Chapter II: Application of Light-Gas (38)

To the beak of the retort properly inclined, the one end of a bent copper tube is to be tightly luted, while the other end is plunged not more than one quarter of an inch beneath the surface of water contained in a small copper or tin trough placed beneath, close to the side of the furnace, or in a wide-mouthed bottle. It is of advantage to let the water be somewhat warm, in order to prevent the concretion of the phosphorus in the copper tube, and the consequent obstruction of the passage. Should the beak of the retort appear to get filled with solid phosphorus, a bent rod of iron may be heated, and passed up the copper tube, without removing its end from the water. The heat of the furnace should be most slowly raised at first, but afterwards equably maintained in a state of bright ignition. After 3 or 4 hours of steady firing, carbonic acid and sulphurous acid gases are evolved in considerable abundance, provided the materials had not been well dried in the iron pot; then sulphuretted hydrogen makes its appearance, and next phosphuretted hydrogen, which last should continue during the whole of the distillation.

The firing should be regulated by the escape of this remarkable gas, which ought to be at the rate of about 2 bubbles per second. If the discharge comes to be interrupted, it is to be ascribed either to the temperature being too low, or to the retort getting cracked; and if upon raising the heat sufficiently no bubbles appear, it is a proof that the apparatus has become defective, and that it is needless to continue the operation. In fact, the great nicety in distilling phosphorus lies in the management of the fire, which must be incessantly watched, and fed by the successive introduction of fuel, consisting of coke with a mixture of dry wood and coal.

We may infer that the process approaches its conclusion by the increasing slowness with which gas is disengaged under a powerful heat; and when it ceases to come over, we may cease firing, taking care to prevent reflux of water into the retort, from condensation of its gaseous contents, by admitting air into it through a recurved glass tube, or through the lute of the copper adopter.

The usual period of the operation upon the great scale is from 24 to 30 hours. Its theory is very obvious. The charcoal at an elevated temperature disoxygenates the phosphoric acid with the production of carbonic acid gas at first, and afterwards carbonic oxide gas, along with sulphuretted, carburetted, and phosphuretted hydrogen, from the reaction of the water present in the charcoal upon the other ingredients.

The phosphorus falls down in drops, like melted wax, and concretes at the bottom of the water in the receiver. It requires to be purified by squeezing in a shamoy leather bag, while immersed under the surface of warm water, contained in an earthen pan. Each bag must be firmly tied into a ball form, of the size of the fist, and compressed, under the water heated to 130°, by a pair of flat wooden pincers, like those with which oranges are squeezed.

The purified phosphorus is moulded for sale into little cylinders, by melting it at the bottom of a deep jar filled with water, then plunging the wider end of a slightly tapering but straight glass tube into the water, sucking this up to the top of the glass, so as to warm it, next immersing the end in the liquid phosphorus, and sucking it up to any desired height.

The tube being now shut at bottom by the application of the point of the left index, may be taken from the mouth and transferred into a pan of cold water to congeal the phosphorus; which then will commonly fall out of itself, if the tube be nicely tapered, or may at any rate be pushed out with a stiff wire. Were the glass tube not duly warmed before sucking up the phosphorus, this would be apt to congeal at the sides, before the middle be filled, and thus form hollow cylinders, very troublesome and even dangerous to the makers of phosphoric match-bottles. The moulded sticks of phosphorus are finally to be cut with scissors under water to the requisite lengths, and put up in phials of a proper size; which should be filled up with water, closed with ground stoppers, and kept in a dark place. For carriage to a distance, each phial should be wrapped in paper, and fitted into a tin-plate case.

Phosphorus has a pale yellow colour, is nearly transparent, brittle when cold, soft and pliable, like wax, at the temperature of 70° F., crystallizing in rhombo-dodecahedrons out of its combination with sulphur, and of specific gravity 1·77. It exhales white fumes in the air, which have a garlic smell, appear luminous in the dark, and spontaneously condense into liquid phosphorous acid. Phosphorus melts in close vessels, at 95°. F., into an oily-looking colourless fluid, begins to evaporate at 217·5°, boils at 554°, and if poured in the liquid state into ice-cold water, it becomes black, but resumes its former colour when again melted and slowly cooled. It has an acrid disagreeable taste, and acts deleteriously in the stomach, though it has been administered as a medicine by some of the poison-doctors of the present day. It takes fire in the open air at the temperature of 165°, but at a lower degree if partially oxidized, and burns with great vehemence and splendour.

Inflammable match-boxes (_briquets phosphoriques_) are usually prepared by putting into a small phial of glass or lead a bit of phosphorus, and oxidizing it slightly by stirring it round with a redhot iron wire. The phial should be unstoppered only at the instant of plunging into it the tip of the sulphur match which we wish to kindle. Bendix has given the following recipe for charging such match-phials. Take one part of fine dry cork raspings, one part of yellow wax, eight parts of petroleum, and four of phosphorus, incorporate them by fusion, and when the mixture has concreted by cooling, it is capable of kindling a sulphur match dipped into it. Phosphorus dissolves in fat oils, forming a solution luminous in the dark at ordinary temperatures. A phial half filled with this oil, being shaken and suddenly uncorked, will give light enough to see the dial of a watch by night.

There are five combinations, of phosphorus and oxygen:--1. the white oxide; 2. the red oxide; 3. hypophosphorous acid; 4. phosphorous acid; 5. phosphoric acid. The last is the only one of interest in the arts. It may be obtained from the syrupy superphosphate of lime above described, by diluting it with water, saturating with carbonate of ammonia; evaporating, crystallizing, and gently igniting the salt in a retort. The ammonia is volatilized, and may be condensed into water by a Woulfe’s apparatus, while the phosphoric acid remains in the bottom of the retort. Phosphoric acid may be more readily produced by burning successive bits of phosphorus in a silver saucer, under a great bell jar inverted upon a glass plate, so as to admit a little air to carry on the combustion. The acid is obtained in a fine white snowy deposit; consisting, in this its dry state, of 44 of phosphorus and 56 of oxygen. That obtained from the syrupy solution is a hydrate, and contains 9·44 per cent. of water. If the atom of phosphorus be called 32 upon the hydrogen radix, then 5 atoms of oxygen = 40 will be associated with it in the dry acid, = 72; and an additional atom of water = 9, in the hydrate, will make its prime equivalent 81. Phosphorous acid seems to contain no more than 3 atoms of oxygen.

The only salts of this acid much in demand, are the phosphate of soda, and the ammonia phosphate of soda. The former is prepared by slightly supersaturating superphosphate of lime with crystals of carbonate of soda; warming the solution, filtering, evaporating, and crystallizing. It is an excellent purgative, and not unpalatable. The triple phosphate is used in docimastic operations; and is described under METALLURGY.

PICAMARE, is a thick oil, one of the six new principles detected by M. Reichenbach, in wood-tar. See CREOSOTE and PARAFFINE. Picamare constitutes 1-6th of beech-tar.

PICROMEL, is the name given by M. Thenard to a black bitter principle which he supposed to be peculiar to the bile. MM. Gmelin and Tiedemann have since called its identity in question.

PICROTOXINE, is an intensely bitter poisonous vegetable principle, extracted from the seeds of the _Menispermum cocculus_, (Cocculus Indicus). It crystallizes in small white needles, or columns; dissolves in water and alcohol. It does not combine with acids, but with some bases, and is not therefore of an alkaline nature, as had been at first supposed.

PIGMENTS, VITRIFIABLE, belong to five different styles of work: 1. to enamel painting; 2. to painting on metals; 3. to painting on stoneware; 4. to painting on porcelain; 5. to stained glass.

PIMENTO; _Myrtus pimenta_, or Jamaica pepper; consists, according to Bonastre’s complicated analysis, of:--

+--------------------------------+---------+--------+
| |Shells or|Kernels.|
| |Capsules.| |
+--------------------------------+---------+--------+
|Volatile oil | 10·0 | 5·0 |
|Soft green resin | 8·0 | 2·5 |
|Fatty concrete oil | 0·9 | 1·2 |
|Extract containing tannin | 11·4 | 39·8 |
|Gum | 3·0 | 7·2 |
|Brown matter dissolved in potash| 4·0 | 8·0 |
|Resinoid matter | 1·2 | 3·2 |
|Extract containing sugar | 3·0 | 8·0 |
|Gallic and malic acids | 0·6 | 1·6 |
|Vegetable fibre | 50·0 | 16·0 |
|Ashes charged with salts | 2·8 | 1·9 |
|Moisture and loss | 4·1 | 4·8 |
+--------------------------------+---------+--------+

Pimento imported for home consumption, in 1835. 1836.
Duty--British possessions, 5_d._; foreign,
1_s._ 3_d._ Lbs. 344,458. 400,914.

PINCHBECK, is a modification of brass; see that article and COPPER.

PINE-APPLE YARN and CLOTH. In Mr. Zincke’s process, patented in December, 1836, for preparing the filaments of this plant, the _Bromelia ananas_, the leaves being plucked, and deprived of the prickles round their edges by a cutting instrument, are then beaten upon a wooden block with a wooden mallet, till a silky-looking mass of fibres be obtained, which are to be freed by washing from the green fecula. The fibrous part must next be laid straight, and passed between wooden rollers. The leaves should be gathered between the time of their full maturity and the ripening of the fruit. If earlier or latter, the fibres will not be so flexible, and will need to be cleared by a boil in soapy water for some hours; after being laid straight under the pressure of a wooden grating, to prevent their becoming entangled. When well washed and dried, with occasional shaking out, they will now appear of a silky fineness. They may be then spun into porous rovings, in which state they are most conveniently bleached by the ordinary methods.

Specimens of cambric, both bleached and unbleached, woven with these fibres, have been recently exhibited, which excited hopes of their rivalling the finest flax fabrics, but in my opinion without good reason, on account of their want of strength.

PINEY TALLOW, is a concrete fat obtained by boiling with water the fruit of the _Vateria indica_, a tree common upon the Malabar coast. It seems to be a substance intermediate between tallow and wax; partaking of the nature of stearine. It melts at 97-1/2° F., is white or yellowish, has a spec. grav. of 0·926; is saponified by alkalies, and forms excellent candles. Dr. Benjamin Babington, to whom we are indebted for all our knowledge of piney tallow, found its ultimate constituents to be, 77 of carbon, 12·3 of hydrogen, and 10·7 of oxygen.

PIN MANUFACTURE. (_Fabrique d’épingles_, Fr.; _Nadelfabrik_, Germ.) A pin is a small bit of wire, commonly brass, with a point at one end, and a spherical head at the other. In making this little article, there are no less than fourteen distinct operations.

1. _Straightening the wire._ The wire, as obtained from the drawing-frame, is wound about a bobbin or barrel, about 6 inches diameter, which gives it a curvature that must be removed. The straightening engine is formed by fixing 6 or 7 nails upright in a waving line on a board, so that the void space measured in a straight line between the first three nails may have exactly the thickness of the wire to be trimmed; and that the other nails may make the wire take a certain curve line, which must vary with its thickness. The workman pulls the wire with pincers through among these nails, to the length of about 30 feet, at a running draught; and after he cuts that off, he returns for as much more; he can thus finish 600 fathoms in the hour. He next cuts these long pieces into lengths of 3 or 4 pins. A day’s work of one man amounts to 18 or 20 thousand dozen of pin-lengths.

2. _Pointing_, is executed on two iron or steel grindstones, by two workmen, one of whom roughens down, and the other finishes. Thirty or forty of the pin wires are applied to the grindstone at once, arranged in one plane, between the two forefingers and thumbs of both hands, which dexterously give them a rotatory movement.

3. _Cutting these wires into pin-lengths._ This is done by an adjusted chisel. The intermediate portions are handed over to the _pointer_.

4. _Twisting of the wire for the pin-heads._ These are made of a much finer wire, coiled into a compact spiral, round a wire of the size of the pins, by means of a small lathe constructed for the purpose.

5. _Cutting the heads._ Two turns are dexterously cut off for each head, by a regulated chisel, A skilful workman may turn off 12,000 in the hour.

6. _Annealing the heads._ They are put into an iron ladle, made redhot over an open fire, and then thrown into cold water.

7. _Stamping or shaping the heads._ This is done by the blow of a small ram, raised by means of a pedal lever and a cord. The pin-heads are also fixed on by the same operative, who makes about 1500 pins in the hour, or from 12,000 to 15,000 per diem; exclusive of one-thirteenth, which is always deducted for waste in this department, as well as in the rest of the manufacture. Cast heads, of an alloy of tin and antimony, were introduced by patent, but never came into general use.

8. _Yellowing or cleaning the pins_, is effected by boiling them for half an hour in sour beer, wine lees, or solution of tartar; after which they are washed.

9. _Whitening or tinning._ A stratum of about 6 pounds of pins is laid in a copper pan, then a stratum of about 7 or 8 pounds of grain tin; and so alternately till the vessel be filled; a pipe being left inserted at one side, to permit the introduction of water slowly at the bottom, without deranging the contents. When the pipe is withdrawn, its space is filled up with grain tin. The vessel being now set on the fire, and the water becoming hot, its surface is sprinkled with 4 ounces of cream of tartar; after which it is allowed to boil for an hour. The pins and tin grains are, lastly, separated by a kind of cullender.

10. _Washing the pins_, in pure water.

11. _Drying and polishing them_, in a leather sack filled with coarse bran, which is agitated to and fro by two men.

12. _Winnowing_, by fanners.

13. _Pricking the papers_ for receiving the pins.

14. _Papering_, or fixing them in the paper. This is done by children, who acquire the habit of putting up 36,000 per day.

The pin manufacture is one of the greatest prodigies of the division of labour; it furnishes 12,000 articles for the sum of three shillings, which have required the united diligence of fourteen skilful operatives.

The above is an outline of the mode of manufacturing pins by hand labour, but several beautiful inventions have been employed to make them entirely or in a great measure by machinery; the consumption for home sale and export amounting to 15 millions daily, for this country alone. One of the most elaborate and apparently complete, is that for which Mr. L. W. Wright obtained a patent in May, 1824. A detailed description of it will be found in the 9th volume of Newton’s London Journal. The following outline will give my readers an idea of the structure of this ingenious machine:--

The rotation of a principal shaft mounted with several cams, gives motion to various sliders, levers, and wheels, which work the different parts. A slider pushes pincers forwards, which draw wire from a reel, at every rotation of the shaft, and advance such a length of wire as will produce one pin. A dye cuts off the said length of wire by the descent of its upper chap; the chap then opens a carrier, which takes the pin to the pointing apparatus. Here it is received by a holder, which turns round, while a bevel-edged file-wheel rapidly revolves, and tapers the end of the wire to a point. The pin is now conducted by a second carrier to a finer file-wheel, in order to finish the point by a second grinding. A third carrier then transfers the pin to the first heading die, and by the advance of a steel punch, the end of the pin wire is forced into a recess, whereby the head is partially swelled out. A fourth carrier removes the pin to a second die, where the heading is perfected. When the heading-bar retires, a forked lever draws the finished pin from the die, and drops it into a receptacle below.

I believe the chief objection to the raising of the heads by strong mechanical compression upon the pins, is the necessity of softening the wire previously; whereby the pins thus made, however beautiful to the eye, are deficient in that stiffness which is so essential to their employment in many operations of the toilet.

PIPERINE, is a crystalline principle extracted from black pepper, by means of alcohol. It is colourless, has hardly any taste, fuses at 212° F.; is insoluble in water, but soluble in acetic acid, ether, and most readily in alcohol.

PITCH, MINERAL, is the same as BITUMEN and ASPHALT.

PITCH _of wood-tar_ (_Poix_, Fr.; _Pech_, Germ.); is obtained by boiling tar in an open iron pot, or in a still, till the volatile matters be driven off. Pitch contains, pyrolignous resin, along with colophany (common rosin), but its principal ingredient is the former, called by Berzelius pyretine. It is brittle in the cold, but softens and becomes ductile with heat. It melts in boiling water, and dissolves in alcohol and oil of turpentine, as well as in carbonated or caustic alkaline lyes. For PYRETINE, see the mode of preparing it from birch wood, for the purpose of preparing _Russia_ LEATHER.

PITCOAL. (_Houille_, Fr.; _Steinkohle_, Germ.) This is by far the most valuable of mineral treasures, and the one which, at least in Great Britain, makes all the others available to the use and comfort of man. Hence it has been searched after with unremitting diligence, and worked with all the lights of science, and the resources of art.

The Brora coal-field in Sutherlandshire is the most remarkable example in this, or in perhaps any country hitherto investigated, of a pseudo coal-basin among the deeper secondary strata, but above the new sandstone or red marl formation. The Rev. Dr. Buckland and Mr. C. Lyell, after visiting it in 1824, had expressed an opinion that the strata there were wholly unconnected with the proper coal formation below the new red sandstone, and were in fact the equivalent of the oolitic series; an opinion fully confirmed by the subsequent researches of Mr. Murchison. (_Geol. Trans._ for 1827, p. 293.) The Brora coal-field forms a part of those secondary deposits which range along the south-east coast of Sutherlandshire, occupying a narrow tract of about twenty miles in length, and three in its greatest breadth.

One stratum of the Brora coal-pit is a coal-shale, composed of a reed-like striated plant of the natural order _Equisetum_, which seems to have contributed largely towards the formation of that variety of coal. From this coal-shale, the next transition upwards is into a purer bituminous substance approaching to _jet_, which constitutes the great bed of coal. This is from 3 feet 3 inches to 3 feet 8 inches thick, and is divided nearly in the middle by a thin layer of impure indurated shale charged with pyrites, which, if not carefully excluded from the mass, sometimes occasions spontaneous combustion upon exposure to the atmosphere; and so much indeed is that mineral disseminated throughout the district, that the shales might be generally termed “pyritiferous.” Inattention on the part of the workmen, in 1817, in leaving a large quantity of this pyritous matter to accumulate in the pit, occasioned a spontaneous combustion, which was extinguished only by excluding the air; indeed the coal-pit was closed in and remained unworked for four years. The fires broke out again in the pit in 1827.

The purer part of the Brora coal resembles common pitcoal; but its powder has the red ferruginous tinge of pulverized lignites. It may be considered one of the last links between lignite and true coal, approaching very nearly in character to jet, though less tenacious than that mineral; and, when burnt, exhaling but slightly the vegetable odour so peculiar to all imperfectly bituminized substances. The fossil remains of shells and plants prove the Brora coal to be analogous to that of the eastern moorlands of Yorkshire, although the extraordinary thickness of the former, compared with any similar deposit of the latter (which never exceeds from 12 to 17 inches), might have formerly led to the belief that it was a detached and anomalous deposit of true coal, rather than a lignite of any of the formations _above_ the new red sandstone: such misconception might more easily arise in the infancy of geology, when the strata were not identified by their fossil organic remains.

On the coast of Yorkshire the strata of this pseudo coal formation appear in the following descending order, from Filey Bay to Whitby. 1. Coral-rag. 2. Calcareous grit. 3. Shale, with fossils of the Oxford clay. 4. Kelloway rock (swelling out into an important arenaceous formation). 5. Cornbrash. 6. Coaly grit of Smith. 7. Pier-stone (according to Mr. Smith, the equivalent of the great oolite). 8. Sandstone and shale, with _peculiar plants and various seams of coal_. 9. A bed with fossils of the inferior oolite. 10. Marl-stone? 11. Alum-shale or lias. All the above strata are identified by abundant organic remains.

In the oolitic series, therefore, where the several strata are developed in conformity with the more ordinary type of these formations, we may venture to predict with certainty, that no carboniferous deposits of any great value will ever be discovered, at all events in Great Britain. A want of such knowledge has induced many persons to make trials for coal in beds subordinate to the English oolites, and even superior to them, in places where the type of formation did not offer the least warrant for such attempts.

The third great class of terrestrial strata, is the proper coal-measures, called the _carboniferous rocks_, our leading object here, and to which we shall presently return.

The transition rocks which lie beneath the coal-measures, and above the primitive rocks, or are anterior to the carboniferous order, and posterior to the primitive, contain a peculiar kind of coal, called anthracite or stone-coal, approaching closely in its nature to carbon. It is chiefly in the transition clay-slate that the anthracite occurs in considerable masses. There is one in the transition slate of the little Saint Bernard, near the village of _la Thuile_ (in the Alps). It is 100 feet long, and 2 or 3 yards thick. The coal burns with difficulty, and is used only for burning lime. There are several of the same kind in that country, which extend down the reverse slope of the mountains looking to Savoy. The slate enclosing them presents vegetable impressions of reeds or analogous plants. To the transition clay-slate we must likewise refer the beds of anthracite that M. Hericart de Thury observed at very great heights in the Alps of Dauphiny, in a formation of schist and grey-wacke with vegetable impressions, which reposes directly on the primitive rocks.

The great carboniferous formation may be subdivided into four orders of rocks: 1. the coal-measures, including their manifold alternations of coal-beds, sandstones, and shales; 2. the millstone grit and shale towards the bottom of the coal-measures; 3. the carboniferous limestone, which projecting to considerable heights above the outcrop of the coal and grit, acquires the title of mountain limestone; 4. the old red sandstone, or connecting link with the transition and primary rock basin in which the coal system lies.

The coal-fields of England, from geographical position, naturally fall under the following arrangement:--1. The _great northern district_; including all the coal-fields north of Trent. 2. The _central district_; including Leicester, Warwick, Stafford, and Shropshire. 3. The _western district_; subdivided into _north-western_, including North Wales, and the _south-western_, including South Wales, Gloucester, and Somersetshire.

There are three principal coal-basins in Scotland: 1. that of Ayrshire; 2. that of Clydesdale; and 3. that of the valley of the Forth, which runs into the second in the line of the Union Canal. If two lines be drawn, one from Saint Andrews on the northeast coast, to Kilpatrick on the Clyde, and another from Aberlady, in Haddingtonshire, to a point a few miles south of Kirkoswald in Ayrshire, they will include between them the whole space where pitcoal has been discovered and worked in Scotland.

794]

The great coal-series consists of a regular alternation of mineral strata deposited in a great concavity or basin, the sides and bottom of which are composed of transition rocks. This arrangement will be clearly understood by inspecting _fig._ 794., which represents a section of the coal-field south of Malmsbury.

1, 1, old red sandstone; 2, mountain limestone; 3, millstone grit; 4, 4, coal seams; 5, Pennant, or coarse sandstone; 6, new red sandstone, or red marl; 7, 7, lias; 8, 8, inferior oolite; 9, great oolite; 10, cornbrash and Forest marble.

No. 1., or the old red sandstone, may therefore be regarded as the characteristic lining of the coal basins; but this sandstone rests on transition limestone, and this limestone on grey-wacke. This methodical distribution of the carboniferous series is well exemplified in the coal-basin of the Forest of Dean in the south-west of England, and has been accurately described by Mr. Mushet.

The _grey-wacke_ consists of highly inclined beds of slaty micaceous sandstone, which on the one hand alternates with and passes into a coarse breccia, having grains as large as peas; on the other, into a soft argillaceous slate. The grey-wacke stands bare on the north-eastern border of the Forest, near the southern extremity of the chain of transition limestone, which extends from Stoke Edith, near Hereford, to Flaxley on the Severn. It is traversed by a defile, through which the road from Gloucester to Ross winds. The abruptness of this pass gives it a wild and mountainous character, and affords the best opportunity of examining the varieties of the rock.

The _Transition limestone_ consists in its _lower beds_ of fine-grained, tender, extremely argillaceous slate, known in the district by the name of _water-stone_, in consequence of the wet soil that is found wherever it appears at the surface. Calcareous matter is interspersed in it but sparingly. Its _upper beds_ consist of shale alternating with extensive beds of stratified limestone. The lowest of the calcareous strata are thin, and alternate with shale. On these repose thicker strata of more compact limestone, often of a dull blue colour. The beds are often dolomitic, which is indicated by straw yellow colour, or dark pink colour, and by the sandy or glimmering aspect of the rock.

The _old red sandstone_, whose limits are so restricted in other parts of England, here occupies an extensive area. The space which it covers, its great thickness, its high inclination, the abrupt character of the surface over which it prevails, and the consequent display of its strata in many natural sections, present in this strict advantages for studying the formation, which are not to be met with elsewhere in South Britain. In the neighbourhood of Mitchel Dean, the total thickness of this formation, interposed conformably between the transition and mountain limestone, is from 600 to 800 fathoms. The old red sandstone is characterized in its upper portion by the presence of siliceous conglomerate, containing siliceous pebbles, which is applied extensively to the fabrication of millstones near Monmouth, and on the banks of the Wye. This sandstone encircles the Forest with a ring of very elevated ground, whose long and lofty ridges on the eastern frontier overhang the valley of the Severn.

The _mountain limestone_, or carboniferous, is distinguished from transition limestone, rather by its position than by any very wide difference in its general character or organic remains. According to the measurements of Mr. Mushet, the total thickness of the mountain limestone is about 120 fathoms. The zone of limestone belonging to this coal-basin, is from a furlong to a mile in breadth on the surface of the ground, according as the dip of the strata is more or less rapid. The angle of dip on the northern and western border is often no more than 10°, but on the eastern it frequently amounts to 80°. The calcareous zone that defines the outer circle of the basin, suffers only one short interruption, scarcely three miles in length, where in consequence of a fault the limestone disappears, and the coal-measures are seen in contact with the old red sandstone.

_Coal measures._--Their aggregate thickness amounts, according to Mr. Mushet, to about 500 fathoms. 1. The lowest beds, which repose on the mountain limestone, are about 40 fathoms thick, and consist here, as in the Bristol coal-basin, of a red siliceous grit, alternating with conglomerate, used for millstones; and with clay, occasionally used for ochre. 2. These beds are succeeded by a series about 120 fathoms thick, in which a grey gritstone predominates, alternating in the lower part with shale, and containing 6 seams of coal. The grits are of a fissile character, and are quarried extensively for flag-stone, ashlers, and fire-stone. 3. A bed of grit, 25 fathoms thick, quarried for hearth-stone, separates the preceding series from the following, or the 4th, which is about 115 fathoms thick, and consists of from 12 to 14 seams of coal alternating with shale. 5. To this succeeds a straw-coloured sandstone, nearly 100 fathoms thick, forming a high ridge in the interior of the basin. It contains several thin seams of coal, from 6 to 16 inches in thickness. 6. On this reposes a series of about 12 fathoms thick, consisting of 3 seams of coal alternating with shale. 7. This is covered with alternate beds of grit and shale, whose aggregate thickness is about 100 fathoms, occupying a tract in the centre of the basin about 4 miles long, and 2 miles broad. The sandstone No. 5. is probably the equivalent of the Pennant in the preceding figure.

The floor, or pavement, immediately under the coal beds is, almost without exception, a grayish-slate clay, which, when made into bricks, strongly resists the fire. This fire-clay varies in thickness from a fraction of an inch to several fathoms. Clay ironstone is often disseminated through the shale.

The most complete and simplest form of a coal-field is the entire basin-shape, which we find in some instances without a dislocation. A beautiful example of this is to be seen at Blairengone, in the county of Perth, immediately adjoining the western boundary of Clackmannanshire, as represented in _fig._ 795., where the outer elliptical line, marked A, B, C, D, represents the crop, outburst, or basset edge of the lower coal, and the inner elliptical line represents the crop or basset edge of the superior coal. _Fig._ 796. is the longitudinal section of the line A B; and _fig._ 797. the transverse section of the line C D. All the accompanying coal strata partake of the same form and parallelism. These basins are generally elliptical, sometimes nearly circular, but are often very eccentric, being much greater in length than in breadth; and frequently one side of the basin on the short diameter has a much greater dip than the other, which circumstance throws the trough or lower part of the basin concavity much nearer to the one side than to the other. From this view of one entire basin, it is evident that the dip of the coal strata belonging to it runs in opposite directions, on the opposite sides, and that all the strata regularly crop out, and meet the alluvial cover in every point of the circumferential space, like the edges of a nest of common basins. The waving line marks the river Devon.

It is from this basin shape that all the other coal-fields are formed, which are segments of a basin produced by slips, dikes, or dislocations of the strata. If the coals (_fig._ 795.) were dislocated by two slips _b c_ and _d e_, the slip _b c_ throwing the strata _down_ to the east, and the slip _d e_ throwing them as much _up_ in the same direction, the outcrops of the coals would be found in the form represented in _fig._ 798., of which _fig._ 799. is the section in the line A B, and _fig._ 800. the section in the line C D.

The chief difficulty in exploring a country in search of coal, or one where coal-fields are known to exist, arises from the great thickness of alluvial and other cover, which completely hides the outcrop or basset edge of the strata, called by miners the _rock-head_; as also the fissures, dikes, and dislocations of the strata, which so entirely change the structure and bearings of coal-fields, and cause often great loss to the mining adventurer. The alluvial cover on the other hand is beneficial, by protecting the seams of the strata from the superficial waters and rains, which would be apt to drown them, if they were naked. In all these figures of coal-basins, the letter _a_ indicates coal.

The absolute shape of the coal-fields in Great Britain has been ascertained with surprising precision. To whatever depth a coal-mine is drained of its water, from that depth it is worked, up to the rise of the water-level line, and each miner continues to advance his room or working-place, till his seam of coal meets the alluvial cover of the outcrop, or is cut off by a dislocation of the strata. In this way the miner travels in succession over every point of his field, and can pourtray its basin-shape most minutely.

_Fig._ 801. represents a horizontal plan of the Clackmannanshire coal-field, as if the strata at the outcrop all around were denuded of the alluvial cover. Only two of the concentric beds, or of their edges _a_, _a_, are represented, to avoid perplexity. It is to be remembered, however, that all the series of attendant strata lie parallel to the above lines. This plan shows the Ochill mountains, with the north coal-fields, of an oblong elliptical shape, the side of the basin next the mountains being precipitous, as if upheaved by the eruptive trap-rocks; while the south, the east, and the west edges of the basin shelve out at a great distance from the lower part of the concavity or _trough_, as miners call it. Thus the alternate beds of coal, shale, and sandstone, all nearly concentric in the north coal-field, dip inwards from all sides towards the central area of the _trough_. The middle coal-field of this district, however, which is formed by the great north slip, is merely the segment of an elliptical basin, where the strata dip in every direction to the middle of the axis marked with the letter X; being the deepest part of the segment. The south coal-field, formed by the great south slip, is likewise the segment of another elliptical basin, similar in all respects to the middle coal-field. Beyond the outcrop of the coals and subordinate strata of the south coal-fields, the counter dip of the strata takes place, producing the mantle-shaped form; whence the coal strata in the Dunmore field, in Stirlingshire, lie in a direction contrary to those of the south coal-field of Clackmannanshire. O, are the Ochill mountains.

_Fig._ 802. is intended to represent an extensive district of country, containing a great coal-basin, divided into numerous subordinate coal-fields by these dislocations. The lines marked _b_ are slips, or faults; the broad lines marked _c_ denote dykes: the former dislocate the strata, and change their level, while dykes disjoin the strata with a wall, but do not in general affect their elevation. The two parallel lines marked _a_, represent two seams of coal, variously heaved up and down by the faults; whereas the dykes are seen to pass through the strata without altering their relative position. In this manner, partial coal-fields are distributed over a wide area of country, in every direction.

The only exception to this general form of the coal-fields in Great Britain, is the inverted basin shape; but this is rare. A few examples occur in some districts of England, and in the county of Fife; but even in extensive coal-fields, this convex form is but a partial occurrence, or a deviation by local violence from the ordinary basin. _Fig._ 803 is an instance of a convex coal-field exhibited in Staffordshire, at the Castle-hill, close to the town of Dudley. 1, 1, are limestone strata; 2, 2, are coal. Through this hill, canals have been cut, for working the immense beds of carboniferous limestone. These occur in the lower series of the strata of the coal-field, and therefore at a distance of many miles from the Castle-hill, beyond the outcrop of all the workable coals in the proper basin-shaped part of the field; but by this apparently inverted basin-form, these limestone beds are elevated far above the level of the general surface of the country, and consequently above the level of all the coals. We must regard this seeming inversion as resulting from the approximation of two coal-basins, separated by the basset edges of their mountain limestone repository.

_Fig._ 804. is a vertical section of the Dudley coal-basin, the upper coal-bed of which has the astonishing thickness of 30 feet; and this mass extends 7 miles in length, and 4 in breadth. Coal-seams 5 or 6 feet thick, are called _thin_ in that district.

_Fig._ 805. is a very interesting section of the main coal-basin of Clackmannanshire, as given by Mr. Bald in the Wernerian Society’s Memoirs, vol. iii. Here we see it broken into three subordinate coal-fields, formed by two great faults or dislocations of the strata; but independently of these fractures across the whole series, the strata continue quite regular in their respective alternations, and preserve nearly unchanged their angle of inclination to the horizon. The section shows the south coal-field dipping northerly, till it is cut across by the great south slip _x_, which dislocates the coal and the parallel strata to the enormous extent of 1230 feet, by which all the coals have been thrown up, not simply to the day, but are not found again till we advance nearly a mile northward, on the line of the dip, where the identical seams of coal, shale, &c. are observed once more with their regular inclination. These coals of the middle area, dip regularly northward till interrupted by the great north slip _y_, which dislocates the strata, and throws them up 700 feet; that is to say, a line prolonged in the direction of any one well-known seam, will run 700 feet above the line of the same seam as it emerges after the middle slip. Immediately adjoining the north slip, the coals and coal-field resume their course, and dip regularly northward, running through a longer range than either of the other two members of the basin, till they arrive at the valley of the Devon, at the foot of the Ochill mountains, where they form a concave curvature, or trough, _a_, and thence rise rapidly in an almost vertical direction at _b_. Here the coals, with all their associate strata, assume conformity and parallelism with the face of the sienitic-greenstone strata of the Ochill mountains _c_; being raised to the high angle of 73 degrees with the horizon. The coal-seams thus upheaved, are called _edge-metals_ by the miners.

In this remarkable coal-field, which has been accurately explored by pitting and boring to the depth of 703 feet, there are no fewer than 142 beds, or distinct strata of coal, shale, and sandstone, &c., variously alternating, an idea of which may be had by inspecting _fig._ 806. Among these are 24 beds of coal, which would constitute an aggregate thickness of 59 feet 4 inches; the thinnest seam of coal being 2 inches, and the thickest 9 feet. The strata of this section contain numerous varieties of sandstone, slate-clay, bituminous shale, indurated clay, or fire-clay, and clay ironstone. Neither trap-rock nor limestone is found in connexion with the workable coals; but an immense bed of greenstone, named Abbey Craig, occurs in the western boundary of Clackmannanshire, under which lie regular strata of slate-clay, sandstone, thin beds of limestone, and large spheroidal masses of clay ironstone, with a mixture of lime.

“With regard to slips in coal fields,” says Mr. Bald, “we find that there is a general law connected with them as to the position of the dislocated strata, which is this:--When a slip is met with in the course of working the mines--if when looking to it, the vertical line of the slip or fissure, it forms an acute angle with the line of the pavement upon which the observer stands, we are certain that the strata are dislocated downwards upon the other side of the fissure. On the contrary, if the angle formed by the two lines above mentioned is obtuse, we are certain that the strata are dislocated or thrown upwards upon the other side of the fissure. When the angle is 90°, or a right angle, it is altogether uncertain whether the dislocation throws up or down on the opposite side of the slip. When dikes intercept the strata, they generally only separate the strata the width of the dike, without any dislocation, either up or down; so that if a coal is intercepted by a dike, it is found again by running a mine directly forward, corresponding to the angle or inclination of the coal with the horizon.”--_Wernerian Society’s Memoirs_, vol. iii. p. 133.[40]

[40] This paper does honour to its author, the eminent coal-viewer of
Scotland.

_a._ Alluvial cover.
_b._ Bed of trap or greenstone.
_c._ Alternating coal strata.
_d._ Coal-seams.
_e._ Position of greenstone, not ascertained.
_f._ Strata in which no coals have been found.
_g._ The overlapped coal.
_h._ The double coal.]

The Johnstone coal-field, in Renfrewshire, is both singular and interesting. The upper stratum of rock is a mass of compact greenstone or trap, above 100 feet in thickness, not at all in a conformable position with the coal strata, but overlying; next there is a few fathoms of soft sandstone and slate-clay, alternating, and uncommonly soft. Beneath these beds, there are no fewer than ten seams of coal, lying on each other, with a few divisions of dark indurated clay. These coal-seams have an aggregate thickness of no less than 100 feet; a mass of combustible matter, in the form of coal, unparalleled for its accumulation in so narrow a space. The greater part of this field contains only 5 beds of coal; but at the place where the section shown in _fig._ 807. is taken, these 5 coals seem to have been overlapped or made to slide over each other by violence. This structure is represented in _fig._ 808., which is a section of the Quarrelton coal in the Johnstone field, showing the overlapped coal and the double coal, with the thick bed of greenstone, overlying the coal-field.

Before proceeding to examine the modes of working coal, I shall introduce here a description of the two principal species of this mineral.

1. _Cubical coal._--It is black, shining, compact, moderately hard, but easily frangible. When extracted in the mine, it comes out in rectangular masses, of which the smaller fragments are cubical. The lamellæ (_reed_ of the coal) are always parallel to the bed or plane on which the coal rests; a fact which holds generally with this substance. There are two varieties of cubical coal; the _open-burning_ and the _caking_. The latter, however small its fragments may be, is quite available for fuel, in consequence of its agglutinating into a mass at a moderate heat, by the abundance of its bitumen. This kind is the true smithy or forge-coal, because it readily forms itself into a vault round the blast of the bellows, which serves for a cupola in concentrating the heat on objects thrust into the cavity.

The open-burning cubical coals are known by several local names; the rough coal or clod coal, from the large masses in which they may be had; and the cherry coal, from the cheerful blaze with which they spontaneously burn; whereas the caking coals, such as most of the Newcastle qualities, require to be frequently poked in the grate. Its specific gravity varies from 1·25 to 1·4.

2. _Slate or splint coal._--This is dull-black, very compact, much harder, and more difficultly frangible than the preceding. It is readily fissile, like slate, but powerfully resists the cross fracture, which is conchoidal. Specific gravity from 1·26 to 1·40. In working, it separates in large quadrangular sharp-edged masses. It burns without caking, produces much flame and smoke, unless judiciously supplied with air, and leaves frequently a considerable bulk of white ashes. It is the best fuel for distilleries and all large grates, as it makes an open fire, and does not clog up the bars with glassy scoriæ. I found good splint coal of the Glasgow field to have a specific gravity of 1·266, and to consist of--carbon, 70·9; hydrogen, 4·3; oxygen, 24·8.

3. _Cannel coal._--Colour between velvet and grayish-black; lustre resinous; fracture even; fragments trapezoidal; hard as splint coal; spec. grav. 1·23 to 1·28. In working, it is detached in four-sided columnar masses, often breaks conchoidal, like pitch, kindles very readily, and burns with a bright white projective flame, like the wick of a candle, whence its name. It occurs most abundantly in the coal-field of Wigan, in Lancashire, in a bed 4 feet thick; and there is a good deal of it in the Clydesdale coal-field, of which it forms the lowest seam that is worked. It produces very little dust in the mine, and hardly soils the fingers with carbonaceous matter. Cannel coal from Woodhall, near Glasgow, spec. grav. 1·228, consists by my analysis of--carbon, 72·22; hydrogen, 3·93; oxygen, 21·05; with a little azote (about 2·8 in 100 parts). This coal has been found to afford, in the Scotch gas-works, a very rich-burning gas. The azote is there converted into ammonia, of which a considerable quantity is distilled over into the tar-pit.

4. _Glance coal._--This species has an iron-black colour, with an occasional iridescence, like that of tempered steel; lustre in general splendent, shining, and imperfect metallic; does not soil; easily frangible; fracture flat conchoidal; fragments sharp-edged. It burns without flame or smell, except when it is sulphureous; and it leaves a white-coloured ash. It produces no soot, and seems, indeed, to be merely carbon, or coal deprived of its volatile matter or bitumen, and converted into coke by subterranean calcination, frequently from contact with whin-dikes. Glance coal abounds in Ireland, under the name of Kilkenny coal; in Scotland it is called blind coal, from its burning without flame or smoke; and in Wales, it is the malting or stone coal. It contains from 90 to 97 per cent. of carbon. Specific gravity from 1·3 to 1·5; increasing with the proportion of earthy impurities.

The dislocations and obstructions found in coal-fields, which render the search for coal so difficult, and their mining so laborious and uncertain, are the following:--

1. _Dikes._ 2. _Slips or Faults._ 3. _Hitches._ 4. _Troubles._

The first three infer dislocation of the strata; the fourth changes in the bed of coal itself.

1. A dike is a wall of extraneous matter, which divides all the beds in a coal-field.

Dikes extend not only in one line of bearing through coal-fields for many miles, but run sometimes in different directions, and have often irregular bendings, but no sharp angular turns. When from a few feet to a few fathoms in thickness, they occur sometimes in numbers within a small area of a coal basin, running in various directions, and even crossing each other. _Fig._ 809. represents a ground plan of a coal-field, intersected with greenstone dikes. A B and C D are two dikes standing parallel to each other; E F and G H are cross or oblique dikes, which divide both the coal strata and the primary dikes A B and C D.

2. _Slips_ or _faults_ run in straight lines through coal-measures, and at every angle of incidence to each other. _Fig._ 810. represents a ground plan of a coal-field, with two slips A B and C D in the line of bearing of the planes of the strata, which throw them down to the outcrop. This is the simplest form of a slip. _Fig._ 811. exhibits part of a coal-field intersected with slips, like a cracked sheet of ice. Here A B is a dike; while the narrow lines show faults of every kind, producing dislocations varying in amount of slip from a few feet to a great many fathoms. The faults at the points _a_, _a_, _a_ vanish; and the lines at _c_ denote four small partial slips called _hitches_.

The effects of slips and dikes on the coal strata appear more prominently when viewed in a vertical section, than in a ground plan, where they seem to be merely walls, veins, and lines of demarcation. _Fig._ 812. is a vertical section of a coal-field, from dip to rise, showing three strata of coal _a_, _b_, _c_. A B represents a dike at right angles to the plane of the coal-beds. This rectangular wall merely separates the coal-measures, affecting their line of rise; but further to the rise, the oblique dike C D interrupts the coals _a_, _b_, _c_, and not only disjoins them, but throws them and their concomitant strata greatly lower down; but still, with this depression, the strata retain their parallelism and general slope. Nearer to the outcrop, another dike E, F, interrupts the coals _a_, _b_, _c_, not merely breaking the continuity of the planes, but throwing them moderately up, so as to produce a steeper inclination, as shown in the figure. It sometimes happens that the coals in the compartment H, betwixt the dikes C and E, may lie nearly horizontal, and the effect of the dike E, F, is then to throw out the coals altogether, leaving no vestige of them in the compartment K. “Such,” says Mr. Bald, from whom these illustrations are borrowed, “are the most prominent changes in the strata, as to their line of direction, produced by dikes; but of these changes there are various modifications.”

The effect of slips on the strata is also represented in the vertical section, _fig._ 813., where _a_, _b_, _c_ are coals with their associated strata. A, B, is an intersecting slip, which throws all the coals of the first compartment much lower, as is observable in the second, No. 2.; and from the amount of the slip, it brings in other coal-seams, marked 1, 2, 3, not in the compartment No. 1. C, D, is a slip producing a similar result, but not of the same magnitude. E, F, represents a slip across the strata, reverse in direction to the former; the effect of which is to throw up the coals, as shown in the area No. 4. Such a slip occasionally brings into play seams seated under those marked _a_, _b_, _c_, as seen at 4, 5, 6; and it may happen that the coal marked 4 lies in the prolongation of a well-known seam, as _c_, in the compartment No. 3., when the case becomes puzzling to the miner. In addition to the above varieties, a number of slips or hitches are often seen near one another, as in the area marked No. 5., where the individual displacements are inconsiderable, but the aggregate dislocation may be great, in reference to the seams of the 6th compartment.

The results of dikes and slips on a horizontal portion of a field are exemplified in _fig._ 814. Where the coal-measures are horizontal, and the faults run at a greater angle than 45° to the line of bearing, they are termed dip and rise faults, as A B, C D, E F.