Chapter M: D’Arcet states the analysis of Marseilles soap at (2)

A, lead generator, for making the gas. B, lead pot, for holding sulphuric acid. C, handle for moving the agitator of the receiver, which stirs up the ingredients in the lead generator. _a_, cap and screw, for charging the lead pot with sulphuric acid. _b_, swivel-joint, which is movable, for occasionally throwing in portions of sulphuric acid for generating gas. _c_, stuffing-box for agitator. _d_, large cap and screw, for charging the lead generator with whiting and water. _e_, cap and screw, for emptying contents of ditto. D, lead pipe, to convey the gas from the lead generator to gasometer. E, wood tub, filled with water, for gasometer to work in. F, copper gasometer. G, strong iron frame, for gasometer and tub to stand on, firmly fixed together by three wrought-iron rods, _f_, _f_. _g_, _g_, two pulleys, for carrying rope and counterbalance weight _h_, for balancing copper gasometer. _i_, cock for discharging atmospheric air contained in the gasometer before making the gas. _k_, cock for occasionally emptying the water out of the tub. _l_, union joint, to which is fixed a copper pipe, passing through the water in the tub, to deliver the gas as generated into the copper gasometer. _m_, another union joint, with a similar copper pipe, passing through the water in the tub, and projecting two or three inches above the surface of the water, to convey the gas from the copper gasometer to the soda-water machine. H, H, condenser for aerating the soda-water. I, safety valve. K, K, bottling valve. L, bottling nipple. M, M, soda-water pump. N, valve-piece. O, O, piston of the pump. P, pipe for conducting gas from the gasometer to pump. Q, copper pan for holding the solution of soda. R, copper pipe for conducting the solution of soda to the force pump. S, S, two cocks for regulating the admission of the solution and gas to the pump. T, copper pipe through which the soda-water is forced to the condenser. U, pinion wheel, to give motion to the agitator revolving inside the condenser. V, V, wheel for driving ditto. W, W, cast-iron frame for carrying machinery. X, X, cast-iron fly-wheel. Z, wrought-iron crank. Y, Z, Z, wood stools and curb, upon which the whole of the machinery is fixed.

SODIUM, the metallic basis of soda, is obtained by processes similar to those by which potassium is procured. By fusing hydrate of soda with a little hydrate of potassa, a mixture is obtained, which yields more readily than soda by itself to the decomposing action of iron-turnings at a high heat, in a bent gun-barrel. The portion of potassium produced, may be got rid of, by digesting the alloy for a few days in some naphtha or oil of turpentine contained in an open vessel. The sodium remains at the bottom of the liquid. Pure sodium may, however, be prepared at once, by subjecting incinerated tartrate of soda to heat in the apparatus of Brunner, described under POTASSIUM. It is white, like silver; softer and more malleable than any other metal, and may be readily reduced into very thin leaves. It preserves its malleability till it approaches the melting point. Its specific gravity is 0·970. It softens at the temperature of 122° F., and at 200° it is perfectly fluid; but it will not rise in vapour until heated to nearly the melting point of glass. In the air it oxidizes slowly, and gets covered with a crust of soda; but it does not take fire till it is made nearly red-hot; and then it emits brilliant scintillations. When thrown upon water, it is rapidly oxidized, but without kindling, like potassium. If a drop of water be thrown upon it, it becomes so hot by the chemical action as to take fire. There are three oxides of sodium; 1. the suboxide; 2. the oxide, or the basis of common soda; and, 3. the suroxide; the last being formed when sodium is heated to redness upon a plate of silver.

SOLDERING (_Souder_, Fr.; _Löthen_, Germ.); is the process of uniting the surfaces of metals, by the intervention of a more fusible metal, which being melted upon each surface, serves, partly by chemical attraction, and partly by cohesive force, to bind them together. The metals thus united may be either the same or dissimilar; but the uniting metal must always have an affinity for both. Solders must be, therefore, selected in reference to their appropriate metals. Thus tin-plates are soldered with an alloy consisting of from 1 to 2 parts of tin, with 1 of lead; pewter is soldered with a more fusible alloy, containing a certain proportion of bismuth added to the lead and tin; iron, copper, and brass are soldered with spelter, an alloy of zinc and copper, in nearly equal parts; silver, sometimes with pure tin, but generally with silver-solder, an alloy consisting of 5 parts of silver, 6 of brass, and 2 of zinc; zinc and lead, with an alloy of from 1 to 2 parts of lead with 1 of tin; platinum, with fine gold; gold, with an alloy of silver and gold, or of copper and gold; &c.

In all soldering processes, the following conditions must be observed: 1. the surfaces to be united must be entirely free from oxide, bright, smooth, and level; 2. the contact of air must be excluded during the soldering, because it is apt to oxidize one or other of the surfaces, and thus to prevent the formation of an alloy at the points of union. This exclusion of air is effected in various ways. The locksmith encases in loam the objects of iron, or brass, that he wishes to subject to a soldering heat; the silversmith and brazier mix their respective solders with moistened borax powder; the coppersmith and tinman apply sal ammoniac, rosin, or both, to the cleaned metallic surfaces, before using the soldering-iron to fuse them together with the tin alloy. The strong solder of the coppersmith consists of 8 parts of brass and 1 of zinc; the latter being added to the former, previously brought into a state of fusion. The crucible must be immediately covered up for two minutes till the combination be completed. The melted alloy is to be then poured out upon a bundle of twigs held over a tub of water, into which it falls in granulations. An alloy of 3 parts of copper and 1 of zinc forms a still stronger solder for the coppersmiths. When several parts are to be soldered successively upon the same piece, the more fusible alloys, containing more zinc, should be used first. A softer solder for coppersmiths is made with 6 parts of brass, 1 of tin, and 1 of zinc; the tin being first added to the melted brass, then the zinc; and the whole well incorporated by stirring.

The edges of sheet lead for sulphuric acid chambers, and its concentration pans, are joined together by melted lead itself, because any solder containing tin would soon be corroded. With this view, the two edges being placed in contact, are flattened down into a long wooden groove, and secured in their situation by a few brass pins driven into the wood. The surfaces are next brightened with a triangular scraper, rubbed over with candle grease, and then covered with a stream of hot melted lead. The riband of lead thus applied is finally equalized by being brought into partial fusion with the plumber’s conical iron heated to redness; the contact of air being prevented by sprinkling rosin over the surface. The sheets of lead are thus _burned_ together, in the language of the workmen.

SOOT (_Noir de fumée_, _Suie_, Fr.; _Rus_, _Flatterrus_, Germ.); is the pulverulent charcoal condensed from the smoke of wood or coal fuel. A watery infusion of the former is said to be antiseptic, probably from its containing some creosote.

The soot of pitcoal has not been analyzed with any minuteness. It contains some sulphate and carbonate of ammonia, along with bituminous matter.

SORBIC ACID, is the same with malic acid; which see.

SOY, is a liquid condiment, or sauce, imported chiefly from China. It is prepared with a species of white haricots, wheat flour, common salt, and water; in the proportions respectively of 50, 60, 50, and 250 pounds. The haricots are washed, and boiled in water till they become so soft as to yield to the fingers. They are then laid in a flat dish to cool, and kneaded along with the flour, a little of the hot water of the decoction being added from time to time. This dough is next spread an inch or an inch and a half thick upon the flat vessel (made of thin staves of bamboo), and when it becomes hot and mouldy, in two or three days, the cover is raised upon bits of stick, to give free access of air. If a rancid odour is exhaled, and the mass grows green, the process goes on well; but if it grows black, it must be more freely exposed to the air. As soon as all the surface is covered with green mouldiness, which usually happens in eight or ten days, the cover is removed, and the matter is placed in the sunshine for several days. When it has become as hard as a stone, it is cut into small fragments, thrown into an earthen vessel, and covered with the 250 pounds of water having the salt dissolved in it. The whole is stirred together, and the height at which the water stands is noted. The vessel being placed in the sun, its contents are stirred up every morning and evening; and a cover is applied at night, to keep it warm and exclude rain. The more powerful the sun, the sooner the soy will be completed; but it generally requires two or three of the hottest summer months. As the mass diminishes by evaporation, well water is added; and the digestion is continued till the salt water has dissolved the whole of the flour and the haricots; after which the vessel is left in the sun for a few days, as the good quality of the soy depends on the completeness of the solution, which is promoted by regular stirring. When it has at length assumed an oily appearance, it is poured into bags, and strained. The clear black liquid is the soy, ready for use. It is not boiled, but is put up into bottles, which must be carefully corked. Genuine soy was made in this way at Canton, by Michael de Grubbens. See _Memoirs of Academy of Sciences of Stockholm_ for 1803.

SPECIFIC GRAVITY, designates the relative weights of different bodies under the same bulk; thus a cubic foot of water weighs 1000 ounces avoirdupois; a cubic foot of coal, 1350; a cubic foot of cast iron, 7280; a cubic foot of silver, 10,400; and a cubic foot of pure gold, 19,200; numbers which represent the specific gravities of the respective substances, compared to water = 1·000. See ALLOY.

SPECULUM METAL, is an alloy of copper and tin; described under COPPER.

SPERMACETI; the _Cetine_ of Chevreul. In certain species of the _cachalot_ whale, as the _Physeter macrocephalus_, _tursio_, _microps_, and _orthodon_, as also the _Delphinus edentulus_, the fat of some parts of their bodies contains a peculiar kind of stearine, called spermaceti. The oil obtained from cavities in the bones of the cranium of the above cetaceæ is the richest in this kind of stearine. This being thrown into great filter-bags, the spermaceti oil passes through, and is subsequently purified by the addition of a small quantity of potash lye, which precipitates certain matters by neutralizing the acid that held them in solution. The solid which remains on the filter is next squeezed in bags, by means of a horizontal hydraulic press encased in steam, then digested with a weak potash lye, in order to dissolve out any oil which may continue to adhere to it, washed with water, finally dissolved in a tub by the agency of steam, laded into tin pans, and allowed slowly to concrete into a white semi-transparent brittle lamellar crystalline mass, which forms elegant candles.

At 60° its specific gravity is 0·943. It melts at 112·5°; 100 parts of alcohol at 0·821 dissolve 3-1/2 of it, of which 0·9 are deposited on cooling. Warm ether dissolves it in very large quantities. It is soluble also in the fat of volatile oils; and if the solutions have been saturated while hot, the greater part of the spermaceti crystallizes on cooling. When this substance has been purified by digesting alcohol upon it repeatedly, what remains is the _cetine_ of Chevreul, or pure spermaceti. Its melting point has now become 116° F., and its boiling point 616° F., at which it distils without alteration. Caustic alkaline lyes saponify it with difficulty.

SPIRIT OF AMMONIA, is, properly speaking, alcohol combined with ammonia gas; but the term is often applied to water of ammonia.

SPIRITS, VINOUS. This subject has been fully discussed in the articles ALCOHOL, DISTILLATION, and FERMENTATION. I have shown that the progressive increase of alcohol in the wash tends progressively to prevent the conversion of the wort into spirit, or checks the fermenting process, though a great deal of fermentable matter remains unchanged. Mr. Sheridan has sought to remove this obstacle to the thorough transmutation of saccharine matter into alcohol, by drawing off the spirit as it is formed. For this purpose he ferments his wash in close tuns, connected with a powerful air-pump worked by machinery, thus continually removing the carbonic acid as it is formed, and maintaining a diminished pressure under which the alcohol readily distils at a temperature of 120° or 130° F. He finds that this degree of heat is not injurious to the fermentation, provided that it be communicated by the air of a stove-room, and not by water or steam pipes traversing the liquid, which would inevitably scald or seeth the particles in succession, and thereby extinguish the fermenting principle.

By the above ingenious plan, Mr. Sheridan tells me he has obtained 28 gallons of proof spirit from a quarter of grain, instead of the average product 21, being an increase of 25 per cent. The experiment was tried upon a considerable scale at Messrs. Currie’s great distillery near London; but could not be established as a mode of manufacture, on account of the excise laws, which prohibit the distillers from carrying on the two processes of fermentation and distillation at the same time.

SPIRIT OF WINE; Alcohol.

SPONGE (_Eponge_, Fr.; _Schwamm_, Germ.); is a cellular fibrous tissue produced by small animals, almost imperceptible, called polypi by naturalists, which live in the sea. This tissue is said to be covered in its recent state with a kind of semi-fluid thin coat of animal jelly, susceptible of a slight contraction or trembling on being touched; which is the only symptom of vitality displayed by the sponge. After death, this jelly disappears, and leaves merely the sponge; formed by the combination of a multitude of small capillary tubes, capable of receiving water in their interior, and of becoming thereby distended. Sponges occur attached to stones at the bottom of the sea; and abound particularly upon the shores of the islands in the Grecian Archipelago. Although analogous in their origin to coral, sponges are quite different in their nature; the former being composed almost entirely of carbonate of lime; while the latter are formed of the same elements as animal matters, and afford, on distillation, a considerable quantity of ammonia.

Dilute sulphuric acid has been recommended for bleaching sponges, after the calcareous impurities have been removed by muriatic acid. Chlorine water answers better.

SPOON MANUFACTURE. See STAMPING OF METALS.

STAINED GLASS. When certain metallic oxides or chlorides, ground up with proper fluxes, are painted upon glass, their colours fuse into its surface at a moderate heat, and make durable pictures, which are frequently employed in ornamenting the windows of churches as well as of other public and private buildings. The colours of stained glass are all transparent, and are therefore to be viewed only by transmitted light. Many metallic pigments, which afford a fine effect when applied cold on canvas or paper, are so changed by vitreous fusion as to be quite inapplicable to painting in stained glass.

The glass proper for receiving these vitrifying pigments, should be colourless, uniform, and difficult of fusion; for which reason crown glass, made with little alkali, or with kelp, is preferred. When the design is too large to be contained on a single pane, several are fitted together, and fixed in a bed of soft cement while painting, and then taken asunder to be separately subjected to the fire. In arranging the glass pieces, care must be taken to distribute the joinings so that the lead frame-work may interfere as little as possible with the effect.

A design must be drawn upon paper, and placed beneath the plate of glass; though the artist cannot regulate his tints directly by his pallet, but by specimens of the colours producible from his pallet pigments after they are fired. The upper side of the glass being sponged over with gum-water, affords, when dry, a surface proper for receiving the colours, without the risk of their running irregularly, as they would be apt to do, on the slippery glass. The artist first draws on the plate, with a fine pencil, all the traces which mark the great outlines and shades of the figures. This is usually done in black, or, at least, some strong colour, such as brown, blue, green, or red. In laying on these, the painter is guided by the same principles as the engraver, when he produces the effect of light and shade by dots, lines, or hatches; and he employs that colour to produce the shades, which will harmonize best with the colour which is to be afterwards applied; but for the deeper shades, black is in general used. When this is finished, the whole picture will be represented in lines or hatches similar to an engraving finished up to the highest effect possible; and afterwards, when it is dry, the vitrifying colours are laid on by means of larger hair pencils; their selection being regulated by the burnt specimen tints. When he finds it necessary to lay two colours adjoining, which are apt to run together in the kiln, he must apply one of them to the back of the glass. But the few principal colours to be presently mentioned, are all fast colours, which do not run, except the yellow, which must therefore be laid on the opposite side. After colouring, the artist proceeds to bring out the lighter effects by taking off the colour in the proper place, with a goose quill cut like a pen without a slit. By working this upon the glass, he removes the colour from the parts where the lights should be the strongest; such as the hair, eyes, the reflection of bright surfaces and light parts of draperies. The blank pen may be employed either to make the lights by lines, or hatches and dots, as is most suitable to the subject.

By the metallic preparations now laid upon it, the glass is made ready for being fired, in order to fix and bring out the proper colours. The furnace or kiln best adapted for this purpose, is similar to that used by enamellers. See ENAMEL, and the _Glaze-kiln_; under POTTERY. It consists of a muffle or arch of fire-clay or pottery, so set over a fireplace, and so surrounded by flues, as to receive a very considerable heat within, in the most equable and regular manner; otherwise some parts of the glass will be melted; while, on others, the superficial film of colours will remain unvitrified. The mouth of the muffle, and the entry for introducing fuel to the fire, should be on opposite sides, to prevent as much as possible the admission of dust into the muffle, whose mouth should be closed with double folding-doors of iron, furnished with small peep-holes, to allow the artist to watch the progress of the staining, and to withdraw small trial slips of glass, painted with the principal tints used in the picture.

The muffle must be made of very refractory fire-clay, flat at its bottom, and only 5 or 6 inches high, with such an arched top as may make the roof strong, and so close on all sides as to exclude entirely the smoke and flame. On the bottom of the muffle a smooth bed of sifted lime, freed from water, about half an inch thick, must be prepared for receiving the pane of glass. Sometimes several plates of glass are laid over each other with a layer of dry pulverulent lime between each. The fire is now lighted, and most gradually raised, lest the glass should be broken; and after it has attained to its full heat, it must be kept up for 3 or 4 hours, more or less, according to the indications of the trial slips; the yellow colour being principally watched, as it is found to be the best criterion of the state of the others. When the colours are properly burnt in, the fire is suffered to die away, so as to anneal the glass.

STAINED-GLASS PIGMENTS.

_Flesh colour._--Take an ounce of red lead, two ounces of red enamel (Venetian glass enamel, from alum and copperas calcined together), grind them to fine powder, and work this up with spirits (alcohol) upon a hard stone. When slightly baked, this produces a fine flesh colour.

_Black colour._--Take 14-1/2 ounces of smithy scales of iron, mix them with two ounces of white glass (crystal), an ounce of antimony, and half an ounce of manganese; pound and grind these ingredients together with strong vinegar. A brilliant black may also be obtained by a mixture of cobalt blue with the oxides of manganese and iron. Another black is made from three parts of crystal glass, two parts of oxide of copper, and one of (glass of) antimony worked up together, as above.

_Brown colour._--An ounce of white glass or enamel, half an ounce of good manganese; ground together.

_Red, rose, and brown colours_, are made from peroxide of iron, prepared by nitric acid. The flux consists of borax, sand, and minium in small quantity.

_Red colour_, may be likewise obtained from one ounce of red chalk pounded, mixed with two ounces of white hard enamel, and a little peroxide of copper.

_A red_, may also be composed of rust of iron, glass of antimony, yellow glass of lead, such as is used by potters (or litharge), each in equal quantity; to which a little sulphuret of silver is added. This composition, well ground, produces a very fine red colour on glass. When protoxide of copper is used to stain glass, it assumes a bright red or green colour, according as the glass is more or less heated in the furnace, the former corresponding to the orange protoxide, the latter having the copper in the state of peroxide.

_Bistres and brown reds_, may be obtained by mixtures of manganese, orange oxide of copper, and the oxide of iron called umber, in different proportions. They must be previously fused with vitreous solvents.

_Green colour._--Two ounces of brass calcined into an oxide, two ounces of minium, and eight ounces of white sand; reduce them to a fine powder, which is to be enclosed in a well luted crucible, and heated strongly in an air-furnace for an hour. When the mixture is cold, grind it in a brass mortar. Green may, however, be advantageously produced by a yellow on one side, and a blue on the other. Oxide of chrome has been also employed to stain glass green.

_A fine yellow colour._--Take fine silver laminated thin, dissolve in nitric acid, dilute with abundance of water, and precipitate with solution of sea salt. Mix this chloride of silver, in a dry powder, with three times its weight of pipe-clay well burnt and pounded. The back of the glass pane is to be painted with this powder; for when painted on the face, it is apt to run into the other colours.

_Another yellow_ can be made by mixing sulphuret of silver with glass of antimony, and yellow ochre previously calcined to a red-brown tint. Work all these powders together, and paint on the back of the glass. Or silver _laminæ_ melted with sulphur, and glass of antimony, thrown into cold water, and afterwards ground to powder, afford a yellow.

_A pale yellow_ may be made with the powder resulting from brass, sulphur, and glass of antimony, calcined together in a crucible, till they cease to smoke; and then mixed with a little burnt yellow ochre.

_The fine yellow_ of M. Merand, is prepared from chloride of silver, oxide of zinc, white-clay, and rust of iron. This mixture, simply ground, is applied on the glass.

_Orange colour._--Take 1 part of silver powder, as precipitated from the nitrate of that metal by plates of copper, and washed; mix it with 1 part of red ochre and 1 of yellow, by careful trituration; grind into a thin pap with oil of turpentine or lavender, and apply this with a brush, dry, and burn in.

In the Philosophical Magazine, of December, 1836, the anonymous author of an ingenious essay, “On the Art of Glass-painting,” says, that if a large proportion of ochre has been employed with the silver, the stain is yellow; if a small proportion, it is orange-coloured; and by repeated exposure to the fire, without any additional colouring-matter, the orange may be converted into red; but this conversion requires a nice management of the heat. Artists often make use of panes coloured throughout their substance in the glass-house pots, because the perfect transparency of such glass gives a brilliancy of effect, which enamel painting, always more or less opaque, cannot rival. It was to a glass of this kind that the old glass-painters owed their splendid red. This is, in fact, the only point in which the modern and antient processes differ; and this is the only part of the art which was ever really lost. Instead of blowing plates of solid red, the old glass-makers (like those of Bohemia, for some time back,) used to _flash_ a thin layer of brilliant red over a substratum of colourless glass; by gathering a lump of the latter upon the end of their iron rod in one pot, covering it with a layer of the former in another pot, then blowing out the two together into a globe or cylinder, to be opened into circular tables, or into rectangular plates. The elegant art of tinging glass red by protoxide of copper, and flashing it on common crown glass, has become general within these few years.

That gold melted with flint glass stains it purple, was originally discovered and practised, as a profitable secret, by Kunckel. Gold has been recently used at Birmingham for giving a beautiful rose-colour to scent bottles. The proportion of gold should be very small, and the heat very great, to produce a good effect. The glass must contain either the oxide of lead, bismuth, zinc, or antimony; for crown glass will take no colour from gold. Glass combined with this metal, when removed from the crucible is generally of a pale rose-colour; nay, sometimes is as colourless as water, and does not assume its ruby colour till it has been exposed to a low red heat, either under a muffle or at the lamp. This operation must be nicely regulated; because a slight excess of fire destroys the colour, leaving the glass of a dingy brown, but with a blue (green?) transparency, like that of gold leaf. It is metallic gold which gives the colour; and, indeed, the oxide is too easily reduced, not to be converted into the metal by the intense heat which is necessarily required.

Upon the kindred art of painting in enamel, Mr. A. Essex has published an interesting paper in the same journal, for June, 1837, in which he says that the antient ruby glass, on being exposed to the heat of a glass-kiln, preserves its colour unimpaired, while the modern suffers considerable injury, and in some cases becomes almost black. Hence the latter cannot be painted upon, as the heat required to fix the fresh colour would destroy the beauty of the original basis. To obviate this difficulty, the artist paints upon a piece of plain glass the tints and shadows necessary for blending the rich ruby glow with the other parts of his picture, leaving those parts untouched where he wishes the ruby to appear in undiminished brilliancy, and fixes the ruby glass in the picture behind the painted piece, so that in such parts, the window is double-glazed. Mr. Essex employs, as did the late Mr. Muss, chrome oxide alone for greens; and he rejects the use of iron and manganese in his enamel colours.

Coloured transparent glass is applied as enamel in silver and gold _bijouterie_, previously _bright-cut_ in the metal with the graver or the rose-engine. The cuts, reflecting the rays of light from their numerous surfaces, exhibit through the glass, richly stained with gold, silver, copper, cobalt, &c., a gorgeous play of prismatic colours, varied with every change of aspect. When the enamel is to be painted on, it should be made opalescent by oxide of arsenic, in order to produce the most agreeable effect.

The artist in enamel has obtained from modern chemistry, preparations of the metals platinum, uranium, and chromium, which furnish four of the richest and most useful colours of his palette. Oxide of platinum produces a substantive rich brown, formerly unknown in enamel painting; a beautiful transparent tint, which no intensity or repetition of firing can injure. Colours proper for enamel painting, he says, are not to be purchased; those sold for the purpose, are adapted only for painting upon china. The constituents of the green enamel used by his brother, Mr. W. Essex, are, silica, borax, oxide of lead, and oxide of chrome.

Mr. Essex’s enamelling furnace is a cubic space of about 12 inches, and contains a fire-clay muffle, without either bottom or back, which is surrounded with coke, except in front. The entire draught of air which supplies the furnace, passes through the muffle; the plates and paintings being placed on a thin slab, made of tempered fire-clay, technically termed _planche_, which rests on the bed of coke-fuel. As the greatest heat is at the back of the muffle, the picture must be turned round while in the fire, by means of a pair of spring tongs. The above furnace serves for objects up to five inches in diameter; but for larger works a different furnace is required, for the description of which I must refer to the original paper.

Relatively to the receipts for enamel colours, and for staining and gilding on glass, for which twenty guineas were voted by the Society for the Encouragement of Arts, in the session of 1817, to Mr. R. Wynn, Mr. A. Essex says, in p. 446. of his essay--“the unfortunate artist who shall attempt to make colours for the purpose of painting in enamel from these receipts, will assuredly find, to his disappointment, that they are utterly useless.” In page 449. he institutes a comparison between Mr. Wynn’s complex _farrago_ for green, as published in the Transactions of the Society, with the simple receipt of his brother, as given above. It is a remarkable circumstance, that not one of our enamel artists, during a period of twenty years, should have denounced the fallacy of these receipts, and the folly of sanctioning imposture by a public reward. Should Mr. Essex’s animadversions be just, the well-intentioned Society in the Adelphi may, from the negligence of its committee, come to merit the _sobriquet_, “For the Discouragement of Arts.”

STAMPING OF METALS. The following ingenious machine for manufacturing metal spoons, forks, and other articles, was made the subject of a patent by Jonathan Hayne, of Clerkenwell, in May, 1833. He employs a stamping-machine with dies, in which the hammer is raised to a height between guides, and is let fall by a trigger. He prefers fixing the protuberant or relief portion of the die to the stationary block or bed of the stamping-machine, and the counterpart or intaglio to the falling hammer or ram.

The peculiar feature of improvement in this manufacture consists in producing the spoon, ladle, or fork perfect at one blow in the stamping-machine, and requiring no further manipulation of shaping, but simply trimming off the barb or fin, and polishing the surface, to render the article perfect and finished.

Heretofore, in employing a stamping-machine, or fly-press, for manufacturing spoons, ladles, and forks, it has been the practice to give the impressions to the handles, and to the bowls or prongs, by distinct operations of different dies, and after having so partially produced the pattern upon the article, the handles had to be bent and formed by the operations of filing and hammering.

By his improved form of dies, which, having curved surfaces and bevelled edges, allow of no parts of the faces of the die and counter-die to come into contact, he is enabled to produce considerable elevations of pattern and form, and to bring up the article perfect at one blow, with only a slight barb or fin upon its edge.

In the accompanying drawings, _fig._ 1042. is the lower or bed die for producing a spoon, seen edgewise; _fig._ 1043. is the face of the upper or counter-die, corresponding; _fig._ 1044. is a section, taken through the middle of the pair of dies, showing the space in which the metal is pressed to form the spoon.

To manufacture spoons, ladles, or forks according to his improved process, he first forges out the ingot into flat pieces, of the shape and dimensions of the die of the intended article; and if a spoon or ladle is to be made, gives a slight degree of concavity to the bowl part; but, if necessary, bends the back, in order that it may lie more steadily, and bend more accurately, upon the lower die; if a fork, he cuts or otherwise removes portions of the metal at those parts which will intervene between the prongs; and, having thus produced the rude embryo of the intended article, scrapes its entire surface clean and free from oxidation-scale or fire-strain, when it is ready to be introduced into the stamping-machine.

He now fixes the lower die in the bed of the stamping-machine, shown at _a_, _a_, in the elevations _figs._ 1045. and 1046., and fixes, in the hammer _b_, the upper or counter-die _c_, accurately adjusting them both, so that they may correspond exactly when brought together. He then places the rudely-formed article above described upon the lower die, and having drawn up the hammer to a sufficient elevation by a windlass and rope, or other ordinary means, lets go the trigger, and allows the hammer with the counter-die to fall upon the under die, on which the article is placed; when, by the blow thus given to the metal, the true and perfect figure and pattern of the spoon, ladle, or fork is produced, and which, as before said, will only require the removal of the slight edging of barb or fin, with polishing, to finish it.

On striking the blow, in the operation of stamping the article, the hammer will recoil and fly up some distance, and if allowed to fall again with reiterated blows, would injure both the article and the dies; therefore, to avoid this inconvenience, he causes the hammer on recoiling to be caught by a pair of palls locking into racks on the face of the standards, seen in _figs._ 1045. and 1046. In _fig._ 1045. the hammer _b_, of the stamping-machine, is seen raised and suspended by a rope attached to a pair of jointed hooks or holders _d_, _d_, the lower ends of which pass into eyes _e_, _e_, extending from the top of the hammer. When the lever or trigger _t_ is drawn forward, as in _fig._ 1046., the two inclined planes _g_, _g_, on the axle _h_, press the two legs of the holders _d_, _d_, inward, and cause their hooks or lower ends to be withdrawn from the eyes _e_, _e_, when the hammer instantly falls, and brings the dies together: such is the ordinary construction of the stamping-machine.

On the hammer falling from a considerable elevation, the violence of the blow causes it to recoil and bound upwards, as before mentioned; it therefore becomes necessary to catch the hammer when it has rebounded, in order to prevent the dies coming again together; this is done by the following mechanism:--

Two latch levers _i_, _i_, are connected by joints to the upper part of the hammer, and two pall levers _k_, _k_, turning upon pins, are mounted in the bridge _l_, affixed to the hammer. Two springs _m_, _m_, act against the lower arms of these levers, and press them outwards, for the purpose of throwing the palls at the lower ends of the levers into the teeth of the ratchet racks _n_, _n_, fixed on the sides of the upright standards.

Previously to raising the hammer, the upper ends of the pall levers _k_, are drawn back, and the latches _i_, being brought down upon them, as in _fig._ 1045., the levers _k_ are confined, and their palls prevented from striking into the side racks; but as the hammer falls, the ends of the latches _i_ strike upon the fingers _o_, _o_, fixed to the side standards, and liberate the palls, the lower ends of which, when the hammer rebounds, after stamping, catch into the teeth of the racks, as in _fig._ 1046., and thereby prevent the hammer from again descending.

STARCH; (_Amidon_, _Fecule_, Fr.; _Stärke_, Germ.); is a white pulverulent substance, composed of microscopic spheroids, which are bags containing the amylaceous matter. It exists in a great many different plants, and varies merely in the form and size of its microscopic particles; as found in some plants, it consists of spherical particles 1/1000 of an inch in diameter; and in others, of ovoid particles, of 1/300 or 1/400 of an inch. It occurs, 1. in the seeds of all the acotyledinous plants, among which are the several species of corns, and those of other _gramineæ_; 2. in the round perennial tap roots, which shoot up an annual stem; in the tuberose roots, such as potatos, the _Convolvulus batatas_ and _edulis_, the _Helianthus tuberosus_, the _Jatropha manihot_, &c., which contain a great quantity of it; 3. in the stems of several monocotyledinous plants, especially of the palm tribe, whence sago comes; but it is very rarely found in the stems and branches of the dicotyledinous plants; 4. it occurs in many species of lichen. Three kinds of starch have been distinguished by chemists; that of wheat, that called _inuline_, and lichen starch. These three agree in being insoluble in cold water, alcohol, ether, and oils, and in being converted into sugar by either dilute sulphuric acid or diastase. The main difference between them consists in their habitudes with water and iodine. The first forms with hot water a mucilaginous solution, which constitutes, when cold, the paste of the laundress, and is tinged blue by iodine; the second forms a granular precipitate, when its solution in boiling-hot water is suffered to cool, which is tinged yellow by iodine; the third affords, by cooling the concentrated solution, a gelatinous mass, with a clear liquor floating over it, that contains little starch. Its jelly becomes brown-gray with iodine.

1. _Ordinary starch._--This may be extracted from the following grains:--wheat, rye, barley, oats, buckwheat, rice, maize, millet, spelt; from the siliquose seeds, as peas, beans, lentiles, &c.; from tuberous and tap roots, as those of the potato, the orchis, manioc; arrowroot, batata, &c. Different kinds of corn yield very variable quantities of starch. Wheat differs in this respect, according to the varieties of the plant, as well as the soil, manure, season, and climate. See BREAD.

Wheat partly damaged by long keeping in granaries, may be employed for the manufacture of starch, as this constituent suffers less injury than the gluten; and it may be used either in the ground or unground state.

1. _With unground wheat._--The wheat being sifted clean, is to be put into cisterns, covered with soft water, and left to steep till it becomes swollen and so soft as to be easily crushed between the fingers. It is now to be taken out, and immersed in clear water of a temperature equal to that of malting-barley, whence it is to be transferred into bags, which are placed in a wooden chest containing some water, and exposed to strong pressure. The water rendered milky by the starch being drawn off by a tap, fresh water is poured in, and the pressure is repeated. Instead of putting the swollen grain into bags, some prefer to grind it under vertical edge-stones, or between a pair of horizontal rollers, and then to lay it in a cistern, and separate the starchy liquor by elutriation with successive quantities of water well stirred up with it. The residuary matter in the sacks or cisterns contains much vegetable albumen and gluten, along with the husks; when exposed to fermentation, it affords a small quantity of starch of rather inferior quality.

The above milky liquor, obtained by expression or elutriation, is run into large cisterns, where it deposits its starch in layers successively less and less dense; the uppermost containing a considerable proportion of gluten. The supernatant liquor being drawn off, and fresh water poured on it, the whole must be well stirred up, allowed again to settle, and the surface-liquor again withdrawn. This washing should be repeated as long as the water takes any perceptible colour. As the first turbid liquor contains a mixture of gluten, sugar, gum, albumen, &c., it ferments readily, and produces a certain portion of vinegar, which helps to dissolve out the rest of the mingled gluten, and thus to bleach the starch. It is, in fact, by the action of this fermented or soured water, and repeated washing, that it is purified. After the last deposition and decantation, there appears on the surface of the starch a thin layer of a slimy mixture of gluten and albumen, which, being scraped off, serves for feeding pigs or oxen; underneath will be found a starch of good quality. The layers of different sorts are then taken up with a wooden shovel, transferred into separate cisterns, where they are agitated with water, and passed through fine sieves. After this pap is once more well settled, the clear water is drawn off, the starchy mass is taken out, and laid on linen cloths in wicker baskets, to drain and become partially dry. When sufficiently firm, it is cut into pieces, which are spread upon other cloths, and thoroughly desiccated in a proper drying-room, which in winter is heated by stoves. The upper surface of the starch is generally scraped, to remove any dusty matter, and the resulting powder is sold in that state. Wheat yields, upon an average, only from 35 to 40 per cent. of good starch. It should afford more by skilful management.

2. In this country, wheat crushed between iron rollers is laid to steep in as much water as will wet it thoroughly; in four or five days the mixture ferments, soon afterwards settles, and is ready to be washed out with a quantity of water into the proper fermenting vats. The common time allowed for the steep, is from 14 to 20 days. The next process consists in removing the stuff from the vats into a stout round basket set across a back below a pump. One or two men keep going round the basket, stirring up the stuff with strong wooden shovels, while another keeps pumping water, till all the _farina_ is completely washed from the bran. Whenever the subjacent back is filled, the liquor is taken out and strained through hair sieves into square frames or cisterns, where it is allowed to settle for 24 hours; after which the water is run off from the deposited starch by plug taps at different levels in the side. The thin stuff, called _slimes_, upon the surface of the starch, is removed by a tray of a peculiar form. Fresh water is now introduced, and the whole being well mixed by proper agitation, is then poured upon fine silk sieves. What passes through is allowed to settle for 24 hours; the liquor being withdrawn, and then the slimes, as before, more water is again poured in, with agitation, when the mixture is again thrown upon the silk sieve. The milky liquor is now suffered to rest for several days, 4 or 5, till the starch becomes settled pretty firmly at the bottom of the square cistern. If the starch is to have the blue tint, called Poland, fine smalt must be mixed in the liquor of the last sieve, in the proportion of 2 or 3 lbs. to the cwt. A considerable portion of these slimes may, by good management, be worked up into starch by elutriation and straining.

The starch is now fit for _boxing_, by shovelling the cleaned deposit into wooden chests, about 4 feet long, 12 inches broad, and 6 inches deep, perforated throughout, and lined with thin canvas. When it is drained and dried into a compact mass, it is turned out by inverting the chests upon a clean table, where it is broken into pieces 4 or 5 inches square, by laying a ruler underneath the cake, and giving its surface a cut with a knife, after which the slightest pressure with the hand will make the fracture. These pieces are set upon half-burned bricks, which by their porous capillarity imbibe the moisture of the starch, so that its under surface may not become hard and horny. When sufficiently dried upon the bricks, it is put into a stove (which resembles that of a sugar refinery), and left there till tolerably dry. It is now removed to a table, when all the sides are carefully scraped with a knife; it is next packed up in the papers in which it is sold; these packages are returned into the stove, and subjected to a gentle heat during some days; a point which requires to be skilfully regulated.

Mr. Samuel Hall obtained a patent for bleaching starch by chloride of lime in 1821. Chlorine water would probably be preferable, and might prove useful in operating upon damaged wheat.

The sour water of the starch manufacture contains, according to Vauquelin, acetic acid, acetate of ammonia, alcohol, phosphate of lime, and gluten.

During the drying, starch splits into small prismatic columns, of considerable regularity. When kept dry, it remains unaltered for a very long period. When it is heated to a certain degree in water, the envelopes of its spheroidal particles burst, and the _farina_ forms a mucilaginous emulsion, magma, or paste. When this apparent solution is evaporated to dryness, a brittle horny-looking substance is obtained, quite different in aspect from starch, but similar in chemical habitudes. When the moist paste is exposed for 2 or 3 months to the air in summer, the starch is converted into sugar to the amount of one-third or one-half of its weight, into gum, and gelatinous starch called _amidine_ by De Saussure, with occasionally a resinous matter. This curious change goes on even in close vessels.

_Starch from potatos._--From the following table of analyses, it appears that potatos contain from 24 to 30 per cent. of dry substance:--

+-------------------+-------+-----------+--------+-----------+------+
| | | Fibrous | Veg. |Gum, Sugar,| |
| |Starch.|parenchyma.|Albumen.|and Salts. |Water.|
+-------------------+-------+-----------+--------+-----------+------+
|Red potato | 15·0 | 7·0 | 1·4 | 9·2 | 75·0 |
|Germinating potatos| 15·2 | 6·8 | 1·3 | 3·7 | 73·0 |
|Kidney potatos | 9·1 | 8·8 | 0·8 | --- | 81·3 |
|Large red potatos | 12·9 | 6·0 | 0·7 | --- | 78·0 |
|Sweet potatos | 15·1 | 8·2 | 0·8 | --- | 74·3 |
|Peruvian potatos | 15·0 | 5·2 | 1·9 | 1·9 | 76·0 |
|English potatos | 12·9 | 6·8 | 1·1 | 1·7 | 77·5 |
|Parisian potatos | 13·3 | 6·8 | 0·9 | 4·8 | 73·1 |
+-------------------+-------+-----------+--------+-----------+------+

_Manufacture of potato starch._--The potatos are first washed in a cylindrical cage formed of wooden spars, made to revolve upon a horizontal axis, in a trough filled with water to the level of the axis. They are then reduced to a pulp by a rasping machine, similar to that represented in _figs._ 1047, 1048., where _a_ is a wooden drum covered with sheet-iron, roughened outside with numerous prominences, made by punching out holes from the opposite side. It is turned by a winch fixed upon each end of the shaft. The drum is enclosed in a square wooden box, to prevent the potato-mash from being scattered about. The hopper _b_ is attached to the upper frame, has its bottom concentric with the rasp-drum, and nearly in contact with it. The pulp chest _c_ is made to slide out, so as when full to be readily replaced by another. The two slanting boards _d_, _d_, conduct the pulp into it. A moderate stream of water should be made to play into the hopper upon the potatos, to prevent the surface of the rasp from getting foul with fibrous matter. Two men, with one for a relay, will rasp, with such a machine, from 2-1/2 to 3 tons of potatos in 12 hours.

The potato pulp must be now elutriated upon a fine wire or hair sieve, which is set upon a frame in the mouth of a large vat, while water is made to flow upon it from a spout with many jets. The pulp meanwhile must be stirred and kneaded by the hand, or by a mechanical brush-agitator, till almost nothing but fibrous particles are left upon the sieve. These, however, generally retain about 5 per cent. of starch, which cannot be separated in this way. This parenchyma should therefore be subjected to a separate rasping upon another cylinder. The water turbid with starch is allowed to settle for some time in a back; the supernatant liquor is then run by a cock into a second back, and after some time into a third, whereby the whole starch will be precipitated. The finest powder collects in the last vessel. The starch thus obtained, containing 33 per cent. of water, may be used either in the moist state, under the name of _green fecula_, for various purposes, as for the preparation of dextrine, and starch syrup; or it may be preserved under a thin layer of water, which must be renewed from time to time, to prevent fermentation; or lastly, it may be taken out and dried.

In trials made with St. Etienne’s rasp and starch machinery, in Paris, which was driven by two horses, nearly 18 cwt. of potatos were put through all the requisite operations in one hour, including the pumping of the water. The product in starch amounted to from 17 to 18 per cent. of the potatos. The quicker the process of potato-starch making, the better is its quality.

_Starch from certain foreign plants._--1. From the pith of the _sago palm_. See SAGO.

2. From the roots of the _Maranta arundinacea_, of Jamaica, the Bahamas, and other West India islands, the powder called arrow-root is obtained, by a process analogous to that for making potato starch.

3. From the root of the _Manioc_, which also grows in the West Indies, as well as in Africa, the _cassava_ is procured, by a similar process. The juice of this plant is poisonous, from which the wholesome starch is deposited. When dried with stirring upon hot iron plates, it agglomerates into small lumps, called _tapioca_; being a gummy fecula.

The characters of the different varieties of starch can be learnt only from microscopic observation; by which means also their sophistication or admixture may be readily ascertained.

Starch, from whatever source obtained, is a white soft powder, which feels crispy, like flowers of sulphur, when pressed between the fingers; it is destitute of taste and smell, unchangeable in the atmosphere, and has a specific gravity of 1·53. I have already described the particles as spheroids enclosed in a membrane. The potato contains some of the largest, and the millet the smallest. Potato starch consists of truncated ovoids, varying in size from 1/300 to 1/3000 of an inch; arrow-root, of ovoids varying in size from 1/800 to 1/2000 of an inch; flower starch, of insulated globules about 1/1000 of an inch; cassava, of similar globules assembled in groups. These measurements I have made with a good achromatic microscope, and a divided glass-slip micrometer of Tully.

For the saccharine changes which starch undergoes by the action of _diastase_, see FERMENTATION.

_Lichenine_, a species of starch obtained from Iceland moss (_Cetraria islandica_), as well as _inuline_, from elecampane (_Inula Helenium_), are rather objects of chemical curiosity, than of manufactures.