes, is not represented in the figure.

Sixteen engines, similar to the above, each possessing the power of pressing with several hundred tons, are arranged in one line, in subdivisions of four; the spaces between each subdivision serving as passages to allow the workmen to go readily from the front to the back of the presses. Each occupies twenty-five feet, so that the total length of the apartment is 100 feet.

To each press is attached a pair of patterns in lead, (or plates as they are called,) the manner of forming which will be described in the sequel. One of these plates is fixed to the upper block of the press. This block is so contrived, that it rests upon a kind of universal joint, which enables this plate to apply more exactly to the under fellow-plate. The latter sits on the moveable part of the press, commonly called the sill. When this is forced up, the two patterns close on each other very nicely, by means of the guide-pins at the corners, which are fitted with the utmost care.

The power which impels this great hydrostatic range is placed in a separate apartment, called the machinery room. This machinery consists of two press cylinders of a peculiar construction, having solid rams accurately fitted to them. To each of these cylinders, three little force-pumps, worked by a steam-engine, are connected.

The piston of the large cylinder is eight inches in diameter, and is loaded with a top-weight of five tons. This piston can be made to rise about two feet through a leather-stuffing or collar. The other cylinder has a piston of only one inch in diameter, which is also loaded with a top-weight of five tons. It is capable, like the other, of being raised two feet through its collar.

Supposing the pistons to be at their lowest point, four of the six small force-pumps are put in action by the steam-engine, two of them to raise the large piston, and two the little one. In a short time, so much water is injected into the cylinders, that the loaded pistons have arrived at their highest points. They are now ready for working the hydrostatic discharge-presses, the water pressure being conveyed from the one apartment to the other, under ground, through strong copper tubes, of small calibre.

Two valves are attached to each press, one opening a communication between the large driving-cylinder and the cylinder of the press, the other between the small driving-cylinder and the press. The function of the first is simply to lift the under-block of the press into contact with the upper-block; that of the second, is to give the requisite compression to the cloth. A third valve is attached to the press, for the purpose of discharging the water from its cylinder, when the press is to be relaxed, in order to remove or draw through the cloth.

From twelve to fourteen pieces of cloth, previously dyed Turkey-red, are stretched over each other, as parallel as possible, by a particular machine. These parallel layers are then rolled round a wooden cylinder, called by the workmen, a drum. This cylinder is now placed in its proper situation at the back of the press. A portion of the fourteen layers of cloth, equal to the area of the plates, is next drawn through between them, by hooks attached to the two corners of the webs. On opening the valve connected with the eight-inch driving-cylinder, the water enters the cylinder of the press, and instantly lifts its lower block, so as to apply the under plate with its cloth, close to the upper one. This valve is then shut, and the other is opened. The pressure of five tons in the one inch prime-cylinder, is now brought to bear on the piston of the press, which is eight inches in diameter. The effective force here will, therefore, be 5 tons × 8² = 320 tons; the areas of cylinders being to each other, as the squares of their respective diameters. The cloth is thus condensed between the leaden pattern-plates, with a pressure of 320 tons, in a couple of seconds;--a splendid example of automatic art.

The next step, is to admit the blanching or discharging liquor, (aqueous chlorine, obtained by adding sulphuric acid to solution of chloride of lime,) to the cloth. This liquor is contained in a large cistern, in an adjoining house, from which it is run at pleasure into small lead cisterns H attached to the presses; which cisterns have graduated index tubes, for regulating the quantity of liquor according to the pattern of discharge. The stopcocks on the pipes and cisterns containing this liquor, are all made of glass.

From the measure-cistern H, the liquor is allowed to flow into the hollows in the upper lead-plate, whence it descends on the cloth, and percolates through it, extracting in its passage the Turkey-red dye. The liquor is finally conveyed into the waste pipe, from a groove in the under block. As soon as the chlorine liquor has passed through, water is admitted in a similar manner, to wash away the chlorine; otherwise, upon relaxing the pressure, the outline of the figure discharged would become ragged. The passage of the discharge liquor, as well as of the water through the cloth, is occasionally aided by a pneumatic apparatus, or blowing machine; consisting of a large gasometer, from which air subjected to a moderate pressure, may be allowed to issue, and act in the direction of the liquid, upon the folds of the cloth. By an occasional twist of the air stopcock, the workman also can ensure the equal distribution of the discharging liquor, over the whole excavations in the upper plate. When the demand for goods is very brisk, the air apparatus is much employed, as it enables the workman to double his product.

The time requisite for completing the discharging process in the first press is sufficient to enable the other three workmen to put the remaining fifteen presses in play. The discharger proceeds now from press to press, admits the liquor, the air, and the water; and is followed at a proper interval by the assistants, who relax the press, move forwards another square of the cloth, and then restore the pressure. Whenever the sixteenth press has been liquored, &c., it is time to open the first press. In this routine, about ten minutes are employed; that is 224 handkerchiefs (16 × 14) are discharged every ten minutes. The whole cloth is drawn successively forward, to be successively treated in the above method.

When the cloth escapes from the press, it is passed between the two rollers in front; from which it falls into a trough of water placed below. It is finally carried off to the washing and bleaching department, where the lustre of both the white and the red is considerably brightened.

By the above arrangement of presses, 1600 pieces, consisting of 12 yards each = 19,200 yards, are converted into Bandannas in the space of ten hours, by the labour of four workmen.

The patterns, or plates, which are put into the presses to determine the white figures on the cloth, are made of lead in the following way. A trellis frame of cast-iron, one inch thick, with turned-up edges, forming a trough rather larger than the intended lead pattern, is used as the solid ground-work. Into this trough, a lead plate about one half inch thick, is firmly fixed by screw nails passing up from below. To the edges of this lead plate, the borders of the piece of sheet-lead are soldered, which covers the whole outer surface of the iron frame. Thus a strong trough is formed, one inch deep. The upright border gives at once great strength to the plate, and serves to confine the liquor. A thin sheet of lead is now laid on the thick lead-plate, in the manner of a veneer on toilette-tables, and is soldered to it round the edges. Both sheets must be made very smooth beforehand, by hammering them on a smooth stone table, and then finishing with a plane: the surface of the thin sheet (now attached), is to be covered with drawing paper, pasted on, and upon this the pattern is drawn. It is now ready for the cutter. The first thing which he does, is to fix down with brass pins all the parts of the pattern which are to be left solid. He now proceeds with the little tools generally used by block-cutters, which are fitted to the different curvatures of the pattern, and he cuts perpendicularly quite through the thin sheet. The pieces thus detached are easily lifted out; and thus the channels are formed which design the white figures on the red cloth. At the bottom of the channels, a sufficient number of small perforations are made through the thicker sheet of lead, so that the discharging liquor may have free ingress and egress. Thus, one plate is finished; from which, an impression is to be taken by means of printers’ ink, on the paper pasted upon another plate. The impression is taken in the hydrostatic press. Each pair of plates constitutes a set, which may be put into the presses, and removed at pleasure.

BARBERRY. The root of this plant contains a yellow colouring matter, which is soluble in water and alcohol, and is rendered brown by alkalis. The solution is employed in the manufacture of Morocco leather.

BARILLA. A crude soda, procured by the incineration of the _salsola soda_, a plant cultivated for this purpose in Spain, Sicily, Sardinia, &c. Good barilla usually contains, according to my analysis, 20 per cent. of real alkali, associated with muriates and sulphates, chiefly of soda, some lime, and alumina, with very little sulphur. Caustic lyes made from it, are used in the finishing process of the hard soap manufacture. 125,068 cwts. were imported in 1835, of which only 5,807 were exported. The duty is 2_s._ per cwt. Of the above quantity, 64,174 came from Spain and the Balearic islands, 39,943 from the Canaries, and 20,432 from Italy and the Italian islands.

BARIUM, the metallic basis of Baryta.

BARK OF OAK, for tanning. Unfortunately, the Tables of Revenue published by the Board of Trade, mix up this bark and the dyeing barks together, and give the sum of the whole for 1835, at 826,566 cwts., of which only 2,264 were re-exported. The duty is 1_d._ per cwt. from British possessions, and 8_d._ from other parts.

BARLEY (_Orge_, Fr. _Gerste_, Germ.) English barley is that with two-rowed ears, or the _hordeum vulgare distichon_ of the botanists; the Scotch beer or bigg, is the _hordeum vulgare hexastichon_. The latter has two rows of ears, but 3 corns come from the same point, so that it seems to be six-eared. The grains of bigg are smaller than those of barley, and the husks thinner. The specific gravity of English barley varies from 1·25 to 1·33; of bigg from 1·227 to 1·265; the weight of the husk of barley is 1/6, that of bigg 2/9. 1000 parts of barley flour contain, according to Einhof, 720 of starch, 56 sugar, 50 mucilage, 36·6 gluten, 12·3 vegetable albumen, 100 water, 2·5 phosphate of lime, 68 fibrous or ligneous matter. Sp. gravity of barley, is 1·235 by my trials.

BARM. The yeasty top of fermenting beer. See BEER, DISTILLATION, FERMENTATION.

BARYTA or BARYTES, one of the simple earths. It may be obtained most easily by dissolving the native carbonate of barytes (Witherite) in nitric acid, evaporating the neutral nitrate till crystals be formed, draining and then calcining these in a covered platina crucible, at a bright red heat. A less pure baryta may be obtained by igniting strongly a mixture of the carbonate and charcoal, both in fine powder and moistened. It is a grayish white earthy looking substance, fusible only at the jet of the oxy-hydrogen blowpipe, has a sharp caustic taste, corrodes the tongue and all animal matter, is poisonous even in small quantities, has a very powerful alkaline reaction; a specific gravity of 4·0; becomes hot, and slakes violently when sprinkled with water, falling into a fine white powder, called the hydrate of baryta, which contains 10-1/2 per cent. of water, and dissolves in 10 parts of boiling water. This solution lets fall abundant columnar crystals of hydrate of baryta as it cools; but it still retains one twentieth its weight of baryta, and is called baryta water. The above crystals contain 61 per cent. of water, of which, by drying, they lose 50 parts. This hydrate may be fused at a red heat without losing any more water. Of all the bases, baryta has the strongest affinity for sulphuric acid, and is hence employed either in the state of the above water, or in that of one of its neutral salts, as the nitrate or muriate, to detect the presence, and determine the quantity of that acid present in any soluble compound. Its prime equivalent, according to Berzelius, is 956,880, oxygen being 100; or 76,676, hydrogen being 1,000. Native sulphate of baryta, or heavy spar, is fraudulently used to adulterate white lead by the English dealers to a shameful extent.

BASSORINE. A constituent part of a species of gum which comes from Bassora, as also of gum tragacanth, and of some gum resins. It is semi-transparent, difficult to pulverise, swells considerably in cold or boiling water, and forms a thick mucilage without dissolving. Treated with ten times its weight of nitric acid, it affords nearly 23 per cent. of its weight of mucic acid, being much more than is obtainable from gum arabic or cherry-tree gum. Bassorine is very soluble in water slightly acidulated with nitric or muriatic acid. This principle is procured by soaking gum Bassora in a great quantity of cold water, and in removing, by a filter, all the soluble parts.

BATHS. (_Bains_, Fr. _Baden_, Germ.) Warm baths have lately come into very general use, and they are justly considered as indispensably necessary in all modern houses of any magnitude, as also in club-houses, hotels, and hospitals. But the mode of constructing these baths, and of obtaining the necessary supplies of hot and cold water, does not appear to have undergone an improvement equal to the extension of their employment.

The several points in regard to warm baths, are,

1. The materials of which they are constructed.
2. Their situation.
3. The supply of cold water.
4. The supply of hot water.
5. Minor comforts and conveniences.

1. As to the materials of which they are constructed.--Of these the best are slabs of polished marble, properly bedded with good water-tight cement, in a seasoned wooden case, and neatly and carefully united at their respective edges. These, when originally well constructed, form a durable, pleasant, and agreeable-looking bath; but the expense is often objectionable, and, in upper chambers, the weight may prove inconvenient. If of white or veined marble, they are also apt to get yellow or discoloured by frequent use, and cannot easily be cleansed; so that large Dutch tiles, as they are called, or square pieces of white earthenware, are sometimes substituted; which, however, are difficultly kept water-tight; so that, upon the whole, marble is preferable.

Where there are reasons for excluding marble, copper or tinned iron plate is the usual material resorted to. The former is most expensive in the outfit, but far more durable than the latter, which is, moreover, liable to leakage at the joints, unless most carefully made. Either the one or the other should be well covered outside and inside, with several coats of paint, which may then be marbled, or otherwise ornamented.

Wooden tubs, square or oblong, and oval, are sometimes used for warm baths; and are cheap and convenient, but neither elegant nor cleanly. The wood always contracts a mouldy smell; and the difficulty and nuisance of keeping them water-tight, and preventing shrinkage, are such as to exclude them from all except extemporaneous application.

2. As to the situation of the bath, or the part of the house in which it is to be placed.--In hotels, and club-houses, this is a question easily determined: several baths are usually here required, and each should have annexed to it, a properly warmed dressing-room. Whether they are up stairs or down stairs, is a question of convenience, but the basement story, in which they are sometimes placed, should always be avoided; there is a coldness and dampness belonging to it, in almost all weathers, which is neither agreeable nor salubrious.

In hospitals, there should be at least two or three baths on each side of the house, (the men’s and women’s), and the supply of hot water should be ready at a moment’s notice. The rooms in which the baths are placed should be light and comparatively large and airy; and such conveniences for getting into and out of the bath should be adopted, as the sick are well known to require. The dimensions of these baths should also be larger than usual.

In private houses, the fittest places for warm baths are dressing-rooms annexed to the principal bed-rooms; or, where such convenience cannot be obtained, a separate bath-room, connected with the dressing-room, and always upon the bed-room floor. All newly-built houses should be properly arranged for this purpose, and due attention should be paid to the warming of the bath-room, which ought also to be properly ventilated. A temperature of 70° may be easily kept up in it, and sufficient ventilation is absolutely requisite, to prevent the deposition of moisture upon the walls and furniture.

The objection which formerly prevailed, in respect to the difficulty of obtaining adequate supplies of water, in the upper rooms, has been entirely obviated, by having cisterns at or near the top of the house; and we would just hint that these should be so contrived, as to be placed out of the reach of frost; a provision of the utmost importance in every point of view, and very easily effected in a newly-built house, though it unfortunately happens, that architects usually regard these matters as trifles, and treat them with neglect, as indeed they do the warming and ventilation of buildings generally.

3. The supply of water of proper quality and quantity, is a very important point, as connected with the present subject. The water should be soft, clean, and pure; and as free as possible from all substances mechanically suspended in it. In many cases, it answers to dig a well for the exclusive supply of a large house with water. In most parts of London this may effectually be accomplished, at a comparatively moderate expense; and, if the well be deep enough, the water will be abundant, soft, and pellucid. The labour of forcing it by a pump to the top of the house, is the only drawback; this, however, is very easily done by a horse-engine, or there are people enough about town, glad to undertake it at a shilling a day. I am led to these remarks by observing the filthy state of the water usually supplied, at very extravagant rates, by the water companies. It often partakes more of the appearance of pea-soup than of the pure element; fills our cisterns and pipes with mud and dirt, and, even when cleared by subsidence, is extremely unpalatable. It deposits its nastiness in the pipes connected with warm baths, and throws down a slippery deposit upon the bottom of the vessel itself to such an extent, as often to preclude its being used, at least as a luxury, which a clear and clean bath really is. This inconvenience may, in some measure, be avoided, by suffering the water to throw down its extraneous matters upon the bottom of the cistern, and drawing our supplies from pipes a little above it; there will, however, always be more or less deposit in the pipes themselves; and every time the water runs into the cistern, the grouts are stirred up, and diffused through its mass: this, from some cause or other, has lately become an intolerable nuisance; and he who reflects upon the miscellaneous contents of Thames water, will not have his appetite sharpened by a draught of the Grand Junction beverage, nor feel reanimated and refreshed by bathing in a compound so heterogeneous and unsavoury.

4. and 5. In public bathing establishments, where numerous and constant baths are required, the simplest and most effective means of obtaining hot water for their supply consists in drawing it directly into the baths from a large boiler, placed somewhere above their level. This boiler should be supplied with proper feeding-pipes and gauges; and, above all things, its dimensions should be ample; it should be of wrought iron or copper, except where sea water is used, in which case the latter metal is sometimes objectionable. The hot water should enter the bath by a pipe at least an inch and a half in diameter; and the cold water by one of the same dimension, or somewhat larger, so that the bath may not be long in filling. The relative proportions of the hot and cold water are, of course, to be adjusted by a thermometer, and every bath should have a two-inch waste-pipe, opening about two inches from the top of the bath, and suffering the excess of water freely to run off; so that when a person is immersed in the bath, or when the supplies of water are accidentally left open, there may be no danger of an overflow.

Where there is a laundry in the upper story of the house, or other convenient place for erecting a copper and its appurtenances, a plan similar to the above may often be conveniently adopted in private houses, for the supply of a bath upon the principal bed-room floor. An attempt is sometimes made to place boilers behind the fires of dressing-rooms, or otherwise to erect them in the room itself, for the purpose of supplying warm water; but this plan is always objectionable, from the complexity of the means by which the supply of water is furnished to the boiler, and often dangerous from the flues becoming choaked with soot, and taking fire. Steam is also apt, in such cases, to escape in quantities into the room; so that it becomes necessary to search for other methods of heating the bath; one or two of the least objectionable of which I shall describe.

1. A contrivance of some ingenuity consists in suffering the water for the supply of the bath to flow from a cistern above it, through a leaden pipe of about one inch diameter, which is conducted into the kitchen or other convenient place where a large boiler for the supply of hot water is required. The bath-pipe is immersed in this boiler, in which it makes many convolutions, and, again emerging, ascends to the bath. The operation is simply this:--the cold water passing through the convolutions of that part of the pipe which is immersed in the boiling water, receives there sufficient heat for the purpose required, and is delivered in that state by the ascending pipe into the bath, which is also supplied with cold water and waste-pipes as usual. The pipe may be of lead, as far as the descending and ascending parts are concerned, but the portion forming the worm, or convolutions immersed in the boiler should be copper, in order that the water within it may receive heat without impediment.

This plan is economical only where a large boiler is constantly kept at work in the lower part of the house; otherwise, the trouble and expense of heating such a boiler, for the mere purpose of the bath, render it unavailable. The worm-pipe is also apt to become furred, upon the outside, by the deposition of the earthy impurities of the water in which it is immersed; it then becomes a bad conductor of heat, is cleansed with difficulty, and the plan is rendered ineffective. This system, however, has been adopted, in some particular cases, with satisfaction.

2. A much more simple, economical, and independent mode of heating a warm bath, by a fire placed at a distance from it, is the following, which is found to answer perfectly in private houses, as well as upon a more extended scale in large establishments. It is certainly open to some objections, but these are overbalanced by its advantages. A waggon-shaped boiler, holding about six gallons of water, is properly placed over a small furnace, in any convenient and safe part of the house, as the kitchen, scullery, servants’ hall, or wash-house. The bath itself, of the usual dimensions and construction, is placed where it is wanted, with a due supply of cold water from above. Two pipes issue from within an inch of the bottom of the bath at its opposite extremities; one at the head of the bath, about one inch, and the other at the foot, an inch and one eighth in diameter. These tubes descend to the boiler, the smaller one entering it at the bottom, and the larger one issuing from its top.

Under these circumstances, supposing the pipes and boiler every where perfectly tight, when the bath is filled, the water will descend into and expel the air from the boiler, and completely fill it. Now, upon making a gentle fire under the boiler, an ascending current of warm water will necessarily pass upwards through the larger pipe which issues from its top, and cold water will descend by the pipe which enters at the bottom; and thus, by the establishment of currents, the whole mass of water in the bath will become heated to the desired point; or, if above it, the temperature may easily be lowered by the admixture of cold water.

The advantages of this form of bath are numerous. The shorter the pipes of communication the better, but they may extend forty or fifty feet without any inconvenience beyond that of expense; so that there is no obstacle to the bath being near the bed-room while the boiler is on the basement story. There is but little time required for heating the bath; the water in which may, if requisite, be raised to about 100° in about half an hour from the time of lighting the fire. The consumption of fuel is also trifling.

The following are the chief disadvantages attendant upon this plan, and the means of obviating them:--

It is necessary, when the water has acquired its proper temperature, to withdraw the fire from the boiler, or not to use the bath immediately, as it may go on acquiring some heat from the boiler, so that we may become inconveniently hot in the bath. When, therefore, this bath is used, we may proceed as follows:--heat the water in it an hour before it is wanted, to about 100°, and then extinguish the fire. The water will retain its temperature, or nearly so, for three or four hours, especially if the bath be shut up with a cover; so that when about to use it, cold water may be admitted till the temperature is lowered to the required point, and thus all the above inconveniences are avoided.

Another disadvantage of this bath arises from too fierce a fire being made under the boiler, so as to occasion the water to boil within it, a circumstance which ought always to be carefully avoided. In that case, the steam rising in the upper part of the boiler, and into the top pipe, condenses there, and occasions violent concussions, the noise of which often alarms the whole house, and leads to apprehensions of explosion, which, however, is very unlikely to occur; but the concussions thus produced injure the pipes, and may render them leaky: so that in regard to these, and all other baths, &c., we may remark, that the pipes should pass up and down in such parts of the house as will not be injured if some leakage takes place; and under the bath itself should be a sufficiently large leaden tray with a waste-pipe, to receive and carry off any accidental drippings, which might injure the ceilings of the rooms below. In all newly-built houses, two or three flues should be left in proper places for the passage of ascending and descending water-pipes; and these flues should in some way receive at their lower part a little warm air in winter, to prevent the pipes freezing: the same attention should also be paid to the situation of the cisterns of water in houses, which should be kept within the house, and always supplied with a very ample waste-pipe, to prevent the danger of overflow. Cisterns thus properly placed, and carefully constructed, should be supplied from the water-mains by pipes kept under ground, till they enter the house, and not carried across the area, or immediately under the pavement, where they are liable to freeze.

3. Baths are sometimes heated by steam, which has several advantages: it may either be condensed directly into the water of the bath, or, if the bath be of copper or tinned iron, it may be conducted into a casing upon its outside, usually called a jacket; in the latter case there must be a proper vent for the condensed water, and for the escape of air and waste steam. Steam is also sometimes passed through a serpentine pipe, placed at the bottom of the bath. But none of these methods are to be recommended for adoption in private houses, and are only advisable in hospitals, or establishments where steam boilers are worked for other purposes than the mere heating of baths.

Many copper and tin baths have been lately constructed in London, with a little furnace attached to one end, and surrounded with a case or jacket, into which the water flows and circulates backwards and forwards till the whole mass in the bath gets heated to the due degree. One of the best of these is that constructed by Mr. Benham, of Wigmore Street. The bath must be placed near the fire-grate, and the smoke-pipe of the attached furnace be conducted up the chimney a certain way to secure a sufficient draught to maintain combustion. The above bath, well managed, heats the water from 50° to 98° in about 20 or 25 minutes, as I have experimentally proved. When the proper temperature is attained, the fire must of course be extinguished.

BDELLIUM. A gum resin, produced by an unknown plant which grows in Persia and Arabia. It comes to us in yellowish or reddish pieces, smells faintly, like myrrh, and consists of 59 resin, 9·2 gum, 30·6 bassorine, and 1·2 ethereous oil.

BEER. (_Bière_, Fr. _Bier_, Germ.) The fermented infusion of malted barley, flavoured with hops, constitutes the best species of beer; but there are many beverages of inferior quality to which this name is given, such as spruce beer, ginger beer, molasses beer, &c.; all of which consist of a saccharine liquor, partially advanced into the vinous fermentation, and flavoured with peculiar substances.

The ancients were acquainted with beer, and the Romans gave it the appropriate name of _Cerevisia_ (quasi _Ceresia_), as being the product of corn, the gift of Ceres. The most celebrated liquor of this kind in the old time, was the _Pelusian_ potation, so called from the town where it was prepared at the mouth of the Nile. Aristotle speaks of the intoxication caused by beer; and Theophrastus very justly denominated it the _wine of barley_. We may, indeed, infer from the notices found in historians, that drinks analogous to our beer were in use among the ancient Gauls, Germans, and in fact almost every people of our temperate zone; and they are still the universal beverage in every land where the vine is not an object of rustic husbandry.

The manufacture of beer, or the art of brewing, may be conveniently considered under five heads:--

1. An examination of the natural productions which enter into its composition; or of barley and hops.

2. The changes which barley must undergo to fit it for making beer; or the processes of malting and mashing.

3. The formation of a proper wort from the mashed malt and hops.

4. The fermentation of that wort; and

5. The fining, ripening, and preservation of the beer.

I. _Of the materials._

1. Barley, wheat, maize, and several other kinds of corn are capable of undergoing those fermentative changes, by which beer may be made; but the first substance is by far the fittest. There are two species of barley, the _hordeum vulgare_ or common barley, having two seeds arranged in a row on its spikes; and the _hordeum hexastichon_, in which three seeds spring from one point, so that its double row has apparently six seeds. The former is the proper barley, and is much the larger sized grain; the latter is little known in England, but is much cultivated in Scotland under the name of _bear_ or _big_; being a hardy plant adapted to a colder country. The finer the climate in which barley grows the denser and larger its seed, and the thinner its husk; thus the Norfolk and Suffolk barley is distinguished in these respects from that of Aberdeenshire. Big is a less compact grain than barley; the weight of a Winchester bushel (2150·42 cubic inches) of the former is only about 47 libs, while that of a bushel of the latter is nearly 51 libs. Their constituents, however, bear much the same proportion to each other.

The quality of barley is proved not only by its density when dry, but by the increase of volume which it acquires when steeped in water. Thus,

100 measures of average English barley thereby swell into 124.
100 -- of -- Scotch ditto, 121.
100 -- of -- -- bigg or bear, 118.
Nay, 100 of very fine Suffolk barley have swollen into 183.
While 100 of an inferior Scotch bigg became no more than 109.

This circumstance indicates so nearly the probable yield of malt, that it is carefully attended to by the officers of excise, who gauge the steep cistern, and levy their duty in conformity with the largest volume, 100 pounds of good barley become almost one half heavier by the absorption of moisture; and weigh upon an average 147 pounds; the best of course taking up most water.

By chemical analysis barley flour seems to consist of 67·18 parts of hordeine, or starch and gluten intimately combined, 7·29 of vegetable fibre, 1·15 of coagulated albumen, 3·52 parts of gluten, 5·21 of sugar, 4·62 of gum, 0·24 of phosphate of lime, and 9·37 of water. The loss amounted to 1·42. To these principles should be added a peculiar volatile oil of a concrete nature, which is obtained during the process of distilling fermented malt wash. (See WHISKEY.) It may also be extracted from barley flour, by the solvent action of alcohol; and never amounts to more than a few parts in the thousand. The husk also contains some of that fetid oil. Proust thought that he had discovered in barley a peculiar principle, to which he gave the name of _hordeine_, and which he separated from starch by the action of both cold and boiling water. He found that by treating barley meal successively with water, he obtained from 89 to 90 parts of a farinaceous substance, composed of from 32 to 33 of starch, and from 57 to 58 of _hordeine_. Einhof obtained from barley seeds, 70·05 of flour, 18·75 of husks or bran, and 11·20 of water.

According to Proust hordeine is a yellowish powder, not unlike fine saw-dust. It contains no azote, for it affords no ammonia by distillation, and is therefore very dissimilar to gluten. In the germination of barley, which constitutes the process of malting, the proportion of hordeine is greatly diminished by its conversion into sugar and starch. Other chemists suppose that the _hordeine_ of Proust is merely a mixture of the bran of the barley with starch and gluten. It is obvious that the subject stands in need of new chemical researches. In barley the husk constitutes from one fourth to one fifth of the whole weight; in oats it constitutes one third; and in wheat, one tenth. From the analysis of barley flour recently made, it appears to consist in 1000 parts: of water, 100; albumine, 22·3; sugar, 56; gum or mucilage, 50; gluten, 37·6; starch, 720; phosphate of lime, 2·5.

2. The hop, _humulus lupulus_, the female flowers of the plant. Ives first directed attention to a yellow pulverulent substance which invests the scales of the catkins, amounting to about one eighth of their weight; and referred to it the valuable properties which hops impart to beer. We may obtain this substance by drying the hops at a temperature of 86° F., introducing them into a coarse canvass bag, and shaking it so that the yellow powder shall pass through the pores of the canvass. This powder bears some resemblance to lycopodium. Of the 13 parts in 100 of this powder, 4 parts are foreign matters, derived from the scales of the cones; leaving 9 parts of a peculiar granular substance. When distilled with water, this substance affords two per cent. of its weight (2/10 for 100 times the weight of hops) of a volatile colourless oil, to which the plant owes its peculiar aroma. This oil dissolves in water in considerable quantity. It appears to contain sulphur (for it blackens solutions of silver), and also acetate of ammonia. No less than 65 per cent. of the yellow dust is soluble in alcohol. This solution, treated with water and distilled, leaves a resin, which amounts to 52·5 per cent. It has no bitter taste, and is soluble in alcohol and ether. The watery solution from which the resin was separated contains the bitter substance which has been called _lupuline_ by Payen and Chevallier, mixed with a little tannin and malic acid. To obtain this in a state of purity, the free acid must be saturated with lime, the solution evaporated to dryness, and the residuum must be treated with ether, which removes a little resin; after which the _lupuline_ is dissolved out by alcohol, which leaves the malate of lime. On evaporating away the alcohol, the lupuline remains, weighing from 8·3 to 12·5 per cent. It is sometimes white, or slightly yellowish, and opaque, sometimes orange yellow, and transparent. At ordinary temperatures it is inodorous, but when heated strongly it emits the smell of hops. It possesses the characteristic taste and bitterness of the hop. Water dissolves it only in the proportion of 5 per cent., but it thereby acquires a pale yellow colour. Lupuline is neither acid nor alkaline; it is acted upon neither by the dilute acids nor alkalies, nor by the solutions of the metallic salts: it is quite soluble in alcohol, but hardly in ether. It contains apparently no azote, for it affords no ammonia by destructive distillation; but only an empyreumatic oil.

The yellow dust of hops contains, moreover, traces of a fatty matter, gum, a small quantity of an azotised substance, and several saline combinations in minute quantity. Boiling water dissolves from 19 to 31 per cent., of the contents of the dust, of which a large proportion is resin. Ives thought that the scales of the catkins of hops, when freed from the yellow powder, contained no principles analogous to it; but Payen and Chevallier have proved the contrary. The cones of hop give up to boiling alcohol 36 per cent. of soluble matter; while the same cones, stripped of their yellow powder, yield only 26 per cent.; and further, these chemists found the same principles in the different parts of the hop, but in different proportions.

The packing of the hop catkins or cones is one of the most important operations towards the preservation of this plant; and is probably the cause of the enormous difference in value between the English and French hops after a few years’ keeping. The former, at the end of six years, possess still great value, and may be sold as an article only two or three years old; while the latter have lost the greater part of their value in three years, and are no more saleable at the end of four. In France, it is packed merely by tramping it with the feet in sacks. Under this slight pressure, large interstitial spaces are left amid the mass of the hops, through which the air freely circulates, carrying off the essential oil, and oxygenating some of the other proximate principles, so as to render them inert. By the English method, on the contrary, the hops, after being well rammed into strong sacks hung in frames, are next subjected to the action of a hydraulic press. The valuable yellow powder thus inclosed on every side by innumerable compact scales, is completely screened from the contact of the atmosphere, and from all its vicissitudes of humidity. Its essential oil, in particular the basis of its flavour, is preserved without decay.

According to the experiments of Chevallier and Payen upon the hops of England, Flanders, the Netherlands, and the department of the Vosges, those of the county of Kent afforded the largest cones, and were most productive in useful secreted and soluble matters. Next to them were the hops of Alost.

The best hops have a golden yellow colour, large cones, an agreeable aroma; when rubbed between the hands, they leave yellow traces, powerfully odoriferous, without any broken portions of the plant, such as leaves, stems, and scaly fragments. When alcohol is digested on good hops, from 9 to 12 per cent. of soluble yellow matter may be obtained by evaporating it to dryness. This is a good test of their quality.

The best-flavoured and palest hops are packed in sacks of fine canvass, which are called pockets, and weigh about 1-1/2 cwt. each. These are bought by the ale brewer. The stronger-flavoured and darker-coloured hops are packed in bags of a very coarse texture like door-mats, called hop bags: these contain generally about 3 cwt., and are sold to the porter and beer brewers. After the end of a year or two, hops are reckoned to have lost much of their marketable value, and are then sold to the second-rate porter brewers, under the name of old hops. The finest hops are grown in the neighbourhood of Canterbury; but those of Worcester have an agreeable mildness of flavour, greatly admired by many ale drinkers. When the bitter and aromatic principles disappear, the hops are no better than so much chaff; therefore, an accurate chemical criterion of their principles would be a great benefit to the brewer.

II. _Malting._--This process consists of three successive operations; the steeping; the couching, sweating, and flooring; and the kiln-drying.

The _steeping_ is performed in large cisterns made of wood or stone, which being filled with clear water up to a certain height, a quantity of barley is shot into them, and well stirred about with rakes. The good grain is heavy, and subsides; the lighter grains, which float on the surface, are damaged, and should be skimmed off; for they would injure the quality of the malt, and the flavour of the beer made with it. They seldom amount to more than two per cent. More barley is successively emptied into the steep cistern, till the water stands only a few inches, about five, above its surface; when this is levelled very carefully, and every light seed is removed. The steep lasts from forty to sixty hours, according to circumstances; new barley requiring a longer period than old, and bigg requiring much less time than barley.

During this steep, some carbonic acid is evolved from the grains, and combines with the water, which, at the same time, acquires a yellowish tinge, and a strawy smell, from dissolving some of the extractive matter of the barley husks. The grain imbibes about one half its weight of water, and increases in size by about one-fifth. By losing this extract, the husk becomes about one seventieth lighter in weight, and paler in colour.

The duration of the steep depends, in some measure, upon the temperature of the air, and is shorter in summer than in winter. In general from 40 to 48 hours will be found sufficient for sound dry grain. Steeping has for its object to expand the farina of the barley with humidity, and thus prepare the seed for germination, in the same way as the moisture of the earth prepares for the growth of the radicle and plumula in seed sown in it. Too long continuance in the steep is injurious; because it prevents the germination at the proper time, and thereby exhausts a portion of the vegetative power: it causes also an abstraction of saccharine matter by the water. The maceration is known to be complete when the grain may be easily transfixed with a needle, and is swollen to its full size. The following is reckoned a good test:--If a barley-corn, when pressed between the thumb and fingers, continues entire in its husk, it is not sufficiently steeped; but if it sheds its flour upon the fingers, it is ready. When the substance exudes in the form of a milky juice, the steep has been too long continued, and the barley is spoiled for germination.

In warm weather it sometimes happens that the water becomes acescent before the grain is thoroughly swelled. This accident, which is manifest to the taste and smell, must be immediately obviated by drawing off the foul water through the tap at the bottom of the cistern, and replacing it with fresh cold water. It does no harm to renew it two or three times at one steep.

The _couch_.--The water being drawn off, and occasionally a fresh quantity passed through, to wash away any slimy matter which may have been generated in warm weather, the barley is now laid upon the couch floor of stone flags, in square heaps from 12 to 16 inches high, and left in that position for 24 hours. At this period, the bulk of the grain being the greatest, it may be gauged by the revenue officers if they think fit. The moisture now leaves the surface of the barley so completely, that it imparts no dampness to the hand. By degrees, however, it becomes warm; the temperature rising 10° above the atmosphere, while an agreeable fruity smell is evolved. At this time, if the hand be thrust into the heap, it not only feels warm, but it gets bedewed with moisture. At this sweating stage, the germination begins; the fibrils of the radicle first sprout forth from the tip of every grain, and a white elevation appears, that soon separates into three or more radicles, which grow rapidly larger. About a day after this appearance, the plumula peeps forth at the same point, proceeding thence beneath the husk to the other end of the seed, in the form of a green leaflet.

The greatest heat of the couch is usually about 96 hours after the barley has been taken out of the steep. In consequence, the radicles tend to increase in length with very great rapidity, and must be checked by artificial means, which constitute the chief art of the maltster. He now begins to spread the barley thinner on the floor, and turns it over several times in the course of a day, bringing the portions of the interior into the exterior surface. The depth, which was originally 15 or 16 inches, is lowered a little at every turning over, till it be brought eventually down to three or four inches. Two turnings a day are generally required. At this period of spreading or flooring, the temperature in England is about 62°, and in Scotland 5 or 6 degrees lower.

About a day after the radicles appear, the rudiments of the stem, or of the plumula, sprout forth, called by the English maltsters the _acrospire_. It issues from the same end of the seed as the radicle, but turns round, and proceeds within the husk towards the other end, and would there come forth as a green leaf, were its progress not arrested. The malting, however, is complete before the acrospire becomes a leaf.

The barley couch absorbs oxygen and emits carbonic acid, just as animals do in breathing, but to a very limited extent; for the grain loses only three per cent. of its weight upon the malt floor, and a part of this loss is due to waste particles. As the acrospire creeps along the surface of the seed, the farina within undergoes a remarkable alteration. The gluten and mucilage disappear, in a great measure, the colour becomes whiter, and the substance becomes so friable that it crumbles into meal between the fingers. This is the great purpose of malting, and it is known to be accomplished when the plumula or acrospire has approached the end of the seed. Now the further growth must be completely stopped. Fourteen days may be reckoned the usual duration of the germinating stage of the malting operations in England; but in Scotland, where the temperature of the couch is lower, eighteen days or even twenty-one, are sometimes required. The shorter the period within the above limits, the more advantageous is the process to the maltster, as he can turn over his capital the sooner, and his malt is also somewhat the better. Bigg is more rapid in its germination than barley, and requires to be still more carefully watched. In dry weather it is sometimes necessary to water the barley upon the couch.

Comments

Log in to leave a comment.

A Dictionary of Arts, Manufactures and MinesChapter C: C C C, fig. 60., is a horizontal section of the furnace over the (3)

0%37 min left in chapter