Chapter C: D E F are the four printing cylinders, named in the order of their (23)

The ribs are scraped with a bit of glass cut circularly, in order to render them very pliant. By drawing the edge of a blunt knife over the filaments they assume the curly form so much admired. The hairs of a dingy colour are dyed black. For 20 pounds of feathers, a strong decoction is made of 25 pounds of logwood in a proper quantity of water. After boiling it for 6 hours, the wood is taken out, 3 pounds of copperas are thrown in; and, after continuing the ebullition for 15 or 20 minutes, the copper is taken from the fire. The feathers are then immersed by handfuls, thoroughly soaked, and worked about; and left in for two or three days. They are next cleansed in a very weak alkaline lye, and soaped three several times. When they feel very soft to the touch, they must be rinsed in cold water, and afterwards dried. White feathers are very difficult to dye a beautiful black. The acetate of iron is said to answer better than the sulphate, as a mordant.

For dyeing other colours, the feathers should be previously well bleached by the action of the sun and the dew; the end of the tube being cut sharp like a toothpick, and the feathers being planted singly in the grass. After fifteen days’ exposure, they are cleared with soap as above described.

_Rose colour_ or _pink_, is given with safflower and lemon juice.

_Deep red_, by a boiling hot bath of Brazil wood, after aluming.

_Crimson._ The above deep red feathers are passed through a bath of cudbear.

_Prune de Monsieur._ The deep red is passed through an alkaline bath.

_Blues of every shade_, are dyed with the indigo vat.

_Yellow_; after aluming, with a bath of turmeric or weld.

Other tints may be obtained by a mixture of the above dyes.

Feathers have some more useful employments than the decoration of the heads of women and soldiers. In one case, they supply us with a soft elastic down on which we can repose our wearied frames, and enjoy sweet slumbers. Such are called _bed_ feathers. Others are employed for writing, and these are called _quills_.

Goose feathers are most esteemed for beds, and they are best when plucked from the living bird, which is done thrice a year, in spring, midsummer, and the beginning of harvest. The qualities sought for in bed feathers, are softness, elasticity, lightness, and warmth. Their only preparation when cleanly gathered are a slight beating to clear away the loose matter, but for this purpose they must be first well dried either by the sun or a stove. Bleaching with lime water is a bad thing, as they can never be freed from white dust afterwards.

The feathers of the eider duck, _anas mollissima_, called eider down, possess in a superior degree all the good qualities of goose down. It is used only as a covering to beds, and never should be slept upon, as it thereby loses its elasticity.

_Quills_ for writing. These consist usually of the feathers plucked out of the wings of geese. Dutch quills have been highly esteemed, as the Dutch were the first who hit upon the art of preparing them well, by clearing them both inside and outside from a fatty humour with which they are naturally impregnated, and which prevents the ink from flowing freely along the pens made with them. The Dutch for a long time employed hot cinders or ashes to attain this end; and their secret was preserved very carefully, but it at length transpired, and the process was then improved. A bath of very fine sand must be kept constantly at a suitable temperature, which is about 140° F.; into this, the quill end of the feather must be plunged, and left in it a few instants. On taking them out they must be strongly rubbed with a piece of flannel, after which they are found to be white and transparent. Both carbonate of potash in solution and dilute sulphuric acid have been tried to effect the same end, but without success. The yellow tint which gives quills the air of age, is produced by dipping them for a little in dilute muriatic acid, and then making them perfectly dry. But this process must be preceded by the sand-bath operation. The above is the French process.

Quills are dressed by the London dealers in two ways; by the one, they remain of their natural colour; by the other, they acquire a yellow tint. The former is called the Dutch method, and the principal workman is called a Dutcher. He sits before a small stove fire, into which he thrusts the barrel of the quill for about a second, then lays its root quickly below his blunt-edged knife called a hook, and, pressing this firmly with the left hand, draws the quill briskly through with his right. The bed on which the quill is laid to receive this pressure is called the plate. It is a rectangular smooth lump of iron, about 3 inches long, 1-1/2 broad, and 2-1/2 thick, which is heated on his stove to about the 350th degree Fahr. The hook is a ruler of about 15 inches in length, somewhat like the patten-makers’ knife, its fulcrum being formed at the one end by a hook and staple, and the power of pressure being applied by the hand at the other end. The quill, rendered soft and elastic by the heat, endures the strong scraping action of the tool, and thus gets stripped of its opaque outer membrane, without hazard of being split. A skilful workman can pass 2000 quills through his hands in a day of 10 hours.

They are next cleaned by being scrubbed by a woman with a piece of rough dog-fish skin, and finally tied up by a man in one quarter of hundred bundles.

In another mode of dressing quills, they are steeped a night in decoction of turmeric, to stain them yellow; taken out and dried in warm sand contained in a pot, then scraped by the Dutcher as above described. The first are reckoned to make the best pens, though the second may appear more beautiful.

Crow quills for draughtsmen, as well as swan quills, are prepared in the same way. The quills plucked from well-fed living birds have most elasticity, and are least subject to be moth-eaten. The best are those plucked, or which are spontaneously cast in the month of May or June, because they are then fully ripe. In the goose’s wing the five exterior feathers only are valuable for writing. The first is the hardest and roundest of all, but the shortest. The next two are the best of the five. They are sorted into those of the right and the left wing, which are differently bent. The heaviest quills are, generally speaking, the best. Lately, steaming for four hours has been proposed as a good preparation.

FECULA (_Fecule_, Fr.; _Stärkemehl_, Germ.); sometimes signifies corn flour, sometimes starch from whatever source obtained.

FELSPAR (_Orthose_, Fr.; _Feldspath_, Germ.) is a mineral crystallizing in oblique rhomboidal prisms, susceptible of two cleavages; lustre more pearly than vitreous; spec. grav. 2·39 to 2·58; scratches glass; yields no water when calcined; fusible at the blowpipe into a white enamel; not affected by acids. The liquid left from its analytical treatment with nitrate of baryta, nitric acid, and carbonate of ammonia, affords on evaporation an alkaline residuum which precipitates platina from its chloride, and appears from this, as well as other tests, to be potash. Felspar consists of--silica, 66·75; alumina, 17·50; potash, 12; lime, 1·25; oxide of iron, 0·75. _Rose._ This mineral is a leading constituent of granite; and in its decomposed state furnishes the petuntse or Cornish stone, so much used in the porcelain and best pottery manufactures.

FELTING; (_Feutrage_, Fr.; _Filzen_, Germ.) is the process by which loose flocks of wool, and hairs of various animals, as the beaver, rabbit, hare, &c., are mutually interlaced into a compact textile fabric. The first step towards making felt is to mix, in the proper proportions, the different kinds of fibres intended to form the stuff; and then, by the vibratory strokes of the bowstring, to toss them up in the air, and to cause them to fall as irregularly as possible, upon the table, opened, spread, and scattered. The workman covers this layer of loose flocks with a piece of thick blanket stuff slightly moistened; he presses it with his hands, moving the hairs backwards and forwards in all directions. Thus the different fibres get interlaced, by their ends pursuing ever tortuous paths; their vermicular motion being always, however, root foremost. As the matting gets denser, the hand pressure should be increased in order to overcome the increasing resistance to the decussation.

A first thin sheet of soft spongy felt being now formed, a second is condensed upon it in like manner, and then a third, till the requisite strength and thickness be obtained. These different pieces are successively brought together, disposed in a way suitable to the wished-for article, and united by continued dexterous pressure. The stuff must be next subjected to the fulling mill. See HAT MANUFACTURE.

FERMENT (Eng. and Fr.; _Hefe_, Germ.) is the substance which, when added in a small quantity to vegetable or animal fluids, tends to excite those intestine motions and changes which accompany fermentation. It seems to be the result of an alteration which vegetable albumen and gluten undergo with contact of air amidst a fermenting mass. The precipitate or lees which fall down when fermentation is finished consist of a mixture of the fermenting principle with the insoluble matters contained in the fermented liquor, some of which, like hordeine, existed in the worts, and others are probably generated at the time.

To prepare a pure ferment, or at least a compound rich in that principle, the precipitate separated during the fermentation of a clear infusion of malt, commonly called yeast or barm, is made use of. This pasty matter must be washed in cold distilled water, drained and squeezed between the folds of blotting paper. By this treatment it becomes a pulverulent mass, composed of small transparent grains, yellowish gray when viewed in the compound microscope. It contains much water, and is therefore soft, like moist gluten and albumen. When dried, it becomes like these bodies, translucid, yellowish brown, horny, hard, and brittle. In the soft humid state it is insipid, inodorous, insoluble in water and alcohol. If, in this state, the _ferment_ be left to itself at a temperature of from 60° to 70° F., but not in too dry a situation, it putrefies with the same phenomena as vegetable gluten and albumen, and leaves, like them, a residuum resembling old cheese.

At the beginning of this change, particularly if the ferment be enclosed in a limited portion of air, there is an absorption of oxygen gas with a fivefold disengagement of carbonic acid gas; while acetic acid makes its appearance in the substance. When distilled by itself it affords the same products as gluten. Dilute acids dissolve it very readily; and so does potash with the production of ammonia, a peculiar circumstance, for in dissolving gluten the alkali causes no such evolution.

The property possessed by yeast of determining the fermentation of a properly diluted solution of sugar is very fleeting, and is lost by very trifling alterations. It is destroyed by complete desiccation, and cannot be restored by moistening it again. The attempts made in London to squeeze out the liquid part of yeast in bags placed in a powerful press, and to obtain a solid cake, in order to transport ferment to India, have had but a very partial success; for its virtue is so impaired that it will rarely excite a perfect fermentation in the best prepared worts. The same method is adopted in Germany, to send yeast to only moderate distances; and therefore with more advantage.

If yeast be boiled for ten minutes, it loses the greater part of its fermenting power, and by longer boiling it becomes inert.

When alcohol is poured upon yeast, it immediately destroys its fermenting faculties, though, on filtering it off, it seems to carry no remarkable principle with it. One thousandth part of sulphuric acid equally deprives yeast of its peculiar property, and so does a little strong acetic acid. All the acids and the salts, especially those which part readily with their oxygen, produce the same effect. A very small quantity of sulphurous acid, or sulphites, mustard powder, particularly the volatile oil of mustard, and in general the volatile oils that contain sulphur, as well as the vegetables which yield them, such as horse-radish and garlick, all kill the fermenting agent. Lastly, fermentation is completely stopped by a moderate depression of temperature.

During fermentation the yeast undergoes a change; it loses the property of causing another wort to ferment. This change probably depends upon the chemical reaction between the ferment and the sugar that is decomposed; for a certain quantity of yeast can effect the fermentation of only a certain quantity of sugar, and all the sugar exceeding this quantity remains unaltered in the liquor. It has been concluded from some rather loose experiments, that one part and a half of yeast (supposed to be in the dry state), is adequate to the fermentation of a solution of 100 parts of pure sugar. When such a solution is fermented by the precise proportion of yeast, the fermenting principle is exhausted, for no new yeast is formed in it. There is a deposit indeed to about half the weight of the yeast employed, of a white matter insoluble in water, which affords no ammonia by dry distillation, and is incapable of acting as a ferment upon a fresh saccharine solution.

Of all the bodies convertible into yeast during fermentation, vegetable gluten and albumen possess the most rapid and energetic powers. But ordinary glue, isinglass, animal fibrine, curd or _caseum_, albumine, urine and other azotized substances, all enjoy the property of causing a solution of sugar to ferment; with this difference, that whilst yeast can establish a complete fermentation in less than an hour, at a temperature of about 68°, the above substances require several days, with a heat of from 77° to 87° F., for becoming ferments, and for occasioning fermentation. Substances devoid of nitrogen do not produce a ferment.

FERMENTATION. (Eng. and Fr.; _Gährung_, Germ.) When organic substances, under the influence of water, air, and warmth, are abandoned to the reciprocal operation of their proximate principles, (sugar, starch, gluten, &c.), they are entirely changed and decomposed, so that their ultimate principles (oxygen, hydrogen, carbon, and in some cases azote,) combine in new proportions, and thus give birth to various new compounds. To this process, the general name of fermentation has been given. These operations and their products differ according to the differences of the substances, and of the circumstances in which they are placed. The following may be enumerated as sufficiently distinct species of fermentation. 1. The _saccharine_ fermentation, in which starch and gum are changed into sugar. 2. The _vinous_ fermentation, in which sugar is converted into alcohol. 3. The _mucilaginous_ fermentation, in which sugar is converted into slime, instead of alcohol. 4. The _acetous_ fermentation, in which alcohol and other substances are converted into vinegar. 5. The _putrid_ fermentation or putrefaction, which characterizes particularly the decomposition of azotized organic substances.

1. _The saccharine fermentation._ When a paste made by boiling one part of starch with twelve parts of water is left entirely to itself, water merely being stirred in as it evaporates, at the end of a month or two in summer weather it is changed into sugar, equal in weight to from one third to one half of the starch, and into gum, equal to from one fifth to one tenth, with a residuum of starch paste somewhat altered. This saccharifying process advances much quicker through the co-operation of vegetable albumine or gluten, acting as a ferment. If we boil two parts of potato starch into a paste with twenty parts of water, mix this paste with one part of the gluten of wheat flour, and set the mixture for 8 hours in a temperature of from 122° to 167° F., the mixture soon loses its pasty character, and becomes by degrees limpid, transparent and sweet, passing at the same time first into gum, and then into sugar. The remainder consists of the unchanged starch with the altered gluten, which has become sour, and has lost the faculty of acting upon fresh portions of starch. It is probable, however, that the sugar formation in the first case, when the starch undergoes a spontaneous change, may be due to the action of a small portion of gluten and albumine left in the starch, since a putrefactive smell is eventually evolved indicative of that azotized matter. The gum into which during this process the starch is first converted, and which becomes afterwards sugar, is of the same nature as British gum, formed by the roasting of starch.

This production of sugar takes place in the germination and kiln-drying of malt; and the mashing of the brewer as well as the sweetening of bread in baking, rests upon the same principles. In many cases the vinous fermentation precedes the saccharification, or accompanies it; the starchy parts of the fermenting mass changing into sugar, while the previously formed sugar becomes wine or beer. In the sweetening of fruits by keeping, a similar process occurs; the gummy and starchy fibres become sugar from the action of the glutinous ferment which they contain; as happens also to the juices of many fruits which sweeten for a little while after they have been expressed.

The nature of this sugar formation through the influence of gluten upon starch, is undoubtedly the same as the conversion of starch into sugar, by boiling it with sulphuric acid; though the whole theory of this change is not entirely developed.

The most energetic substance for the conversion of starch into sugar, is the malt of barley. According to the researches of Payen and Persoz, the gum which by this process is first formed, may be prevented from going into sugar, by merely exposing it to a boiling heat, and hence we have it in our power either to make sugar or gum at pleasure. Of finely ground malt from 10 to 25 parts must be taken for 100 parts of starch. Into a pan placed in a water bath, 400 parts of water being warmed to from 77° to 86° F., the ground malt must be stirred in, and the temperature must be raised to 140°. The 100 parts of starch must now be added, and well mixed. The heat is then to be increased to 158°F.; and be so regulated that it shall not fall below 149°, nor rise above 167°. In the course of 20 or 30 minutes the originally milky and pasty liquid will become gradually more attenuated, and eventually it will turn as fluid nearly as water. This is the point of time in which the starch has passed into gum, or into the substance lately denominated _dextrine_ by the chemists. Should this mucilaginous matter, which appears to be a mixture of gum and a little starchy sugar, be wished for in that state, the temperature of the liquid must be suddenly raised to the boiling point, whereby the further action of the malt upon it is stopped. But on the other hand if sugar be desired, then the temperature must be steadily maintained at from 158° to 167° for three quarters of an hour, in which time the greater part of the starch will have become sugar, and from the evaporation of the fluid a starchy syrup will be obtained, entirely similar to that procurable by the action of very dilute sulphuric acid upon starch.

The substance which operates this saccharine change, or the appropriate yeast of the sugar fermentation, which had been previously imagined to be a residuum of gluten or vegetable albumen in the germinated grain, has been traced by Payen and Persoz to a peculiar proximate vegetable principle called by them _diastase_. This substance is generated during the germination of barley, oats, and wheat, and may be obtained separately by infusing the ground malt in a small quantity of cold water, straining off the liquor, then filtering it, and heating the clear solution in a water bath to the temperature of 158° F. The greater part of the vegetable albumen is thus coagulated, and must be separated by a fresh filtration; the liquid is afterwards treated with alcohol as long as the flocculent precipitate of diastase falls. In order to purify it still more completely from the azotized matter, it may be once more dissolved in water, and again precipitated by alcohol. When dried at a low temperature, it appears as a white solid, which contains no azote, is insoluble in strong alcohol, but dissolves in weak alcohol and water. Its solution is neutral and tasteless; and if left to itself, it changes spontaneously sooner or later according to the degree of warmth, and becomes sour. At the temperature of from 149° to 168°, it has the property of converting starch into gum or dextrine, and sugar; and, when sufficiently pure, it does this with such energy, that one part of it is capable of saccharifying 2000 parts of dry starch. It acts the more rapidly the larger its proportion. Whenever the solution of diastase with starch or dextrine, has been heated to the boiling point, it loses the property of transforming these substances. One hundred parts of well malted barley appear to contain about one part of this new body.

2. _The Vinous Fermentation._--In this fermentation the sugar existing in watery solution is, by the operation of the ferment or yeast, converted into alcohol, with disengagement of carbonic acid gas. If we dissolve one part of pure sugar in ten parts of water, and leave the solution in a temperature of from 68° to 77° F., which is that most favourable to fermentation, it will remain unaltered. But if we stir into that solution some beer yeast, the phenomena of fermentation soon appear in the above circumstances; for carbonic acid gas is evolved, with intestine movements of the liquid, and an increase of its temperature. A body of yeast rises to the surface, and exhibits a continual formation and rupture of air bubbles. At length the sugar being in a great measure decomposed, the motions cease, the liquor becomes clear, and instead of being a syrup, it is now a dilute alcohol. The yeast has by this time fallen to the bottom in a somewhat compact form, and of a whitish colour, deprived of the property of exciting fermentation in fresh syrup, provided no undue excess of it was added at first, for that alone would remain effective. Experience shows that for the conversion of a determinate quantity of sugar by fermentation, a determinate quantity of yeast is necessary, which has been estimated at about 1-1/2 per cent. in the dry state. When the yeast has been decomposed by fermenting its definite proportion of sugar, it loses its fermentable property, and leaves the excess of sugar unaffected, forming a sweet vinous solution. The same thing happens if the yeast be separated from the wort by a filter in the progress of the fermentation, for then all intestine motion speedily stops, although much saccharine matter remains.

In the juices of sweet fruits, of grapes, for example, the ferment is intimately associated with the sugar. It is at first soluble and inactive, till it absorbs oxygen from the atmosphere, whereby it becomes an operative ferment, but, at the same time, insoluble, so as to precipitate at the end of the process. When the expressed juice of the grape, or _must_, is inclosed in a vessel out of contact of air, and there subjected to the heat of boiling water, the small portion of oxygen present is rendered inactive, and the liquor experiences no fermentative change. If the grapes be squeezed in an atmosphere deprived of oxygen, and confined in the same, the juice will also remain unaltered. Recently expressed grape juice is limpid, and manifests the commencement of fermentation by the separation of the yeasty substance, which can take place only with access of air. The solution becomes turbid after a certain time, gas begins to be evolved, and the separated ferment decomposes the sugar. At the end of the process the yeast collects at the bottom of the vessel, usually in larger quantity than was sufficient to complete the fermentation; and hence a considerable portion of it possesses still the fermentative faculty. The fermentation itself, when once begun, that is, whenever the yeasty particles are evolved, and float in the liquid, for which evolution a very minute quantity of oxygen is sufficient, is thenceforth independent of the contact of air, and goes on as well in close as in open vessels; so that the production of alcohol and carbonic acid depends solely upon the mutual reaction of the ferment and the sugar.

The yeast, which may be obtained tolerably pure from a fine infusion of malt in a state of fermentation, after being washed with cold water to separate the soluble, gummy, and saccharine matter, and after being pressed between folds of blotting paper, constitutes a pulverulent, grayish yellow, granular substance, destitute of both taste and smell, insoluble both in water and alcohol. Cold water dissolves, indeed, only 1/400, and boiling water very little more.

The essentially operative constituent of yeast is a peculiar azotized matter, which in the wine vat is mixed with some tartar and other salts, and in the beer tun with gum, starch, &c. This animalized substance may be obtained in a separate state, according to Braconnot, by acting upon the washed yeast powder with a weak lye of carbonate of potash, and by decomposing the solution with vinegar, whereby the matter is thrown down in a gelatinous form. The substance thus obtained is insoluble in cold water and alcohol, but dissolves readily in very dilute alkaline lyes, and even in lime water. When diffused through water, it assumes a homogeneous aspect, as if it were really dissolved; but when this mixture is heated, the animalized matter coagulates, and separates in thick flocks. In this state it has lost its former properties, being no longer soluble in alkaline lyes, even when concentrated. Acids exercise no solvent power over this peculiar matter; they precipitate it from its solutions, as do also the earthy and metallic salts, which, moreover, combine with it. This is also the case with tannin. The combination of the ferment stuff with acids increases the stability of its constitution, and counteracts its tendency to influence solutions of sugar. These properties of the operative principle of yeast explain many of the phenomena of fermentation, as we shall presently see.

The animalized matter of yeast resembles gluten, albumen, caseum, and other azotized substances; if any one of these be put into a saccharine solution ready for fermentation, it will begin to operate a change, when aided by warmth and time, if it be previously decomposed in some measure to facilitate its influence; or if these substances be brought into a slightly putrescent state beforehand, they will cause more speedy fermentation. Thus white of egg, when added to saccharine liquors, requires a period of three weeks, with a temperature of 96° F., before it will excite fermentation; afterwards the excess of the albumen forms a precipitate which may be used instead of yeast upon other sweet worts. The rapidity with which such azotized substances are capable of being converted into ferments of more or less purity and power is very variable; vegetable gluten and albumen being best fitted for this purpose. This conversion is accelerated when the sweet liquor in which the substance is diffused or dissolved has already begun to ferment; whence it appears that the presence of carbonic acid gas, combined with the liquor, is here of singular influence. Upon it, in fact, the formation and elimination of the yeast in fermenting liquors depend.

A solution of pure sugar, which has been made to ferment by the addition of yeast, furnishes no new yeast; but there remains after the process a portion of the yeast originally mixed, in an altered inoperative condition, should its quantity have been exactly adequate to the decomposition of the sugar, or in an operative state, should the quantity have been originally excessive.

But if the fermentable liquor contains vegetable albumen and gluten, as is commonly the case with the sweet juices of fruits and beer worts, these substances become changed into ferments in the course of the fermentation induced by the yeast, and, being superfluous, so to speak, for that particular process, they remain entire at the end, and may be collected for use in other operations.

Upon this principle is founded the increased production of yeast, and the manufacture of what has been called _artificial barm_, in which the fermentation is conducted chiefly with a view to the formation of yeast. To the fermenting mass, those kinds of meal are added which abound in albumen and gluten, as barley, beans, or wheat, for instance; and the process is similar to the production of a great lump of leaven, from the action of a small piece of it upon dough. The following prescription will illustrate this subject. Take three ounces of bean flour, add to it five quarts of boiling water, and boil the mixture for half an hour. Pour the decoction into a vessel, and stir into it, while hot, 56 ounces of wheaten flour. After the mixture cools to the temperature of 54° F., add to it about two quarts of beer barm, stirring the whole well together. About 24 hours after the commencement of the fermentation, incorporate with the mixture 112 ounces of barley or bean flour, till it becomes a uniform dough, which must be thoroughly kneaded, rolled out into cakes about an inch thick, and cut into pieces of the size of a dollar. These cakelets must be dried upon laths in the sun in favourable weather, and then put up in a dry situation. For use, one of these discs is to be broken into pieces, laid in warm water, and set in a warm place during 12 hours. The soft mass will then serve the purpose of beer yeast.

Or we may mix equal parts of barley malt, wheat malt, and crushed rye, pour water at the temperature of 122° F. over them into a tub till it stand a span above their surface; then stir well together, and allow the whole to remain at rest for a few hours, till it cools to about 65° F. We must now add for each pound of the mingled meals, a quarter of an ounce of beer barm. The tub must be then covered, and preserved at a temperature of 63° F. The husks, as they begin to rise to the surface, in consequence of the fermentation, must be taken off, and squeezed through a cloth over the vessel. When the meal comes afterwards to subside to the bottom, the whole must be strained through a canvas bag, and freed from the superfluous moisture by squeezing. The bag with its doughy mass must next be surrounded with dry ashes, to remove the remaining humidity, and to arrest any further fermentation. This consistent ferment may be used instead of beer yeast.

It is difficult to prepare an artificial yeast without barm. The best process for this purpose is the following. Take five parts of honey, one part of powdered tartar, and sixteen parts of wheat or barley malt, stir the whole in water of the temperature of 122° F., and place in a fermenting heat; when the yeast will, as usual, be eliminated.

The change which gluten or vegetable albumen undergoes in the different kinds of meal, when it becomes a ferment, consists apparently in an oxidation, since analysis shows that this ferment contains more oxygen than gluten does.

It has been already stated that yeast in its liquid condition readily putrefies, and becomes altogether useless for the process of fermentation. In order to preserve it for some time, it must be dried to such a degree as to resist spontaneous decomposition without losing its fermentative faculty; but completely dried yeast loses that property, and does not recover it by being again moistened. Beer barm may be dried after being washed several times with cold water, till the last quantity comes off clear; but the insoluble portion must be allowed to settle fully before the water is poured away from it. The residuum being freed as much as possible from water, by drainage and pressure between flannel cloths, is to be dried in the shade by a current of warm air as quickly as possible, with the aid of frequent turning over. It must be afterwards kept in dry earthen vessels. Yeast may also be preserved a short time in activity by being kneaded with as much barley or wheat flour as it can take up without losing the doughy consistence. Dried yeast has, however, always an impaired activity. The easiest and most certain method of preserving yeast in its primitive power, is by mixing it, after pressure in flannel, with as much pulverized sugar as will render it dry, and putting up the mixture in air-tight vessels. The fermentative power of yeast is destroyed by the following means: 1. as already stated, by making it completely dry either by the evaporation of the water, or its abstraction by alcohol; 2. by boiling, which if continued for ten minutes renders yeast quite inoperative; 3. by the action of such substances as dissolve out its essential constituents; by alkalis, for instance, since the particles of yeast seem to be operative only in their insoluble granular state; 4. by such substances as form combinations with it, and thereby either alter its nature, or at least increase the cohesion of its constituent parts, so that they can no longer operate upon sweet liquors by the decomposing affinity of its ultimate particles. Such bodies are the acids, especially the mineral ones, tannin and most salts, particularly the metallic, which unite with the yeast into new compounds. The volatile oils which contain sulphur exercise the same paralyzing influence upon yeast.

The circumstances which promote, and are necessary to, the vinous fermentation are, conformably to the above views, the following:--1. The presence of the proper quantity of active yeast, and its proper distribution through the worts. If in the course of a slack fermentation the yeast subsides to the bottom, the intestine motions cease entirely, but they may be excited anew by stirring up the ingredients, or rousing the tun, as the brewers say. 2. A certain degree of warmth, which should never be less than 51° F., nor more than 86°; the temperature of from 68° to 77° being the most propitious for the commencement and progress of fermentation. When other circumstances are the same, the rapidity of the fermentation is proportional to the temperature within certain limits, so that by lowering it, the action may be moderated at pleasure. 3. The fermentation proceeds the better and more equably the greater the mass of fermenting liquor, probably on account of the uniformly high temperature, as well as the uniform distribution of the active particles of the yeast by the greater energy of the intestine movements. 4. The saccharine solution must be sufficiently diluted with water; when too much concentrated it will not ferment. Hence very sweet musts furnish wines containing much undecomposed sugar. For a complete fermentative action, one part of sugar should be dissolved in ten parts of water.

Fermentation maybe tempered or stopped: 1. by those means which render the yeast inoperative, particularly by the oils that contain sulphur, as oil of mustard; as also by the sulphurous and sulphuric acids. The operation of the sulphurous acid in obstructing the fermentation of must consists partly, no doubt, in its absorbing oxygen, whereby the elimination of the yeasty particles is prevented. The sulphurous acid, moreover, acts more powerfully upon fermenting liquors that contain tartar, as grape juice, than sulphuric acid. This acid decomposes the tartaric salts, and, combining with their bases, sets the vegetable acid free, which does not interfere with the fermentation; but the sulphurous acid operates directly upon the yeast: 2. by the separation of the yeast, either with the filter or by subsidence: 3. by lowering the temperature to 45° F. If the fermenting mass become clear at this temperature, and be drawn off from the subsided yeast, it will not ferment again, though it should be heated to the proper pitch.

The products of vinous fermentation are carbonic acid gas, and alcohol; of which the former escapes during the process, except in the case of the sparkling wines, like champaign, that are partially fermented in close vessels. The alcohol remains in the fermented liquor. 100 parts of sugar afford by complete decomposition nearly 50 parts of alcohol. According to Thenard, 100 parts of sugar are converted into 46·8 parts of carbonic acid, and 49·38 of alcohol; besides 3·82 parts of carbon otherwise employed, which the sugar contained, above what is present in the former two products. This chemist found in the fermented liquor 4 per cent. of an extractive matter, soluble in water, and having an acidulous reaction, to whose formation, probably, that excess of carbon may be necessary. In what way the action of the yeasty particles upon the saccharine substance is carried on in the vinous fermentation, or what may be the interior working of this process, is not accurately understood. The quantitative relation of the carbonic acid and alcohol to the sugar is pretty well made out; but the determination of the ultimate principles of the ferment itself, before and after the vinous change, and of the residuum dissolved in the fermented liquor, has not been well ascertained. It is probable that the yeast undergoes in the process a similar decomposition to that of the putrefactive, and that its elementary constituents enter into new combinations, and abstract so much carbon and hydrogen from the sugar, that the remainder, amounting to 96 per cent. of the whole, may constitute one atom of alcohol and one of carbonic acid.

3. _The slimy or glutinous fermentation._--This process takes place in weak solutions of sugar, at ordinary fermenting temperatures, where, from defect of good yeast, the vinous fermentation cannot proceed. In such circumstances from one part of sugar, one third part of gum is formed. According to Desfosses however, 100 parts of sugar afford 109·48 of gum or slime. This is formed when one part of sugar is dissolved in twenty parts of water, which had been previously boiled with washed barm or gluten, and then filtered. The process proceeds slowly and quietly, equally well in close vessels, as with contact of air, and continues at ordinary temperatures about 12 days; but it goes on more rapidly and completely at the heat of from 77° to 86° F. A small quantity of hydrogen and carbonic acid gas is disengaged, in the proportion of two to one by volume. The fermented liquor becomes turbid, and assumes a tough thready appearance, like a decoction of linseed. A small addition of sulphuric or sulphurous acid, of muriatic acid and alum, or of tannin, impedes this species of fermentation; because these substances combine, as in the vinous fermentation, with the ferment into an insoluble precipitate, unsusceptible of further change. In many wines, especially when bottled, this slimy fermentation occurs, and occasions their ropiness, which may be best remedied or prevented by the addition of as much tannin as will precipitate the dissolved mucous matter. This species of fermentation attacks very rapidly the rinsing waters of the sugar refiner, which always contain some fermentative gluten. A little alum is the best preventative in this case, because it precipitates the dissolved ferment.

4. _The acetous or sour fermentation._--In this process, alcohol, more or less dilute, is resolved into water and vinegar, in consequence of the operation of the ferment; oxidizement of the alcohol being effected by the oxygen of the atmospherical air. The requisites of this process have been already detailed under the article ACETIC ACID. They are the presence of atmospherical air; alcohol diluted to a certain degree with water ferment or yeast, and a temperature above 66° F. The most active ferments are such substances as have already passed into the acetous state; hence vinegar, especially when it contains some yeasty particles, or is combined with porous and spongy bodies, so as to multiply its points of contact with the vinous liquor, is particularly powerful. Common yeast may also be employed for vinegar ferments, if it be imbued with a little vinegar, with leaven, crusts of bread soaked in vinegar, the stalks and husks of grapes, sawdust and shavings of beech or oak impregnated with vinegar, or the slimy sediment of vinegar casks called _mother_; all of which operate as ferments chiefly in consequence of the vinegar which they contain. The inside shavings of the staves of vinegar tuns act on the same principle.

The acetous fermentation may, moreover, go on along with the vinous in the same liquor, when this contains sugar as well as alcohol. Whilst the acidification of the alcohol is effected by the absorption of oxygen from the atmosphere, the sugar becomes alcohol with disengagement of carbonic acid, and then passes into vinegar. Since most liquors intended for making vinegar, such as wine, juices of fruits, ales, &c., contain still a little sugar, they disengage always a little carbonic acid. Besides spirits, some other substances, such as gum, the mucilage of plants, and starch paste, directly ferment into vinegar. Sugar also seems to be convertible into vinegar without any vinous change. The albuminous matter of potato juice, precipitated by vinegar, serves as a proper ferment for that purpose, when added in its moist state to weak syrup. 5. See PUTREFACTION.

Mr. William Black, in his treatise on Brewing, has, with much ingenuity and apparent truth, endeavoured to show that the process of fermentation is strongly influenced by electricity, not only that of the atmosphere, as has been long known from the circumstance of beer and wine becoming speedily sour after thunderstorms, but the voltaic, produced by electric combinations of metals in the fermenting tuns. He therefore recommends these tuns to be made with as little metallic work as possible, and to be insulated from the floor of the brewhouse. For the propriety of this advice he adduces some striking examples. Wort which had become stationary in its fermentation, on being pumped out of square gyles imbedded in the floor, into casks placed upon wooden stillions, began immediately to work very well, and gained about 6 degrees of attenuation while throwing off its yeast. From the stagnation of the process in the gyles, he had in the morning predicted an approaching thunderstorm, which accordingly supervened in the course of the evening. In further support of his views he instances the fact, that, in dairies where the milk is put into porcelain vessels, and placed upon wooden shelves, it is seldom injured by lightning; but when contained in wooden or leaden vessels, and placed upon the ground, it almost invariably turns sour in thundery weather. His general conclusion is “that the preservation or destruction of beer depends upon electricity; and the most certain mode of preservation is to insulate as much as possible, both the squares and all other utensils or vessels connected with the brewing or storing of beer.”

Mr. Black further considers that unsoundness of worts is often the result of electricity excited between the mash tun and the copper.

Why is beer liable to get spoiled in thunder storms, though apparently well insulated in glass bottles?

I shall conclude this article with Mr. Black’s description of the phenomena of beer fermentation. In every regular process there are five distinct stages. In the first we see a substance like cream forming all round the edges of the gyle tun; which extends towards the centre until the whole is creamed over, constituting the first change. Next a fine curl appears like cauliflower, which also spreads over the square surface, and according to the strength and appearance of this curl, the quality of the fermentation may be predicated. This he calls the second stage. What is technically called the _stomach_ or vinous vapour now begins to be smelt, and continues to gain strength till the process is concluded. From the vinous energy of this odour, and the progressive attenuation of the wort, the vigour of the fermentation may be inferred. The experienced brewer is much guided in his operations by the peculiarity of this effluvium. The third change is when the cauliflower or curling top rises to a fine rocky or light yeasty head; and when this falls down, the fourth stage has arrived. Finally the head should rise to what is called close yeasty, having the appearance of yeast all over. About this period the gas becomes so powerful as to puff up occasionally in little bells or bladders about the size of a walnut, which immediately break. The bells should appear bright and clear. If they be opaque or whey coloured, there is some unsoundness in the wort. The great point is to add just so much yeast as to carry the fermentation completely through these five changes at the regular periods.

FERROCYANATE, or, more correctly, FERROCYANIDE. (_Ferrocyanure_, Fr.; _Eisencyanid_, Germ.) Several compounds of cyanogen and metals possess the property of uniting together into double cyanides; of which there are none so remarkable in this respect, as the protocyanide of iron. This appears to be capable of combining with several simple cyanides, such as that of potassium, sodium, barium, strontium, calcium, and ammonium. The only one of these double cyanides of any importance in manufactures is the first, which is described under its commercial name, PRUSSIATE OF POTASH.

FERROPRUSSIATES; another name for Ferrocyanides.

FIBRE, VEGETABLE, called also LIGNINE; (_Ligneux_, Fr.; _Pflanzen-faserstoff_, Germ.) is the most abundant and general ingredient of plants, existing in all their parts, the root, the leaves, the stem, the flowers, and the fruit; amounting in the compact wood to 97 or 98 per cent. It is obtained in a pure state by treating saw-dust successively with hot alcohol, water, dilute muriatic acid, and weak potash lye, which dissolve, first, the resinous; second, the extractive, and saline matters; third, the carbonate and phosphate of lime; and, lastly, any residuary substances. Ligneous fibres, such as saw-dust, powdered barks, straw, hemp, flax, linen, and cotton cloth, are convertible by the action of strong sulphuric acid into a gummy substance analogous to _dextrine_, and a sugar resembling that of the grape.

If we put into a glass mortar 24 parts, by weight, of dry old cordage, chopped small, and sprinkle over it 34 parts of sulphuric acid, by degrees, so as to avoid heating the mixture, while we constantly stir it; and if, in a quarter of an hour, we triturate the mass with a glass pestle, the fibres will disappear without the disengagement of gas. A tenacious mucilage will be produced, almost entirely soluble in water. The gum being thus formed, may be separated from the acid by dilution with water, and addition of the requisite quantity of chalk; then straining the saturated liquid through linen cloth, concentrating it by evaporation, throwing down any remaining lime by oxalic acid, filtering anew, and mixing the mucilage with alcohol in great excess, which will take up the free acid, and throw down the gum. From 24 parts of hemp fibres thus treated, fully 24 parts of a gummy mass may be obtained, containing, however, probably some water.

When, instead of saturating the diluted acid paste with chalk, we boil it for 10 hours, the gummy matter disappears, and is replaced by sugar, which may be purified without any difficulty, by saturation with chalk, filtration, and evaporation to the consistence of syrup. In 24 hours crystallization begins, and, in 2 or 3 days, a concrete mass of grape sugar is formed; which needs merely to be pressed strongly between old linen cloths doubled, and then crystallized a second time. If this syrup be treated with bone black, a brilliant white sugar will be procured. 20 parts of linen rags yield 23 of good sugar. _Braconnot_. Guerin got 87-1/2 of dry sugar from 100 parts of rags, treated with 250 of sulphuric acid. See WOOD.

FIBRINE, (Eng. and Fr.; _Thierischer Faserstoff_, Germ.) constitutes the principal part of animal muscle; it exists in the chyle, the blood, and may be regarded as the most abundant constituent of animal bodies. It may be obtained in a pure state by agitating or beating new drawn blood with a bundle of twigs, when it will attach itself to them in long reddish filaments, which may be deprived of colour by working them with the hands under a streamlet of cold water, and afterwards freed from any adhering grease by digestion in alcohol or ether.

Fibrine, thus obtained, is solid, white, flexible, slightly elastic, insipid, inodorous, denser than water, but containing 4 fifths of its weight of it, and without action on litmus. When dried, it becomes semi-transparent, yellowish, stiff, and brittle: water restores its softness and flexibility. 100 parts of fibrine consist of 53·36 carbon, 19·68 oxygen, 7·02 hydrogen, and 19·31 azote. As the basis of flesh, it is a very nutritious substance, and is essential to the sustenance of carnivorous animals.

FILE (_Lime_, Fr.; _Feile_, Germ.), is a well known steel instrument, having teeth upon the surface for cutting and abrading metal, ivory, wood, &c.

When the teeth of these instruments are formed by a straight sharp-edged chisel, extending across the surface, they are properly called files; but when by a sharp-pointed tool, in the form of a triangular pyramid, they are termed rasps. The former are used for all the metals, as well as ivory, bone, horn, and wood; the latter for wood and horn.

Files are divided into two varieties, from the form of their teeth. When the teeth are a series of sharp edges, raised by the flat chisel, appearing like parallel furrows, either at right angles to the length of the file, or in an oblique direction, they are termed _single cut_. But when these teeth are crossed by a second series of similar teeth, they are said to be _double cut_. The first are fitted for brass and copper, and are found to answer better when the teeth run in an oblique direction. The latter are suited for the harder metals, such as cast and wrought iron and steel. Such teeth present sharp angles to the substance, which penetrate it, while single cut files would slip over the surface of these metals. The double cut file is less fit for filing brass and copper, because its teeth would be very liable to become clogged with the filings.

Files are also called by different names according to their various degrees of fineness. Those of extreme roughness are called rough; the next to this is the bastard cut; the third is the second cut; the fourth, the smooth; and the finest of all, the dead smooth. The very heavy square files used for heavy smith-work, are sometimes a little coarser than the rough; they are known by the name of rubbers.

Files are also distinguished from their shape, as flat, half-round, three-square, four-square, and round. The first are sometimes of uniform breadth and thickness throughout, and sometimes tapering. The cross section is a parallelogram. The half-round is generally tapering, one side being flat, and the other rounded. The cross section is a segment of a circle, varying a little for different purposes, but seldom equal to a semi-circle. The three-square generally consists of three equal sides, being equilateral prisms, mostly tapering; those which are not tapering are used for sharpening the teeth of saws. The four-square has four equal sides, the section being a square. These files are generally thickest in the middle, as is the case with the smith’s rubber. In the round file, the section is a circle, and the file generally conical.

The heavier and coarser kinds of files are made from the inferior marks of blistered steel. Those made from the Russian iron, known by the name of old sable, called from its mark CCND, are excellent. The steel made from the best Swedish iron, called hoop L or Dannemora, makes the finest Lancashire files, for watch and clock makers; a manufacture for which the house of Stubbs in Warrington is celebrated.

The steel intended for files is more highly converted than for other purposes, to give them proper hardness. It should however be recollected, that if the hardness be not accompanied with a certain degree of tenacity, the teeth of the file break, and do but little service.

Small files are mostly made of cast steel, which would be the best for all others, if it were not for its higher price. It is much harder than the blistered steel, and from having been in the fluid state, is entirely free from those seams and loose parts so common to blistered steel, which is no sounder than as it comes from the iron forge before conversion.